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Richard J. Goldfarb

Publications and source records attributed to Richard J. Goldfarb.

At least 19 recordsLinked to original sources

Formation of orogenic gold deposits by progressive movement of a fault-fracture mesh through the upper crustal brittle-ductile transition zone

Orogenic gold deposits are comprised of complex quartz vein arrays that form as a result of fluid flow along transcrustal fault zones in active orogenic belts. Mineral precipitation in these deposits occurs under variable pressure conditions, but a mechanism explaining how the pressure regimes evolve through time has not previously been proposed. Here we show that extensional quartz veins at the Garrcon deposit in the Abitibi greenstone belt of Canada preserve petrographic characteristics suggesting that the three recognized paragenetic stages formed within different pressure regimes. The first stage involved the growth of interlocking quartz grains competing for space in fractures held open by hydrothermal fluids at supralithostatic pressures. Subsequent fluid flow at fluctuating pressure conditions caused recrystallization of the vein quartz and the precipitation of sulfide minerals through wall-rock sulfidation, with some of the sulfide minerals containing microscopic gold. These pressure fluctuations between supralithostatic to near-hydrostatic conditions resulted in the post-entrapment modification of the fluid inclusion inventory of the quartz. Late fluid flow occurred at near-hydrostatic conditions and resulted in the formation of fluid inclusions that have not been affected by post-entrapment modification as pressure conditions never returned to supralithostatic conditions. This late fluid flow is interpreted to have formed the texturally late, coarse native gold that occurs along quartz grain boundaries and in open spaces. The systematic evolution of the pressure regimes in orogenic gold deposits such as Garrcon can be explained by relative movement of fault-fracture meshes across the base of the upper crustal brittle-ductile transition zone. We conclude that early vein quartz in orogenic deposits is precipitated at near-lithostatic conditions whereas the paragenetically late gold is introduced at distinctly lower pressure.

Scientific Reports

Late Jurassic-Early Cretaceous orogenic gold mineralization in the Klamath Mountains, California: Constraints from 40Ar/39Ar dating of hydrothermal muscovite

The Klamath Mountains gold province is the second most important historical producer in California, having produced more than 7 Moz of gold from both lode and placer sources. Hydrothermal muscovite grains from gold-bearing veins provide the first 40 Ar/ 39 Ar age constraints indicative of a protracted period of mineralization in the Klamath Mountains. The data indicate that the window for orogenic gold mineralization in the Klamath Mountains was from ∼160–140 Ma, coinciding in age with the oldest orogenic gold deposits in the Sierra Nevada foothills province to the south, although mineralization continued in the latter along the Mother Lode belt for another 20–30 million years. Despite the broad age overlap between hydrothermal activity and magmatism, the former relates to a regional thermal event, and there is no genetic link between the two. Instead, a correlation exists between the timing of lode gold formation and discrete tectonic events, changes in stress regime, and fault movement. The maximum age corresponds to a major plate reorganization in the Pacific basin and initial gold mineralization continuing into the Sierra Nevada foothills gold province to the south. The minimum age corresponds to the westerly lateral offset of the Klamath Mountains from the Sierra Nevada and the then-active arc, marking the termination of both magmatism and gold-producing hydrothermal activity in the Klamath Mountains. Lode gold mineralization in the Klamath Mountains is compatible with a crustal source of metals and fluids that were released during metamorphic devolatilization and focused via hydrothermal fluid flow along regional faults.

California

Early Neoproterozoic gold deposits of the Alto Guaporé province, southwestern Amazon craton, western Brazil

The Alto Guaporé gold province, southwestern Amazon craton, contains gold deposits that have been mined since the beginning of the 18th century and these deposits, together, have modern-day, pre-mining gold resources of at least 1.8 Moz. The ore is associated with quartz vein systems along the southeastern part of the Aguapei belt, a ~35-km-wide and ~500-km-long, NNW-trending shear zone formed due to reactivation of a terrane-bounding suture. The Aguapei belt evolved by ca. 1150 to 1100 Ma rifting and deposition of siliciclastic sediments in an aulacogen basin, followed by deformation and low-grade metamorphism of the sedimentary sequences during 1100 to 900 Ma terrane collision along the craton margin. The deformation was characterized by a compressional regime until ca. 950 Ma and transition to a transpressional setting during the final 50 m.y. The gold deposits are hosted in a variety of structures that are second-order to the main Aguapei shear zone. The Ernesto and Pau-a-Pique deposits are located ~40 km apart and at jogs along the Aguapei belt. They are marginal to pre-ore igneous rocks, with Ernesto hosted in the basal part of the metasedimentary Fortuna Formation that overlies tonalite and Pau-a-Pique at the contact between metasedimentary rocks and diorite. Three deformational phases comprise the compressional (D 1 to D 2 ) to transpressional (D 3 ) tectonic events. In the Pau-a-Pique deposit and the deeper level of the Ernesto deposit, the ore-bearing veins are bedding parallel and follow D 2 strike-slip and reverse fault zones, respectively. However, the veins formed during D 3 reactivation of the older structures by an array of oblique accommodation faults. In contrast, ores at shallower levels of Ernesto, both in discordant and bedding-parallel veins, are hosted within a ~20-m-thick rigid metaconglomerate with associated dilation due to the structural complexity as sedimentary rocks of the Aguapei Group were folded around the dome-shaped roof of the pre-ore tonalite. The ores in both deposits, as well as in many other deposits of the province, are characterized by disseminated and vein-hosted pyrite. Gold occurs mainly as inclusions in the pyrite, with other hydrothermal phases comprising muscovite, Fe-Ti oxides, and minor apatite, chalcopyrite, and galena. Fluid inclusion data, coupled with stable isotope geochemistry and geothermometry, indicate that gold precipitated from a low-salinity, CO 2 -rich fluid at ~300°C and ~2.5 kbar. The source for the fluid and gold was the interbedded pelites during devolatilization of the Aguapei Group sequence. The aqueous-carbonic fluid inclusions and the narrow range of δ 18 O values of quartz (12 ± 1 ‰ ) from many auriferous veins from the central part of the province represent a regional ore-forming fluid. The broad range of δ D for hydrous minerals (–116 to –55 ‰ ) reflects influx of small amounts of meteoric water into the steeply dipping shear zones during postgold exhumation. The 40 Ar/ 39 Ar geochronology from hydrothermal muscovite indicates a widespread hydrothermal event along the belt between 928 and 920 Ma. Collectively, the geological, geochronological, and geochemical data suggest that metamorphic fluids migrated laterally into and then upward along the Aguapei belt and deposited gold in lower-order structures where strain gradients existed between lithounits. The province has many characteristics of large orogenic gold provinces worldwide and represents a highly prospective and underexplored target region for early Neoproterozoic gold, a time period that generally is not well endowed in gold ores.

