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R. A. Volkert

Publications and source records attributed to R. A. Volkert.

11 recordsLinked to original sources

Evidence for an Alleghanian (Early Carboniferous to Late Permian) tectonothermal event in the New Jersey Coastal Plain basement from 40 Ar/ 39 Ar biotite data, geochemistry and gravity modeling

40 Ar/ 39 Ar dating of biotite from felsic orthogneiss recovered from the -3890-foot level of the Island Beach State Park (IBSP) well beneath the outer New Jersey Coastal Plain was accomplished using CO 2 laser incremental-heating techniques. Over 75% of the Ar released from the incremental-heating experiment form a well-behaved plateau with a calculated age of 243.98 ?? 0.10 Ma. The new 244 Ma biotite age reported here is a cooling age younger than the metamorphic event that crystallized or reheated the biotite. We consider reheating of older biotite to be unlikely because the concordant 40 Ar/ 39 Ar spectrum upon repeated incremental laser heating showed a well-developed plateau. Thus, biotites from the IBSP gneiss are interpreted as having crystallized during a single thermal event, followed by cooling to below 300 ??C. The IBSP well falls on a structural and geophysical anomaly trend that is along strike with rocks of the Bronson Hill anticlinorium to the north of the IBSP gneiss. Locally graphitic metasedimentary schists and gneisses recovered from New Jersey wells inboard of the IBSP well gneiss correlate to similar lithologies of the Connecticut Valley synclinorium west of the Hartford basin. Our reinterpretation of the IBSP gneiss as metamorphosed dacite or dacitic tuff is consistent with a correlation to some rocks of the Bronson Hill magmatic arc east of the Hartford basin. If correct, this would imply a Late Ordovician age for the protolith of the IBSP gneiss. Reported 40 Ar/ 39 Ar biotite ages of 235-253 Ma from southwestern Rhode Island, and of 238-247 Ma from southeastern Connecticut, are interpreted as cooling ages following a tectonothermal event associated with the Alleghanian orogeny (Early Carboniferous to Late Permian). Cooling ages of Alleghanian age (Early Carboniferous to Late Permian) are not recognized west of the Bronson Hill volcanic arc in either central Connecticut or in Massachusetts. Therefore, the 244 Ma cooling age presented here, and the geochemical affinity of the IBSP gneiss to some orthogneisses of the Bronson Hill arc, support an interpretation of the IBSP well as representing the southern continuation of the Bronson Hill arc into New Jersey. Moreover, it documents the presence of rocks beneath the outer New Jersey Coastal Plain that experienced a Permian Alleghanian metamorphism. ?? 2009 Elsevier Ltd. All rights reserved.

Journal of Geodynamics

Calcite-graphite thermometry of the Franklin Marble, New Jersey Highlands

We present new stable-isotope data for the Mesoproterozoic Franklin Marble from outcrops along an 80-km traverse parallel to and across strike of the structural grain of the western New Jersey Highlands. Calcite and dolomite from marble have an average ??13C of 0.35??? ?? 0.73??? PDB (n = 46) and a more limited range than other Mesoproterozoic marbles from the Adirondacks and the Canadian Grenville Province. The small range of ??13C values from the New Jersey samples is consistent with the preservation of a primary marine isotopic signature and limited postdepositional isotopic modification, except proximal to Zn or Fe ore deposits and fault zones. Fractionations between calcite and well-formed graphite (??13C[Cal-Gr]) for analyzed Franklin Marble samples average 3.31???. ?? 0.25??? (n = 34), and dolomite-graphite fractionations average 3.07??? ?? 0.30??? (n = 6). Taken together, these indicate an average temperature of 769?? ?? 43??C during metamorphism associated with the Ottawan Orogeny in the New Jersey Highlands. Thus, carbon isotope fractionations demonstrate that the Franklin Marble was metamorphosed at granulite facies conditions. Metamorphic temperatures are relatively constant for the area sampled and overprint the metamorphosed carbonatehosted Zn-Fe-Mn ore deposits. The results of this study support recent work proposing that pressure and temperature conditions during Ottawan orogenesis did not vary greatly across faults that partition the Highlands into structural blocks. ?? 2006 by The University of Chicago. All rights reserved.

