Geology topics

Ronald Amundson

Publications and source records attributed to Ronald Amundson.

12 recordsLinked to original sources

USGS2017

Paleoclimatic reconstruction using the correlation in δ 18 O of hackberry carbonate and environmental water, North America

Celtis sp. (commonly known as “hackberry”) fruits were collected from 101 North American sites located in 13 states and one Canadian province between the years of 1979–1994. The biomineralized carbonate endocarp of the hackberry, which is a common botanical fossil found throughout the Quaternary sediments of the Great Plains, was analyzed for its δ 18 O value and plotted against the δ 18 O value of site environmental water to demonstrate the potential of the hackberry as a paleoclimate indicator. This correlation was reinforced by intensive studies on extracted tissue-water δ 18 O value and hackberry endocarp carbonate δ 18 O value from three trees in Sterling, Colorado. The observed correlation in the large data set between hackberry endocarp carbonate δ 18 O value and environmental water is [endocarp δ 18 O=38.56+0.69×environmental water δ 18 O] ( R =0.88; R 2 =0.78; p value<0.0001). The relation of the hackberry carbonate to temperature in the Great Plains was the following: (average daily-maximum growing season temperature [°C])=6.33+0.67 (δ 18 O of endocarp carbonate) ( R =0.73; R 2 =0.54; p value=0.0133). The δ 18 O value of early Holocene fossil hackberry carbonate in the Pintwater Cave, southern Nevada, suggested precipitation δ 18 O values more positive than today (&sim;−4&permil; early Holocene vs &sim;−9 to −10&permil; today). This shift, combined with paleobotanical data, suggests an influx of summer monsoonal moisture to this region in the early Holocene. Alternatively, the more positive δ 18 O values could be viewed as suggestive of warmer temperatures, although the direct use of Great Plains hackberry/temperature relationships to the Great Basin is of debatable value.

Quaternary Research↗

USGS2010

Interpreting Ca and Fe stable isotope signals in carbonates: A new perspective

No abstract available.

Conference Paper↗

USGS2009

Spatial patterns and controls of soil chemical weathering rates along a transient hillslope

Hillslopes have been intensively studied by both geomorphologists and soil scientists. Whereas geomorphologists have focused on the physical soil production and transport on hillslopes, soil scientists have been concerned with the topographic variation of soil geochemical properties. We combined these differing approaches and quantified soil chemical weathering rates along a grass covered hillslope in Coastal California. The hillslope is comprised of both erosional and depositional sections. In the upper eroding section, soil production is balanced by physical erosion and chemical weathering. The hillslope then transitions to a depositional slope where soil accumulates due to a historical reduction of channel incision at the hillslope's base. Measurements of hillslope morphology and soil thickness were combined with the elemental composition of the soil and saprolite, and interpreted through a process-based model that accounts for both chemical weathering and sediment transport. Chemical weathering of the minerals as they moved downslope via sediment transport imparted spatial variation in the geochemical properties of the soil. Inverse modeling of the field and laboratory data revealed that the long-term soil chemical weathering rates peak at 5 g m - 2 yr - 1 at the downslope end of the eroding section and decrease to 1.5 g m - 2 yr - 1 within the depositional section. In the eroding section, soil chemical weathering rates appear to be primarily controlled by the rate of mineral supply via colluvial input from upslope. In the depositional slope, geochemical equilibrium between soil water and minerals appeared to limit the chemical weathering rate. Soil chemical weathering was responsible for removing 6% of the soil production in the eroding section and 5% of colluvial influx in the depositional slope. These were among the lowest weathering rates reported for actively eroding watersheds, which was attributed to the parent material with low amount of weatherable minerals and intense coating of the primary minerals by secondary clay and iron oxides. We showed that both the morphologic disequilibrium of the hillslope and the spatial heterogeneity of soil properties are due to spatial variations in the physical and chemical processes that removed mass from the soil. ?? 2009 Elsevier B.V.

