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Robert A. Zielinski

Publications and source records attributed to Robert A. Zielinski.

46 records · Page 3Linked to original sources
USGS1980

Uranium in secondary silica: A possible exploration guide

Study of uraniferous silica precipitates in the Shirley Basin, Wyoming, identified areas where ancient uraniferous ground water once ponded. Chalcedony collected from and directly beneath thick accumulations of rhyolite ash contain as much as 250 ppm uranium in a pre-ash topographic low and lesser concentrations (10 to 160 ppm) elsewhere. Differences in the U concentration of chalcedony collected from approximately the same stratigraphic horizon reflect the enrichment of uranium in ground water as it percolated downward and basinward through the overlying rhyolite ash. Uranium is homogeneously distributed as a uranyl species within the chalcedony and reflects coprecipitation of dissolved uranium and colloidal silica in a uraniferous silica-gel. Laboratory measurements of the partitioning of uranium between various solutions and silica-gel precipitates indicate that, for ranges of pH and dissolved carbonate typical of ground water, dried silica-gel contains about 400 to 1,000 times the uranium concentration of the solution from which it forms. Uranium is postulated to be incorporated as an adsorbed uranyl-silica-hydroxyl complex. A 20-m.y.-minimum apparent age for uraniferous chalcedony was obtained by U-Pb isotope dating. Reported minimum ages for nearby sedimentary uranium deposits generally lie between this age and the age of rhyolite which hosts the silica (32.4 + or - 2.6 m.y.). Leaching of uranium from ash during the period 20 to 32 m.y. is therefore compatible with a volcanic source-rock hypothesis.

Wyoming↗
USGS1980

Uranium contents of glassy and devitrified andesites and dacites, Mount Mazama, Oregon

By direct comparison of devitrified and granophyrically crystallized specimens with nonhydrated glassy materials from the same units, Rosholt and coworkers (Rosholt and Noble, 1969; Rosholt et al., 1971) showed that specimens of primarily crystallized but otherwise unaltered peralkaline and subalkaline rhyolite from the western United States had lost from 30 to 80 percent of the uranium that they originally possessed. They suggested that uranium was lost both during crystallization, perhaps as the volatile hexafluoride, and/or later through the action of ground water. Similar results have been obtained by Shatkov et al. (1970) and Kovalev and Maylasova (1973). Zielinski (1978) compared the uranium contents of paired nonhydrated glassy and primarily devitrified phases of a number of subalkaline rhyolitic lavas and tuffs from various localities in the western United States. He found a generally smaller degree of uranium loss than had been observed by Rosholt et al. (1971) for peralkaline materials. In addition, Zielinski noted that older specimens had, as a group, lost a greater percentage of their original uranium than had younger rocks and suggested that uranium is generally lost progressively over periods of many millions of years.

Oregon↗
USGS1979

Uranium mobility during interaction of rhyolitic obsidian, perlite and felsite with alkaline carbonate solution: T = 120° C, P = 210 kg/cm 2

Well-characterized samples of rhyolitic obsidian, perlite and felsite from a single lava flow are leached of U by alkaline oxidizing solutions under open-system conditions. Pressure, temperature, flow rate and solution composition are held constant in order to evaluate the relative importance of differences in surface area and crystallinity. Under the experimental conditions U removal from crushed glassy samples proceeds by a mechanism of glass dissolution in which U and silica are dissolved in approximately equal weight fractions. The rate of U removal from crushed glassy samples increases with decreasing average grain size (surface area). Initial rapid loss of a small component (≈ 2.5%) of the total U from crushed felsite. followed by much slower U loss, reflects variable rates of attack of numerous uranium sites. The fractions of U removed during the experiment ranged from 3.2% (felsite) to 27% (perlite). An empirical method for evaluating the relative rate of U loss from contemporaneous volcanic rocks is presented which incorporates leaching results and rock permeability data.

