Summary and highlights of the 10th International Symposium on Antarctic Earth Sciences
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Geology topics
S.B. Mukasa
Publications and source records attributed to S.B. Mukasa.
Isotopic and trace element compositions of upper mantle and lower crustal xenoliths, Cima volcanic field, California: Implications for evolution of the subcontinental lithospheric mantle
Ultramafic and mafic xenoliths from the Cima volcanic field, southern California, provide evidence of episodic modification of the upper mantle and underplating of the crust beneath a portion of the southern Basin and Range province. The upper mantle xenoliths include spinel peridotite and anhydrous and hydrous pyroxenite, some cut by igneous-textured pyroxenite-gabbro veins and dikes and some by veins of amphibole ?? plagioclase. Igneous-textured pyroxenites and gabbros like the dike rocks also occur abundantly as isolated xenoliths inferred to represent underplated crust. Mineral and whole rock trace element compositions among and within the different groups of xenoliths are highly variable, reflecting multiple processes that include magma-mantle wall rock reactions, episodic intrusion and it filtration of basaltic melts of varied sources into the mantle wall rock, and fractionation. Nd, Sr, and Pb isotopic compositions mostly of clinopyroxene and plagioclase mineral separates show distinct differences between mantle xenoliths (??Nd = -5.7 to +3.4; 87Sr/86Sr = 0.7051 - 0.7073; 206Pb/204Pb = 19.045 - 19.195) and the igneous-textured xenoliths (??Nd = +7.7 to +11.7; 87Sr/86Sr = 0.7027 - 0.7036 with one carbonate-affected outlier at 0.7054; and 206Pb/204Pb = 18.751 - 19.068), so that they cannot be related. The igneous-textured pyroxenites and gabbros are similar in their isotopic compositions to the host basaltic rocks, which have ??Nd of+5.1 to +9.3; 87Sr/86Sr of 0.7028 - 0.7050, and 206Pb/204Pb of 18.685 - 21.050. The igneous-textured pyroxenites and gabbros are therefore inferred to be related to the host rocks as earlier cogenetic intrusions in the mantle and in the lower crust. Two samples of peridotite, one modally metasomatized by amphibole and the other by plagioclase, have isotopic compositions intermediate between the igneous-textured xenoliths and the mantle rock, suggesting mixing, but also derivation of the metasomatizing magmas from two separate and distinct sources. Sm-Nd two-mineral "isochrons" yield apparent ages for petrographically identical rocks believed to be coeval ranging from -0 to 113 ?? 26 Ma, indicating the unreliability of dating these rocks with this method. Amphibole and plagioclase megacrysts are isotopically like the host basalts and probably originate by mechanical breakup of veins comagmatic with the host basaltic rocks. Unlike other Basin and Range localities, Cima Cr-diopside group isotopic compositions do not overlap with those of the host basalts. Copyright 1997 by the American Geophysical Union.
