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R.A. Boyd

Publications and source records attributed to R.A. Boyd.

3 recordsLinked to original sources

Distribution of nitrate and orthophosphate in selected streams in Central Nebraska

The Central Nebraska Basins is one of 60 study units in the National Water-Quality Assessment Program of the U.S. Geological Survey. The study unit includes the Platte River and two major tributaries, the Loup and Elkhorn Rivers. Agriculture is the predominant land use in the study unit, with only eight urbanized communities exceeding a population of 10,000. Water samples were collected from selected streams in the study unit during 1993- 1995. The data were used to assess the distribution of nitrogen compounds and phosphorus in the streams and to relate the concentrations of these constituents to environmental settings. This article focuses on dissolved nitrate and orthophosphate. Dissolved nitrate concentrations were highest (90th percentiles were less than 7.0 milligrams per liter as nitrogen) in areas with extensive cropland and pasture, where chemical fertilizers are intensively applied. Synoptic measurements conducted in March and August 1994 indicate that relatively little residual fertilizer, as nitrate, applied during a single crop-growing season enters streams. Dissolved nitrate concentrations showed a seasonal pattern, being highest during winter months and lowest during the late spring and summer. Dissolved orthophosphate concentrations tended to be low across the study unit, 90 percent of all analyses did not exceed 1.7 milligrams per liter as phosphorus.

Water Resources Bulletin↗

Herbicides and herbicide degradates in shallow groundwater and the Cedar River near a municipal well field, Cedar Rapids, Iowa

Water samples were collected near a Cedar Rapids, Iowa municipal well field from June 1998 to August 1998 and analyzed for selected triazine and acetanilide herbicides and degradates. The purpose of the study was to evaluate the occurrence of herbicides and herbicide degradates in the well field during a period following springtime application of herbicides to upstream cropland. The well field is in an alluvial aquifer adjacent to the Cedar River. Parent herbicide concentrations generally were greatest in June, and decreased in July and August. Atrazine was most frequently detected and occurred at the greatest concentrations; acetochlor, cyanazine and metolachlor also were detected, but at lesser concentrations than atrazine. Triazine degradate concentrations were relatively small (<0.50 ??g/l) and generally decreased from June to August. Although the rate of groundwater movement is relatively fast (approx. 1 m per day) in the alluvial aquifer near the Cedar River, deethylatrazine (DEA) to atrazine ratios in groundwater samples collected near the Cedar River indicate that atrazine and DEA probably are gradually transported into the alluvial aquifer from the Cedar River. Deisopropylatrazine (DIA) to DEA ratios in water samples indicate most DIA in the Cedar River and alluvial aquifer is produced by atrazine degradation, although some could be from cyanazine degradation. Acetanilide degradates were detected more frequently and at greater concentrations than their corresponding parent herbicides. Ethanesulfonic-acid (ESA) degradates comprised at least 80% of the total acetanilide-degradate concentrations in samples collected from the Cedar River and alluvial aquifer in June, July and August; oxanilic acid degradates comprised less than 20% of the total concentrations. ESA-degradate concentrations generally were smallest in June and greater in July and August. Acetanilide degradate concentrations in groundwater adjacent to the Cedar River indicate acetanilide degradates are transported into the alluvial aquifer in a manner similar to that indicated for atrazine and DEA. Copyright (C) 2000 Elsevier Science B.V.

Conference Paper↗

Selected hydrologic data from the Cedar Rapids area, Linn County, Iowa, April 1996 through March 1999

The City of Cedar Rapids, Iowa obtains its municipal water supply from four well fields along the Cedar River. The wells are completed at depths of about 60 to 80 feet in a shallow alluvial aquifer adjacent to the Cedar River. The City of Cedar Rapids and the U.S. Geological Survey have conducted a cooperative study of the groundwater flow system and water quality near the well fields since 1992. The purpose of this report is to document selected hydrologic data collected from April 1996 through March 1999. Data include the results of water-quality analyses, ground-waterlevels continuously measured with pressure transducers and data recorders, and physical properties continuously monitored using multiprobe instruments. Water-quality samples were collected from selected wells and the Cedar River to conduct periodic monitoring, to evaluate ground-water geochemistry, to assess the occurrence of pesticides and herbicide degradates in the alluvial aquifer, and to characterize water quality in shallow ground water near a wetland area in the Seminole Well Field. Types of water-quality analyses included common ions (calcium, chloride, iron, magnesium, manganese, potassium, silica, sodium, and sulfate), trace elements (boron, bromide, and fluoride), nutrients (ammonia as nitrogen, nitrite as nitrogen, nitrite plus nitrate as nitrogen, and orthophosphate as phosphorus), dissolved organic carbon, and selected pesticides and herbicide degradates. Ground-water levels in selected observation wells were continuously measured to assess temporal trends in groundwater levels in the alluvial aquifer and bedrock aquifer, to help calibrate a ground-water flow model being constructed to simulate local groundwater flow under transient conditions near the well fields, and to assess hydrologic conditions near a wetland area in the Seminole Well Field. Physical properties (specific conductance, pH, dissolved oxygen, and water temperature) were continuously monitored to assess temporal variation and to help evaluate the interaction between the Cedar River and ground water in the alluvial aquifer.

Iowa↗