Journal of Geology

U-Pb zircon geochronology of Mesoproterozoic postorogenic rocks and implications for post-Ottawan magmatism and metallogenesis, New Jersey Highlands and contiguous areas, USA

Postorogenic rocks are widespread in Grenville terranes of the north-central Appalachians where they form small, discordant, largely pegmatitic felsic intrusive bodies, veins, and dikes, and also metasomatic calcic skarns that are unfoliated and postdate the regional 1090 to 1030 Ma upper amphibolite- to granulite-facies metamorphism related to the Grenville (Ottawan) Orogeny. Zircons from magmatic and nonmagmatic rocks from northern New Jersey and southern New York were dated to provide information on the regional tectonomagmatic and metallogenic history following Ottawan orogenesis. We obtained U-Th-Pb zircon ages of 1004 ?? 3 Ma for pegmatite associated with the 1020 ?? 4 Ma Mount Eve Granite near Big Island, New York, 986 ?? 4 Ma for unfoliated, discordant pegmatite that intrudes supracrustal marble at the Buckwheat open cut, Franklin, New Jersey, ???990 Ma for a silicate-borate skarn layer in the Franklin Marble at Rudeville, New Jersey, and 940 ?? 2 Ma for a calc-silicate skarn layer at Lower Twin Lake, New York. This new data, together with previously published ages of 1020 ?? 4 to 965 ?? 10 Ma for postorogenic rocks from New Jersey and southern New York, provide evidence of magmatic activity that lasted for up to 60 Ma past the peak of high-grade metamorphism. Postorogenic magmatism was almost exclusively felsic and involved relatively small volumes of metaluminous to mildly peraluminous melt that fractionated from an A-type granite parent source. Field relationships suggest the melts were emplaced along lithosphere-scale fault zones in the Highlands that were undergoing extension and that emplacement followed orogenic collapse by least 30 Ma. Postorogenic felsic intrusions correspond to the niobium-yttrium-fluorine (NYF) class of pegmatites of C??erny?? (1992a). Geochronologic data provide a temporal constraint on late-stage hydrothermal activity and a metallogenic event in New Jersey at ???990 to 940 Ma that mineralized pegmatites with subeconomic to economic deposits of magnetite ?? U ?? Th ?? rare earth element (REE) and formed metasomatic calcic skarn bodies in marble and reactive carbonate rocks. Mineralization associated with this event overlaps the timing of pegmatite emplacement, suggesting a petrogenetic relationship. Coeval metallogeny at 975 to 950 Ma in the New York Hudson Highlands and 980 to 937 Ma in the Canadian Grenville Province implies that this event was widespread following the Ottawan phase of the Grenville Orogeny. ?? 2005 Elsevier B.V. All rights reserved.

Precambrian Research

Vestiges of an Iapetan rift basin in the New Jersey Highlands: Implfications for the Neoproterozoic Laurentian margin

Thin, discontinuous remnants of Neoproterozoic intracratonic rift-basin deposits of the Chestnut Hill Formation occur in the western New Jersey Highlands. These deposits form an important link between well-documented Iapetan rift-basins in both the northern and southern Appalachians. The close spatial relations of Chestnut Hill rocks to Paleozoic sedimentary rocks open the possibility that additional Iapetan rift-basins could be concealed beneath the rocks of the Valley and Ridge Province to the west indicating a much broader zone of rifting than has been previously proposed. The Chestnut Hill Formation is intermittently exposed along a 100 km-long band that extends northeast from Pennsylvania nearly to New York State. The lower part of the Chestnut Hill Formation is composed of interbedded lithic pebble- to boulder-conglomerate and feldspathic sandstone grading upward into interbedded phyllite, feldspathic and quartz sandstone, local paleosaprolite, quartz-pebble conglomerate, thin limestone lenses, volcanic, and volcaniclasic rocks, abundant bedded ironstone (hematite ore), and ultimately into diamictites that are interpreted as possible tilloids and containing rounded intra and extrabasinal clasts of the other lithologies. Extensive soft-sediment deformation, cross bedding, and clastic dikes are common in all but the lowest and upper facies. Banded hematite layers occur preferentially in fine-grained tuffs and tuffaceous sediments, but hematitization has affected most lithologies. Volcanic rocks consist of altered rhyolitic tuffs and lapilli tuffs that are interbedded with sediments. The Chestnut Hill Formation is interpreted to have been deposited in early alluvial, and later a complex of fluvial, lacustrine and deltaic environments. Provenance studies based upon petrographic and geochemical analysis of clastic rocks indicate that the sediments are predominantly immature and reflect derivation from local uplifted felsic basement sources in a rifted-margin tectonic setting. Low to moderate weathering of the source rocks is indicated by the geochemistry of most samples, as is the locally intense effect of hydrothermal alteration. Most occurrences of the Chestnut Hill Formation are associated with major faults that exhibit normal movement of apparent Neoproterozoic age. Rocks from the Morgan Hill fault near Easton, Pennsylvania display consistent normal shear sense and vary from low temperature S-C mylonites to breccia that contains deformed pieces of Chestnut Hill Formation. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics

