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Robert G. Coleman

Publications and source records attributed to Robert G. Coleman.

10 recordsLinked to original sources

New Idria serpentinite protrusion, Diablo Range, California: From upper mantle to the surface

The New Idria serpentinite body in the Coast Ranges of California is a diapir that resulted from the interaction of the migrating Mendocino trench-ridge-transform fault triple junction, transpression, metasomatic fluids, and previously subducted oceanic crust and mantle. Northward propagation of the San Andreas fault progressively eliminated the original subduction zone, allowing seawater to penetrate into the formerly subducting abyssal peridotite mantle, triggering serpentinization. The associated physical changes in density, volume, and strength yielded an expanding, buoyantly rising serpentinite protrusion, facilitated by transpression along the San Andreas fault. Sedimentary facies and intrusion of minor cross cutting syenite and alkali basalt dikes indicate that the serpentinization-driven diapir buoyantly rose and widely breached the surface by ca. 14 Ma, attending migration of the Mendocino Triple Junction past the latitude of New Idria.

California

Chromium geochemistry of serpentinous sediment in the Willow core, Santa Clara County, California

A preliminary investigation of Cr geochemistry in serpentinous sediment completed for a multiple-aquifer ground-water monitoring well (Willow core of Santa Clara County, CA) determined sediment at depths >225 meters contains Cr concentrations ranging from 195 to 1155 mg/kg. Serpentinous sediment from this site is a potential source of non-anthropogenic Cr contamination. Chromium-bearing minerals such as Cr-spinel appear to be the main source of Cr in the sediment; however, Cr-bearing silicates and clay minerals are additional Cr sources. Aqueous Cr concentrations in the sediment are <4.6 mg/L; however, the valence of Cr was not identified in the solutions or in the sediment. Although there is no indication of Cr(VI) contamination derived from the serpentinous sediment, elevated Cr concentrations in the sediment, the observed ‘dissolution’ textures of the Cr-bearing minerals, the estimated redox environment, and water chemistry indicate the formation of Cr(VI) is potentially favorable.

California

A-type granite and the Red Sea opening

Miocene-Oligocene A-type granite intrudes the eastern side of the Red Sea margin within the zone of extension from Jiddah, Saudi Arabia south to Yemen. The intrusions developed in the early stages of continental extension as Arabia began to move slowly away from Africa (around 30–20 Ma). Within the narrow zone of extension silicic magmas formed dikes, sills, small plutons and extrusive equivalents. In the Jabal Tirf area of Saudi Arabia these rocks occur in an elongate zone consisting of late Precambrian basement to the east, which is gradually invaded by mafic dikes. The number of dikes increases westward until an igneous complex is produced parallel to the present Red Sea axis. The Jabal Tirf igneous complex consists of diabase and rhyolite-granophyre sills (20–24 Ma). Although these are intrusine intrusive rocks their textures indicate shallow depths of intrusion (< 1 km). To the south, in the Yemen, contemporaneous with alkali basaltic eruptions (26–30 Ma) and later silicic eruptions, small plutons, dikes, and stocks of alkali granite invaded thick (1500 m) volcanic series, at various levels and times. Erosion within the uplifted margin of Yemen suggests that the maximum depth of intrusion was less than 1–2 km. Granophyric intrusions (20–30 Ma) within mafic dike swarms similar to the Jabal Tirf complex are present along the western edge of the Yemen volcanic plateau, marking a north-south zone of continental extension. The alkali granites of Yemen consist primarily of perthitic feldspar and quartz with some minor alkali amphiboles and acmite. These granites represent water-poor, hypersolvus magmas generated from parent alkali basalt magmas. The granophyric, two-feldspar granites associated with the mafic dike swarms and layered gabbros formed by fractional crystallization from tholeiitic basalt parent developed in the early stages of extension. Initial 87 Sr/ 86 Sr ratios of these rocks and their bulk chemistry indicate that production of peralkaline and metaluminous granitic magmas involved both fractiónation and partial melting as they ascended through the late Precambrian crust of the Arabian plate.

