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Richard H. Coupe

Publications and source records attributed to Richard H. Coupe.

30 records · Page 2Linked to original sources
USGS2004

Concentrations of selected organochlorine compounds in fish tissue in the Mississippi Embayment Study Unit : Arkansas, Kentucky, Louisiana, Mississippi, Missouri, and Tennessee, 1995-99

Whole fish were collected at 52 sites during 1995-99 to evaluate the occurrence and distribution of selected organochlorine compounds in the Mississippi Embayment Study Unit. Samples were collected as part of the U.S. Geological Survey National Water Quality Assessment Program. From 5 to 8 fish were collected at each site; the fish were composited, and an aliquot of the tissue was analyzed for 28 organo-chlorine compounds, which included pesticides, pesticide degradates, and polychlorinated biphenyls. The use of these organochlorine compounds has been discontinued or severely restricted within the United States, but the continued detection of these compounds or their degradates in the air, water, soil, and biota in national surveys, coupled with known environmental problems associated with these compounds (such as a long half-life and the propensity to accumulate in living tissue), is cause for continued interest in their environmental fate. At least one organochlorine compound was detected in every fish-tissue sample, and as many as 15 different compounds were detected in some. The most frequently detected com-pounds were the degradates of p,p'-dichlorodiphenyltrichlo-roethane (p,p'-DDT); p,p'-dichlorodiphenyldichloroethylene (p,p'-DDE) was detected in every sample above the method reporting limit, and p,p'-dichlorodiphenyldichloroethane (p,p'-DDD), was detected in 94 percent of the samples. Polychlorinated biphenyl compounds and dieldrin were detected in 83 and 78 percent of fish-tissue samples, respectively. Because these were whole fish samples, the results are not directly comparable to human health standards, which are based on fish fillets. Comparison of these results, however, to the guidelines for the protection of fish-eating wildlife indicates that concentrations of the p,p'-DDT degradates and toxaphene continue to be of environmental concern.

Scientific Investigations Report↗
USGS2002

Streamflow and nutrient data for the Yazoo River below Steele Bayou near Long Lake, Mississippi, 1996-2000

Increased nutrient loading to the Gulf of Mexico from off-continent flux has been identified as contributing to the increase in the areal extent of the low dissolved-oxygen zone that develops annually off the Louisiana and Texas coast. The proximity of the Yazoo River Basin in northwestern Mississippi to the Gulf of Mexico, and the intensive agricultural activities in the basin have led to speculation that the Yazoo River Basin contributes a disproportionate amount of nitrogen and phosphorus to the Mississippi River and ultimately to the Gulf of Mexico. An empirical measurement of the flux of nitrogen and phosphorus from the Yazoo Basin has not been possible due to the hydrology of the lower Yazoo River Basin. Streamflow for the Yazoo River below Steele Bayou is affected by backwater from the Mississippi River. Flow at the gage is non-uniform and varying, with bi-directional and reverse flows possible. Streamflow was computed by using remote sensing and acoustic and conventional discharge and velocity measurement techniques. Streamflow from the Yazoo River for the 1996-2000 period accounted for 2.8 percent of the flow of the Mississippi River for the same period. Water samples from the Yazoo River were collected from February 1996 through December 2000 and were analyzed for total nitrogen, nitrate, total phosphorus, and orthophosphorus as part of the U.S. Geological Survey National Water-Quality Assessment Program. These data were used to compute annual loads of nitrogen and phosphorus discharged from the Yazoo River for the period 1996-2000. Annual loads of nitrogen and phosphorus were calculated by two methods. The first method used multivariate regression and the second method multiplied the mean annual concentration by the total annual flow. Load estimates based on the product of the mean annual concentration and the total annual flow were within the 95 percent confidence interval for the load calculated by multivariate regression in 10 of 20 cases. The Yazoo River loads, compared to average annual loads in the Mississippi River, indicated that the Yazoo River was contributing 1.4 percent of the total nitrogen load, 0.7 percent of the nitrate load, 3.4 percent of the total phosphorus load, and 1.6 percent of the orthophosphorus load during 1996 - 2000. The total nitrogen, nitrate, and orthophosphorus loads in the Yazoo River Basin were less than expected, whereas the total phosphorus load was slightly higher than expected based on discharge.

Water-Resources Investigations Report↗
USGS2001

It's not just how high; it's how clean: Sampling the spring 2001 flood in the Upper Mississippi River Basin

Floods can cause water-quality problems because of the large amounts of contaminants (sediment, nutrients, pesticides, and bacteria) that can be transported by floodwaters. during the flood on the Upper Mississippi River in 2001, water-quality and water-quality data were collected during near-record streamflow. This is the first time that samples for determining organic wastewater contaminants (pharmaceuticals, hormones, and industrial/household use compounds) and pesticide degradates have been collected during a flood of this magnitude.