Geophysical modeling of the northern Appalachian Brompton-Cameron, Central Maine, and Avalon terranes under the New Jersey Coastal Plain

A regional terrane map of the New Jersey Coastal Plain basement was constructed using seismic, drilling, gravity and magnetic data. The Brompton-Cameron and Central Maine terranes were coalesced as one volcanic island arc terrane before obducting onto Laurentian, Grenville age, continental crust in the Taconian orogeny [Rankin, D.W., 1994. Continental margin of the eastern United States: past and present. In: Speed, R.C., (Ed.), Phanerozoic Evolution of North American Continent-Ocean Transitions. DNAG Continent-Ocean Transect Volume. Geological Society of America, Boulder, Colorado, pp. 129-218]. Volcanic island-arc rocks of the Avalon terrane are in contact with Central Maine terrane rocks in southern Connecticut where the latter are overthrust onto the Brompton-Cameron terrane, which is thrust over Laurentian basement. Similarities of these allochthonous island arc terranes (Brompton-Cameron, Central Maine, Avalon) in lithology, fauna and age suggest that they are faulted segments of the margin of one major late Precambrian to early Paleozoic, high latitude peri-Gondwana island arc designated as "Avalonia", which collided with Laurentia in the early to middle Paleozoic. The Brompton Cameron, Central Maine, and Avalon terranes are projected as the basement under the eastern New Jersey Coastal Plain based on drill core samples of metamorphic rocks of active margin/magmatic arc origin. A seismic reflection profile across the New York Bight traces the gentle dipping (approximately 20 degrees) Cameron's Line Taconian suture southeast beneath allochthonous Avalon and other terranes to a 4 sec TWTT depth (approximately 9 km) where the Avalonian rocks are over Laurentian crust. Gentle up-plunge (approximately 5 degrees) projections to the southwest bring the Laurentian Grenville age basement and the drift-stage early Paleozoic cover rocks to windows in Burlington Co. at approximately 1 km depth and Cape May Co. at approximately 2 km depths. The antiformal Shellburne Falls and Chester domes and Chain Lakes-Pelham dome-Bronson Hill structural trends, and the synformal Connecticut Valley-Gaspe structural trend can be traced southwest into the New Jersey Coastal Plain basement. A Mesozoic rift basin, the "Sandy Hook basin", and associated eastern boundary fault is identified, based upon gravity modeling, in the vicinity of Sandy Hook, New Jersey. The thickness of the rift-basin sedimentary rocks contained within the "Sandy Hook basin" is approximately 4.7 km, with the basin extending offshore to the east of the New Jersey coast. Gravity modeling indicates a deep rift basin and the magnetic data indicates a shallow magnetic basement caused by magnetic diabase sills and/or basalt flows contained within the rift-basin sedimentary rocks. The igneous sills and/or flows may be the eastward continuation of the Watchung and Palisades bodies. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics

Sr and Nd isotopic compositions, age and petrogenesis of A-type granitoids of the Vernon Supersuite, New Jersey Highlands, USA