Red Sea

The Briggs Creek Amphibolite, Klamath Mountains, Oregon: Its origin and dispersal

The Briggs Creek Amphibolite (BCA) in southwestern Oregon is an allochthonous slice of metamorphosed oceanic crust emplaced during the Nevadan orogenic event. Even though the evidence is not clear, the authors prefer to have the protolith for the BCA formed in a back‐arc basin contemporaneously as part of the Josephine Ophiolite during late Callovian to early Oxfordian. Although major rearrangement of some of the chemical elements took place during metamorphism, it is possible, by use of major and rare earth elements, to suggest that the BCA formed in an oceanic spreading centre rather than an island arc setting. Meta‐morphic mineral assemblages and composition of the hornblendes indicate that metamorphism attained amphibolite facies grade. Widespread occurrence of allochthonous blocks of BCA in Western Oregon indicate that its dispersion following metamorphism can be related to the accretionary history of the continental margin. Westward thrusting of these blocks of BCA over the Chetco Arc during the Nevadan orogenic event provided blocks that slid into the outboard active Early Cretaceous trench. These blocks were then incorporated into the downgoing subduction complex and overprinted by high P/T metamorphic assemblages. Tectonic blocks within the Early Cretaceous Otter Point trench melange (Franciscan Complex equivalent) contain amphibolites correlated with the BCA and overprinted by high P/T mineral assemblages.

Oregon

Eclogites from southwestern Oregon

Eclogite, high-grade blueschist, and amphibolite blocks occur within the Mesozoic Otter Point Formation of southwestern Oregon and are inferred to have been tectonically emplaced by eastward-directed overthrusting involving Colebrooke Schist and serpentinite. Eclogite from southwestern Oregon is very similar in bulk chemistry and mineralogy to the well-studied eclogite of California. Calculations of phase equilibria at load pressures of 7 and 10 kb and T = 400°C to 550°C suggest that many of the hydrates found in eclogite could have been stable at very low H 2 O fugacities. The lack of lawsonite and the presence of almandine-grossular garnet set a maximum limit on H 2 O fugacity for a given P s -T. Chemically, Group C eclogite from Oregon and California characteristically is nepheline normative and is enriched in normative diopside relative to basaltic compositions. The present chemistry of this eclogite may be the result of metasomatism in an ultramafic environment with low a SiO 2 and high a Ca, but outside the stability field of serpentine. The generally high jadeite content of clinopyroxene from Group C eclogite compared with Group A and Group B eclogite is largely a function of bulk rock chemistry. Crystallization under low a SiO 2 conditions stabilizes jadeite in clinopyroxene at lower P s for a given T.

Oregon

Petrologic and geophysical nature of serpentinites

Mineralogically, serpentinites consist predominantly of lizardite, clinochrysotile, and antigorite. Recent work has shown that these minerals are not polymorphs. Chrysotile is the only mineral recognized as a synthetic product in experimental studies of the system MgO-SiO 2 -H 2 O. Antigorite seems to be stable at higher temperatures than lizardite or chrysotile. The density of individual serpentine species is dependent on their morphology; the low-density serpentinites (<2.55g/cc) consist predominantly of clino-chrysotile. Seismic velocities and magnetic susceptibilities of serpentinites are related to the degree of serpentinization. The transition of massive serpentinites from ductile to brittle behavior in laboratory experiments at high confining pressures and temperatures above 300°C has been related to dehydration which may provide a mechanism for developing deep-focus earthquakes along Benioff zones. Serpentinite is formed by direct hydration of ultramafic protolith in the crust. The most common ultramafic protoliths are harzburgite, dunite, and Iherzolite. The assemblage generally developed from these is lizardite + chrysotile + brucite + magnetite. In areas of high-grade metamorphism, antigorite is the predominant serpentine mineral. The common, large, alpine-type serpentinized ultramafic masses contain brucite and have MgO/SiO 2 ratios similar to those of their protolith, resulting in volume increase during serpentinization. Metamorphic serpentinites and some highly sheared alpine-type serpentinites have lower MgO/SiO 2 ratios than their protolith, lack brucite, and appear t o have been formed by volume-for-volume replacement with concomitant loss of magnesium or addition of silica. Many large, young masses of peridotite appear to be slabs of oceanic mantle over-thrust onto continental edges. Subsequent sedimentation, serpentinization, and tectonism have greatly modified these original slabs so that their recognition in older orogenic zones is equivocal. The concept of the tectonic evolution of ultramafic rocks from oceanic crust-mantle slabs invading continental margins and being incrementally serpentinized and moved by later tectonic events provides a working hypothesis that allows a better explanation of the many peculiar and varied occurrences of serpentinite. The evidence does not support Hess' suggestion that the third layer of the oceanic crust consists of partly serpentinized mantle peridotite.