Illinois, Iowa, Minnesota, Missouri, Wisconsin↗
USGS2000

Occurrence of pesticides in five rivers of the Mississippi Embayment Study Unit, 1996-98

The occurrence and temporal distribution of more than 80 pesticides and pesticide metabolites were determined in five rivers of the Mississippi Embayment National Water-Quality Assessment study unit from February 1996 through January 1998. More than 230 samples were collected and analyzed during the 2-year study. The five rivers sampled included three rivers with small, primarily agricultural watersheds; one river with a small urban watershed in Memphis, Tennessee; and one large river with mixed land use (row-crop agriculture, pasture, forest, and urban). Pesticides, usually herbicides, were frequently detected in water samples from every river. Insecticides were frequently detected (chlorpyrifos and diazinon in all samples) only in the river that drains the urban watershed. The occurrence of pesticides in surface water varied among the agricultural watersheds as well as between the agricultural and urban watersheds. The pesticides detected in the rivers that drain the agricultural watersheds were related to the major crop types cultivated in the watershed?corn is mostly grown in the northern part of the study unit, whereas cotton and rice are mostly grown in the southern part. The occurrence of pesticides in the Yazoo River, which drains the mixed land-use watershed, was similar to pesticide occurrence in the rivers that drain smaller agricultural watersheds, although concentrations were lower in the Yazoo River. Likewise, simazine, which was detected in all urban stream samples, was also detected in all Yazoo River samples, but in lower concentrations. The aquatic-life criteria for diazinon and chlorpyrifos was exceeded in 24 of 25 and 12 of 25 urban river samples, respectively, but only once or twice in agricultural and mixed-use watershed samples. Atrazine exceeded the aquatic-life criterion in about 20 percent of the samples from each river, particularly in the spring following pesticide application.

Water-Resources Investigations Report↗
USGS1999

Monitoring the Water Quality of the Nation's Large Rivers: Mississippi River Basin NASQAN Program

The U.S. Geological Survey (USGS) has monitored water quality in the Mississippi River Basin as part of the National Stream Quality Accounting Network (NASQAN) since 1995, applying a basinwide perspective to understanding water quality on a regional scale (Hooper and others, 1997). The objectives of the Mississippi River Basin NASQAN Program are to provide an ongoing characterization of the concentrations and mass fluxes of sediment and chemicals at key locations in the basin, to determine regional source areas for these materials, and to assess the effect of human influences on observed concentrations and fluxes. NASQAN complements the ongoing USGS National Water-Quality Assessment (NAWQA) Program, which is performing a detailed assessment in 23 subbasins within the Mississippi River Basin (Hirsch and others, 1988). NASQAN monitors the large rivers in the Mississippi River Basin, downstream of NAWQA study units. NASQAN, in conjunction with NAWQA, can provide the data and information needed by other USGS programs, Federal and State agencies, other segments of the scientific community, and by the public to address the present and future status of water quality in the Mississippi River Basin.

Fact Sheet↗
USGS1998

Concentrations and loads of nitrogen and phosphorus in the Yazoo River, northwestern Mississippi, 1996-97

Increased nutrient loading to the Gulf of Mexico from off-continent flux has been identified as contributing to the increase in the areal extent of the low dissolved-oxygen zone that develops annually off the coast of Louisiana and Texas. The proximity of the Yazoo River Basin in northwestern Mississippi to the Gulf of Mexico, and the intensive agriculture in the basin have lead to speculation that the Yazoo River Basin contributes a disproportionate amount of nitrogen and phosphorus to the Mississippi River and ultimately the Gulf of Mexico. Water samples from the Yazoo River were collected during 1996 and 1997 and were analyzed for total nitrogen, nitrate as nitrogen, total phosphorus, and orthophosphorus as part of the U.S. Geological Survey?s National Water-Quality Assessment Program. These data were used to compute annual loads of nitrogen and phosphorus discharged from the Yazoo River for 1996 and 1997. Annual loads of nitrogen and phosphorus were calculated by two methods. The first used multivariate regression and the second multiplied the mean annual concentration by the total annual flow. Load estimates based on the product of the mean annual concentration and the total annual flow were within the 95 percent confidence interval for the load calculated by multivariate regression in all cases. The Yazoo River loads, compared to long-term annual loads in the Mississippi River, indicated that the Yazoo River was contributing 2.3 percent or less of the total nitrogen load, 5.7 percent or less of the total phosphorus load, and 1 percent or less of the nitrate load in 1996 and 1997. The total nitrogen load from the Yazoo River Basin into the Mississippi River and ultimately the Gulf of Mexico was proportional to its discharge, the nitrate load was less than expected, whereas the total phosphorus load was slightly higher than expected based on discharge.

Mississippi↗