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Robert L. Runkel

Publications and source records attributed to Robert L. Runkel.

78 records · Page 5Linked to original sources

Quantification of metal loading in Fisher Creek by tracer injection and synoptic sampling, Park County, Montana, August 1997

A cid mine drainage from abandoned and inactive mines affects the water quality of the upper reaches of Fisher Creek, Montana. A sodium chloride tracer was added to the stream for 29.5 hours to provide a hydrologic context for synoptic sampling of metal chemistry in the stream and its inflows. The detailed profile of stream discharge obtained from the sampling helped to indicate those areas of Fisher Creek where most of the metal loading occurred. Inflows to the stream can be divided between visible surface inflows, which were sampled, and subsurface inflows, which were not sampled, but the effects of both types of inflows on the stream load were quantified. Substantial loads were attributed to both sources. These results indicate that treatment of large visible inflows, particularly the Glengary adit, could still leave metal concentrations in Fisher Creek at levels that may adversely affect aquatic life.

Montana↗

One-Dimensional Transport with Inflow and Storage (OTIS): A Solute Transport Model for Streams and Rivers

OTIS is a mathematical simulation model used to characterize the fate and transport of water-borne solutes in streams and rivers. The governing equation underlying the model is the advection-dispersion equation with additional terms to account for transient storage, lateral inflow, first-order decay, and sorption. This equation and the associated equations describing transient storage and sorption are solved using a Crank-Nicolson finite-difference solution. OTIS may be used in conjunction with data from field-scale tracer experiments to quantify the hydrologic parameters affecting solute transport. This application typically involves a trial-and-error approach wherein parameter estimates are adjusted to obtain an acceptable match between simulated and observed tracer concentrations. Additional applications include analyses of nonconservative solutes that are subject to sorption processes or first-order decay. OTIS-P, a modified version of OTIS, couples the solution of the governing equation with a nonlinear regression package. OTIS-P determines an optimal set of parameter estimates that minimize the squared differences between the simulated and observed concentrations, thereby automating the parameter estimation process. This report details the development and application of OTIS and OTIS-P. Sections of the report describe model theory, input/output specifications, sample applications, and installation instructions.

Water-Resources Investigations Report↗

Reactive solute transport in streams: 1. Development of an equilibrium- based model

An equilibrium-based solute transport model is developed for the simulation of trace metal fate and transport in streams. The model is formed by coupling a solute transport model with a chemical equilibrium submodel based on MINTEQ. The solute transport model considers the physical processes of advection, dispersion, lateral inflow, and transient storage, while the equilibrium submodel considers the speciation and complexation of aqueous species, precipitation/dissolution and sorption. Within the model, reactions in the water column may result in the formation of solid phases (precipitates and sorbed species) that are subject to downstream transport and settling processes. Solid phases on the streambed may also interact with the water column through dissolution and sorption/desorption reactions. Consideration of both mobile (water-borne) and immobile (streambed) solid phases requires a unique set of governing differential equations and solution techniques that are developed herein. The partial differential equations describing physical transport and the algebraic equations describing chemical equilibria are coupled using the sequential iteration approach.

Water Resources Research↗

Reactive solute transport in streams: 2. Simulation of a pH modification experiment

We present an application of an equilibrium-based solute transport model to a p H-modification experiment conducted on the Snake River, an acidic, metal-rich stream located in the Rocky Mountains of Colorado. During the experiment, instream p H decreased from 4.2 to 3.2, causing a marked increase in dissolved iron concentrations. Model application requires specification of several parameters that are estimated using tracer techniques, mass balance calculations, and geochemical data. Two basic questions are addressed through model application: (1) What are the processes responsible for the observed increase in dissolved iron concentrations? (2) Can the identified processes be represented within the equilibrium-based transport model? Simulation results indicate that the increase in iron was due to the dissolution of hydrous iron oxides and the photoreduction of ferric iron. Dissolution from the streambed is represented by considering a trace compartment consisting of freshly precipitated hydrous iron oxide and an abundant compartment consisting of aged precipitates that are less soluble. Spatial variability in the solubility of hydrous iron oxide is attributed to heterogeneity in the streambed sediments, temperature effects, and/or variability in the effects of photoreduction. Solubility products estimated via simulation fall within a narrow range ( pK sp from 40.2 to 40.8) relative to the 6 order of magnitude variation reported for laboratory experiments ( pK sp from 37.3 to 43.3). Results also support the use of an equilibrium-based transport model as the predominate features of the iron and p H profiles are reproduced. The model provides a valuable tool for quantifying the nature and extent of p H-dependent processes within the context of hydrologic transport.

Water Resources Research↗

Transport of reacting solutes in rivers and streams

In this chapter we discuss the major processes affecting solutes in rivers and streams. Here a solute is generally defined as any substance or entity that is transported downstream by the flowing waters. Under this definition, solutes may be pollutants, such as pesticides and hydrocarbons, or naturally occurring substances such as dissolved gases, nutrients, and trace elements. Study of the processes affecting solutes is an important undertaking, as pollutants may pose a threat to public health when the affected waterbody is used as a water supply or for recreational purposes. Another important issue is the effect of pollutants on the aquatic organisms that inhabit the stream ecosystem.

Book chapter↗