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Robert B. Halley

Publications and source records attributed to Robert B. Halley.

At least 37 records · Page 2Linked to original sources

Geology and hydrogeology of the Florida Keys

This chapter discusses the geology and hydrogeology of the Florida Keys, and focuses on the islands formed of Pleistocene limestone. These islands, which are crossed when driving from Miami to Key West, are typically regarded as "the Florida Keys." The outstanding and fragile character of ecosystems on and around the Florida Keys has prompted State and Federal efforts to protect and preserve the remaining public portions of the region. The Florida Keys were largely ignored during the sixteenth, seventeenth, and eighteenth centuries, although the waters just offshore provided a major shipping thoroughfare to and from the New World. The Florida Keys are now recognized as one of the great recreational and environmental resources of the United States. The islands are outposts of a laid-back, tropical resort culture that has as its foundation warmth and clear water. A significant part of the attraction is fishing, diving, and boating around the area's coral reefs, which the islands protect. But the reefs were not always so highly valued. The Florida Keys that have protected the reefs for millennia, may now be the source of the agents that may accomplish what Agassiz thought was beyond man's power a century ago.

Florida↗

The stable oxygen and carbon isotopic record from a coral growing in Florida Bay: a 160 year record of climatic and anthropogenic influence

A 160 year record of skeletal δ 13 C and δ 18 O was examined in a specimen of the coral Solenastrea bournoni growing in Florida Bay. Variations in the δ 18 O of the skeleton can be correlated to changes in salinity while changes in the δ 13 C reflect cycling of organic material within the Bay. Based on the correlation between salinity and skeletal δ 18 O, we have concluded that there has been no long term increase in salinity in this area of Florida Bay over the past 160 years. Using salinity correlations between the various basins obtained from instrumental data, we have been able to extend our interpretations to other parts of Florida Bay reaching similar conclusions. In contrast to current ideas which have focused on changes in Florida Bay water quality over the past 20-yr history of the Bay as causative in its decline, we have determined that changes in water quality in this basin were already set in motion between 1905 and 1912 by the construction of the Florida East Coast Railway from Miami to Key West. The construction of the railway resulted in the restriction of the exchange of water between the Florida reef tract and the Gulf of Mexico causing Florida Bay to become more eutrophic. Evidence of this process is observed in the sudden shift to relatively lower δ 13 C values coincident with railway construction. Natural events also appear to have influenced the water in the Bay. Between 1912 and 1948 frequent hurricanes had the effect of increasing exchange of water between the Bay and reef tract and removing large quantities of organic rich sediments. However, since 1948 the number of hurricanes affecting the area has decreased and the products of the oxidation of organic material have been increasingly retained within the basin promoting the initiation of eutrophic conditions.

Florida↗

The south Florida environment: A region under stress

This report provides an overview of the environmental setting in South Florida and serves as review and framework for developing U.S. Geological Survey programs in the region. The report describes the predevelopment and the current (present-day) environmental conditions in South Florida with emphasis on the quantity and quality of water. The geographical area covered is the southern one-half of the State and includes the South Florida National Water-Quality Assessment study area and adjacent coastal waters. This study area covers about 19,500 square miles and is the watershed of the larger regional ecosystem. The regional ecosystem includes the coastal waters between Charlotte Harbor on the Gulf of Mexico and the St. Lucie River on the Atlantic Ocean and the lands that drain into these waters.

Florida↗

Decade-scale trend in sea water salinity revealed through d18O analysis of Montastraea annularis annual growth bands