Earth and Planetary Science Letters↗

USGS2008

Changes in the soil C cycle at the arid-hyperarid transition in the Atacama Desert

We examined soil organic C (OC) turnover and transport across the rainfall transition from a biotic, arid site to a largely abiotic, hyperarid site. With this transition, OC concentrations decrease, and C cycling slows precipitously, both in surface horizons and below ground. The concentration and isotopic character of soil OC across this transition reflect decreasing rates of inputs, decomposition, and downward transport. OC concentrations in the arid soil increase slightly with depth in the upper meter, but are generally low and variable (???0.05%; total inventory of 1.82 kg m-2); OC-??14C values decrease from modern (+7???) to very 14C-depleted (-966???) with depth; and OC-??13C values are variable (-23.7??? to -14.1???). Using a transport model, we show that these trends reflect relatively rapid cycling in the upper few centimeters, and spatially variable preservation of belowground OC from root inputs, possibly during a previous, wetter climate supporting higher soil OC concentrations. In the driest soil, the OC inventory is the lowest among the sites (0.19 kg m-2), and radiocarbon values are 14C-depleted (-365??? to -696???) but show no trend with depth, indicating belowground OC inputs and long OC residence times throughout the upper meter (104 y). A distinct depth trend in ??13C values and OC/ON values within the upper 40 cm at the driest site may reflect photochemical alteration of organic matter at the soil surface, combined with limited subsurface decomposition and downward transport. We argue that while root inputs are preserved at the wetter sites, C cycling in the most hyperarid soil occurs through infrequent, rapid dissolved transport of highly photodegraded organic matter during rare rain events, each followed by a pulse of decomposition and subsequent prolonged drought. These belowground inputs are likely a primary control on the character, activity, and depth distribution of small microbial populations. While the lack of water is the dominant control on C cycling, very low C/N ratios of organic matter suggest that when rainfall occurs, hyperarid soils are effectively C limited. The preservation of fossil root fragments in the sediment beneath the driest soil indicates that wetter climate conditions preceded formation of this soil, and that vadose zone microbial activity has been extremely limited for the past 2 My. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

USGS2008

On the in situ aqueous alteration of soils on Mars

Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO4, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface. ?? 2008 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

USGS2007

Rainfall limit of the N cycle on Earth

In most climates on Earth, biological processes control soil N. In the Atacama Desert of Chile, aridity severely limits biology, and soils accumulate atmospheric NO 3 − . We examined this apparent transformation of the soil N cycle using a series of ancient Atacama Desert soils (>2 My) that vary in rainfall (21 to <2 mm yr −1 ). With decreasing rainfall, soil organic C decreases to 0.3 kg C m −2 and biological activity becomes minimal, while soil NO 3 − and organic N increase to 4 kg N m −2 and 1.4 kg N m −2 , respectively. Atmospheric NO 3 − (Δ 17 O = 23.0‰) increases from 39% to 80% of total soil NO 3 − as rainfall decreases. These soils capture the transition from a steady state, biologically mediated soil N cycle to a dominantly abiotic, transient state of slowly accumulating atmospheric N. This transition suggests that oxidized soil N may be present in an even more arid and abiotic environment: Mars.

Global Biogeochemical Cycles↗

USGS2003

Global patterns of the isotopic composition of soil and plant nitrogen

We compiled new and published data on the natural abundance N isotope composition (δ 15 N values) of soil and plant organic matter from around the world. Across a broad range of climate and ecosystem types, we found that soil and plant δ 15 N values systematically decreased with increasing mean annual precipitation (MAP) and decreasing mean annual temperature (MAT). Because most undisturbed soils are near N steady state, the observations suggest that an increasing fraction of ecosystem N losses are 15 N-depleted forms (NO 3 , N 2 O, etc.) with decreasing MAP and increasing MAT. Wetter and colder ecosystems appear to be more efficient in conserving and recycling mineral N. Globally, plant δ 15 N values are more negative than soils, but the difference (δ 15 N plant -δ 15 N soil ) increases with decreasing MAT (and secondarily increasing MAP), suggesting a systematic change in the source of plant-available N (organic/NH 4 + versus NO 3 − ) with climate. Nitrogen isotopes reflect time integrated measures of the controls on N storage that are critical for predictions of how these ecosystems will respond to human-mediated disturbances of the global N cycle.

Global Biogeochemical Cycles↗

USGS2002

A multiisotope C and N modeling analysis of soil organic matter turnover and transport as a function of soil depth in a California annual grassland soil chronosequence

We examine soil organic matter (SOM) turnover and transport using C and N isotopes in soil profiles sampled circa 1949, 1978, and 1998 (a period spanning pulse thermonuclear 14 C enrichment of the atmosphere) along a 3‐million‐year annual grassland soil chronosequence. Temporal differences in soil Δ 14 C profiles indicate that inputs of recently living organic matter (OM) occur primarily in the upper 20–30 cm but suggest that OM inputs can occur below the primary rooting zone. A three‐pool SOM model with downward transport captures most observed variation in Δ 14 C, percentages of C and N, δ 13 C, and δ 15 N, supporting the commonly accepted concept of three distinct SOM pools. The model suggests that the importance of the decadal SOM pool in N dynamics is greatest in young and old soils. Altered hydrology and possibly low pH and/or P dynamics in highly developed old soils cause changes in soil C and N turnover and transport of importance for soil biogeochemistry models.

