Geology topics

S.B. Shirey

Publications and source records attributed to S.B. Shirey.

7 recordsLinked to original sources

USGS2012

Midcontinent rift volcanism in the Lake Superior region: Sr, Nd, and Pb isotopic evidence for a mantle plume origin

Between 1091 and 1098 Ma, most of a 15- to 20-km thickness of dominantly tholeiitic basalt erupted in the Midcontinent Rift System of the Lake Superior region, North America. The Portage Lake Volcanics in Michigan, which are the youngest MRS flood basalts, fall into distinctly high- and low-TiO 2 types having different liquid lines of descent. Incompatible trace elements in both types of tholeiites are enriched compared to depleted or primitive mantle (La/Yb = 4.3–5.3; Th/Ta = 2.12–2.16; Zr/Y = 4.3–4.4), and both basalt types are isotopically indistinguishable. Sr, Nd, and Pb isotopic compositions of the Portage Lake tholeiites have 87 Sr/ 86 Sr i ≈ 0.7038, ε Nd (1095 Ma) ≈ 0±2, and μ 1 ≈ 8.2. Model ages with respect to a depleted mantle source ( T DM ) average about 1950–2100 Ma. Portage Lake rhyolites fall into two groups. Type I rhyolites have Nd and Pb isotopic characteristics (ε Nd (1095 Ma) ≈ 0 to −4.7; μ 1 ≈ 8.2–7.8) consistent with contamination of tholeiitic rocks by 5–10% Archean crust. The one type II rhyolite analyzed has Nd and Pb isotopic compositions (ε Nd (1095 Ma) ≈ −13 to −16; μ 1 ≈ 7.6–7.7) which are consistent with partial melting of Archean crust. Early Proterozoic crust was not a major contaminant of MRS rocks in the Lake Superior region. Most reported Nd and Pb isotopic compositions of MRS tholeiites from the main stage of volcanism in the Lake Superior region and of the Duluth Complex are comparable to the Nd and Pb isotopic data for Portage Lake tholeiites. The isotopic enrichment of the MRS source compared to depleted mantle is striking and must have occurred at least 700 m.y. before 1100 Ma. There are two likely sources for such enriched MRS tholeiitic magmatism: subcontinental lithospheric mantle enriched during the early Proterozoic or enriched mantle derived from an upwelling plume. Subcontinental lithospheric mantle alone as a source cannot be ruled out strictly on isotopic grounds, but melting of enriched lithosphere potentially ranging in age from 3.6 to 1.8 Ga would have been less likely to generate either the homogeneity or the volume of MRS tholeiites. Decompression melting of an upwelling enriched mantle plume in a region of lithosphere thinned by extension could have successfully generated the enormous volume (850×10 3 km 3 ) of relatively homogeneous magma in a restricted time interval.

Journal of Geophysical Research Solid Earth↗

USGS2008

Isotopic and trace element constraints on the petrogenesis of lavas from the Mount Adams volcanic field, Washington

Strontium, Nd, Pb, Hf, Os, and O isotope compositions for 30 Quaternary lava flows from the Mount Adams stratovolcano and its basaltic periphery in the Cascade arc, southern Washington, USA indicate a major component from intraplate mantle sources, a relatively small subduction component, and interaction with young mafic crust at depth. Major- and trace-element patterns for Mount Adams lavas are distinct from the rear-arc Simcoe volcanic field and other nearby volcanic centers in the Cascade arc such as Mount St. Helens. Radiogenic isotope (Sr, Nd, Pb, and Hf) compositions do not correlate with geochemical indicators of slab-fluids such as (Sr/P)n and Ba/Nb. Mass-balance modeling calculations, coupled with trace-element and isotopic data, indicate that although the mantle source for the calc-alkaline Adams basalts has been modified with a fluid derived from subducted sediment, the extent of modification is significantly less than what is documented in the southern Cascades. The isotopic and trace-element compositions of most Mount Adams lavas require the presence of enriched and depleted mantle sources, and based on volume-weighted chemical and isotopic compositions for Mount Adams lavas through time, an intraplate mantle source contributed the major magmatic mass of the system. Generation of basaltic andesites to dacites at Mount Adams occurred by assimilation and fractional crystallization in the lower crust, but wholesale crustal melting did not occur. Most lavas have Tb/Yb ratios that are significantly higher than those of MORB, which is consistent with partial melting of the mantle in the presence of residual garnet. 18O values for olivine phenocrysts in Mount Adams lavas are within the range of typical upper mantle peridotites, precluding involvement of upper crustal sedimentary material or accreted terrane during magma ascent. The restricted Nd and Hf isotope compositions of Mount Adams lavas indicate that these isotope systems are insensitive to crustal interaction in this juvenile arc, in stark contrast to Os isotopes, which are highly sensitive to interaction with young, mafic material in the lower crust. Springer-Verlag 2008.