Stable oxygen isotope ratios (1)180) of coral skeletons are influenced by ambient water temperature and by the oxygen isotope ratio in the surrounding sea water, which, in turn, is linked to evaporation (salinity) and precipitation. To investigate this relationship more thoroughly, we collected hourly temperature data from the Hen and Chickens Reef in the Florida Keys between 1975 and 1988 and compared them to'the 1)180 of Montastraea annularis skeleton that grew during the same interval. To ensure that we obtained the correct oxygen isotopic range in the skeleton we typically sampled the coral at a resolution of 20-30 samples in 1 year; in 1 year we sampled the coral at a resolution of 70 samples·year-'. Despite our high-resolution sampling, we were unable to obtain the full temperature-induced 1)180 range in the skeleton. Our data suggest that, during the summer, evaporation causes isotopic enrichment in the water, partially masking the temperature-induced signal. Our data also show that oxygen isotopic composition of seawater at the reef has increased since 1981. This increase indicates that salinity has increased slightly during the past decade, perhaps as a result of increased evaporation in waters of Florida Bay and the Keys. This phenomenon is probably not caused by a decrease in the outflow of freshwater into Florida Bay from the Everglades but may be related to the measured deficit in precipitation that has occurred over the past decade.

Bulletin of Marine Science↗

Environmental implications of growth rate changes in Montastrea Annularis : Biscayne National Park, Florida

Long-term annual growth rates were determined for 25 Montastrea annularis colonies at eight reef sites in Biscayne National Park, Florida. X-radiographs of slabbed coral cores revealed chronologies that averaged 113.5 years in length with a range of 40 to 242 years. A total of 2,837 annual growth increments were identified and measured. Dating of density bands was verified by visually crossdating fluorescent bands within the coral skeleton. Average accretion rates of individual colonies varied from 5.0 mm·yr −1 in the northernmost sector of the Park to 11.3 mm·yr −1 in the southernmost sector. Long-term growth rates of most corals in this study were greatest prior to about 1950 except for a major, 3–5 year, decline in the growth record of older corals centered around 1878. Waxing and waning coral growth rates are discussed in relation to natural and anthropogenic perturbations that impact this high latitude reef ecosystem. Attention is drawn to nutrients from sewage outfalls as a possible contributing factor to observed growth rate decline since 1950.

Florida↗

Accumulation of bank-top sediment on the western slope of Great Bahama Bank: rapid progradation of a carbonate megabank

High-resolution seismic profiles and submersible observations along the leeward slope of western Great Bahama Bank show large-scale export of bank-top sediment and rapid progradation of the slope during the Holocene. A wedge-shaped sequence, up to 90 m thick, is present along most of the slope and consists of predominantly aragonite mud derived from the bank since flooding of the platform 6-8 ka. Total sediment volume of the slope sequence is 40%-80% that of Holocene sediment currently retained on the bank. Maximum rates of vertical accumulation and lateral progradation are 11-15 m/ka and 80-110 m/ka, respectively: 10 to 100 times greater than previously known for periplatform muds. Slope deposition of exported mud during sea-level highs appears to have been a major mechanism for the westward progradation of Great Bahama Bank throughout the Quaternary; this may provide a critical modern analogue for ancient progradational margins.

Geology↗

Thermal and cementation histories of Permian shelf-edge carbonate rocks in the Nanpanjiang Basin, South China

As of 1984, the Nanpanjiang Basin of South China has had almost no exploration by drilling although oil seeps exist among its margins and producing wells occur in adjacent basins. however, cooperative studies by petroleum geologists and geochemists of the United States and the People's Republic of China (1982-1984) show that calcite-cemented reef and fore-reef carbonate rocks near Ziyun contain bitumen in Upper Permian shelf-edge sediment. the cementation history consists of three episodes: (1)precipitation of syndepositional marine cement (formerly botryoidal aragonnite and fibrous magnesian calcite); (2)precipitation of post-depositional early cement (radiaxial calcite); and (3)precipitation of late burial cement (white calcite spar). Hydrocarbons were introduced into the rocks between cementation episodes 2 and 3. Fluid inclusion analysis of secondary inclusions in the burial cement indicates that the rocks were heated to nearly 200 C after hydrocarbon migration and cementation episode 3. Bitumen remains in the rocks as evidence of the earlier presence of liquid hydrocarbons. During this study, Ordovician through Permian carbonate rocks and Cambrian through Triassic clastic rocks were analyzed for total organic carbon (TOC) vitrinite reflectance (R 0 ), and extractable hydrocarbon (HC) content and composition. Within the basin, TOC values ranged from 0.02% to 3.91%, total HC ranged from 0.004 to 0.11 mg/g, and R 0 values were mostly greater than 2.0%. Previous studies by several groups of scientists in this region have found low TOC values and evidence of overmaturity. Our studies found higher TOC values, but otherwiese confirm the earlier findings. We conclude that portions of the basin have been heated beyond the level of liquid hydrocarbon generation and retention. Although our observations do not favor the occurrence of liquid hydrocarbons in the Paleozoic strata along the western maring of the basin, the possibility of significant gas accumulations in fractured reservoirs or of other hydrocarbon accumulations in the basin cannot be ruled out.