Alto Guaporé gold province, Amazon craton

Structural evolution of a gold-bearing transtensional zone within the Archean Porcupine-Destor deformation zone, southern Abitibi greenstone belt, eastern Ontario, Canada

The Garrison camp comprises four structurally distinct orogenic gold deposits that formed in different host lithologies during progressive deformation. Detailed field mapping, drill core logging, and geochronological constraints suggest that the 2678 ± 2 Ma Garrison granitic stock played a fundamental rheological role in the location of the four deposits. Initial local shear movement occurred along the southwestern margin of the stock leading to the development of the NW-trending sinistral NE-side-up Buffonta shear zone, which hosts the Buffonta deposit. Subsequently, a transtensional zone formed between the NE-trending sinistral Porcupine-Destor and Munro deformation zones, which host the 903 and Jonpol deposits, respectively. Finally, a local change in shortening orientation from NE to NNW caused westerly directed extension resulting in the formation of the younger gold-bearing veins composing the Garrcon deposit. In situ U-Pb laser ablation-inductively coupled plasma-mass spectrometry performed on monazite grains formed within the shear fabric of the Munro deformation zone indicates that transtension occurred at 2657 ± 15 Ma. Therefore, at least three of the four deposits formed subsequent to crystallization of the Garrison granitic stock. The reported U-Pb dates represent the first direct age constraints on the movement along a gold-bearing deformation zone in the southern Abitibi greenstone belt.

Ontario

Tellurium

Tellurium (Te) is a very rare element that averages only 3 parts per billion in Earth’s upper crust. It shows a close association with gold and may be present in orebodies of most gold deposit types at levels of tens to hundreds of parts per million. In large-tonnage mineral deposits, such as porphyry copper and seafloor volcanogenic massive sulfide deposits, sulfide minerals may contain hundreds of parts per million tellurium, although the orebodies likely have overall concentrations of 0.1 to 1.0 parts per million tellurium. Tellurium is presently recovered as a primary ore from only two districts in the world; these are the gold-tellurium epithermal vein deposits located adjacent to one another at Dashuigou and Majiagou (Sichuan Province) in southwestern China, and the epithermal-like mineralization at the Kankberg deposit in the Skellefteå VMS district of Västerbotten County, Sweden. Combined, these two groups of deposits account for about 15 percent (about 70 metric tons) of the annual global production of between 450 and 470 metric tons of tellurium. Most of the world’s tellurium, however, is produced as a byproduct of the mining of porphyry copper deposits. These deposits typically yield concentrations of 1 to 4 percent tellurium in the anode slimes recovered during copper refining. Present production of tellurium from the United States is solely from the anode slimes at ASARCO LLC’s copper refinery in Amarillo, Texas, and may total about 50 metric tons per year. The main uses of tellurium are in photovoltaic solar cells and as an additive to copper, lead, and steel alloys in various types of machinery. The environmental data available regarding the mining of tellurium are limited; most concerns to date have focused on the more-abundant metals present in the large-tonnage deposits from which tellurium is recovered as a byproduct. Global reserves of tellurium are estimated to be 24,000 metric tons, based on the amount of tellurium likely contained in global copper reserves and on a 50 percent recovery rate from refinery anode slimes during the commonly used electrolytic process, also known as solvent extraction-electrolytic refining. If the more economical solvent-leach process—a process that does not recover tellurium—is increasingly used in the future to recover lower grades of copper from porphyry and other large-tonnage deposits, then additional high-grade tellurium-rich gold deposits may become new primary sources for tellurium, particularly epithermal vein deposits associated with alkaline magmatism.