Washington↗

USGS2003

New osmium isotope evidence for intracrustal recycling of crustal domains with discrete ages

New 187Os/188Os ratios of Quaternary Mount Adams volcanic rocks from the Cascade arc in southern Washington vary by >300% (187Os/188Os = 0.165-0.564) and fall into high (>0.319) and low (0.166 to 0.281) groups of 187Os/188Os ratios that are substantially more radiogenic than mantle values. These Os isotope compositions and groupings are interpreted to reflect recycling of discrete intracrustal domains with high 187Os/188Os ratios but differing ages, thus recording the process of crustal hybridization and homogenization. Os isotope compositions provide new constraints on amounts of intracrustal recycling in young subduction-zone environments that reflect the magmatic history of the arc. Sr, Nd, Hf, and Pb isotope variations in this young, mafic are complex are too small to allow such constraints.

Geology↗

USGS1997

Rift-wide correlation of 1.1 Ga Midcontinent rift system basalts: Implications for multiple mantle sources during rift development

Magmatism that accompanied the 1.1 Ga Midcontinent rift system (MRS) is attributed to the upwelling and decompression melting of a mantle plume beneath North America. Five distinctive flood-basalt compositions are recognized in the rift-related basalt succession along the south shore of western Lake Superior, based on stratigraphically correlated major element, trace element, and Nd isotopic analyses. These distinctive compositions can be correlated with equivalent basalt types in comparable stratigraphic positions in other MRS localities around western Lake Superior. Four of these compositions are also recognized at Mamainse Point more than 200 km away in eastern Lake Superior. These regionally correlative basalt compositions provide the basis for determining the sequential contribution of various mantle sources to flood-basalt magmatism during rift development, extending a model originally developed for eastern Lake Superior. In this refined model, the earliest basalts were derived from small degrees of partial melting at great depth of an enriched, ocean-island-type plume mantle source (ε Nd(1100) value of about 0), followed by magmas representing melts from this plume source and interaction with another mantle source, most likely continental lithospheric mantle (ε Nd(1100 ) < 0). The relative contribution of this second mantle source diminished with time as larger degree partial melts of the plume became the dominant source for the voluminous younger basalts (ε Nd(1100) value of about 0). Towards the end of magmatism, mixtures of melts from the plume and a depleted asthenospheric mantle source became dominant (ε Nd(1100) = 0 to +3).

Michigan, Wisconsin↗

USGS1991

Re - Os isotopic constraints on the origin of volcanic rocks, Gorgona Island, Colombia: Os isotopic evidence for ancient heterogeneities in the mantle