Nanpanjian Basin↗

Strontium-isotope stratigraphy of Enewetak Atoll

87 Sr/ 86 Sr ratios determined for samples from a 350 m core of Neogene lagoonal, shallow-water limestones from Enewetak Atoll display a remarkably informative trend. Like the recently published data for Deep Sea Drilling Project (DSDP) carbonates, 87 Sr/ 86 Sr at Enewetak increases monotonically but not smoothly from the early Miocene to the Pleistocene. The data show intervals of little or no change in 87 Sr/ 86 Sr, punctuated by sharp transitions to lower values toward greater core depths. The sharp transitions correlate with observed solution disconformities caused by periods of subaerial erosion, whereas the intervals of little or no change in 87 Sr/ 86 Sr correspond to intervals of rapid accumulation of shallow-water carbonate sediments. When converted to numerical ages using the published DSDP 590B trend, the best-resolved time breaks are at 282 m (12.3 to 18.2 Ma missing) and 121.6 m (3.0 to 5.3 Ma missing) below the lagoon floor. At Enewetak, Sr isotopes offer a stratigraphic resolution for these shallow-marine Neogene carbonates comparable to that of nannofossil zonation in deep-sea carbonates (0.3-3 m.y.). In addition, the correlation of times of Sr-isotope breaks at Enewetak with times of rapid Sr-isotope change in the DSDP 590B samples confirms the importance off sea-level changes in the evolution of global-marine Sr isotopes and shows that the Sr-isotope response to sea-level falls is rapid.

Geology↗

Source-rock evaluation of outcrop samples from Vanuatu (Malakula, Espiritu Santo, Maewo, and Pentecost)

Thirty-nine outcrop samples of mudstones, siltstones, and limestones were collected for source-rock evaluation of the sedimentary column in Vanuatu. Twenty-nine samples showing the least evidence of oxidation were selected for total organic analysis from the Miocene Matanui Group and Port Sandwich Formation in Malakula, and from the Miocene Ilava, Peteao, and Pelapa Formations in Espiritu Santo. An additional 13 samples from the upper Miocene to Pleistocene sequence in the islands of Maewo and Pentecost were taken from the sample collection stored at the Department of Geology, Mines, and Rural WAter Supplies in Port Vila and analyzed for total organic carbon (T.O.C.). Of the 42 samples analyzed for total organic carbon content, four yielded values above the generally accepted minimum for source rock: three from the Peteao Formation (T.O.C. ranging from 0.52% to 1.44%), and one from the Pelapa Formation (T.O.C. = 0.54%). Rock-Eval pyrolysis on the rocks and reflected light microscopy on the separated organic matter indicate that the organic matter is poor in hydrogen and is dominantly type III kerogen; therefore, it is of a chemical type that does not yield liquid hydrocarbons but may havev limited potential for generating gas. The Rock-Eval pyrolysis and the vitrinite reflectance analysis indicate that the organic matter in these samples is thermally immature. The samples collected for the present study represent only a portion of the sedimentary column in the various sedimentary basins of Vanuatu. The characterize only the outer margins of the sedimentary basins and do not necessarily reflect the source-rock potential of the deeper (offshore) parts of the basins.