Chemical Geology↗
USGS1978

Uranium abundances and distribution in associated glassy and crystalline rhyolites of the western United States

The abundance and distribution of uranium have been determined in 11 units of rhyolitic lava and ash-flow tuff of calc-alkaline and transitional composition from the western United States in order to further evaluate the potential of rhyolitic glass as a source of uranium ores. Samples consist of coexisting obsidians, perlites, and felsites that range in age from Pleistocene to Oligocene. Uranium abundances in analyzed obsidians are 5 to 46 ppm. Obsidians and coexisting perlites have identical (±5%) uranium concentrations, which confirms that little or no uranium is lost during hydration. Felsites show uranium depletions as high as 80% relative to coexisting obsidians and perlites. Combination of this data with the results of earlier work on peralkaline rhyolites indicates that uranium depletion seems to increase with age, with different rates of depletion for calc-alkaline (slowest) and peralkaline (fastest) compositions. Uranium distribution is homogeneous in obsidians, perlites, and spherulites, but inhomogeneous in felsites. Electron microprobe analyses of the least-depleted felsites indicate that uranium is associated with concentrations of Fe-Ti-Mn oxides or is in accompanying accessory minerals. Secondary Fe-Mn oxides in older, depleted felsites are uranium-bearing, especially along fractures or flow layers. Uranium loss from felsites seems to be largely controlled by low-temperature solution over long time periods, with some precipitation in secondary phases.

GSA Bulletin↗
USGS1978

Uranium in waters and aquifer rocks at the Nevada Test Site, Nye County, Nevada

Previous chemical, geological, and hydrological information describing the physical and chemical environment of the Nevada Test Site (a Federal reserve for the testing of nuclear explosive devices) has been combined with new radiochemical and isotope data for water and rock samples in order to explain the behavior of uranium during alteration of thick sequences of rhyolitic volcanic rocks and associated volcaniclastic sediments. A model is proposed in which uranium mobility is controlled by two competing processes. Uranium is liberated from the volcanic rocks through dissolution of the glassy constituents and is carried in solution as a uranyl carbonate complex. Uranium is subsequently removed from solution by adsorption on secondary oxides of iron, titanium, and manganese, as observed in fission-track maps of aquifer rocks. The model explains the poor correlation of dissolved uranium with depth within tuffaceous sequences in which percolation of ground water is predominantly downward. Good positive correlation of dissolved uranium with dissolved Na, total dissolved solids, and total carbonate supports the glass dissolution model, while inverse correlation of dissolved uranium with U 234 /U 238 ratios of waters implies uranium is being absorbed by a relatively insoluble, surficial phase. Alpha radioactivity of Test Site water is primarily caused by high U 234 contents, and beta activity is highly correlated with dissolved K (K 40 ). Small amounts of dissolved radium, Pb 210 , and Po 210 are present but no evidence was found for alpha activity sources related to nuclear testing (Pu, U 235 ). A filtered but unacidified carbonate solution of uranium was found to be stable (± 10 percent of original U concentration) for years when stored in acid-washed polyethylene bottles.

Nevada↗
USGS1977

Uranium mobility during interaction of rhyolitic glass with alkaline solutions: dissolution of glass

This report concerns investigations designed to identify the important physical and chemical parameters influencing the rate of release of uranium from glass shards of rhyolitic air-fall ash. Oxidizing, silica undersaturated, alkaline solutions are eluted through a column of rhyolitic glass shards at a carefully controlled temperature, pressure, and flow rate. The solutions are monitored for the concentration of uranium and selected additional elements (Si, K, Li, F), and the glass is recovered and examined for physical and/or chemical evidence of attack. The flushing mode is designed to mimic leaching of glass shards by intermittent, near-surface waters with which the glass is not in equilibrium. Reported rates are applicable only to the experimental conditions (120?C, 7,000 psi), but it is assumed that the reaction mechanisms and the relative importance of rate-influencing parameters remain unchanged, at reduced temperature and pressure. Results of the above experiment indicate that silica and uranium are released from glass shards at comparable rates, while lithium and potassium are released faster and fluorine slower than either Si or U. Rates of release of silica and uranium correlate positively with the surface area of the shards. Rhyolitic shards release uranium at faster rates than rhyodacitic shards of comparable surface area. Changes in the shards resulting from experimental treatment and observed in the original glass separates from an Oligocene ash (compared to a Pleistocene ash) include; surface pitting, increased surface area, devitrification rinds (<1l micron wide) and reduced lithium contents. Future investigations will study the effect of temperature, pressure, solution composition, and flow rate on the relative mobility of U, Si, Li, F, and K.