Professional Paper

The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

It is quite evident that it is not anomalous metal transport, nor unique depositional conditions, nor any single factor at the deposit scale, that dictates whether a mineral deposit becomes a giant or not. A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments. For giant orogenic, intrusion-related gold systems (IRGS) and Carlin-type gold deposits and iron oxide-copper-gold (IOCG) deposits, there are common factors among all of these at the lithospheric to crustal scale. All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or, in the case of most Phanerozoic orogenic giants, define the primary suture zones between tectonic terranes. Giant provinces of IRGS, IOCG, and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province. The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids, whereas the association of such melts with Carlin-type ores is more indirect and enigmatic. Giant orogenic gold provinces show no direct relationship to such magmatism, forming from metamorphic fluids, but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures. In contrast to their province scale similarities, the different giant gold deposit styles show contrasting critical controls at the district to deposit scale. For orogenic gold deposits, the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits, with resultant geometrical and lithostratigraphic complexity as a guide to their location. There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits, and those few giants are essentially preservational exceptions. Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks, enriched in syngenetic gold, to be located below an impermeable cap along antiformal “trends”. Hydrocarbons probably played an important role in concentrating metal. The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock. All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources, partly due to economic factors for this relatively poorly understood, low Cu-Au grade deposit type. The supergiant Olympic Dam deposit, the most shallowly formed deposit among the larger IOCGs, probably owes its origin to eruption of volatile-rich hybrid magma at surface, with formation of a large maar and intense and widespread brecciation, alteration and Cu-Au-U deposition in a huge rock volume.

Geoscience Frontiers

Paleozoic magmatism and porphyry Cu-mineralization in an evolving tectonic setting in the North Qilian Orogenic Belt, NW China

The NWW-striking North Qilian Orogenic Belt records the Paleozoic accretion–collision processes in NW China, and hosts Paleozoic Cu–Pb–Zn mineralization that was temporally and spatially related to the closure of the Paleo Qilian-Qinling Ocean. The Wangdian Cu deposit is located in the eastern part of the North Qilian Orogenic Belt, NW China. Copper mineralization is spatially associated with an altered early Paleozoic porphyritic granodiorite, which intruded tonalites and volcaniclastic rocks. Alteration zones surrounding the mineralization progress outward from a potassic to a feldspar-destructive phyllic assemblage. Mineralization consists mainly of quartz-sulfide stockworks and disseminated sulfides, with ore minerals chalcopyrite, pyrite, molybdenite, and minor galena and sphalerite. Gangue minerals include quartz, orthoclase, biotite, sericite, and K-feldspar. Zircon LA-ICPMS U–Pb dating of the ore-bearing porphyritic granodiorite yielded a mean 206 Pb/ 238 U age of 444.6 ± 7.8 Ma, with a group of inherited zircons yielding a mean U–Pb age of 485 ± 12 Ma, consistent with the emplacement age (485.3 ± 6.2 Ma) of the barren precursor tonalite. Rhenium and osmium analyses of molybdenite grains returned model ages of 442.9 ± 6.8 Ma and 443.3 ± 6.2 Ma, indicating mineralization was coeval with the emplacement of the host porphyritic granodiorite. Rhenium concentrations in molybdenite (208.9–213.2 ppm) suggest a mantle Re source. The tonalities are medium-K calc-alkaline. They are characterized by enrichment of light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), depletion of heavy rare-earth elements (HREEs) and high-field-strength elements (HFSEs), and minor negative Eu anomalies. They have ε Hf ( t ) values in the range of +3.6 to +11.1, with two-stage Hf model ages of 0.67–1.13 Ga, suggesting that the ca. 485 Ma barren tonalites were products of arc magmatism incorporating melts from the mantle wedge and the lithosphere. In contrast, the 40-m.y.-younger ore-bearing porphyritic granodiorite is sub-alkaline and peraluminous. They are enriched in LREEs and LILEs, depleted in HFSEs, and show weak negative Eu anomalies. They display ε Hf ( t ) values of captured or inherited zircons in the range of +8.5 to +10.0, and younger two-stage Hf model ages of 0.78 Ga and 0.86 Ga, similar to those of ca. 485 Ma tonalite. The ca. 445 Ma zircons have ε Hf ( t ) values of −2.1 to +9.9, with two-stage Hf model ages of 0.75–1.27 Ga. Moreover, they have relatively high oxygen fugacity than that of the precursor barren tonalite. The ca. 445 Ma magmas at Wangdian thus formed in a subduction setting, and incorporated melts from the subduction-modified lithosphere that had previously been enriched by additions of chalcophile and siderophile element-rich materials by the earlier magmatism and metasomatism during the Paleo Qilian-Qinling Ocean subduction event.

North Qilian Orogenic Belt

Critical elements in Carlin, epithermal, and orogenic gold deposits

Carlin, epithermal, and orogenic gold deposits, today mined almost exclusively for their gold content, have similar suites of anomalous trace elements that reflect similar low-salinity ore fluids and thermal conditions of metal transport and deposition. Many of these trace elements are commonly referred to as critical or near-critical elements or metals and have been locally recovered, although typically in small amounts, by historic mining activities. These elements include As, Bi, Hg, In, Sb, Se, Te, Tl, and W. Most of these elements are now solely recovered as by-products from the milling of large-tonnage, base metal-rich ore deposits, such as porphyry and volcanogenic massive sulfide deposits. A combination of dominance of the world market by a single country for a single commodity and a growing demand for many of the critical to near-critical elements could lead to future recovery of such elements from select epithermal, orogenic, or Carlin-type gold deposits. Antimony continues to be recovered from some orogenic gold deposits and tellurium could potentially be a primary commodity from some such deposits. Tellurium and indium in sphalerite-rich ores have been recovered in the past and could be future commodities recovered from epithermal ores. Carlin-type gold deposits in Nevada are enriched in and may be a future source for As, Hg, Sb, and/or Tl. Some of the Devonian carbonaceous host rocks in the Carlin districts are sufficiently enriched in many trace elements, including Hg, Se, and V, such that they also could become resources. Thallium may be locally enriched to economic levels in Carlin-type deposits and it has been produced from Carlin-like deposits elsewhere in the world (e.g., Alsar, southern Macedonia; Lanmuchang, Guizhou province, China). Mercury continues to be recovered from shallow-level epithermal deposits, as well as a by-product of many Carlin-type deposits where refractory ore is roasted to oxidize carbon and pyrite, and mercury is then captured in air pollution control devices.

