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Raymond H. Johnson

Publications and source records attributed to Raymond H. Johnson.

31 records · Page 2Linked to original sources

Geochemical data from waters in Prospect Gulch, San Juan County, Colorado, that span pre- and post-Lark Mine remediation

In San Juan County, Colorado, the effects of historical mining continue to contribute dissolved metals to groundwater and surface water. Water samples in Prospect Gulch near Silverton, Colorado, were collected at selected locations that span pre- and post-reclamation activities at the Lark Mine, located in the Prospect Gulch watershed. Geochemical results from those water samples are presented in this report. Water samples were analyzed for specific conductance, pH, temperature, and dissolved oxygen with handheld field meters, and metals were analyzed using inductively coupled plasma-mass spectrometry.

Colorado

Geochemical Analyses of Rock, Sediment, and Water from the Region In and Around the Tuba City Landfill, Tuba City, Arizona

The Tuba City Landfill (TCL) started as an unregulated waste disposal site in the 1940s and was administratively closed in 1997. Since the TCL closure, radionuclides have been detected in the shallow ground water. In 2006, the Bureau of Indian Affairs (BIA) contracted with the U.S. Geological Survey (USGS) to better understand the source of radionuclides in the ground water at the TCL compared to the surrounding region. This report summarizes those data and presents interpretations that focus on the geochemistry in the rocks and water from the Tuba City region. The TCL is sited on Navajo Sandstone above the contact with the Kayenta Formation. These formations are not rich in uranium but generally are below average crustal abundance values for uranium. Uranium ores in the area were mined nearby in the Chinle Formation and processed at the Rare Metals mill (RMM). Regional samples of rock, sediment, leachates, and water were collected in and around the TCL site and analyzed for major and minor elements, 18O, 2H, 3H, 13C, 14C,34S, 87Sr, and 234U/238U, as appropriate. Results of whole rock and sediment samples, along with leachates, suggest the Chinle Formation is a major source of uranium and other trace elements in the area. Regional water samples indicate that some of the wells within the TCL site have geochemical signatures that are different from the regional springs and surface water. The geochemistry from these TCL wells is most similar to leachates from the Chinle Formation rocks and sediments. Isotope samples do not uniquely identify TCL-derived waters, but they do provide a useful indicator for shallow compared to deep ground-water flow paths and general rock/water interaction times. Information in this report provides a comparison between the geochemistry within the TCL and in the region as a whole.

Open-File Report

Factoring uncertainty into restoration modeling of in-situ leach uranium mines

Postmining restoration is one of the greatest concerns for uranium in-situ leach (ISL) mining operations. The ISL-affected aquifer needs to be returned to conditions specified in the mining permit (either premining or other specified conditions). When uranium ISL operations are completed, postmining restoration is usually achieved by injecting reducing agents into the mined zone. The objective of this process is to restore the aquifer to premining conditions by reducing the solubility of uranium and other metals in the ground water. Reactive transport modeling is a potentially useful method for simulating the effectiveness of proposed restoration techniques. While reactive transport models can be useful, they are a simplification of reality that introduces uncertainty through the model conceptualization, parameterization, and calibration processes. For this reason, quantifying the uncertainty in simulated temporal and spatial hydrogeochemistry is important for postremedial risk evaluation of metal concentrations and mobility. Quantifying the range of uncertainty in key predictions (such as uranium concentrations at a specific location) can be achieved using forward Monte Carlo or other inverse modeling techniques (trial-and-error parameter sensitivity, calibration constrained Monte Carlo). These techniques provide simulated values of metal concentrations at specified locations that can be presented as nonlinear uncertainty limits or probability density functions. Decisionmakers can use these results to better evaluate environmental risk as future metal concentrations with a limited range of possibilities, based on a scientific evaluation of uncertainty.

