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Robert O. Fournier

Publications and source records attributed to Robert O. Fournier.

At least 19 recordsLinked to original sources
USGS2014

Hydrogeology of the Old Faithful area, Yellowstone National Park, Wyoming, and its relevance to natural resources and infrastructure

A panel of leading experts (The Old Faithful Science Review Panel) was convened by Yellowstone National Park (YNP) to review and summarize the geological and hydrological understanding that can inform National Park Service management of the Upper Geyser Basin area. We give an overview of present geological and hydrological knowledge of the Old Faithful hydrothermal (hot water) system and related thermal areas in the Upper Geyser Basin. We prioritize avenues for improving our understanding of key knowledge gaps that limit informed decision-making regarding human use in this fragile natural landscape. Lastly, we offer guidelines to minimize impacts to the hydrothermal system that could be used to aid decisions by park management. Old Faithful sits within the Upper Geyser Basin, an area of abundant hydrothermal activity where boiling waters extend from the surface to significant depth within glacial sediments and underlying volcanic rocks. The geyser systems are directly fed by waters recharged decades to millennia ago, which are surrounded by colder, younger waters. Activity of the geysers is controlled by complex subsurface plumbing with fractures and conduits separated by regions of low permeability. Observations over the past century indicate that the thermal areas and their features are both fragile and highly dynamic. Although Old Faithful has erupted regularly for the past 150 years, it exhibits changes in eruptive behavior over time, and the average interval between eruptions has increased by about 50 percent over the past 50 years. It is clear that human activity has modified the hydrothermal system in the past; conversely, natural features pose ongoing hazards to humans and human infrastructure. Current (2014) long-term programs to measure heat discharge by chloride-flux monitoring, and more recently by thermal-infrared imaging, are crucial for assessing the status of the hydrothermal system. Complementary studies could include airborne resistivity, environmental tracers, numerical modeling, and greater emphasis on measuring the discharge of water during geyser eruptions. Such data are needed to better understand the subsurface plumbing systems that feed the geysers. Further understanding can be gained through installation of shallow groundwater observation wells, surface geophysical studies, and direct measurement of temperature gradients near the surface. It also is critical to archive existing data from all studies in a manner that will be readily accessible to scientists and decision makers. Monitoring and data collection can be achieved through the YNP geology program, by direct funding to other groups, or by encouraging and facilitating externally funded research. There are many documented examples at YNP and elsewhere where human infrastructure and natural thermal features have negatively affected each other. Unless action is taken, human conflicts with the Old Faithful hydrothermal system are likely to increase over the coming years. This is partly because of the increase in park visitation over the past decades, but also because the interval between eruptions of Old Faithful has increased, lengthening the time spent (and services needed) for each visitor at Old Faithful. To avoid an increase in visitor impacts, the National Park Service should consider 2 alternate strategies to accommodate people, vehicles, and services in the Upper Geyser Basin, such as shuttle services from staging (parking and dining) areas with little or no recent hydrothermal activity. We further suggest that YNP consider a zone system to guide maintenance and development of infrastructure in the immediate Old Faithful area. A “red” zone includes hydrothermally active land where new development is discouraged and existing infrastructure is modified with great care. An outer “green” zone represents areas where cooler temperatures and less hydrothermal flow are thought to exist, and where development and maintenance could proceed as occurs elsewhere in the park. An intermediate “yellow” zone would require preliminary assessment of subsurface temperatures and gas concentrations to assess suitability for infrastructure development. The panel recommends that YNP management follow the lead of the National Park System Advisory Board Science Committee (2012) by applying the “precautionary principle” when making decisions regarding the interaction of hydrothermal phenomena and park infrastructure in the Old Faithful area and other thermal areas within YNP.

Wyoming↗
USGS2008

Taming of a wild research well in Yellowstone National Park during November 1992

Much of our current understanding of Yellowstone's geothermal areas comes from research drilling by the USGS during 1967 and 1968. Thirteen wells were drilled in thermal areas around the park. Scientists collected waters and rocks, measured temperatures and pressures and performed other tests to characterize the shallow subsurface at Yellowstone. Most wells were plugged and abandoned, but a few were left open for future scientific tests and sampling. One of those wells, the Y8, was located at Biscuit Basin, 2 miles north of Old Faithful. In November 1992, a valve at the ground surface failed, leading to a blowout, an uncontrolled eruption of steam and hot water. The USGS and Yellowstone National Park worked with a drilling contractor to control the flow and plug the well. The lead scientist, Robert Fournier, used video taken by the drilling contractor, Tonto Services, to create this fascinating 28-minute-long film. It is followed by a short news story by CNN, also from November 1992. Fifteen years later, we felt that the video was of sufficient scientific and historical interest that it was worth publishing as a USGS Open-file report, where it can be accessed into the future. Enjoy!

