Geology ReportsSearch

Geology topics

Roger E. Stoffregen

Publications and source records attributed to Roger E. Stoffregen.

3 recordsLinked to original sources

Mapping advanced argillic alteration at Cuprite, Nevada, using imaging spectroscopy

Mineral maps based on Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were used to study late Miocene advanced argillic alteration at Cuprite, Nevada. Distributions of Fe-bearing minerals, clays, micas, sulfates, and carbonates were mapped using the Tetracorder spectral-shape matching system. The Al content of white micas increases toward altered areas and near intrusive rocks. Alunite composition varies from pure K to intimate mixtures of Na-K endmembers with subpixel occurrences of huangite, the Ca analogue of alunite. Intimately mixed Na-K alunite marks areas of relatively lower alteration temperature, whereas co-occurring Na-alunite and dickite may delineate relict hydrothermal conduits. The presence of dickite, halloysite, and well-ordered kaolinite, but absence of disordered kaolinite, is consistent with acidic conditions during hydrothermal alteration. Partial lichen cover on opal spectrally mimics chalcedony, limiting its detection to lichen-free areas. Pods of buddingtonite are remnants of initial quartz-adularia-smectite alteration. Thus, spectral maps provide a synoptic view of the surface mineralogy, and define a previously unrecognized early steam-heated hydrothermal event. Faulting and episodes of hydrothermal alteration at Cuprite were intimately linked to upper plate movements above the Silver Peak-Lone Mountain detachment and growth, collapse, and resurgence of the nearby Stonewall Mountain volcanic complex between 8 and 5 Ma. Isotopic dating indicates that hydrothermal activity started at least by 7.61 Ma and ended by about 6.2 Ma. Spectral and stable isotope data suggest that Cuprite is a late Miocene low-sulfidation adularia-sericite type hot spring deposit overprinted by late-stage, steam-heated advanced argillic alteration formed along the margin of the Stonewall Mountain caldera.

Nevada

Experimental studies of alunite: I. 18 O- 16 O and D-H fractionation factors between alunite and water at 250-450°C

We have determined oxygen and hydrogen isotope fractionation factors between alunite and water over a temperature range of 250-450??C by reacting synthetic natroalunite with 0.7 m K2SO4 -0.1 to 0.65 m H2SO4 solutions to produce K-rich alunite. From 88 to 95% alkali and isotope exchange were observed in most of these experiments, and the partial equilibrium method was used to compute equilibrium fractionation factors. Least-squares fits of the data give 103 In ??alunite(so4)-H2O = 3.09 ( 106 T2 (K)) - 2.94 and 103 In ??alunite(OH)-H2O = 2.28 ( 106 T2 (K)) - 3.90. The intramineral 18O- 16O fractionation factor 103 In ??alunite(so4-OH site) is given by the expression 0.8 ( 106 T2 (K)) + 0.96. The alunite-water D-H fractionation factor ranges from -19 at 450??C to -6 at 250??C and does not appear to be strongly dependent on temperature. Runs with alkali exchange in the opposite direction were used to obtain 18O- 16O and D-H fractionation factors between natroalunite (mol% Na = 70-75) and water at 350-450??C. These indicate that mol% Na has negligible effect on the fractionation factors over this temperature range. Measured 18O-16O and D-H fractionation factors between alunite and 1.0 m KCl -0.5 m H2SO4 fluids also agree within 2?? with the values obtained from the K2SO4-H2SO4 fluids. However, experiments with alunite and distilled water at 400??C gave a value of 103 In ??alunite(SO4)-H2O of 0.0, compared with a value of 3.9 obtained at this temperature with K2SO4- and H2SO4-bearing fluids. This suggests that changes in fluid composition can affect alunite-water 18O-16O fractionation factors. Reconnaissance experiments with fine-grained natural natroalunite demonstrate that alunite-water D-H exchange can occur by hydrogen diffusion, although this process is generally not significant in the experiments with coarser grained synthetic alunites. ?? 1994.

Geochimica et Cosmochimica Acta