The Re - Os isotopic systematics of komatiites and spatially associated basalts from Gorgona Island, Colombia, indicate that they were produced at 155??43 Ma. Subsequent episodes of volcanism produced basalts at 88.1??3.8 Ma and picritic and basaltic lavas at ca. 58 Ma. The age for the ultramafic rocks is important because it coincides with the late-Jurassic, early-Cretaceous disassembly of Pangea, when the North- and South-American plates began to pull apart. Deep-seated mantle upwelling possibly precipitated the break-up of these continental plates and caused a tear in the subducting slab west of Gorgona, providing a rare, late-Phanerozoic conduit for the komatiitic melts. Mantle sources for the komatiites were heterogeneous with respect to Os and Pb isotopic compositions, but had homogeneous Nd isotopic compositions (??Nd+9??1). Initial 187Os/186Os normalized to carbonaceous chondrites at 155 Ma (??Os) ranged from 0 to +22, and model-initial ?? values ranged from 8.17 to 8.39. The excess radiogenic Os, compared with an assumed bulk-mantle evolution similar to carbonaceous chondrites, was likely produced in portions of the mantle with long-term elevated Re concentrations. The Os, Pb and Nd isotopic compositions, together with major-element constraints, suggest that the sources of the komatiites were enriched more than 1 Ga ago by low (<20%) and variable amounts of a basalt or komatiite component. This component was added as either subducted oceanic crust or melt derived from greater depths in the mantle. These results suggest that the Re - Os isotope system may be a highly sensitive indicator of the presence of ancient subducted oceanic crust in mantle-source regions. ?? 1991 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS1989

Re-Os, Rb-Sr, and O isotopic systematics of the Archean Kolar schist belt, Karnataka, India

The Re-Os, Rb-Sr, and O isotopic compositions of mafic and ultramafic amphibolites, gold ores, and granitic gneisses of the circa 2700 Ma Kolar schist belt reveal at least two episodes of post-magmatic alteration that affected these systems. The Re-Os isotopic systematics of many of the rocks of the belt indicate that Os was introduced to the area via fluids that carried very radiogenic Os ( 187 Os 186 Os 2.4Ga > 39 "> 187 Os 186 Os 2.4Ga > 39 ). The source of the radiogenic Os was likely ancient crust. On an outcrop scale, this alteration is also characterized by relatively minor additions of excess 87 Sr and δ 18 O values higher than magmatic. The Rb-Sr systematics of most of these rocks are consistent with closed-system behavior since a period between 2700 and 2400 Ma ago, indicating that the alteration event likely occurred no later than the early Proterozoic. In contrast to this late Archean or early Proterozoic alteration, samples of several komatiitic amphibolites have very 187 Os-depleted compositions, indicating that open-system behavior also occurred at a much later time. This alteration may have been caused by surficial weathering or the interaction of the rocks with fluids bearing unradiogenic Os. Results suggest that the Re-Os system may have only limited utility for geochronologic applications in regions for which post-crystallization noble metal mineralization is evident (e.g., gold ores). In such regions, however, the system may have an important application in assessing the timing and the ultimate sources of noble metal additions.

Geochimica et Cosmochimica Acta↗

USGS1989

Rhenium-osmium and samarium-neodymium isotopic systematics of the Stillwater Complex

Isotopic data for the Stillwater Complex, Montana, which formed about 2700 Ma (million years ago), were obtained to evaluate the role of magma mixing in the formation of strategic platinum-group element (PGE) ore deposits. Neodymium and osmium isotopic data indicate that the intrusion formed from at least two geochemically distinct magmas. Ultramafic affinity (U-type) magmas had initial ε Nd of -0.8 to -3.2 and a chondritic initial 187 Os/ 186 Os ratio of ∼0.88, whereas anorthositic affinity (A-type) magmas had ε Nd of -0.7 to +1.7 and an initial 187 Os/ 186 Os ratio of ∼1.13. These data suggest that U-type magmas were derived from a lithospheric mantle source containing recycled crustal materials whereas A-type magmas originated either by crustal contamination of basaltic magmas or by partial melting of basalt in the lower crust. The Nd and Os isotopic data also suggest that Os, and probably the other PGEs in ore horizons such as the J-M Reef, was derived from A-type magmas. The Nd and Os isotopic heterogeneity observed in rocks below the J-M Reef also suggests that A-type magmas were injected into the Stillwater U-type magma chamber at several stages during the development of the Ultramafic series.

Montana↗