Geology topics

R. M. Siebert

Publications and source records attributed to R. M. Siebert.

3 recordsLinked to original sources

USGS1977

A thermostatic water bath for experimental studies in aqueous solutions

A temperature-controlled water bath for the study of ion-pairing equilibria and mineral solubility in aqueous solutions below 100°C is described. The bath is similar to a previously described system (P. B. Hostetler and C. L. Christ, 1968, U.S. Geol. Survey Prof. Paper 600-D, p. D217-D221) but incorporates several significant improvements. Included among these are a more efficient stirring mechanism, a potentially larger solid-to-solution ratio, and improved equilibration of the gas phase with the solution.

Journal of Research of the U.S. Geological Survey↗

USGS1974

Stabilities of calcite and aragonite

A revaluation of the 25° C activity-product constants of calcite ( K C ) and aragonite ( K A ) was made on the basis of the known solubilities of these phases for which the activity of total dissolved calcium was corrected for the presence of the ion pair CaHCO 3 + in the aqueous phase. The value of the dissociation constant of CaHCO 3 + was taken to be 10 -1.225±0.02 . This value, combined with values of the analytical concentrations in solutions with partial pressure P CO2 =0.97 atmosphere, leads to K C =l0 -8.52±0.04 and K A = 10 -8.36±0.04 . Based on these K values, standard free energies of formation of calcite and aragonite were calculated to be -270,144±375 and -269,926±375 calories mole -1 , (-1,130,282±1,569 and -1,129,370±1,569 joules mole -1 ), respectively. From the 25°C K values, using appropriate entropy and heat capacity data, values of K C and K A were calculated over the temperature range 0° to 200°C. Possible errors in interpretation of measured pH values and inferred P CO2 values and the bearing of these errors on calculations of K values are discussed.

Journal of Research of the U.S. Geological Survey↗

USGS1974

Activity-product constants of aragonite at 90° and 51°C

The activity-product constants of aragonite, K A =[Ca 2+ ][CO 3 2- ] (where the brackets denote activities), were determined experimentally at 90°C and at 51°C. Results at 90°C were obtained from four separate dolomite dissolution runs, in which aragonite precipitated and came to equilibrium with the aqueous phase (from the direction of. supersaturation), and from two runs starting with aragonite suspended in dilute MgCl 2 solutions (from the direction of undersaturation). The average values of K A from the six runs were in excellent agreement; for the negative logarithm of K A , P K A , they yield a value of 8.95±0.05. One run was made at 51° C starting with aragonite suspended in dilute MgCl 2 solution; the value of p K A at 51°C is 8.61±0.05. No X-ray detectable calcite was found at the conclusion of any of the runs, including a dolomite dissolution run at 90°C (D-10) that was sampled over a period of 10,268 h and toward the end had a concentration of approximately 0.002 molal total dissolved magnesium.

Journal of Research of the U.S. Geological Survey↗