Book chapter

Mineral deposits and metallogeny of Alaska

Alaska, the largest State within the United States, and mainly located north of latitude 60°, is an important part of the Circum-Arctic region. Alaska is a richly endowed region with a long and complex geologic history. The mining history is short by world standards but nevertheless there are a number of world-class deposits in Alaska, of which Red Dog and Pebble are among the largest of their respective types in the world. Alaska is a collection of geologic terranes or regions having distinct histories, most of which were tectonically assembled in the period from 400 million years to 50 million years ago (late Paleozoic through early Tertiary). They now occur as numerous fault-bounded blocks in the northernmost part of the North American Cordillera on the western margin of the Laurentian craton. These terranes are comprised of rocks ranging in age from Paleoproterozoic to Recent.

Alaska

Rare earth element deposits in China

China is the world’s leading rare earth element (REE) producer and hosts a variety of deposit types. Carbonatite- related REE deposits, the most significant deposit type, include two giant deposits presently being mined in China, Bayan Obo and Maoniuping, the first and third largest deposits of this type in the world, respectively. The carbonatite-related deposits host the majority of China’s REE resource and are the primary supplier of the world’s light REE. The REE-bearing clay deposits, or ion adsorption-type deposits, are second in importance and are the main source in China for heavy REE resources. Other REE resources include those within monazite or xenotime placers, beach placers, alkaline granites, pegmatites, and hydrothermal veins, as well as some additional deposit types in which REE are recovered as by-products. Carbonatite-related REE deposits in China occur along craton margins, both in rifts (e.g., Bayan Obo) and in reactivated transpressional margins (e.g., Maoniuping). They comprise those along the northern, eastern, and southern margins of the North China block, and along the western margin of the Yangtze block. Major structural features along the craton margins provide first-order controls for REE-related Proterozoic to Cenozoic carbonatite alkaline complexes; these are emplaced in continental margin rifts or strike-slip faults. The ion adsorption-type REE deposits, mainly situated in the South China block, are genetically linked to the weathering of granite and, less commonly, volcanic rocks and lamprophyres. Indosinian (early Mesozoic) and Yanshanian (late Mesozoic) granites are the most important parent rocks for these REE deposits, although Caledonian (early Paleozoic) granites are also of local importance. The primary REE enrichment is hosted in various mineral phases in the igneous rocks and, during the weathering process, the REE are released and adsorbed by clay minerals in the weathering profile. Currently, these REE-rich clays are primarily mined from open-pit operations in southern China. The complex geologic evolution of China’s Precambrian blocks, particularly the long-term subduction of ocean crust below the North and South China blocks, enabled recycling of REE-rich pelagic sediments into mantle lithosphere. This resulted in the REE-enriched nature of the mantle below the Precambrian cratons, which were reactivated and thus essentially decratonized during various tectonic episodes throughout the Proterozoic and Phanerozoic. Deep fault zones within and along the edges of the blocks, including continental rifts and strike-slip faults, provided pathways for upwelling of mantle material.

Book chapter

Application of U-Th-Pb phosphate geochronology to young orogenic gold deposits: New age constraints on the formation of the Grass Valley gold district, Sierra Foothills province, California

The Grass Valley orogenic gold district in the Sierra Nevada foothills province, central California, the largest historic gold producer of the North American Cordillera, comprises both steeply dipping east-west (E-W) veins located along lithologic contacts in accreted ca. 300 and 200 Ma oceanic rocks and shallowly dipping north-south (N-S) veins hosted by the Grass Valley granodiorite; the latter have yielded about 70 percent of the 13 million ounces of historic lode gold production in the district. The oceanic host rocks were accreted to the western margin of North America between 200 and 170 Ma, metamorphosed to greenschist and amphibolite facies, and uplifted between 175 and 160 Ma. Large-scale magmatism in the Sierra Nevada occurred between 170-140 Ma and 120-80 Ma, with the Grass Valley granodiorite being emplaced during the older episode of magmatism. Uranium-lead isotopic dating of hydrothermal xenotime yielded the first absolute age of 162&plusmn;5 Ma for the economically more significant N-S veins. The vein-hosted xenotime, as well as associated monazite, are unequivocally of hydrothermal origin as indicated by textural and chemical characteristics, including grain shape, lack of truncated growth banding, lack of a Eu anomaly, and low U and Th concentrations. Furthermore, the crack-seal texture of the veins, with abundant wallrock slivers, suggests their formation as a result of episodic fluid flow possibly related to reoccurring seismic events, rather than a period of fluid exsolution from an evolving magma. The N-S veins are temporally distinct from a younger 153-151 Ma gold event that was previously reported for the E-W veins. Overlapping U-Pb zircon (159.9&plusmn;2.2 Ma) and 40Ar/39Ar biotite and hornblende (159.7&plusmn;0.6 to 161.9&plusmn;1.4 Ma) ages and geothermobarometric calculations indicate that the Grass Valley granodiorite was emplaced at ca. 160 Ma at elevated temperatures (~800&deg;C) within approximately 3 km of the paleosurface and rapidly cooled to the ambient temperature of the surrounding country rocks (<300&deg;C). The age of the granodiorite is indistinguishable from that of the N-S veins, as recorded by the U-Pb age of xenotime in those veins. Consequently, the N-S veins must have formed between 162 and 157 Ma, the maximum permissive age of magma emplacement and the youngest permissive xenotime U-Pb age, respectively, during an E- to ENE-directed compressional regime. The geochemistry of the Grass Valley granodiorite is consistent with it being the product of arc magmatism. It served as a receptive host for mineralization, but it is has no direct genetic relationship to gold mineralization. Initial uplift of the intrusive mass correlates with the initial voluminous fluid flow event and vein formation at depths of no greater than 3 km. The E-W gold-bearing veins hosted within greenschist-facies country rocks adjacent to the intrusion formed during a second hydrothermal event 5-10 million years later than the magmatism and were contemporaneous with a shift to a transtensional deformation denoted by sinistral strike-slip faulting.