Global Biogeochemical Cycles↗

USGS2001

Soil N and 15N variation with time in a California annual grassland ecosystem

The %N and ??15N values of soils and plants were measured along a chronosequence spanning 3 to 3000 Ky in a California annual grassland. Total soil N decreased with increasing soil age (1.1 to 0.4 kg N m-2) while the mean ?? 15N values of the soil N increased by several ??? from the youngest to oldest sites (+3.5 to +6.2 ???). The ?? 15N values of plants varied along the gradient, reflecting changing soil N pools and differences in the form of N uptake. The decline in total N storage with time is hypothesized to be due to a shift from N to P limitation with increasing soil age. The general increase in ?? 15N values with time is interpreted using a N mass balance model, and appears to reflect a shift toward an increasing proportional losses of inorganic mineral forms of N (vs. organic forms) with increasing soil age. We develop a quantitative index of this trend (mineral vs. organic forms of N loss) using mass balance considerations and parameters. The %N and ?? 15N values along the California age gradient were compared to the published data for a comparably aged chronosequence in Hawaii. Most striking in this comparison is the observation that the California soil and plant ?? 15N values are several ??? greater than those on comparably aged Hawaiian sites. Multiple explanations are plausible, but assuming the sites have a similar range in ?? 15N values of atmospheric inputs, the isotopic differences suggest that N may be, at least seasonally, in greater excess in the strongly seasonal, semi-arid, California grassland. Copyright ?? 2001 Elsevier Science Ltd.

Geochimica et Cosmochimica Acta↗

USGS1999

An assessment the effects of human-caused air pollution on resources within the interior Columbia River basin

An assessment of existing and potential impacts to vegetation, aquatics, and visibility within the Columbia River basin due to air pollution was conducted as part of the Interior Columbia Basin Ecosystem Management Project. This assessment examined the current situation and potential trends due to pollutants such as ammonium, nitrogen oxides, sulfur oxides, particulates, carbon, and ozone. Ecosystems and resources at risk are identified, including certain forests, lichens, cryptogamic crusts, high elevation lakes and streams, arid lands, and class I areas. Current monitoring data are summarized and air pollution sources identified. The assessment also includes a summary of data gaps and suggestions for future research and monitoring related to air pollution and its effects on resources in the interior Columbia River basin.

General Technical Report↗

USGS1998

Carbon cycling in terrestrial environments: Chapter 17

This chapter reviews a number of applications of isotopic techniques for the investigation of carbon cycling processes. Carbon dioxide (C0 2 ) is an important greenhouse gas. Its concentration in the atmosphere has increased from an estimated 270 ppm at the beginning of the industrial revolution to &sim; 360 ppm at present. Climatic conditions and atmospheric C0 2 concentration also influence isotopic discrimination during photosynthesis. Natural and anthropogenically induced variations in the carbon isotopic abundance can be exploited to investigate carbon transformations between pools on various time scales. It also discusses one of the isotopes of carbon, the 14 C, that is produced in the atmosphere by interactions of cosmic-ray produced neutrons with stable isotopes of nitrogen (N), oxygen (O), and carbon (C), and has a natural abundance in the atmosphere of &sim;1 atom 14 C per 10 12 atoms 12 C. The most important factor affecting the measured 14 C ages of soil organic matter is the rate of organic carbon cycling in soils. Differences in the dynamics of soil carbon among different soils or soil horizons will result in different soil organic 14 C signatures. As a result, the deviation of the measured 14 C age from the true age could differ significantly among different soils or soil horizons.

Book chapter↗

USGS1996

Isotopic evidence for shifts in atmospheric circulation patterns during the late Quaternary in mid-North America

Wyoming is now at the eastern margin of westerlies originating in the Pacific, but in the Pleistocene appears to have received moisture from elsewhere, possibly the Gulf of Mexico. Oxygen isotope ratios of pedogenic carbonate in postglacial terraces correspond to ratios in equilibrium with present meteoric waters, which show a strong relation to precipitation seasonality and storm sources. In contrast, the oxygen isotope ratios of all pre-Holocene soils are significantly more positive, even though the carbon isotope composition of coexisting organic matter suggests that the carbonate formed in temperatures cooler than today. The oxygen isotope ratios of paleowaters in mid–North America appear to be more useful for identifying past storm sources than for estimating paleotemperatures.

Geology↗