Open-File Report↗
USGS1996

The generation of HCl in the system CaCl 2 -H 2 O: Vapor-liquid relations from 380-500°C

We determined vapor-liquid relations (P-T-x) and derived critical parameters for the system CaCl2-H2O from 380-500??C. Results show that the two-phase region of this system is extremely large and occupies a significant portion of the P-T space to which circulation of fluids in the Earth's crust is constrained. Results also show the system generates significant amounts of HCl (as much as 0.1 mol/kg) in the vapor phase buffered by the liquid at surprisingly high pressures (???230 bars at 380??C, <580 bars at 500??C), presumably by hydrolysis of CaCl2: CaCl2 + 2H2O = Ca(OH)2 + 2HCl. We interpret the abundance of HCl in the vapor as due to its preference for the vapor phase, and by the preference of Ca(OH)2 for either the liquid phase or solid. The recent recognition of the abundance of CaCl2 in deep brines of the Earth's crust and their hydrothermal mobilization makes the hydrolysis of CaCl2 geologically important. The boiling of Ca-rich brines produces abundant HCl buffered by the presence of the liquid at moderate pressures. The resultant Ca(OH)2 generated by this process reacts with silicates to form a variety of alteration products, such as epidote, whereas the vapor produces acid-alteration of rocks through which it ascends.

Geochimica et Cosmochimica Acta↗
USGS1996

Geology and geothermal potential of Alid volcanic center, Eritrea, Africa

Alid volcanic center, a 700-meter-tall mountain in Eritrea, northeast Africa, straddles the axis of an active crustal-spreading center called the Danakil Depression. Boiling-temperature fumaroles are common on Alid, and their gas compositions indicate a reservoir temperature of at least 250 ??C. The history of volcanism and the high reservoir temperature indicated by the Alid fumarole gases suggest that a geothermal resource of electrical grade lies beneath the mountain. Though drilling is needed to determine subsurface conditions, the process of dome formation and the ongoing crustal spreading can create and maintain fracture permeability in the hydrothermal system that feeds the Alid fumaroles.

Conference Paper↗
USGS1995

Trace metals and major and rare earth elements in cuttings from five high-temperature wells in the northwest region of The Geysers, California, vapor-dominated geothermal system

Temperatures within the main vapor-dominated steam reservoir at The Geysers geothermal field generally are in the range 238°C to 244°C. A few deep wells in the northwestern part of the field have penetrated beneath this reservoir into a second vapor-dominated reservoir where temperatures are >315°C, while vapor pressure remains nearly constant at about 35.9 bars (Walters et al., 1992). Vapor-dominated reservoirs generally are thought to operate like heat pipes in which steam formed near the base of the system convects upward (along with other gases, such as CC>2 and H2S), while liquid that has condensed from steam near the top of the reservoir counterflows downward (White et al., 1971). To the extent that this steam condensate carries H2S in solution, it may dissolve gold from the surrounding rock during the counterflow. Re-evaporation of the down-flowing condensate and precipitation of dissolved material might occur at the base of the upper reservoir where there is a relatively sharp increase in temperature while vapor pressure remains nearly constant. In addition, brine that once was present throughout the system (Moore, 1992) may have deposited a variety of ore minerals when and where boiling was vigorous during the transition from previous hot water-dominated to present-day vapor-dominated conditions. The investigation reported here was a geochemical reconnaissance survey looking for evidence of accumulation of Au and other metals in the transition zone between the two reservoirs. The petrology of the cuttings was not examined as part of the investigation.