California

Tellurium: providing a bright future for solar energy

Tellurium is one of the least common elements on Earth. Most rocks contain an average of about 3 parts per billion tellurium, making it rarer than the rare earth elements and eight times less abundant than gold. Grains of native tellurium appear in rocks as a brittle, silvery-white material, but tellurium more commonly occurs in telluride minerals that include varied quantities of gold, silver, or platinum. Tellurium is a metalloid, meaning it possesses the properties of both metals and nonmetals. Tellurium was discovered within gold ores in the late 1780s in Transylvania, Romania. Fifteen years later, the element was isolated as a distinct substance and named tellurium, after the Latin word &ldquo;tellus,&rdquo; which means &ldquo;fruit of the Earth.&rdquo; Recovered tellurium has historically been used in metallurgy as an additive to stainless steel and in alloys made with copper, lead, and iron. Because of its low abundance, little is known about environmental baseline concentrations for tellurium or its toxic effect on humans and ecosystems. Human exposure to tellurium can lead to a garlic odor on the breath, nausea, and eventual respiratory problems.

Fact Sheet

Geochemistry of hydrothermal alteration at the Qolqoleh gold deposit, northern Sanandaj–Sirjan metamorphic belt, northwestern Iran: Vectors to high-grade ore bodies

The Qolqoleh orogenic gold deposit in the northern part of the Sanandaj–Sirjan metamorphic belt in northwestern Iran is hosted by a steeply dipping sequence of greenschist facies Cretaceous volcano–sedimentary rocks, including mafic to intermediate metavolcanic rocks, sericite and chlorite schist, and marble. Geochemical and petrochemical data including the ∑ REE, (La/Yb) N and Eu/Eu* ratios were obtained from country rocks, ore-enveloping alteration zones, and mineralized zones to assess the nature of the trace element and rare earth element (REE) interaction between the wall rock and the mineralizing fluid. Quartz–sulfide veins at the deposit are characterized by a pyrite–pyrrhotite–chalcopyrite–sphalerite–arsenopyrite–native gold assemblage. Alteration halos border the mineralized zones and broadly comprise: (1) an outer carbonate–chlorite alteration zone in all rock types, particularly in chlorite schist; (2) a middle sericite–carbonate alteration zone in the sericite schist; and (3) an inner quartz–sulfide alteration zone in sericite schist and mafic to intermediate metavolcanic rocks. The geochemical data indicate that the concentrations of Al 2 O 3 , P 2 O 5 , TiO 2 , Y, and Zr are relatively constant, suggesting that these elements were the least mobile during hydrothermal activity. Using Al 2 O 3 as the immobile component, there is evidence for mobility of trace elements, particularly light REE, TiO 2 , and Zr in the altered wall rocks. The altered rocks show a relatively light REE depletion ((La/Yb) N ≅ 9.41), which clearly correlates with the grades of gold mineralization and intensity of the alteration (3 ppm Au). The depletion of light REE is best indicated by a decrease in (La/Yb) N as shown by ratios of 10.5 to 11.8. Wall rock decarbonation reactions during infiltration of the mineralizing fluid resulted in differential mobilization of REE, from a fluid with initially low REE content. The overall trace element geochemistry of the altered wall rock is controlled by the initial composition of the wall rocks and the ore-fluid composition. Hydrothermal ore-forming fluids are recognized as CO 2 -rich near-neutral reduced fluids with high values of H 2 S, K, and S content. Observed variability in alteration halos at the Qolqoleh deposit points to major differences in REE and trace element content in original host rocks that have interacted with a relatively similar ore fluid. Therefore, depending on the composition of each host rock lithology, the geochemistry of hydrothermal alteration (e.g., ∑ REE content and (La/Yb) N ratios) and alteration mineralogy including the carbonate–sericite–quartz–sulfide assemblages may be used as a primary tool for lithogeochemical exploration for gold deposits in northwestern Iran.