Open-File Report

Results and Interpretations of U.S. Geological Survey Data Collected In and Around the Tuba City Open Dump, Arizona

This Open-File Report was originally an Administrative Report presentation to the Bureau of Indian Affairs based on U.S. Geological Survey data that has been collected and presented in four previous reports (Open-File Reports 2009-1020, 2008-1380, and 2008-1374, and an Administrative Report on geophysical data). This presentation was given at a technical meeting requested by the BIA on March 3 and 4, 2009, in Phoenix, Arizona. The idea for this meeting was for all the technical people working on issues related to the Tuba City Open Dump site to come together and share their data collection procedures, results, interpretations, and working hypotheses. The meeting goal was to have a clear record of each party's interpretations and a summary of additional data that would be needed to solve differences of opinion. The intention of this presentation is not to provide an exhaustive summary of U.S. Geological Survey efforts at the Tuba City Open Dump site given in the four previously published Open-File Reports listed above, since these reports have already been made available. This presentation briefly summarizes the data collected for those reports and provides results, interpretations, and working hypotheses relating to the data available in these reports. The major questions about the Tuba City Open Dump addressed by the U.S. Geological Survey are (1) what are the sources for uranium and other constituents found in the ground water in and around the Tuba City Open Dump, (2) what is the current distribution of ground water contaminants away from the Tuba City Open Dump (can plume limits be delineated), and (3) what controls the mobility of uranium and other constituents in and around the Tuba City Open Dump? Data collection, results, and interpretations by the U.S. Geological Survey that address these questions are presented herein.

Open-File Report

Temporal Geochemistry Data from Five Springs in the Cement Creek Watershed, San Juan County, Colorado

Temporal data from five springs in the Cement Creek watershed, San Juan County, Colorado provide seasonal geochemical data for further research in the formation of ferricretes. In addition, these data can be used to help understand the ground-water flow system. The resulting data demonstrate the difficulty in gathering reliable seasonal data from springs, show the unique geochemistry of each spring due to local geology, and provide seasonal trends in geochemistry for Tiger Iron Spring.

Open-File Report

Geochemical data from analyses of rock, sediment, water, and solid-phase leaching at the Tuba City Open Dump, Tuba City, Arizona

This report releases data collected by the U.S. Geological Survey from the Tuba City Open Dump area from January 2008 to September 2008 with cooperation from the U.S. Bureau of Indian Affairs and the Navajo and Hopi Tribes. These data were collected in support of investigations into the possible sources and resulting transport of radionuclides and other dissolved constituents in the surrounding ground water from the Tuba City Open Dump. This report provides a discussion of data collection and analytical methods with the data in a tabular format.

Arizona

Ground water flow modeling with sensitivity analyses to guide field data collection in a mountain watershed

In mountain watersheds, the increased demand for clean water resources has led to an increased need for an understanding of ground water flow in alpine settings. In Prospect Gulch, located in southwestern Colorado, understanding the ground water flow system is an important first step in addressing metal loads from acid-mine drainage and acid-rock drainage in an area with historical mining. Ground water flow modeling with sensitivity analyses are presented as a general tool to guide future field data collection, which is applicable to any ground water study, including mountain watersheds. For a series of conceptual models, the observation and sensitivity capabilities of MODFLOW-2000 are used to determine composite scaled sensitivities, dimensionless scaled sensitivities, and 1% scaled sensitivity maps of hydraulic head. These sensitivities determine the most important input parameter(s) along with the location of observation data that are most useful for future model calibration. The results are generally independent of the conceptual model and indicate recharge in a high-elevation recharge zone as the most important parameter, followed by the hydraulic conductivities in all layers and recharge in the next lower-elevation zone. The most important observation data in determining these parameters are hydraulic heads at high elevations, with a depth of less than 100 m being adequate. Evaluation of a possible geologic structure with a different hydraulic conductivity than the surrounding bedrock indicates that ground water discharge to individual stream reaches has the potential to identify some of these structures. Results of these sensitivity analyses can be used to prioritize data collection in an effort to reduce time and money spend by collecting the most relevant model calibration data.

