Geology topics

S.F. Murphy

Publications and source records attributed to S.F. Murphy.

3 recordsLinked to original sources

USGS2005

Chemical loading into surface water along a hydrological, biogeochemical, and land use gradient: A holistic watershed approach

Identifying the sources and impacts of organic and inorganic contaminants at the watershed scale is a complex challenge because of the multitude of processes occurring in time and space. Investigation of geochemical transformations requires a systematic evaluation of hydrologic, landscape, and anthropogenic factors. The 1160 km 2 Boulder Creek Watershed in the Colorado Front Range encompasses a gradient of geology, ecotypes, climate, and urbanization. Streamflow originates primarily as snowmelt and shows substantial annual variation. Water samples were collected along a 70-km transect during spring-runoff and base-flow conditions, and analyzed for major elements, trace elements, bulk organics, organic wastewater contaminants (OWCs), and pesticides. Major-element and trace-element concentrations were low in the headwaters, increased through the urban corridor, and had a step increase downstream from the first major wastewater treatment plant (WWTP). Boron, gadolinium, and lithium were useful inorganic tracers of anthropogenic inputs. Effluent from the WWTP accounted for as much as 75% of the flow in Boulder Creek and was the largest chemical input. Under both hydrological conditions, OWCs and pesticides were detected in Boulder Creek downstream from the WWTP outfall as well as in the headwater region, and loads of anthropogenic-derived contaminants increased as basin population density increased. This report documents a suite of potential endocrine-disrupting chemicals in a reach of stream with native fish populations showing indication of endocrine disruption.

Environmental Science & Technology↗

USGS1998

Chemical weathering in a tropical watershed, Luquillo Mountains, Puerto Rico: I. Long-term versus short-term weathering fluxes

The pristine Rio Icacos watershed in the Luquillo Mountains in eastern Puerto Rico has the fastest documented weathering rate of silicate rocks on the Earth's surface. A regolith propagation rate of 58 m Ma-1 calculated from iso-volumetric saprolite formation from quartz diorite, is comparable to the estimated denudation rate (25-50 Ma-1) but is an order of magnitude faster than the global average weathering rate (6 Ma-1). Weathering occurs in two distinct environments; plagioclase and hornblende react at the saprock interface and biotite and quartz weather in the overlying thick saprolitic regolith. These environments produce distinctly different water chemistries, with K, Mg, and Si increasing linearly with depth in saprolite porewaters and with stream waters dominated by Ca, Na, and Si. Such differences are atypical of less intense weathering in temperate watersheds. Porewater chemistry in the shallow regolith is controlled by closed-system recycling of inorganic nutrients such as K. Long-term elemental fluxes through the regolith (e.g., Si = 1.7 ?? 10-8 moles m-2 s-1) are calculated from mass losses based on changes in porosity and chemistry between the regolith and bedrock and from the age of the regolith surface (200 Ma). Mass losses attributed to solute fluxes are determined using a step-wise infiltration model which calculates mineral inputs to the shallow and deep saprolite porewaters and to stream water. Pressure heads decrease with depth in the shallow regolith (-2.03 m H2O m-1), indicating that both increasing capillary tension and graviometric potential control porewater infiltration. Interpolation of experimental hydraulic conductivities produces an infiltration rate of 1 m yr-1 at average field moisture saturation which is comparable with LiBr tracer tests and with base discharge from the watershed. Short term weathering fluxes calculated from solute chemistries and infiltration rates (e.g., Si = 1.4 ?? 10-8 moles m-2 s-1) are compared to watershed flux rates (e.g., Si = 2.7 ?? 10-8 moles m-2 s-1). Consistency between three independently determined sets of weathering fluxes imply that possible changes in precipitation, temperature, and vegetation over the last several hundred thousand years have not significantly impacted weathering rates in the Luquillo Mountains of Puerto Rico. This has important ramifications for tropical environments and global climate change. Copyright ?? 1998 Elsevier Science Ltd.

Geochimica et Cosmochimica Acta↗

USGS1998

Chemical weathering in a tropical watershed, Luquillo Mountains, Puerto Rico: II. Rate and mechanism of biotite weathering

Samples of soil, saprolite, bedrock, and porewater from a lower montane wet forest, the Luquillo Experimental Forest (LEF) in Puerto Rico, were studied to investigate the rates and mechanisms of biotite weathering. The soil profile, at the top of a ridge in the Rio Icacos watershed, consists of a 50–100-cm thick layer of unstructured soil above a 600–800 cm thick saprolite developed on quartz diorite. The only minerals present in significant concentration within the soil and saprolite are biotite, quartz, kaolinite, and iron oxides. Biotite is the only primary silicate releasing significant K and Mg to porewaters. Although biotite in samples of the quartz diorite bedrock is extensively chloritized, chlorite is almost entirely absent in the saprolite phyllosilicates. Phyllosilicate grains are present as 200–1000 μm wide books below about 50 cm depth. X-ray diffraction (XRD) and electron microprobe analyses indicate that the phyllosilicate grains contain a core of biotite surrounded by variable amounts of kaolinite. Lattice fringe images under transmission electron microscope (TEM) show single layers of biotite altering to two layers of kaolinite, suggesting dissolution of biotite and precipitation of kaolinite at discrete boundaries. Some single 14-Å layers are also observed in the biotite under TEM. The degree of kaolinitization of individual phyllosilicate grains as observed by TEM decreases with depth in the saprolite. This TEM work is the first such microstructural evidence of epitaxial growth of kaolinite onto biotite during alteration in low-temperature environments. The rate of release of Mg in the profile, calculated as a flux through the soil normalized per watershed land area, is approximately 500 mol hectare −1 yr −1 (1.6 × 10 −9 mol Mg m soil −2 s −1 ). This rate is similar to the flux estimated from Mg discharge out the Rio Icacos (1000 mol hectare −1 yr −1 , or 3.5 × 10 −9 mol Mg m soil −2 s −1 ), indicating that scaling up from the soil to the watershed is possible for Mg release. The rate of Mg release from biotite, normalized to Brunauer-Emmett-Teller (BET) surface area, is calculated using a mass balance equation which includes the density and volume of phyllosilicate grains, porewater chemistry and flux, and soil porosity. The mean rates of biotite weathering calculated from K and Mg release rates are approximately 6 and 11 × 10 −16 mol biotite m biotite −2 s −1 respectively, significantly slower than laboratory rates (10 −12 to 10 −11 mol biotite m biotite −2 s −1 ). The discrepancy in scaling down from the soil to the laboratory is probably explained by (1) differences in weathering mechanism between the two environments, (2) higher solute concentrations in soil porewaters, (3) loss of reactive surface area of biotite in the saprolite due to kaolinite and iron oxide coatings, and/or (4) unaccounted-for heterogeneities in flow path through the soil.

El Yunque, Luquillo Experimental Forest, Luquillo ↗