Voluminous late Mesoproterozoic monzonite through granite of the Vernon Supersuite underlies an area of approximately 1300 km2 in the Highlands of northern New Jersey. The Vernon Supersuite consists of hastingsite ?? biotite-bearing granitoids of the Byram Intrusive Suite (BIS) and hedenbergite-bearing granitoids of the Lake Hopatcong Intrusive Suite (LHIS). These rocks have similar major and trace element abundances over a range of SiO2 from 58 to 75 wt.%, are metaluminous to weakly peraluminous, and have a distinctive A-type chemistry characterized by high contents of Y, Nb, Zr, LREE, and Ga/Al ratios, and low MgO, CaO, Sr and HREE. Whole-rock Rb-Sr isochrons of BIS granite yield an age of 1116 ?? 41 Ma and initial 87Sr/86Sr ratio of 0.70389, and of LHIS granite an age of 1095 ?? 9 Ma and initial 87Sr/86Sr ratio of 0.70520. Both suites have similar initial 143Nd/144Nd ratios of 0.511267 to 0.511345 (BIS) and 0.511359 to 0.511395 (LHIS). Values of ??(Nd) are moderately high and range from +1.21 to +2.74 in the BIS and +2.24 +2.95 in the LHIS. Petrographic evidence, field relationships, geochemistry, and isotopic data support an interpretation of comagmatism and the derivation of both suites from a mantle-derived or a juvenile lower crustal parent with little crustal assimilation. Both suites crystallized under overlapping conditions controlled by P-T-f(H(2)O). Lake Hopatcong magma crystallized at a liquidus temperature that approached 900??C and a pressure of about 6 kbar, and remained relatively anhydrous throughout its evolution. Initial P-T conditions of the Byram magma were ??? 850??C and about 5.5 kbar. BIS magma was emplaced contemporaneous with, or slightly preceding LHIS magma, and both magmas were emplaced during a compressional tectonic event prior to granulite facies metamorphism that occurred in the Highlands between 1080 and 1030 Ma. (C) 2000 Elsevier Science B.V. All rights reserved.

LITHOS

Mesoproterozoic graphite deposits, New Jersey Highlands: Geologic and stable isotopic evidence for possible algal origins

Graphite deposits of Mesoproterozoic age are locally abundant in the eastern New Jersey Highlands, where they are hosted by sulphidic biotite–quartz–feldspar gneiss, metaquartzite, and anatectic pegmatite. Gneiss and metaquartzite represent a shallow marine shelf sequence of locally organic-rich sand and mud. Graphite from massive deposits within metaquartzite yielded δ13C values of –26 ± 2‰ (1σ), and graphite from massive deposits within biotite–quartz–feldspar gneiss yielded δ13C values of –23 ± 4‰. Disseminated graphite from biotite–quartz–feldspar gneiss country rock was –22 ± 3‰, indistinguishable from the massive deposits hosted by the same lithology. Anatectic pegmatite is graphitic only where generated from graphite-bearing host rocks; one sample gave a δ13C value of –15‰. The δ34S values of trace pyrrhotite are uniform within individual deposits, but vary from 0 to 9‰ from one deposit to another. Apart from pegmatitic occurrences, evidence is lacking for long-range mobilization of carbon during Grenvillian orogenesis or post-Grenvillian tectonism. The field, petrographic, and isotope data suggest that massive graphite was formed by granulite-facies metamorphism of Proterozoic accumulations of sedimentary organic matter, possibly algal mats. Preservation of these accumulations in the sedimentary environment requires anoxic basin waters or rapid burial. Anoxia would also favour the accumulation of dissolved ferrous iron in basin waters, which may explain some of the metasediment-hosted massive magnetite deposits in the New Jersey Highlands.

New Jersey

Generation of trondhjemite from partial melting of dacite under granulite facies conditions: An example from the New Jersey Highlands, USA

New field and geochemical data place the Losee Metamorphic Suite (a tonalite/trondhjemite complex) of northern New Jersey into the context of a major Proterozoic continental are represented by a discontinuous belt of northern Appalachian metadacite. Samples of Losee rock range from extremely leucocratic trondhjemite locally associated with amphibolite, to banded biotite, hornblende, pyroxene, and garnet-bearing tonalites. The major element and REE composition of the tonalite closely resembles dacite from continental are settings and model melts extracted from an eclogite residue by partial melting at 15 kbar. The REE composition of most Losee trondhjemite is enriched in REE, particularly HREE, compared with Losee tonalite, and is interpreted as the product of local anatectic melting of Losee tonalite (metadacite) that occurred in a granulite facies environment during the Grenville orogeny.

New Jersey