Journal of Geochemical Exploration

Phanerozoic continental growth and gold metallogeny of Asia

The Asian continent formed during the past 800 m.y. during late Neoproterozoic through Jurassic closure of the Tethyan ocean basins, followed by late Mesozoic circum-Pacific and Cenozoic Himalayan orogenies. The oldest gold deposits in Asia reflect accretionary events along the margins of the Siberia, Kazakhstan, North China, Tarim–Karakum, South China, and Indochina Precambrian blocks while they were isolated within the Paleotethys and surrounding Panthalassa Oceans. Orogenic gold deposits are associated with large-scale, terrane-bounding fault systems and broad areas of deformation that existed along many of the active margins of the Precambrian blocks. Deposits typically formed during regional transpressional to transtensional events immediately after to as much as 100 m.y. subsequent to the onset of accretion or collision. Major orogenic gold provinces associated with this growth of the Asian continental mass include: (1) the ca. 750 Ma Yenisei Ridge, ca. 500 Ma East Sayan, and ca. 450–350 Ma Patom provinces along the southern margins of the Siberia craton; (2) the 450 Ma Charsk belt of north-central Kazakhstan; (3) the 310–280 Ma Kalba belt of NE Kazakhstan, extending into adjacent NW Xinjiang, along the Siberia–Kazakhstan suture; (4) the ca. 300–280 Ma deposits within the Central Asian southern and middle Tien Shan (e.g., Kumtor, Zarmitan, Muruntau), marking the closure of the Turkestan Ocean between Kazakhstan and the Tarim–Karakum block; (5) the ca. 190–125 Ma Transbaikal deposits along the site of Permian to Late Jurassic diachronous closure of the Mongol–Okhotsk Ocean between Siberia and Mongolia/North China; (6) the probable Late Silurian–Early Devonian Jiagnan belt formed along the margin of Gondwana at the site of collision between the Yangtze and Cathaysia blocks; (7) Triassic deposits of the Paleozoic Qilian Shan and West Qinling orogens along the SW margin of the North China block developed during collision of South China; and (8) Jurassic(?) ores on the margins of the Subumusu block in Myanmar and Malaysia. Circum-Pacific tectonism led to major orogenic gold province formation along the length of the eastern side of Asia between ca. 135 and 120 Ma, although such deposits are slightly older in South Korea and slightly younger in the Amur region of the Russian Southeast. Deformation related to collision of the Kolyma–Omolon microcontinent with the Pacific margin of the Siberia craton led to formation of 136–125 Ma ores of the Yana–Kolyma belt (Natalka, Sarylakh) and 125–119 Ma ores of the South Verkhoyansk synclinorium (Nezhdaninskoe). Giant ca. 125 Ma gold provinces developed in the Late Archean uplifted basement of the decratonized North China block, within its NE edge and into adjacent North Korea, in the Jiaodong Peninsula, and in the Qinling Mountains. The oldest gold-bearing magmatic–hydrothermal deposits of Asia include the ca. 485 Ma Duobaoshan porphyry within a part of the Tuva–Mongol arc, ca. 355 Ma low-sulfidation epithermal deposits (Kubaka) of the Omolon terrane accreted to eastern Russia, and porphyries (Bozshakol, Taldy Bulak) within Ordovican to Early Devonian oceanic arcs formed off the Kazakhstan microcontinent. The Late Devonian to Carboniferous was marked by widespread gold-rich porphyry development along the margins of the closing Ob–Zaisan, Junggar–Balkhash, and Turkestan basins (Amalyk, Oyu Tolgoi); most were formed in continental arcs, although the giant Oyu Tolgoi porphyry was part of a near-shore oceanic arc. Permian subduction-related deformation along the east side of the Indochina block led to ca. 300 Ma gold-bearing skarn and disseminated gold ore formation in the Truong Son fold belt of Laos, and along the west side to ca. 250 Ma gold-bearing skarns and epithermal deposits in the Loei fold belt of Laos and Thailand. In the Mesozoic Transbaikal region, extension along the basin margins subsequent to Mongol–Okhotsk closure was associated with ca. 150–125 Ma formation of important auriferous epithermal (Balei), skarn (Bystray), and porphyry (Kultuminskoe) deposits. In northeastern Russia, Early Cretaceous Pacific margin subduction and Late Cretaceous extension were associated with epithermal gold-deposit formation in the Uda–Murgal (Julietta) and Okhotsk–Chukotka (Dukat, Kupol) volcanic belts, respectively. In southeastern Russia, latest Cretaceous to Oligocene extension correlates with other low-sulfidation epithermal ores that formed in the East Sikhote–Alin volcanic belt. Other extensional events, likely related to changing plate dynamics along the Pacific margin of Asia, relate to epithermal–skarn–porphyry districts that formed at ca. 125–85 Ma in northeastmost China and ca. 105–90 Ma in the Coast Volcanic belt of SE China. The onset of strike slip along a part of the southeastern Pacific margin appears to correlate with the giant 148–135 Ma gold-rich porphyry–skarn province of the lower and middle Yangtze River. It is still controversial as to whether true Carlin-like gold deposits exist in Asia. Those deposits that most closely resemble the Nevada (USA) ores are those in the Permo-Triassic Youjiang basin of SW China and NE Vietnam, and are probably Late Triassic in age, although this is not certain. Other Carlin-like deposits have been suggested to exist in the Sepon basin of Laos and in the Mongol–Okhotsk region (Kuranakh) of Transbaikal.