Journal of Geophysical Research B: Solid Earth↗
The Nd-, Sr- and Pb-isotopic character of lavas from Taal, Laguna de Bay and Arayat volcanoes, southwestern Luzon, Philippines: Implications for arc magma petrogenesis
Following the amalgamation of a collage of pre-Neogene terranes largely by strike-slip and convergence mechanisms to form the Philippine islands, volcanic chains, related to oppositely dipping subduction zones, developed along the eastern and western margins of the archipelago. There is ample field evidence that this volcanic activity, predominantly calc-alkaline in chemical character, had commenced by the Oligocene. Volcanoes resulting from subduction along the Manila-Negros trench in the west (e.g. Taal, Laguna de Bay and Arayat) form a high-angle linear array, trending away from the MORE field on Pb-isotopic covariation diagrams; have the highest Sr- and lowest Nd-isotopic compositions, of the two chains (but nevertheless plotting above bulk earth on the 87 Sr/ 86 Sr versus 143 Nd/ 144 Nd covariation diagram); and exhibit Sm/Nd and Rb/Sr values that are lower and higher, respectively, than the estimated values for bulk earth. While the Sm/Nd and Rb/Sr characteristics are common to both chains, volcanoes associated with the Philippine-East Luzon trench have Pb-isotopic compositions that fall in the Indian Ocean MORB field and that require time-integrated evolution in a high Th/U environment. They also have higher Nd- and lower Sr-isotopic ratios. The source materials of Philippine volcanoes, therefore, have undergone varied recent enrichments in LILE, as indicated by the decoupling of isotopic and elemental ratios. These enrichments, particularly for the western volcanoes, cannot be entirely due to small degrees of partial melting in the mantle wedge, considering that they were accompanied by elevations in radiogenic Pb. Elevated Pb ratios are best explained by the introduction of subducted, continentally derived sediments. The sedimentary component in the western volcanoes is probably the South China Sea sediments derived largely from Eurasia. That this component is not available in the Philippine-East Luzon trench is reflected by the fact that the eastern volcanoes have higher Nd- and lower Sr-isotopic ratios as well as less radiogenic common Pb.
southwestern Luzon↗
Intrinsic Nd, Pb, and Sr isotopic heterogeneities exhibited by the Lherz Alpine Peridotite Massif, French Pyrenees
Optically clear, acid-leached Cr-diopside, Al-augite, pargasitic amphibole, and phlogopite from peridotite and ultramafic dikes of the Lherz massif (French Pyrenees) exhibit chemical and isotopic heterogeneities indicative of a complex history. The data cover a wide range on the 143 Nd/ 144 Nd vs. 87 Sr/ 86 Sr covariation diagram, encompassing much of the mantle array and a large area below the array. Pb-isotopic signatures cover a wide range on Pb-Pb correlation diagrams, with several samples falling in the mid-ocean ridge basalt (MORB) field, but with others defining trends towards the enriched mantle II (EM II) and high-mu (HIMU) endmembers of Zindler & Hart (1986). Peridotites display the largest range in isotopic compositions, which formed in response to variable degrees of partial melting and subsequent enrichment during the intrusion of the ultramafic dikes. The ultra-mafic dikes represent at least four generations. Dike isotopic compositions range from ‘depleted’ to ‘enriched’, relative to Bulk Earth, reflecting the average composition of their source regions and subsequent melt-wall rock interactions. No simple isochronous relationships are observed on the 143 Nd/ 144 Nd vs. 147 Sm/ 144 Nd diagram for any lithologic group, demonstrating that the rock assemblages were not created by simple mixing of two homogeneous endmembers. Some ultramafic dikes, which represent low-temperature melt fractions, are enriched in the heavy isotopes of Sr, Nd, and Pb; any magmas derived from partial melting of these dikes are likely to have enriched isotopic signatures, particularly when the degrees of partial melting are only a few per cent.