Open-File Report↗
USGS1976

Trace-element variations at Summer Coon volcano, San Juan Mountains, Colorado, and the origin of continental-interior andesite

The Oligocene Summer Coon center, an eroded continental-interior volcano of the eastern San Juan Mountains, Colorado, was the source of magmas ranging in composition from basaltic andesite to rhyolite. Previous Pb and Sr isotope studies indicate derivation of the magmas from an isotopically homogeneous source. This study presents new data for rare-earth elements (REE), U, Th, Ba, Sr, Rb, and Ni from 10 samples of the Summer Coon sequence. Alkali elements are high in all rocks; as SiO 2 increases, Ba increases from 900 to 2,000 ppm, Rb increases from 35 to 90 ppm, Sr decreases from 900 to 350 ppm, K/Rb decreases slightly, Ba/Sr increases, U increases from 0.5 to 2.5 ppm, and Th increases from 2 to 7 ppm. Chondrite-normalized REE patterns are strongly fractionated in comparison with oceanic-arc andesite-dacite sequences. La is 80 to 120 times chondritic abundance, but Yb and Lu are less than 10 times chondritic abundance. Small negative Eu anomalies characterize the rhyolites. Nickel in the andesites is 40 to 70 ppm. The origin of the andesite is interpreted in terms of nonmodal partial melting of a trace-element—enriched garnet-bearing source, possibly subducted crust that has converted to eclogite. Rhyodacite and rhyolite are interpreted as low-pressure crystal-fractionation products of silicic andesite, in which crystallizing phases are hornblende rich in REE and plagioclase.

Colorado↗
USGS1975

Radiochemical determination of very low concentrations of nickel in rocks and minerals

A radiochemical procedure has been developed for the determination of very low concentrations of nickel in rocks and minerals. Sensitivity is 0.01 μ g Ni. Accuracy and precision is estimated to be ±5 percent to levels as low as 0.1 μ g Ni a marked improvement over other analytical techniques. Samples are irradiated, combined with nickel carrier, and treated by a series of chemical procedures: (1) collection of nickel in a lead bead using a fire-assay technique, (2) refusion of the lead bead and precipitation of basic element hydroxides, (3) anion-exchange chromatography, and (4) precipitation of nickel dimethylglyoxime. The nickel precipitate is weighed to determine chemical yield and counted for β activity of Ni 65 along with a precipitate from irradiated nickel standard solution.

Journal of Research of the U.S. Geological Survey↗
USGS1974

An experimental study of the partitioning of a rare earth element (Gd) in the system diopside—Aqueous vapour

The partitioning of Gd in the experimental system diopside-aqueous vapor as a function of temperature, pressure, composition of the phases, time, grain size, solid-liquid ratio and Gd concentration has been investigated. A radioactive tracer measurement was used to determine Gd concentration in the separated phases. Diposides were reacted with aqueous vapor containing tracer Gd and reversibility was tested by reacting Gd-doped diopsides with pure aqueous vapor. Equilibration of Gd between the bulk of the diopside and the liquid was found to be limited by the slow rate of Gd diffusion in diopside, maximum value of D = 2 × 10 −15 cm 2 sec −1 at 800°C and 1 kb. Depending on whether the diopside was previously synthesized or synthesized from an oxide mix during the experiment, Gd concentrations were zoned in the crystal such that higher concentrations existed at the edges or center, respectively. Equilibrium is difficult to achieve in these experiments, but at the optimum experimental conditions for equilibration, the Gd diopside-aqueous vapor distribution coefficient is 20 ± 6 (800°C, 1 kb) in approximate agreement with previous results of 55 ± 23. Changing the composition of the aqueous vapor indicated that possible mechanisms for Gd substitution included coupling of Gd 3+ with H + or Na + replacing 2Ca 2+ , or substitution of 2Gd 3+ for 3Ca 2+ with formation of a cation vacancy.

Geochimica et Cosmochimica Acta↗