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Richard E. Willey

Publications and source records attributed to Richard E. Willey.

17 recordsLinked to original sources
USGS2008

Real-Time and Delayed Analysis of Tree and Shrub Cores as Indicators of Subsurface Volatile Organic Compound Contamination, Durham Meadows Superfund Site, Durham, Connecticut, August 29, 2006

This study examined volatile organic compound concentrations in cores from trees and shrubs for use as indicators of vadose-zone contamination or potential vapor intrusion by volatile organic compounds into buildings at the Durham Meadows Superfund Site, Durham, Connecticut. The study used both (1) real-time tree- and shrub-core analysis, which involved field heating the core samples for 5 to 10 minutes prior to field analysis, and (2) delayed analysis, which involved allowing the gases in the cores to equilibrate with the headspace gas in the sample vials unheated for 1 to 2 days prior to analysis. General correspondence was found between the two approaches, indicating that preheating and field analysis of vegetation cores is a viable approach to real-time monitoring of subsurface volatile organic compounds. In most cases, volatile organic compounds in cores from trees and shrubs at the Merriam Manufacturing Company property showed a general correspondence to the distribution of volatile organic compounds detected in a soil-gas survey, despite the fact that most of the soil-gas survey data in close proximity to the relevant trees were collected about 3 years prior to the tree-core collection. Most of the trees cored at the Durham Meadows Superfund Site, outside of the Merriam Manufacturing Company property, contained no volatile organic compounds and were in areas where indoor air sampling and soil-gas sampling showed little or no volatile organic compound concentrations. An exception was tree DM11, which contained barely detectable concentrations of trichloroethene near a house where previous investigations found low concentrations of trichloroethene (0.13 to 1.2 parts per billion by volume) in indoor air and 7.7 micrograms per liter of trichloroethene in the ground water. The barely detectable concentration of trichloroethene in tree DM11 and the lack of volatile organic compound detection in nearby tree DM10 (adjacent to the well having 7.7 micrograms of trichloroethene) may be attributable to the relatively large depth to water (17.6 feet), the relatively low soil-vapor trichloroethene concentration, and the large amount of rainfall during and preceding the tree-coring event. The data indicate that real-time and delayed analyses of tree cores are viable approaches to examining subsurface volatile organic compound soil-gas or vadose-zone contamination at the Durham Meadows Superfund Site and other similar sites. Thus, the methods may have application for determining the potential for vapor intrusion into buildings.

Scientific Investigations Report↗
USGS2002

Comparison of vapor concentrations of volatile organic compounds with ground-water concentrations of selected contaminants in sediments beneath the Sudbury River, Ashland, Massachusetts, 2000

A mixed plume of contaminants in ground water, including volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), and metals, near the former Nyanza property in Ashland, Massachusetts, discharges to the Sudbury River upstream and downstream of Mill Pond and a former mill raceway. Polyethylene-membrane vapor-diffusion (PVD) samplers were installed in river-bottom sediments to determine if PVD samplers provide an alternative to ground-water sampling from well points for identifying areas of detectable concentrations of contaminants in sediment pore water near the ground-water and surface-water interface. In August and September 2000, the PVD samplers were installed near well points at depths of 8 to 12 inches in both fine and coarse sediments, whereas the well points were installed at depths of 1 to 5 feet in coarse sediments only. Comparison between vapor and water samples at 29 locations upstream from Mill Pond show that VOC vapor concentrations from PVD samplers in coarse river-bottom sediments are more likely to correspond to ground-water concentrations from well points than PVD samplers installed in fine sediments. Significant correlations based on Kendall's Tau were shown between vapor and ground-water concentrations for trichloroethylene and chlorobenzene for PVD samplers installed in coarse sediments where the fine organic layer that separated the two sampling depths was 1 foot or less in thickness. VOC concentrations from vapor samples also were compared to VOC, SVOC, and metals concentrations from ground-water samples at 10 well points installed upstream and downstream from Mill Pond, and in the former mill raceway. Chlorobenzene vapor concentrations correlated significantly with ground-water concentrations for 5 VOCs, 2 SVOCs, and 10 metals. Trichloroethylene vapor concentrations did not correlate with any of the other ground-water constituents analyzed at the 10 well points. Chlorobenzene detected by use of PVD samplers appears to be a strong indicator of the presence of VOCs, SVOCs, and metals in ground water sampled from well points at this site. Results from PVD samplers indicate that contaminant concentrations in water from well points installed 1 to 5 ft below fine sediments may not reflect concentrations in pore water less than 1 foot below the river bottom. There is insufficient information available to determine if VOC concentrations detected in PVD samplers are useful for identifying detectable aqueous concentrations of SVOCs and metals in sediment pore water at this site. Samples of pore water from a similar depth as PVD samplers are needed for confirmation of this objective.