Open-File Report↗
USGS1994

A field-trip guide to Yellowstone National Park, Wyoming, Montana, and Idaho: Volcanic, hydrothermal, and glacial activity in the region

This field-trip guide was originally prepared for the 7th International Symposium on Water/Rock Interaction (WRI-7) held in July 1992 in Park City, Utah. A large and diversified group of earth scientists and accompanying family members participated in this 3 1/2-day field trip that focused on water/rock interactions over widely ranging temperatures and pressures in the Yellowstone/Grand Teton region. Emphasis was placed on the geochemical and hydrologic characteristics of the thermal waters in the major "geyser basins" of Yellowstone National Park. Information specific to the WRI-7 trip about logistics, lodging, and meals has been deleted from the present guide. The scientific content remains mostly unchanged, except for the addition of a glossary, two illustrations, all photographs, and some text previously presented to the field-trip participants in supplementary materials (see appendix A). Most of the geyser basins in Yellowstone National Park are on a high volcanic plateau at elevations of 2,000 to 2,200 m and are surrounded by much higher mountain ranges. In the middle of summer there generally are cool evenings and early mornings and warm afternoons. Visits to the localities described require short walks, mostly on boardwalks, but some are on what may be wet ground. No long, strenuous climbs are required. Expect brief afternoon thunder showers, particularly at Old Faithful. Please remember that the collecting of any kind of sample in a national park is prohibited except by those who have specific sampling permits issued by the National Park Service. Field-trip participants are asked to leave geologic picks and hammers at home or in their luggage while in Yellowstone National Park.

Idaho, Montana, Wyoming↗
USGS1993

Composition of steam in the system NaCl-KCl-H 2 O-quartz at 600°C

In the system NaCl-KCl-H2O, with and without ??-quartz present, steam was equilibrated in a large-volume reaction vessel with brine and/or precipitated salt at 600??C and pressures ranging from about 100 to 0.4 MPa. Episodically, steam was extracted for chemical analysis, accompanied by a decrease in pressure within the reaction vessel. In the absence of precipitated salt, within the analytical uncertainty stoichiometric quantities of Cl and total alkali, metals (Na + K) dissolve in steam coexisting with chloriderich brine. In contrast, in the presence of precipitated salt (in our experiments halite with some KCl in solid solution), significant excess chloride as associated hydrogen chloride (HCl0??) dissolves in steam. The HCl0 is generated by the reaction of steam with solid NaCl(s), producing solid NaOH(s) that diffuses into halite, forming a solid solution. In our quasistatic experiments, compared to dynamic flow-through experiments of others, higher initial ratios of H2O/NaCl have apparently resulted in higher model fractions of NaOH(s) in solid solution in halite. This, in turn, resulted in incrementally higher concentrations of associated NaOHo dissolved in steam. Addition of quartz to the system NaCl + KC1 + H2O resulted in an order of magnitude increase in the concentration of HCl0 dissolved in steam, apparently as a consequence of the formation of sodium disilicate by reaction of silica with NaOH(s). The measured dissolved silica in steam saturated with alkali halides at 600??C in the pressure range 7-70 MPa agrees nicely with calculated values of the solubility of ??-quartz obtained using the equation of Fournier and Potter (1982), corrected for dissolved salt by the method of fournier (1983). Na K ratios in steam at 600??C tend to be slightly greater than in coexisting brine. When precipitated halite is present, larger mole fractions of NaOH(s) in solid solution in that halite apparently result in even larger Na K ratios in coexisting steam. Precipitation of more halite as a consequence of repeated depressurization episodes results in decreased Na K ratios in both the brine and coexisting steam phases, indicating that the lower pressures begin to favor K over Na in the vapor. When steam is in contact with precipitated salts in the absence of brine, the Na K ratio in the steam is less than that of the bulk composition of the salt-H2O system. ?? 1993.

Geochimica et Cosmochimica Acta↗
USGS1993

Taming a wild geothermal research well in yellowstone national park

In November 1992 the valve at the top of a U.S. Geological Survey drill hole in Yellowstone National Park parted from the casting as a result of corrosion. This allowed uncontrolled venting of boiling water and steam from the well at an estimated liquid flow rate of about 25-50 gallons per minute. A flow diverter assembly was designed, fabricated and installed on the well within 16 days, which allowed drill rods to be safely stripped into the well through on annular Blow-Out Preventer. Once this was accomplished it was a relatively routine matter to set a packer in the casting and cement the well shut permanently. The drill hole was brought under control and cemented shut within 18 days of the wellhead failure at a total cost of $47,066, which was about $5,000 less than anticipated.