Bulletin of the Geological Society of America

O18/O16 ratios of coexisting minerals in glaucophane-bearing metamorphic rocks

Oxygen isotope analyses have been obtained for coexisting minerals in several blue-schist-facies metamorphic rocks from California, Oregon, and New Caledonia. Detailed isotopic studies were made on a continuous exposure of schist in Ward Creek, California, previously described by Coleman and Lee (1962). The oxygen isotope fractionations among coexisting minerals in a variety of rock types, including metasediments and metabasalts, are systematic and larger than those measured in pelitic schists metamorphosed at the grade of biotite zone or higher. Therefore, these Ward Creek rocks (termed Type III) must have formed at lower temperatures than have such pelitic schists. Evidence for significant isotopic equilibration and homogenization is observed in the Ward Creek sequence. Six different metasediments and metavolcanics collected within 25 m of one another show almost identical mineral δ; -values: quartz (15.8 to 16.3), aragonite (13.1 to 13.3), glaucophane (9.8 to 10.0), muscovite (10.9 to 11.3), lawsonite (9.3 to 9.5), and garnet (8.0 to 8.4), given as per mil enrichment in O 18 relative to mean ocean water. These rocks seem to have reached equilibrium at about the same temperature in contact with abundant metamorphic pore fluids. Not all the Ward Creek rocks have completely equilibrated with the postulated metamorphic pore fluids. In particular, the metacherts seem to have been relatively impermeable to the aqueous fluids during metamorphism, as indicated by the large δ -values of quartz in such rocks (17 to 19.2) and by their appreciably higher Fe +3 /Fe +2 ratios. Gradients in O 18 /O 16 and Fe +3 /Fe +2 have been generally “smoothed out” in the rocks during metamorphism, but the process has gone to completion only locally. Cherts and limestones have apparently been lowered in O 18 content by 10 to 15 per mil, and the metabasalts are enriched by 3 to 4 per mil over their unmetamorphosed parent rocks. Using the calibrated quartz-muscovite and quartz—CaCO 3 geothermometers, the measured quartz-muscovite and quartz-aragonite fractionations indicate essentially “concordant” temperatures of formation for the Type III rocks of 270° to 315° C. Inasmuch as aragonite is part of the equilibrium assemblage, these rocks must therefore have been metamorphosed at pressures of at least 6.4 to 7.0 kb. Oxygen isotope fractionations for the mineral pairs aragonite-lawsonite, quartz-muscovite, and quartz-glaucophane progressively decrease from Type II (low-grade) through Type III to Type IV (high-grade tectonic blocks) metabasalts. The higher-grade blueschists from New Caledonia exhibit quartz-muscovite and quartz-glaucophane fractionations similar to the Type IV metabasalts at Ward Creek, indicating temperatures of formation of 400° to 550° C. Thus, glaucophane-bearing metamorphic rocks apparently form over a temperature range of 200° C to 550° C, encompassing the probable temperature range of the entire greenschist and epidote-amphibolite facies. This suggests that glaucophane schists should be separated into at least two metamorphic facies, a lower-grade, lawsonite-aragonite blueschist facies and a higher-grade, epidote-rutile blueschist facies, both representing higher pressures than are attained during ordinary low-rank and middle-rank regional metamorphism.

California, Oregon