Geology topics

Robinson

Publications and source records attributed to Robinson.

11 recordsLinked to original sources

USGS2020

Pyrrhotite distribution in the conterminous United States, 2020

In parts of Connecticut and Massachusetts, foundations of some homes are cracking and crumbling. Failing foundations can reduce the market value of a home and lifting a house to replace and repour a foundation is an expensive undertaking. In response, some homeowners are defaulting on their mortgages and abandoning their homes. The culprit is pyrrhotite, which occurs in construction aggregate (crushed stone) that was used as a filler in concrete. When pyrrhotite is naturally exposed to water and oxygen, it breaks down to produce sulfuric acid and secondary minerals, including gypsum, which have larger volumes than the pyrrhotite they replace. The expanded volume of the secondary minerals cracks and degrades concrete. Pyrrhotite occurs in rocks in many areas of the United States. To help assess the national risk of pyrrhotite in aggregate, the fiscal year 2019 appropriations bill for the U.S. Geological Survey’s (USGS) Mineral Resources Program allocated funds to develop a map showing the distribution of pyrrhotite across the United States. The purpose of this fact sheet is to (1) present a nationwide map that shows where pyrrhotite may occur in rocks in the United States, (2) describe and discuss the factors that control the presence and abundance of pyrrhotite in rocks, (3) provide information on geographic information system datasets that deliver more detailed information on these distributions, and (4) describe U.S. and international standards on aggregate that are designed to prevent failing concrete. While this map and fact sheet provide general information about the possible distribution of pyrrhotite in the United States, they are no substitute for site-specific characterization and quality control programs designed to ensure that aggregate used in concrete is of appropriate quality for its intended purpose.

Conterminous United States↗

USGS2020

Porphyry copper potential of the U.S. Southern Basin and Range using ASTER data integrated with geochemical and geologic datasets to assess potential near-surface deposits in well-explored permissive tracts

ArcGIS was used to spatially assess and rank potential porphyry copper deposits using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data together with geochemical and geologic datasets in order to estimate undiscovered deposits in the southern Basin and Range Province in the southwestern United States. The assessment was done using a traditional expert opinion three-part method and a prospectivity model developed using weights of evidence and logistic regression techniques to determine if ASTER data integrated with other geologic datasets can be used to find additional areas of prospectivity in well-explored permissive tracts. ASTER hydrothermal alteration data were expressed as 457 alteration polygons defined from a low-pass filtered alteration density map of combined argillic, phyllic, and propylitic rock units. Sediment stream samples were plotted as map grid data and used as spatial information in ASTER polygons. Gravity and magnetic data were also used to define basins greater than 1 km in depth. Each ASTER alteration polygon was ranked for porphyry copper potential using alteration types, spatial amounts of alteration, stream sediment geochemistry, lithology, polygon shape, proximity to other alteration polygons, and deposit and prospects data. Permissive tracts defined for the assessment in the southern Basin and Range Province include the Laramide Northwest, Laramide Southeast, Jurassic, and Tertiary tracts. Expert opinion estimates using the three-part assessment method resulted in a mean estimate of 17 undiscovered porphyry copper deposits, whereas the prospectivity modeling predicted a mean estimate of nine undiscovered deposits. In the well-explored Laramide Southeast tract, which contains the most deposits and has been explored for over 100 years, an average of 4.3 undiscovered deposits was estimated using ASTER alteration polygon data versus 2.8 undiscovered deposits without ASTER data. The Tertiary tract, which contains the largest number of ASTER alteration polygons not associated with known Tertiary deposits, was predicted to contain the most undiscovered resources in the southern Basin and Range Province.

Economic Geology↗

USGS2019

Resource Assessment Economic Filter (RAEF)—A graphical user interface supporting implementation of simple engineering mine cost analyses of quantitative mineral resource assessment simulations

Economic evaluations of undiscovered mineral resources provide important context in which to consider the results of quantitative mineral resource assessments. The U.S. Geological Survey economic analysis method uses a simple engineering cost model approach developed by the U.S. Bureau of Mines that applies mine and mill engineering cost equations to simulated undiscovered deposits. The important characteristics of these deposits are derived from Monte Carlo simulations that combine probabilistic estimates of undiscovered deposits that might occur in a study area and a grade-tonnage model defined for a specific deposit type. This report describes the Resource Assessment Economic Filter (RAEF), a graphical user interface (GUI) tool that applies a set of mine cost equations to the deposits under consideration. RAEF, which is written in the open-source statistical programming language R, is an easy-to-use tool to apply user-defined mine, mill, and study area parameters to simulated deposits. For a given deposit type, it estimates the undiscovered resources that might be economic to extract. In addition, RAEF provides a series of graphical, tabular, and statistical summaries that document the results of the economic filter analysis.