Gondwana Research

40 Ar/ 39 Ar geochronological constraints on the formation of the Dayingezhuang gold deposit: New implications for timing and duration of hydrothermal activity in the Jiaodong gold province, China

China's largest gold resource is located in the highly endowed northwestern part of the Jiaodong gold province. Most gold deposits in this area are associated with the NE- to NNE-trending shear zones on the margins of the 130&ndash;126 Ma Guojialing granite. These deposits collectively formed at ca. 120 &plusmn; 5 Ma during rapid uplift of the granite. The Dayingezhuang deposit is a large (> 120 t Au) orogenic gold deposit in the same area, but located along the eastern margin of the Late Jurassic Linglong Metamorphic Core Complex. New 40 Ar/ 39 Ar geochronology on hydrothermal sericite and muscovite from the Dayingezhuang deposit indicate the gold event is related to evolution of the core complex at 130 &plusmn; 4 Ma and is the earliest important gold event that is well-documented in the province. The Dayingezhuang deposit occurs along the Linglong detachment fault, which defines the eastern edge of the ca. 160&ndash;150 Ma Linglong granite&ndash;granodiorite massif. The anatectic rocks of the massif were rapidly uplifted, at rates of at least 1 km/m.y. from depths of 25&ndash;30 km, to form the metamorphic core complex. The detachment fault, with Precambrian metamorphic basement rocks in the hangingwall and the Linglong granitoids and migmatites in the footwall, is characterized by early mylonitization and a local brittle overprinting in the footwall. Gold is associated with quartz&ndash;sericite&ndash;pyrite&ndash;K-feldspar altered footwall cataclasites at the southernmost area of the brittle deformation along the detachment fault. Our results indicate that there were two successive, yet distinct gold-forming tectonic episodes in northwestern Jiaodong. One event first reactivated the detachment fault along the edge of the Linglong massif between 134 and 126 Ma, and then a second reactivated the shears along the margins of the Guojialing granite. Both events may relate to a component of northwest compression after a middle Early Cretaceous shift from regional NW&ndash;SE extension to a NE&ndash;SW extensional regime.

Gondwana Research

Tectonic setting of the pebble and other copper-gold-molybdenum porphyry deposits within the evolving middle cretaceous continental margin of Northwestern North America

The Pebble Cu-Au-Mo deposit in southwestern Alaska, containing the largest gold resource of any known porphyry in the world, developed in a tectonic setting significantly different from that of the present-day. It is one of a series of metalliferous middle Cretaceous porphyritic granodiorite, quartz monzonite, and diorite bodies, evolved from lower crust and metasomatized lithospheric mantle melts, which formed along much of the length of the North American craton suture with the Peninsular-Alexander-Wrangellia arc. The porphyry deposits were emplaced within the northernmost two of a series of ca. 130 to 80 Ma flysch basins that define the suture, as well as into arc rocks immediately seaward of the two basins. Deposits include the ca. 100 to 90 Ma Pebble, Neacola, and other porphyry prospects along the Kahiltna basin-Peninsula terrane boundary, and the ca. 115 to 105 Ma Baultoff, Carl Creek, Horsfeld, Orange Hill, Bond Creek, and Chisna porphyries along the Nutzotin basin-Wrangellia terrane boundary. The porphyry deposits probably formed along the craton margin more than 1,000 km to the south of their present latitude. Palinspastic reconstructions of plate kinematics from this period are particularly difficult because magmatism overlaps the 119 to 83 Ma Cretaceous Normal Superchron, a period when sea-floor magnetic data are lacking. Our favored scenario is that ore formation broadly overlaps the cessation of sedimentation and contraction and the transition to a transpressional continental margin regime, such that the remnant ocean basins were converted to strike-slip basins. The basins and outboard Peninsular-Alexander-Wrangellia composite superterrane, which are all located seaward of the deep crustal Denali-Farewell fault system, were subjected to northerly dextral transpression for as long as perhaps 50 m.y., beginning at ca. 95 ± 10 Ma. The onset of this transpression was marked by development of the mineralized bodies along fault segments on the seaward side of the basins. Geochemical and radiogenic isotopic data for igneous rocks associated with the Pebble porphyry deposit suggest continuous melt derivation from enriched lithosphere of a recently metasomatized mantle. These geochemical characteristics, coupled with the arc-continent-related collisional setting, suggest that lithospheric thickening and postcollisional lithospheric melting are the most likely cause of the ore-related magmatism. Subsequent to translation of the Alaskan margin terranes and early Tertiary oroclinal bending of Alaska, the northernmost Kahiltna basin and the Pebble deposit, as well as the other porphyry systems, reached their present-day locations along southern Alaska.

Alaska, Yukon

The dilemma of the Jiaodong gold deposits: Are they unique?