Groundwater Monitoring & Remediation

Geochemistry of Surface and Ground Water in Cement Creek from Gladstone to Georgia Gulch and in Prospect Gulch, San Juan County, Colorado

In San Juan County, Colo., the effects of historical mining continue to contribute metals to ground water and surface water. Previous research by the U.S. Geological Survey identified ground-water discharge as a significant pathway for the loading of metals to surface water in the upper Animas River watershed from both acid-mine drainage and acid-rock drainage. In support of this ground-water research effort, Prospect Gulch was selected for further study and the geochemistry of surface and ground water in the area was analyzed as part of four sampling plans: (1) ten streamflow and geochemistry measurements at five stream locations (four locations along Cement Creek plus the mouth of Prospect Gulch from July 2004 through August 2005), (2) detailed stream tracer dilution studies in Prospect Gulch and in Cement Creek from Gladstone to Georgia Gulch in early October 2004, (3) geochemistry of ground water through sampling of monitoring wells, piezometers, mine shafts, and springs, and (4) samples for noble gases and tritium/helium for recharge temperatures (recharge elevation) and ground-water age dating. This report summarizes all of the surface and ground-water data that was collected and includes: (1) all sample collection locations, (2) streamflow and geochemistry, (3) ground-water geochemistry, and (4) noble gas and tritium/helium data.

Colorado

Mineralogy from Cores in Prospect Gulch, San Juan County, Colorado

In the late nineteenth century, San Juan County, Colorado, was the center of a metal mining boom in the San Juan Mountains. Although most mining activity ceased by the 1990s, the effects of historical mining continue to contribute metals to ground water and surface water. Previous research by the U.S. Geological Survey identified ground-water discharge as a significant pathway for the loading of metals to surface water from both acid-mine drainage and acid-rock drainage. In an effort to understand the ground-water flow system in the upper Animas River watershed, Prospect Gulch was selected for further study because of the amount of previous data provided in and around that particular watershed. In support of this ground-water research effort, data was collected from drill core, which included: (1) detailed descriptions of the subsurface geology and hydrothermal alteration patterns, (2) depth of sulfide oxidation, and (3) quantitative mineralogy.

Open-File Report

Completion reports, core logs, and hydrogeologic data from wells and piezometers in Prospect Gulch, San Juan County, Colorado

In the late nineteenth century, San Juan County, Colorado, was the center of a metal mining boom in the San Juan Mountains. Although most mining activity ceased by the 1990s, the effects of historical mining continue to contribute metals to ground water and surface water. Previous research by the U.S. Geological Survey identified ground-water discharge as a significant pathway for the loading of metals to surface water from both acid-mine drainage and acid-rock drainage. In an effort to understand the ground-water flow system in the upper Animas River watershed, Prospect Gulch was selected for further study because of the amount of previous data provided in and around that particular watershed. In support of this ground-water research effort, wells and piezometers were installed to allow for coring during installation, subsurface hydrologic testing, and the monitoring of ground-water hydraulic heads and geochemistry. This report summarizes the data that were collected during and after the installation of these wells and piezometers and includes (1) subsurface completion details, (2) locations and elevations, (3) geologic logs and elemental data, (4) slug test data for the estimation of subsurface hydraulic conductives, and (5) hydraulic head data.