Pyrenees↗
Petrology, isotope characteristics, and K-Ar ages of the Maranhão, northern Brazil, Mesozoic basalt province
Northern Brazil contains remnants of Mesozoic flood basalts and hypabyssal rocks that were apparently emplaced during tectonism related to opening of the Atlantic Ocean. Analyses and new K-Ar ages reveal that this ∼700x250 km Maranhão province (5°–8°S) has low-Ti basalts (∼1.1 wt% TiO 2 ) in the western part that range about 160 to 190 Ma, and high-Ti basalts (3.4–4.4 wt% TiO 2 ) in the eastern part about 115–122 Ma. Low-Ti basalt compositions are less evolved and have a smaller range, Mg# 62-56, than the high-Ti basalts, Mg# 44–33. General characteristics of the least evolved members of low- and high-Ti groups include, respectively, Zr 100 and 250 ppm, Sr 225 and 475 ppm, Ba 200 and 500 ppm, Nb 10 and 26 ppm, Y 29 and 36 ppm, La/Yb (n) 4.2 and 8.8, where La (n) is 30 and 90. Overall compositions resemble the low- and high-Ti basaltic rocks of the Mesozoic Serra Geral (Paraná) province in southern Brazil. The Maranhão low-Ti basalts have more radiogenic Sr and Pb and higher δ 18 O than the high-Ti basalts. Respectively, low- vs high-Ti: ɛ Sr 26−54 vs 15−18; 206 Pb/ 204 Pb=18.25–.78 vs 18.22–.24; and δ 18 O 8.9–12.6 vs 6.5–8.6. Nd isotopes overlap: ɛ Nd −1.6 to −3.8 vs −2.1 to −3. Ages, compositions, and isotopes indicate that the low- and high-Ti groups had independent parentages from enriched subcontinental mantle. However, both groups can be modeled from one source composition if low-Ti basalt isotopes reflect crustal contamination, and if the parentages for each group were picritic liquids that represent either higher (for low-Ti) or lower (for high-Ti) percentages of melting of that single source. When comparing Pb isotopes of Maranhão and Serra Geral high-Ti basalts (uncontaminated) to evaluate the DUPAL anomaly, Maranhão has Pb Δ7/4=4.6–11, and Pb Δ8/4=72–87; Serra Geral has Pb Δ7/4=10–13, and Pb Δ8/4=95–125. The small difference is not enough to conform to DUPAL contours, and is inconsistent with large-scale isotopic heterogeneity of mantle beneath Brazil prior to rifting of South America from Africa. Maranhão low-Ti magmas probably relate to the opening of central North Atlantic, and high-Ti magmas to the opening of equatorial Atlantic. The proposed greater percentage of source melting for low-Ti basalts may reflect a Triassic-Jurassic hotspot, while lesser melting for high-Ti magmas may relate to Cretaceous decompressional (rifting) melting.
Contributions to Mineralogy and Petrology↗
40Ar/39Ar and K-Ar data bearing on the metamorphic and tectonic history of western New England
40 Ar/ 39 Ar ages of coexisting biotite and hornblende from Proterozoic Y gneisses of the Berkshire and Green Mountain massifs, as well as 40 Ar/ 39 Ar and K-Ar mineral and whole-rock ages from Paleozoic metamorphic rocks, suggest that the thermal peak for the dominant metamorphic recrystallization in western New England occurred 465 ± 5 m.y. ago (Taconian). Although textural data indicate a complex metamorphic-tectonic history for Paleozoic rocks, no evidence in rocks at least as high as kyanite grade dictates an Acadian age for the Barrovian metamorphism. Available 40 Ar/ 39 Ar and K-Ar data suggest that the low-grade metamorphism and cleavage formation in Taconic allochthons and the higher-grade metamorphism and emplacement of the Berkshire massif allochthon are Taconian. 40 Ar/ 39 Ar age data from a poorly defined terrane beginning near the east margin of the Green Mountain massif and extending along the eastern one-third of the Berkshire massif as far south as Otis, Massachusetts, suggest that the area has been retrograded during a metamorphism that peaked at least 376 ± 5 m.y. ago (Acadian). Available age and petrologic data from western New England indicate the presence of at least three separate metamorphic-structural domains of Taconian age: (1) a small area of relict high-pressure and low-temperature metamorphism in northern Vermont (T-1 domain), (2) a broad area in Vermont and eastern New York of normal Barrovian metamorphism from chlorite to garnet grade and characterized by a gentle metamorphic gradient (T-2 domain), and (3) a rather narrow belt of steep-gradient, Barrovian series metamorphic rocks extending from near the Cortlandt Complex northeastward through Dutchess County, New York, to the Berkshire massif in western Massachusetts (T-3 domain). Areas of maximum metamorphic intensity within the T-3 domain coincide with areas of maximum crustal thickening resulting from imbricate thrusting (Berkshire massif) or from recumbent folding (Manhattan Prong) of remobilized North American continental crust in the later stages of the Taconic orogeny.
Geological Society of America Bulletin↗