The ca. 126–120 Ma Au deposits of the Jiaodong Peninsula, eastern China, define the country's largest gold province with an overall endowment estimated as >3000 t Au. The vein and disseminated ores are hosted by NE- to NNE-trending brittle normal faults that parallel the margins of ca. 165–150 Ma, deeply emplaced, lower crustal melt granites. The deposits are sited along the faults for many tens of kilometers and the larger orebodies are associated with dilatational jogs. Country rocks to the granites are Precambrian high-grade metamorphic rocks located on both sides of a Triassic suture between the North and South China blocks. During early Mesozoic convergent deformation, the ore-hosting structures developed as ductile thrust faults that were subsequently reactivated during Early Cretaceous “Yanshanian” intracontinental extensional deformation and associated gold formation. Classification of the gold deposits remains problematic. Many features resemble those typical of orogenic Au including the linear structural distribution of the deposits, mineralization style, ore and alteration assemblages, and ore fluid chemistry. However, Phanerozoic orogenic Au deposits are formed by prograde metamorphism of accreted oceanic rocks in Cordilleran-style orogens. The Jiaodong deposits, in contrast, formed within two Precambrian blocks approximately 2 billion years after devolatilization of the country rocks, and thus require a model that involves alternative fluid and metal sources for the ores. A widespread suite of ca. 130–123 Ma granodiorites overlaps temporally with the ores, but shows a poor spatial association with the deposits. Furthermore, the deposit distribution and mineralization style is atypical of ores formed from nearby magmas. The ore concentration requires fluid focusing during some type of sub-crustal thermal event, which could be broadly related to a combination of coeval lithospheric thinning, asthenospheric upwelling, paleo-Pacific plate subduction, and seismicity along the continental-scale Tan-Lu fault. Possible ore genesis scenarios include those where ore fluids were produced directly by the metamorphism of oceanic lithosphere and overlying sediment on the subducting paleo-Pacific slab, or by devolatilization of an enriched mantle wedge above the slab. Both the sulfur and gold could be sourced from either the oceanic sediments or the serpentinized mantle. A better understanding of the architecture of the paleo-Pacific slab during Early Cretaceous below the eastern margin of China is essential to determination of the validity of possible models.

Shandong Province

Tectonic evolution and Cretaceous gold metallogenesis of southwestern Alaska

Cretaceous gold metallogenesis in southwestern Alaska comprises three distinct episodes related to the accretionary evolution of northwestern North America. The oldest mineralizing event is characterized by 112 Ma Cu-Au-Bi-Te porphyry-type(?) veining in the zoned Bonanza and adjacent plutons that intruded rocks of the Nyac terrane. Tectonic reconstructions and limited geological and geochemical data suggest that Cu-Au mineralization in the Nyac district may be related to terminal subduction during accretion of the Togiak-Koyukuk arc. The subsequent 100 to 89 Ma metallogenic event is a product of subduction-related magmatism immediately following accretion of the Peninsular-Alexander-Wrangellia superterrane and includes formation of the giant Pebble porphyry Cu-Au-Mo deposit. Pebble underwent a complex history of highly oxidized magmatism that is isotopically linked to enriched lithosphere or metasomatized mantle sources. Pebble and other porphyryrelated plutons were emplaced as a consequence of changes in plate motion and onset of dextral transpression along the continental margin to the southeast of their present-day locations. The final 75 to 65 Ma metallogenic event is regionally the most extensive. It followed a ~15-m.y.-long magmatic lull and is related to enigmatic subduction-related magmatism in the western part of the Alaska Range and the Kuskokwim basin. This event resulted in the formation of porphyry, reduced pluton-related, orogenic, and possible epithermal Au deposits. In the better-studied relatively low-relief areas of the Kuskokwim basin, many of the mineralized systems are spatially associated with ilmenite-series monzonite to quartz monzonite composite plutons that have isotopic signatures consistent with derivation from crustally contaminated mantle sources. These pluton-hosted Au deposits comprise low-sulfide stockworks, sheeted veins, and/or breccias in the cupolas of moderately differentiated intrusions that contain high Au; anomalous As, Bi, Sb, and/or Te; and have variable, but not uneconomic, Cu concentrations. In addition, Au, Sb, and/or Hg deposits hosted by competent NE-trending granite porphyry dike-sill complexes or along faults in flysch are widespread in the Kuskokwim basin. These deposits, including the giant Donlin Creek Au deposit, formed at shallow crustal levels and are classified here as epizonal orogenic Au deposits and related Hg and Sb lodes. Mesozonal orogenic Au deposits were formed along the margins of the uplifting Willow Creek pluton that is now exposed along the southern side of the Talkeetna Mountains batholith. Recent discoveries in the rugged Alaska Range comprise less well-studied porphyry Au-Cu (Whistler, Island Mountain), epithermal(?) Au (Terra), and reduced pluton-hosted Au deposits (Estelle). The cause of the broad latest Cretaceous magmatism associated with the final metallogenic event is enigmatic, but indicates widespread high heat flow possibly related to flat-slab subduction, lithospheric mantle delamination, or escape tectonics. Plutonism postdated regional folding and coincided with periods of movement along regional faults and formation of the NE-trending structural fabric. Magmatism resulted from initiation of transpressional faulting in more landward positions during oblique subduction of the Kula plate. Crustal contamination of mantle melts, either near their source or during ascent through the thick flysch of the Kuskokwim basin, produced low oxidation state magmas and controlled much of the metallogeny, particularly for those deposits that display similarities to both reduced porphyry Au-Cu deposits and, to a lesser degree, reduced intrusion-related Au systems. High heat flow also induced crustal melting and metamorphic devolatilization to form orogenic Au deposits. A transition to extension at ~60 Ma recorded elsewhere in Alaska temporally corresponds to termination of gold deposit formation in southwestern Alaska. The multiple periods of gold metallogenesis in southwestern Alaska offer a wide variety of targets for exploration within discrete parts of the region.

Society of Economic Geologists Special Publication