Book chapter↗

Occurrence and preservation of Eocene squamariacean and coralline rhodoliths: Eau, Tonga

A widespread rhodolith facies occurs within middle Eocene limestones of Eua, Tonga (Fig. 1). These limestones, first described by Hoffmeister (1932), represent a portion of a broad, early Tertiary platform that developed in the Tonga area prior to disruption and uplift by later Tertiary plate movements (Kroenke and Tongilava 1975). Algal rhodoliths form beds several meters thick within Eocene limestones and occur at localities several kilometers apart along the length of Eua.

Eau↗

Dolomitization in a mixing zone of near-seawater composition, Late Pleistocene, northeastern Yucatan Peninsula

Patches of dolomite occur in cores of reefal limestone from the shallow subsurface on the northeastern coast of the Yucatan Peninsula. This limestone accumulated during an interglacial high stand of sea level about 200,000 years ago. Dolomitization was preceded by freshwater diagenesis, including precipitation of sparry calcite cement, stabilization of Mg-calcitic skeletal fragments, and partial dissolution of aragonitic components. This suggests a predolomitization lowering of sea level with the consequent freshening of pore water. The subsequent precipitation of dolomite indicates a return to high sea level with the consequent increase in Mg/Ca ratio of pore water. Dolomitization took place during a brief high stand of sea level, either shortly after deposition about 200,000 yr BP, or, more likely, about 125,000 yr BP. Dolomite occurs both as microcrystalline replacement dolomite and as cement. The cement is part of the following diagenetic sequence: 1) limpid euhedral-subhedral calcian dolomite crystals, 2) zoned dolomite crystals with zones formed by variations of the calcium/magnesium ratio in dolomite, 3) layers of alternating calcian dolomite and magnesian calcite or calcite, and 4) calcite. This sequence represents the progressive freshening of ground water during the initial stage of a fall in sea level. Average cation composition of the limpid dolomite cement is Ca 57 Mg 43 (electron microprobe analysis). Zoned cement crystals are composed of Ca (sub 57-59) Mg (sub 43-41) layers and Ca 62 Mg 38 layers. Most of the higher-calcium dolomite layers are dissolved, forming hollow-zone crystals. In cement with alternating dolomite and calcite zones, the calcite is Ca (sub 99-97) Mg (sub 1-3) (low-Mg calcite) and Ca (sub 96-93) Mg (sub 4-7) (Mg calcite). The dolomite and Mg calcite zones are partially to totally leached. delta 18 O compositions of Yucatecan dolomite and of modern ground water suggest dolomite precipitation from mixed water ranging from about 75% seawater, 25% freshwater to nearly all seawater. (Isotope analyses are for the most stable calcian dolomites; more soluble, calcium-rich dolomite presumably is analyzed with calcite and thought to be isotopically lighter than the less soluble dolomite.) In the cement sequence, the most stable dolomite is followed by more soluble dolomite as ground water becomes less saline. Isotope analyses, together with position of dolomite in the cement sequence, suggest the most stable calcian dolomite (including limpid dolomite) precipitated from mixed water with large proportions of seawater, and the less stable, more calcian dolomite precipitated from fresher mixed water.

Yucatan Peninsula↗

Selected characteristics of limestone and dolomite reservoirs in the United States

Data from the United States Oil and Gas File (TOTL) developed by the University of Oklahoma, Norman, Oklahoma, are used to characterize the lithology, location (state and basin), geologic age, year of discovery, depth to top of pay, porosity, permeability, water saturation, volume of crude oil and nonassociated gas originally in place, and net-pay thickness of limestone and dolomite reservoirs in the United States. Distributions of these parameters, representing thousands of reservoirs, establish a framework to which individual carbonate reservoirs can be compared, and provide insights into geologic processes affecting reservoir characteristics. Limestone reservoirs are more numerous in the United States than dolomite reservoirs (by a ratio of about 3 to 1) because limestones are more abundant than dolomites. However, in the eight states that account for over 90% of United States carbonate reservoirs, there is a statistical tendency for carbonate reservoirs to occur preferentially in dolomites. Dolomite reservoirs, on the average, are larger and deeper than those of limestone, yet they often have lower matrix porosities and permeabilities. This line of investigation offers supplemental evidence that dolomitization tends to improve the reservoir properties of a given formation, and that effective fracture systems at reservoir depths are more likely to occur in dolomites than in limestones.