Open-File Report↗
USGS2000

Field tests of polyethylene-membrane diffusion samplers for characterizing volatile organic compounds in stream-bottom sediments, Nyanza Chemical Waste Dump Superfund site, Ashland, Massachusetts

A plume of volatile organic compounds (VOCs) in ground water extends from the Nyanza Chemical Waste Dump Superfund site in Ashland, Massachusetts, northward toward a mill pond on the Sudbury River and eastward toward the Sudbury River and former mill raceway downstream from the mill pond. Polyethylene-membrane water-to-vapor (vapor) and water-to-water (water) diffusion samplers were installed January 1999 in bottom sediments along the Sudbury River and former mill raceway in a pilot study to determine if vapor samplers would be useful in this setting for delineating a plume of contaminants in ground water near the river and raceway, to evaluate equilibration time for vapor-diffusion samplers, and to determine if diffusion samplers might be an alternative to seepage meters (inverted steel drums) and sediment sampling for evaluating concentrations of VOCs in bottom sediments. Of five tested compounds (benzene, trichloroethene, toluene, tetrachloroethene, and chlorobenzene), chlorobenzene and trichloroethene were most frequently detected in vapor from vapor-diffusion samplers. The distribution of VOCs was generally consistent with a previously mapped plume of contaminants in ground water. The field evaluation of equilibration times for vapor-diffusion samplers was inconclusive because of changing hydrologic conditions that may have affected concentrations of VOCs, possible variations in concentrations ofVOCs over short distances, and imprecise sampling and analytical methods. The limited data, however, indicated that equilibration may require 3 weeks or more in some settings. VOCs detected in samples from water-diffusion samplers and their concentrations were comparable to results from seepage meters, and VOCs detected in vapor-diffusion samplers correlated with VOCs detected in water-diffusion samplers. These results indicate that either vapor-or water-diffusion samplers would serve as an economical alternative to seepage meters for sampling of VOCs in pore water from stream-bottom sediments. Results from diffusion samplers correlated poorly with results from sediment samples, partly because of high quantitation limits for chemical analyses of sediments. In general, results from the diffusion samplers better represented the distribution of VOCs than the results from the sediment samples. This pilot study indicates that diffusion samplers are an economical means of identifying 'hotspots' for contaminants in bottom sediments and can provide insights on transport pathways for contaminants near surface-water bodies. After establishing equilibration times for a particular site, diffusion samplers also may be useful for studying variations in concentrations of VOCs over short distances, variations with time and changing hydrologic conditions, and processes such as chemical transformations by biodegradation and exchanges between surface water and ground water in the hyporheic zone.

Water-Resources Investigations Report↗
USGS1983

Ground-water resources of the Rutland area, Vermont

Ground water in the Rutland area occurs both in the bedrock and the overlying unconsolidated glacial deposits. Bedrock in the area is composed of a series of metamorphic and igneous rocks. Water from wells drilled in bedrock can be obtained in sufficient quantities for domestic use nearly anywhere in the area. The median well yield for 4 different bedrock hydrogeologic units ranges from 2 to 7 gallons per minute. Unconsolidated deposits in the Rutland area include till, clay, sand, and gravel. Saturated sand and gravel capable of yielding more than 200 gallons per minute is found in the major valleys of the area. Chemical analyses of water from 72 wells indicate that 29 percent of these sources contain one or more constituents that exceed the limits recommended by the U.S. Environmental Protection Agency (1977, 1978) for public drinking water supplies. The most common problem constituents are iron and manganese. In addition, elevated levels of chloride and nitrate suggest that 65 percent of the sampled sources have some water-quality deterioration. (USGS)

