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R.W. Potter

Publications and source records attributed to R.W. Potter.

8 recordsLinked to original sources
USGS2002

Solubility of NaCl in aqueous electrolyte solutions from 10 to 100°C

The solubilities of NaCl in aqueous KCl, MgCl2, CaCl2, and mixed CaCl2-KCl solutions have been determined from 10 to 100??C. The data were fit to an equation, and the equation was used to calculate values of the change in solubility of NaCl, ???[NaCl]/???T. These values are required for calculations of the rate of migration of fluids in a thermal gradient in rock salt. The data obtained here indicate that the values of ???[NaCl]/???T are 36-73% greater for solutions containing divalent ions than for the NaCl-H2O system.

Journal of Chemical and Engineering Data↗
USGS2002

Solubility of some alkali and alkaline earth chlorides in water at moderate temperatures

Solubilities for the binary systems, salt-H2O, of the chlorides of lithium, rubidium, cesium, magnesium, calcium, strontium, and barium from near 0??C to the saturated boiling point are reported. The experimental data and coefficients of an equation for a smoothed curve describing each system are listed in the tables. The data are improvements on those previously reported in the literature, having a precision on the average of ??0.09%.

Journal of Chemical and Engineering Data↗
USGS1982

The densities of halite-saturated WIPP-A and NBT-6 brines and their NaCl contents in weight percent, molal, and molar units from 20 to 100 degrees C

A series of density measurements has been performed at 30?, 50?, 70?, and 90?C for halite-undersaturated WIPP-A and NBT-6 brines with various NaCl contents approaching saturation. The densities of halite-saturated WIPP-A and NBT-6 brines were obtained by extrapolating these measured densities to halite saturation points. The maximum difference between the densities obtained in this Fashion and those calculated from the model of Potter and Haas is 0.015 g/cm3. The NaCl contents in halite-saturated WIPP-A and NBT-6 brines are reported in wt %, molal, and molar units from 20? to 100?C.

Open-File Report↗
USGS1979

Magnesium correction to the Na K Ca chemical geothermometer

Equations and graphs have been devised to correct for the adverse effects of magnesium upon the Na-K-Ca chemical geothermometer. Either the equations or graphs can be used to determine appropriate temperature corrections for given waters with calculated Na-K-Ca temperatures > 70°C and R < 50, where R = { Mg (Mg + Ca + K) } &#xD7; 100 "> R = {Mg(Mg + Ca + K)} × 100 with cation concentrations expressed in equivalents. Waters with R > 50 are probably derived from relatively cool aquifers with temperatures approximately equal to the measured spring temperature, irrespective of much higher calculated Na-K-Ca temperatures.

Geochimica et Cosmochimica Acta↗
USGS1978

The solubility of the noble gases He, Ne, Ar, Kr, and Xe in water up to the critical point

The solubility of the noble gases Ar, He, Ne, Kr, and Xe in pure water was measured from 298 to 561??K. These data in turn were extrapolated to the critical point of water, thus providing a complete set of Henry's law constants from 274 to 647??K when combined with the existing literature data. Equations describing the behavior of the Henry's law constants over this temperature range are also given. The data do not confirm extrapolations of empirical correlations based on low-temperature solubility data. ?? 1978 Plenum Publishing Corporation.

Journal of Solution Chemistry↗
USGS1976

An investigation of the critical liquid-vapor properties of dilute KCl solutions

The three parameters that define the critical point, temperature, pressure, and volume have been experimentally determined by means of filling studies in a platinum-lined system for five KCl solutions ranging from 0.006 to 0.568 m . The platinum-lined vessels were used to overcome the problems with corrosion experienced by earlier workers. The critical temperature ( t c ), pressure ( P c ), and volume ( V c ) were found to fit the equations t c = 374.14 &#xA0; + &#xA0; 16.602 m &#xA0; + &#xA0; 41.740 m&#xA0; &#x00B1; 0.5 &#x2218; C P c = 220.9 &#xA0; + &#xA0; 135.164 m&#xA0; + &#xA0; 41.173 m 2 &#xA0; &#x00B1; &#xA0; 0.5 b a r s V c = 3.155 &#xA0; &#x2212; &#xA0; 1.373 m &#xA0; + &#xA0; 0.507 m&#xA0; &#x00B1; &#xA0; 0.008 c m 3 &#x2212; g &#x2212; 1 "> t c = 374.14 + 16.602 m −−√ + 41.740 m ± 0.5 ∘ C P c = 220.9 + 135.164 m + 41.173 m 2 ± 0.5 b a r s V c = 3.155 − 1.373 m −−√ + 0.507 m ± 0.008 c m 3 − g − 1 tc=374.14 + 16.602m + 41.740m ±0.5∘CPc=220.9 + 135.164m + 41.173m2 ± 0.5barsVc=3.155 − 1.373m + 0.507m ± 0.008cm3−g−1 from infinite dilution to 1.0 m .

Journal of Solution Chemistry↗