American Association of Petroleum Geologists Bulle↗

Alternative diagenetic models for cretaceous talus deposits, Deep Sea Drilling Project Site 536, Gulf of Mexico

Talus deposits recovered from Site 536 show evidence of aragonite dissolution, secondary porosity development, and calcite cementation. Although freshwater diagenesis could account for the petrographic features of the altered talus deposits, it does not uniquely account for isotopic or trace-element characteristics. Also, the hydrologic setting required for freshwater alteration is not easily demonstrated for the Campeche Bank. A mixing-zone model does not account for the available trace-element data, but does require somewhat less drastic assumptions about the size of the freshwater lens. Although a seawater (bottom-water) alteration model requires no hydrologic difficulties, unusual circumstances are required to account for the geochemical characteristics of the talus deposits using this model.

Gulf of Mexico↗

High-porosity Cenozoic carbonate rocks of South Florida: Progressive loss of porosity with depth

Porosity measurements by borehole gravity meter in subsurface Cenozoic carbonates of south Florida reveal an extremely porous mass of limestone and dolomite which is transitional in total pore volume between typical porosity values for modern carbonate sediments and ancient carbonate rocks. A persistent decrease of porosity with depth, similar to that of chalks of the Gulf Coast, occurs in these rocks. We make no attempt to differentiate depositional or diagenetic facies which produce scatter in the porosity-depth relationship; the dominant data trends thus are functions of carbonate rocks in general rather than of particular carbonate facies. Carbonate strata with less than 20% porosity are absent from the rocks studied here. Aquifers and aquicludes cannot be distinguished on the basis of porosity. Although aquifers are characterized by great permeability and well-developed vuggy and even cavernous porosity in some intervals, they are not exceptionally porous when compared to other Tertiary carbonate rocks in south Florida. Permeability in these strata is governed more by the spacial distribution of pore space and matrix than by the total volume of porosity present. Dolomite is as porous as, or slightly less porous than, limestones in these rocks. This observation places limits on any model proposed for dolomitization and suggests that dolomitization does not take place by a simple ion-for-ion replacement of magnesium for calcium. Dolomitization may be selective for less porous limestone, or it may involve the incorporation of significant amounts of carbonate as well as magnesium into the rock. The great volume of pore space in these rocks serves to highlight the inefficiency of early diagenesis in reducing carbonate porosity and to emphasize the importance of later porosity reduction which occurs during the burial or late near-surface history of limestones and dolomites.

Florida↗

Geology and sediment accumulation rates at Carrie Bow Cay, Belize

A 24 km long transect of cores consisting of four rotary drill cores and seven vibrocores was drilled in a line extending from the seaward side of the reef crest at Carrie Bow Cay to the mainland at a point between Sittee Point and the town of Stann Creek. Two of the four rotary cores were drilled seaward of the reef crest, one through a spur to a depth of 7.6 m and the other into the adjacent groove to a depth of 18.3 m. The two cores show no evidence that the spur and groove system was erosional in origin; rather they demonstrate that it was constructional. Submarine cementation, chiefly in the form of fine-grained high-magnesium calcite, was found mainly in cemented internal sediment in both cores drilled seaward of the reef crest. Two other rotary cores were drilled landward of the reef crest. One was drilled on the reef flat to a depth of 8.8 m, and the other was drilled on the southwest tip of Carrie Bow Cay to a depth of 17.7 m. Both cores encountered essentially uncemented carbonate reef sands with some coral rubble. Of the four rotary cores, only the Carrie Bow Cay core encountered Pleistocene bedrock. Radiocarbon dating of a large head of Siderastrea siderea , growing on bedrock from the Carrie Bow Cay core at a depth of 15.04 m below sea level, gave an age of 6960±110 years. The leached calcitic coralline bedrock, at a depth of 15.7 m below sea level in the Carrie Bow Cay core, contained root marks, and iron staining indicative of subaerial exposure.

Carrie Bow Cay↗