Vermont↗
USGS1977

Hydrologic data of the coastal drainage basins of southeastern Massachusetts, Plymouth to Weweantic River, Wareham

The principal basins in this study in southeastern Massachusetts are those of Town Brook, Eel River, and Beaverdam Brook, all draining to Cape Cod Bay; Herring Brook draining to the Cape Cod Canal; and Red Brook, Agawam River, Wankinco River, and Weweantic River, all draining to Buzzards Bay. This report presents, in tabular form, selected records of wells, test wells , borings, and important springs; measurements of stream discharge, specific conductance, and temperature at partial-record stations; chemical analyses of ground water and surface water; and a summary of municipal water sources and additional sources available. The data were collected from 1969 to 1971 in cooperation with the Massachusetts Water Resources Commission. (Woodard-USGS)

Open-File Report↗
USGS1977

Ground-water resources of the Upper Winooski River basin, Vermont

Ground water in the upper Winooski River basin, Vermont, occurs in bedrock and in overlying unconsolidated deposits of glacial origin. Bedrock in the area is composed of a series of metamorphic and igneous rocks. Median yield for 126 wells in four different bedrock formations ranges from 5 to 6 gallons per minute, and median depth ranges from 130 to 200 feet. Lineaments, interpreted as fracture of breakage zones in bedrock, were mapped to identify zones where well yields are expected to be higher than average. Unconsolidated deposits in the upper Winooski River basin include unsorted till, water-sorted clay, silt, sand, and gravel. Properly constructed wells in saturated deposits of sand or gravel having high permeability can yield large quantities of water. Twenty-six domestic wells in these unconsolidated deposits have a median yield of 18 gallons per minute and a median depth of 58 feet. Chemical analysis of water from six wells indicate a median hardness of 120 milligrams per liter, (as CaCO 3 ), which is moderately hard. Iron and manganese are common constituents of ground water in the area, and several analyses show concentrations of these elements which exceed recommended National Academy of Sciences and National Academy of Engineering (1973) limits for public drinking water supplies.

Vermont↗
USGS1975

Hydrologic data of the coastal drainage basins of southeastern Massachusetts, Weir River, Hingham, to Jonas River, Kingston

The principal basins are those of Weir River, James Brook, Bound Brook, North River, South River, and Jones River, all draining to Massachusetts Bay and Cape Cod Bay. These basins are bounded on the north by the Weymouth River basins, on the west by the Taunton River basin, and on the south by small basins that drain to Cape Cod Bay. The basins included all, or parts of, the Norwell, Pembroke, Plymouth, Plympton, Rockland, Scituate, Weymouth, and Whitman. With the following exceptions, each town is served by its own municipal water system--Hingham and northwest Cohasset by the Hingham Water Company; Abington and Rockland by the Abington-Rockland Joint Water Works; and Plympton lacks a public water supply. Weymouth and Cohasset are in Norfolk County; the other towns are in Plymouth County. This report presents, in tabular form, selected records of wells, test wells, borings, and springs; measurements of stream discharge, specific conductance, and temperature at partial-record stations; chemical analyses of ground water and surface water; and a summary of municipal water sources and additional sources available. The data were collected during a study of the drainage basins from 1969 to 1971 in cooperation with the Massachusetts Water Resources Commission. The report is released in order to make available to the public and to local, state, and federal agencies basic hydrologic information that may aid in planning water-resources development. Basic records contained in this report and streamflow data published elsewhere (U.S. Geol. Survey, 1960 et seq.) complement an interpretive report (Williams and Tasker, 1974).

Massachusetts↗
USGS1974

Evaluation of data availability and examples of modeling for ground-water management on Cape Cod, Massachusetts

Cape Cod is a seashore resort area of national renown. It is a hookshaped peninsula which extends 40 miles into the Atlantic Ocean and is separated from the mainland by Cape Cod Canal, a salt-water channel connecting Buzzards Bay and Cape Cod Bay (fig. 1). It is 440 square miles in area and is underlain by unconsolidated earth materials that contain a lens-like reservoir of fresh ground water "floating" on salty ground water. The fresh ground-water reservoir is the principal source of supply for the rapidly growing population of Cape Cod. Because of increasing resident population and increasing numbers of summer vacationers, there is local and State concern for problems of meeting increased water demands, deterioration of water quality, changes of water table and pond levels, and changes in ecology owing to changes in salinity of water in brackish-water bodies.