Techniques and Methods↗

USGS2019

User’s guide for Assessment Tract Aggregation GUI (ATA GUI)—A graphical user interface for the AggtEx.fn R script

The U.S. Geological Survey three-part method for mineral resource assessments estimates numbers of undiscovered mineral deposits as probability distributions in geologically defined regions termed “permissive tracts.” This report describes a graphical user interface (GUI) script developed in open-source statistical software (R) that aggregates estimated undiscovered deposits of a given type from two or more permissive tracts using the AggtEx.fn R script. The AggtEx.fn R script aggregates undiscovered deposit estimates assuming independence, total dependence, or some degree of correlation among aggregated areas, given a user-specified correlation matrix. The script outputs three sets of aggregated estimates based on those three assumptions. The GUI script described in this report, Assessment Tract Aggregation GUI (ATA GUI), provides an easy-to-use tool that supports implementation of the AggtEx.fn R script, installation of the R packages needed to run the application, and creation of a combined input file from individual files generated by the MapMark4GUI software. Users can also use EMINERS output information by creating a file of output values following the MapMark4GUI output file format. The probabilistic estimates of aggregated undiscovered deposits produced by ATA GUI can be used as input for MapMark4GUI to estimate contained resources for the aggregated tracts. MapMark4GUI uses Monte Carlo simulation to combine undiscovered deposit estimates with tonnage and grade models to simulate undiscovered mineral resources for a region of interest. This simulation includes the amounts of commodities and rock that could be present within a permissive tract. This report includes instructions on installing and running the ATA GUI script and describes the input and output files used and created during the aggregation process.

Techniques and Methods↗

USGS1992

Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: I. Iron-copper-zinc-lead sulfide solubility relations

Experimental studies, using cold-seal and extraction vessel techniques, were conducted on Fe, Pb, Zn, and Cu sulfide solubilities in chloride solutions at temperatures from 300 degrees to 700 degrees C and pressures from 0.5 to 2 kbars. The solutions were buffered in pH by a quartz monzonite and the pure potassium feldspar-muscovite-quartz assemblage and in f (sub S 2 ) - f (sub O 2 ) largely by the assemblage pyrite-pyrrhotite-magnetite. Solubilities increase with increasing temperature and total chloride, and decrease with increasing pressure. The rise in solubility is particularly steep between 300 degrees and 500 degrees C and between 1,000 and 500 bars. With increasing temperature at any given pressure, or with decreasing pressure at any given temperature, metal solubility eventually passes through a maximum due to increasing competition for chloride by the alkali, hydrogen, and base metal ions and because intersection with a two-fluid region eventually occurs. In that portion of the two-fluid region encountered in the study, metal solubilities in the brine were very high, but solubilities in the gas phase also were significant. In a system controlled by the potassium feldspar-muscovite-quartz buffer, 1-m total Cl (super -) , and the assemblage pyrite-pyrrhotite-magnetite-sphalerite-galena-chalcopyrite, solubilities in ppm at 1 kbar and 300 degrees , 400 degrees , and 500 degrees C were 237, 1,216, and 5,636, for Fe; 51, 613, and 3,105 for Pb; 36, 423, and 2,649 for Zn; and 11, 40, and 113 for Cu, respectively. At 400 degrees C, 0.5 and 2 kbars, the values were 2,627 and 500 for Fe; 1,262 and 194 for Pb; 983 and 120 for Zn; and 60 and 29 for Cu, respectively. All of the above were in the single-fluid region. Single-metal solubilities also were investigated to assess the influence of iron on the solubility of the other metals and to corroborate preliminary dissociation constants for the metal chloride complexes involved. The effect of increasing chloride concentration on solubility reflects primarily a shift to lower pH via the silicate buffer reactions. The effect of decreasing pressure reflects primarily the relative change in the dissociation constants of the chloride complexes involved. Increasing sulfur fugacity lowers solubility, but in systems controlled at relatively low values by an f (sub S 2 ) buffer or wall-rock sulfidation reactions, solutions of high metal content relative to reduced sulfur will tend to develop at high chloride concentrations. Similarity in behavior with respect to the temperature and pressure of Fe, Zn, and Pb sulfide solubilities points to similarity in chloride speciation, and the neutral species appear to be dominant in the high-temperature region. At 500 degrees C and 1 kbar, the log K D values for FeCl degrees 2 , PbCl degrees 2 , ZnCl degrees 2 , and CuCl degrees are, respectively, -8.76, -9.14, -10.86, and -6.22.

Economic Geology↗

USGS1990