Open-File Report

Interpreting DNAPL saturations in a laboratory-scale injection using one- and two-dimensional modeling of GPR Data

Ground-penetrating radar (GPR) is used to track a dense non-aqueous phase liquid (DNAPL) injection in a laboratory sand tank. Before modeling, the GPR data provide a qualitative image of DNAPL saturation and movement. One-dimensional (1D) GPR modeling provides a quantitative interpretation of DNAPL volume within a given thickness during and after the injection. DNAPL saturation in sublayers of a specified thickness could not be quantified because calibration of the 1D GPR model is nonunique when both permittivity and depth of multiple layers are unknown. One-dimensional GPR modeling of the sand tank indicates geometric interferences in a small portion of the tank. These influences are removed from the interpretation using an alternate matching target. Two-dimensional (2D) GPR modeling provides a qualitative interpretation of the DNAPL distribution through pattern matching and tests for possible 2D influences that are not accounted for in the 1D GPR modeling. Accurate quantitative interpretation of DNAPL volumes using GPR modeling requires (1) identification of a suitable target that produces a strong reflection and is not subject to any geometric interference; (2) knowledge of the exact depth of that target; and (3) use of two-way radar-wave travel times through the medium to the target to determine the permittivity of the intervening material, which eliminates reliance on signal amplitude. With geologic conditions that are suitable for GPR surveys (i.e., shallow depths, low electrical conductivities, and a known reflective target), the procedures in this laboratory study can be adapted to a field site to delineate shallow DNAPL source zones.

Ground Water Monitoring and Remediation

Interpreting DNAPL saturations in a laboratory-scale injection with GPR data and direct core measurements

Ground penetrating radar (GPR) is used to track a dense non-aqueous phase liquid (DNAPL) injection in a laboratory sand tank. Before data reduction, GPR data provide a qualitative measure of DNAPL saturation and movement. One-dimensional (1D) GPR modeling provides a quantitative interpretation of DNAPL volume within a given thickness during and after the injection. This is confirmed qualitatively by visual inspection of cores and two-dimensional GPR modeling. DNAPL saturation in sub-layers of that thickness could not be quantified because calibration of the 1D GPR model is non-unique when both permittivity and depth of multiple layers are unknown. Accurate quantitative interpretation of DNAPL volumes using 1D GPR modeling requires: 1) identification of a suitable target that produces a strong reflection and is not subject to any multidimensional interference; 2) knowledge of the exact depth of that target; and 3) use of two-way radar-wave travel times through the medium to the target to determine the permittivity of the intervening material, which eliminates reliance upon reflection amplitude. With geologic conditions that are suitable for GPR surveys (i.e., shallow depths and low electrical conductivities), the procedures in this laboratory study can be adapted to a field site to identify DNAPL source zones after a release has occurred.

Open-File Report

Modeling GPR data to interpret porosity and DNAPL saturations for calibration of a 3-D multiphase flow simulation

Dense nonaqueous phase liquids (DNAPLs) are a pervasive and persistent category of groundwater contamination. In an effort to better understand their unique subsurface behavior, a controlled and carefully monitored injection of PCE (perchloroethylene), a typical DNAPL, was performed in conjunction with the University of Waterloo at Canadian Forces Base Borden in 1991. Of the various geophysical methods used to monitor the migration of injected PCE, the U.S. Geological Survey collected 500-MHz ground penetrating radar (GPR) data. These data are used in determining calibration parameters for a multiphase flow simulation. GPR data were acquired over time on a fixed two-dimensional surficial grid as the DNAPL was injected into the subsurface. Emphasis is on the method of determining DNAPL saturation values from this time-lapse GPR data set. Interactive full-waveform GPR modeling of regularized field traces resolves relative dielectric permittivity versus depth profiles for pre-injection and later-time data. Modeled values are end members in recursive calculations of the Bruggeman-Hanai-Sen (BHS) mixing formula, yielding interpreted pre-injection porosity and post-injection DNAPL saturation values. The resulting interpreted physical properties of porosity and DNAPL saturation of the Borden test cell, defined on a grid spacing of 50 cm with 1-cm depth resolution, are used as observations for calibration of a 3-D multiphase flow simulation. Calculated values of DNAPL saturation in the subsurface at 14 and 22 hours after the start of injection, from both the GPR and the multiphase flow modeling, are interpolated volumetrically and presented for visual comparison.

Open-File Report