Massachusetts↗
USGS1973

Hydrologic Data of the Neponset and Weymouth River Basins, Massachusetts

The Neponset, Weymouth Fore, and Weymouth Back River basins occupy an area of 183 square miles in eastern Massachusetts south of Boston and Braintree, Brockton, Canton, Dedham, Dover, Foxborough, Hingham, Holbrook, Medfield, Milton, Norwood, Quincy, Randolph, Rockland, Sharon, Stoughton, Walpole, Westwood, and Weymouth. Hydrologic data presented in this report were collected during an investigation of the water resources in the areas of these basins that are upstream from tide effect or heavy urbanization. This investigation was conducted by the U.S. Geological Survey in cooperation with the Massachusetts Water Resources Commission. The data are released in order to make available to the public basic hydrologic and related information that will facilitate the planning of water-resources development and will complement an interpretive report, "Hydrology and water resources of the Neoponset and Weymouth River basins, Massachusetts" (HA-484). The well and boring data contained herein were selected from a larger group of data in order to minimize redundancy of information for intensely drilled areas. All of the data are on filed and available for inspection at the office of the U.S. Geological Survey, Water Resources Division, Boston, Massachusetts.

Massachusetts↗
USGS1970

Taunton River basin

The Taunton River, emptying into an arm of Narragansett Bay at Fall River, drains 528 square miles of interior southeastern Massachusetts. The Taunton River basin is separated from the basins of short streams draining to the coast by low divides on the east, south, and southwest. On the west and north, the basin is bordered by the Ten Mile, Charles, Neponset, and Weymouth River basins. Principal tributaries of the lower Taunton River are Segreganset, Threemile, Mill, Assonet, Nemasket, and Winnetuxet Rivers. The upper part of the basin is drained by the Canoe, Wading, and Rumford Rivers which empty into Mill and Threemile Rivers and by the Matfield and Town Rivers which unite to form the Taunton River. This report presents in tabular form selected records of wells, test wells, and borings collected during a study of the basin from 1966 to 1968 in cooperation with the Massachusetts Water Resources Commission, and during earlier studies. This report is released in order to make available to the public and to local, state, and federal agencies basic ground-water information that may aid in planning water-resources development. Basic records contained in this report will complement an interpretative report on the Taunton River basin to be released at a later date.

Massachusetts↗
USGS1967

Northern part, Ten Mile and Taunton River basins

The northern part of the Ten Mile and Taunton River basins is an area of about 195 square miles within Norfolk, Plymouth, and Bristol Counties in southeastern Massachusetts. The northern boundary of the area (plate 1) is the drainage divide separating these basins from that of the Charles, Neponset, and Weymouth River basins. The western boundary is, for the most part, the divide separating the basins from the Blackstone River basin. The eastern boundary is at the edge of the Brockton-Pembroke area (Petersen, 1962; Petersen and Shaw, 1961). The southern boundary in Seekonk is the northern limit of the East Providence quadrangle, for which a ground-water map was prepared by Allen and Gorman (1959); eastward, the southern boundaries of the city of Attleboro and the towns of Norton, Easton, and West Bridgewater form the southern boundary of the area. This report is one of two prepared by the Geological Survey for the Water Resources Commission. The principal purpose of this report is to make available the basic data on which the other, a map showing availability of ground water, is based. This basic-data report also can be used by engineers, planners, and others interested in or responsible for water-resources planning to determine the materials to be encountered (tables 3 and 4) and the yields which may be obtained from wells and test holes (tables 1 and 2) in the stratified sand and gravel that are the principal source of ground water and in bedrock. Partial and complete chemical analyses (tables 7 and 8) of these test holes and of some privately-owned wells provide information on the general quality of the water for domestic and other uses. A tabulation of existing municipal supplies, their capacity, production (table 5), and chemical quality of the water (table 6) may be used for regional planning purposes. Water-level measurements (figure 1) can be used to determine the annual fluctuations of the water table in certain types of materials. Seismic work (table 9) in the Canoe River valley, Norton, and test drilling with a power augur (tables 2 and 4) were done for the Geological Survey as part of the investigation.

Massachusetts↗