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Geology topics

R.F. Commeau

Publications and source records attributed to R.F. Commeau.

14 recordsLinked to original sources

Separation and identification of the silt-sized heavy-mineral fraction in sediments

The separation of silt-sized minerals by specific gravity is made possible by using a nontoxic, heavy liquid medium of sodium polytungstate and water. Once separated, the silt-sized heavy-mineral fraction is prepared for analysis with a scanning electron microscope equipped with an automatic image analyzer and energy-dispersive spectrometer. Particles within each sample are sized and sorted according to their chemistry, and the data are tabulated in histograms and tables. Where possible, the user can define the chemical categories to simulate distinct mineral groups. Polymorphs and minerals that have overlapping compositions are combined into a group and differentiated by X-ray diffraction. Hundreds of particles can be rapidly sized and classified by chemistry. The technique can be employed on sediments from any environment.

Circular↗

Seabed measurements of modern corrosion rates on the Florida escarpment

A mooring containing diverse carbonate and anhydrite substrates was exposed to bottom waters for 9 months at the base of the Florida Escarpment to determine the influence of dissolution on the development of this continental margin. Weight loss was measured on all samples. Etching, pitting, and loss of the original framework components were observed on substrates with known characteristics. Extrapolations of modern dissolution rates predict only about 1.6 meters of corrosion per million years. However, more rapid anhydrite dissolution, up to 1 km per million years, would cause exposed anhydrite beds to undercut and destabilize intercalated limestones.

Florida↗

Compositions, ages, and diagenetic histories of the carbonate, sulfide, oxide, and phosphatic concretions at Gay Head, Massachusetts

The calcite/ankerite concretions were formed in a hot, seasonally arid, caliche-prone environment of early Raritan age; the pyrite, marcasite, and siderite concretions precipitated in sediments deposited in low-energy, marshy, estuarine environments of late Raritan age. The phosphate concretions formed in a middle to inner shelf environment. The goethite and lepidocrocite concretions are secondary oxidation or alteration products of the prexistent Cretaceous concretions that were excavated during the Pleistocene and incorporated into the glacial drift. -from Authors

Northeastern Geology↗

Chemistry and mineralogy of pyrite-enriched sediments at a passive margin sulfide brine seep: Abyssal Gulf of Mexico

Pyrite is rapidly accumulating at the contact between the Cretaceous limestones of the Florida Platform and the hemipelagic sediments of the abyssal Gulf of Mexico. Sediments sampled with the submersible “Alvin” in 3266 m of water are associated with a dense community of organisms that depend on chemosynthetic primary production as a food source. Analysis of the chemistry, mineralogy, and textural composition of these sediments indicate that iron sulfide mineralization is occurring at the seafloor within an anoxic micro-habitat sustained by the advection of hydrogen sulfide-charged saline brines from the adjacent platform. The chemosynthetic bacteria that directly overlie the sediments oxidize hydrogen sulfide for energy and provide elemental sulfur that reacts with iron monosulfide to form some of the pyrite. The sediments are mixtures of pyrite (∼ 30 wt.%), Ba Sr sulfates (∼ 4 wt.%), clays, and locally derived biogenic carbonates and are progressively being cemented by iron sulfides. Oxidation of hydrogen sulfide produces locally acidic conditions that corrode the adjacent limestones. Potential sources of S, H 2 S, Fe, Ba, and Sr are discussed.

Earth and Planetary Science Letters↗

Formation of the Shelf-edge Cretaceous-Tertiary contact off the southeastern U.S. Coast

Submarine erosion, associated with changes in position of the proto-Gulf Stream, was the dominant mechanism controlling the formation of the Cretaceous-Tertiary unconformity in AMCOR borehole 6004. Paleontologic evidence indicates that this unconformity, which is marked by a gravelly-sand enriched in glauconitic and phosphoritic concretions, represents a hiatus of about 7 m.y. Both Cretaceous and Paleocene sediments contain middle-outer neritic foraminiferal assemblages that become more diverse with distance from the contact. Of the elemental abundances measured, Al, Ba, Co, Fe, Ga, K, Mg/Ca, Mo, Ni, P, Sr/Ca, V, Y, and Zn show a strong positive correlation with proximity to the contact, probably as a result of the concentration of authigenic and heavy minerals present as lag sediments on the erosion surface.

Florida, Georgia, South Carolina↗

Composition and morphology of ferromanganese coatings on glacial erratics in Lydonia Canyon, United States East Coast

Ferromanganese coatings have been found on glacial erratics in Lydonia Canyon, off the United States northeastern coast. The coatings, which are about 17 ??m thick, consist of an outer manganese-rich layer which covers the top of the erratic, a middle transitional layer, and an internal iron-rich layer that encircles the entire surface of the erratic. Chemical analyses of the coatings, when compared with similar data on abyssal marine ferromanganese deposits, reveal comparable Mn/Fe ratios, higher P and Ti concentrations, and an order of magnitude less of Co, Ni, Cu, and most other metals. A comparison of the Lydonia Canyon coatings with desert varnishes reveals obvious chemical, mineralogical, and morphological differences.

Geo-Marine Letters↗

Elemental X-ray mapping of agglutinated foraminifer tests: A non- destructive technique for determining compositional characteristics.

The composition of agglutinated foraminiferal tests vary remarkably in response to local substrate characteristics, physiochemical properties of the water column and species- dependant selectivity of test components. We have employed a technique that combines a scanning electron microscope with an energy dispersive X-ray spectrometer system to identify major and minor elemental constituents of agglutinated foraminiferal walls. As a sample is bombarded with a beam of high energy electrons, X-rays are generated that are characteristic of the elements present. As a result, X- ray density maps can be produced for each of several elements present in the tests of agglutinated foraminifers.

Micropaleontology↗

Ferromanganese crust resources in the Pacific and Atlantic Oceans

Ferromanganese crusts on raised areas of the ocean floor have joined abyssal manganese nodules and hydrothermal sulfides as potential marine resources. Significant volumes of cobalt-rich (about 1% Co) crusts have been identified to date within the US Exclusive Economic Zone (EEZ) in the Central Pacific: in the NW Hawaiian Ridge and Seamount region and in the seamounts in the Johnston Island and Palmyra Island regions. Large volumes of lower grade crusts, slabs, and nodules are also present in shallow ( greater than 1000 m) waters on the Blake plateau, off Florida-South Carolina in the Atlantic Ocean. Data on ferromanganese crusts have been increased by recent German and USGS cruises, but are still sparse, and other regions having crust potential are under current investigation. The authors discuss economic potentials for cobalt-rich crusts in the Central Pacific and Western North Atlantic oceans, with special reference to US EEZ areas. Additional research is needed before more quantitative resource estimates can be made.

Conference Paper↗

Biological control of the removal of abiogenic particles from the surface ocean

Concurrent measurements of particle concentrations in the near-surface water and of particle fluxes in the deep water of the Sargasso Sea show a close coupling between the two for biogenic components. The concentrations of suspended matter appear to follow an annual cycle similar to that of primary production and deepwater particle flux. Although the concentration of particulate aluminum in the surface water appears to vary randomly with respect to that cycle, the removal of aluminum to deep water is intimately linked to the rapid downward transport of organic matter.

Science↗