Conference Paper↗
USGS1985

Geologic characteristics of sediment- and volcanic-hosted disseminated gold deposits - Search for an occurrence model

The current expansion of resource information, particularly on "disseminated" gold, and the improved technologies now available for resource investigations should place us in an enhanced position for developing a better predictive methodology for meeting one of the important responsibilities of the U.S. Geological Survey-to examine and assess the mineral resources of the geologic terranes composing the public (and privately owned) lands of the United States. The first step is systematic organization of these data. Geologic-occurrence models are an effective systematic method by which to organize large amounts of resource information into a logical sequence facilitating its use more effectively in meeting several industry and Survey objectives, which include the exploration for resources and the assessment of resource potential for land-use decisions. Such models also provide a scientific basis for metallogenesis research, which considers the observable features or attributes of ore occurrence and their "fit" into the Earth's resource puzzle. The use of models in making resource assessments/appraisals was addressed by Shawe (1981), who reported the results of a workshop on methods for resource appraisal of Wilderness and Conterminous United States Mineral Appraisal Program (CUSMAP; 1:250,000-scale quadrangles) areas. The Survey's main objective in the 1982 workshop was to evaluate the status of knowledge about disseminated or very fine grained gold deposits and, if possible, to develop an occurrence model(s). This report on the workshop proceedings has three main objectives: (1) Education through the publication of a summary review and presentation of new thinking and observations about the scientific bases for those geologic processes and environments that foster disseminated gold-ore formation; (2) systematic organization of available geologic, geochemical, and geophysical information for a range of typical disseminated gold deposits (including recognition of gaps in those data); and (3) assessment of current understanding (as presented in objective 2) toward formulating an empirical ore-occurrence model for this type of deposit. As such, this volume represents a preliminary first step at classification and provides a source of pertinent background information. Readers of this volume will soon discover, however, that full agreement has not yet been achieved in the interpretation of some of the geologic evidence. The resulting variations in tentative occurrence models for these controversial deposits ultimately will be resolved by filling the gaps in information that have already been identified. Thus, this volume does not report a U.S. Geological Survey consensus; the conclusions expressed in each chapter represent the particular interpretations of the various workshop participants.

Arizona, California, Idaho, Nevada, Utah↗
USGS1983

Calculation of amorphous silica solubilities at 25° to 300°C and apparent cation hydration numbers in aqueous salt solutions using the concept of effective density of water

The solubility of amorphous silica in aqueous salt solutions at 25&deg; to 300&deg;C can be calculated using information on its solubility in pure water and a model in which the activity of water in the salt solution is defined to equal the effective density. p e , of &ldquo;free&rdquo; water in that solution. At temperatures of 100&deg;C and above, p e closely equals the product of the density of the solution times the weight fraction of water in the solution. At 25&deg;C, a correction parameter must be applied to p e that incorporates a term called the apparent cation hydration number, h . Because of the many assumptions and other uncertainties involved in determining values of h , by the model used here, the reported numbers are not necessarily real hydration numbers even though they do agree with some published values determined by activity and diffusion methods. Whether or not h is a real hydration number, it would appear to be useful in its inclusion within a more extensive activity coefficient term that describes the departure of silica solubilities in concentrated salt solutions from expected behavior according to the model presented here. Values of h can be calculated from measured amorphous silica solubilities in salt solutions at 25&deg;C provided there is no complexing of dissolved silica with the dissolved salt, or if the degree of complexing is known. The previously postulated aqueous silica-sulfate complexing in aqueous Na 2 SO 4 solutions is supported by results of the present effective density of water model

Geochimica et Cosmochimica Acta↗
USGS1982

An equation correlating the solubility of quartz in water from 25° to 900°C at pressures up to 10,000 bars

The solubility of quartz in water from 25&deg; to 900&deg;C at specific volume of the solvent ranging from about 1 to 10 and from 300&deg; to 600&deg;C at specific volume of the solvent ranging from about 10 to 100 is given by an empirically derived equation of the form: log m = A + B (log V ) + C (log V ) 2 where m is the molal silica concentration, V is the specific volume of pure water, and A = &minus;4.66206 + 0.0034063 T + 2179.7 T &minus;1 &minus; 1.1292 &times; 10 6 T &minus;2 + 1.3543 &times; 10 8 T &minus;3 B = &minus;0.0014180 T &mdash; 806.97 T &minus;1 C = 3.9465 &times; 10 &minus;4 T T is temperature in kelvins. The experimental data used in formulating the empirical relation ranged in pressure from 1 bar at 25&deg;C to about 10,000 bars at 900&deg;C, and the lowest pressure in the low-density steam region was about 30 bars. According to the above equation, the average difference in molality between 518 measured and calculated solubilities is &minus;0.016 m with a standard deviation of 0.089.

Geochimica et Cosmochimica Acta↗
USGS1982

The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350&deg;C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.

Geochimica et Cosmochimica Acta↗