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R. J. Hunt

Publications and source records attributed to R. J. Hunt.

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Simulation of the recharge area for Frederick Springs, Dane County, Wisconsin

The Pheasant Branch watershed in Dane County is expected to undergo development. There are concerns that this development will adversely affect water resources, including Frederick Springs, a large spring complex in the watershed. The spring's recharge area was delineated using a telescopic mesh refinement (TMR) model constructed from an existing regional-scale ground-water flow model, and further refined by adding nearby surface-water features, a refined recharge array based on a surface-water model, and increasing the vertical leakage between the deep aquifers. This TMR model was formally optimized using the parameter estimation code UCODE. The results of optimization demonstrated that the best fit to measured heads and fluxes was obtained by using a horizontal hydraulic conductivity two times that of the original regional model for layer 2 and 80 percent smaller for layer 3. This range of parameter values was formally considered using a stochastic Monte Carlo approach. Two-hundred model runs used uniformly distributed, randomly sampled, horizontal hydraulic conductivity values within the range given by the TMR optimized values and the previously constructed regional model. A probability distribution of particles captured by the spring, or a probabilistic capture zone' was calculated from the realistic Monte Carlo results (136 runs of 200). In addition to portions of the local surface watershed, the capture zone encompassed distant areas in the North Fork of the Pheasant Branch watershed and areas entirely outside of the Pheasant Branch - demonstrating that the ground-watershed and surface watershed do not coincide. Analysis of samples from the springs and a nearby municipal well identified large contrasts in chemistry, even for springs within 50 feet of one another. The differences were stable over time, were present in both ion and isotope analyses, and showed a distinct gradation from high nitrate, high calcium, Ordovician-carbonate dominated water in western spring vents to low nitrate, lower calcium, Cambrian-sandstone influenced water in eastern spring vents. The difference in chemistry was attributed to distinctive bedrock geology as demonstrated by overlaying the 50 percent probability capture zone over a bedrock geology map for the area. This finding gives additional confidence to the capture zone calculated by the ground-water flow model.

Wisconsin

Assessing hydrogeochemical heterogeneity in natural and constructed wetlands

While 'water quality function' is cited as an important wetland function to design for and preserve, we demonstrate that the scale at which hydrochemical samples are collected can significantly influence interpretations of biogeochemical processes in wetlands. Subsurface, chemical profiles for both nutrients and major ions were determined at a site in southwestern Wisconsin that contained areas of both natural and constructed wetlands. Sampling was conducted on three different scales: (1) a large scale (3 m between sampling points), (2) an intermediate scale (0.15 m between sampling points), and (3) a small scale (1.5 cm between sampling points). In most cases, significant vertical heterogeneity was observed at the 0.15 m scale, which was much larger than previously reported for freshwater wetlands and not detected by sampling water table wells screened over the same interval. However, profiles of ammonia and total phosphorus showed tenfold changes in the upper 0.2 meters of the saturated zone when sampled at the small (1.5 cm) scale, that was not depicted by sampling at the intermediate scale. At the intermediate scale of observation, one constructed wetland site differed geochemically from the natural wetlands and the other constructed wetland site due to application of off-site salvaged marsh surface and downward infiltration of rain. While important differences in dissolved inorganic phosphorus and dissolved inorganic carbon concentrations existed between the constructed wetland and the natural wetlands, we also observed substantial differences between the natural wetland sites for these constituents. A median-polishing analysis of our data showed that temporal variations in constituent concentrations within profiles, although extensively recognized in the literature, were not as important as spatial variability.

Biogeochemistry