Geology Reports⌕ Search

Geology topics

Peter D. Warwick

Publications and source records attributed to Peter D. Warwick.

At least 37 records · Page 2Linked to original sources

National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources — Summary

Introduction In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources that might be produced by using current carbon dioxide enhanced oil recovery (CO 2 -EOR) technologies in amenable conventional oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes estimates of the mass of CO 2 that could be stored (retained) in the assessed oil reservoirs following the application of the CO 2 -EOR process. The USGS assessment team evaluated more than 3,500 oil reservoirs that were miscible to injected CO 2 . The assessed reservoirs are in 185 previously defined USGS plays in 33 petroleum provinces of 7 national regions. The team estimated that the total technically recoverable oil resulting from the application of the CO 2 -EOR process ranges from approximately 25,000 million barrels (MMbbl) at the P 5 percentile to as much as 32,000 MMbbl at the P 95 percentile, with a mean of 29,000 MMbbl. The associated CO 2 retention ranges from approximately 7,400 million metric tons (Mt) at the P 5 percentile to as much as 9,500 Mt at the P 95 percentile, with a mean of 8,400 Mt. The results are summarized in this fact sheet and are provided in more detail in the companion data release and circular. The West Texas and Eastern New Mexico region (primarily its Permian Basin) and the Gulf Coast region together contain 60 percent of the mean assessed CO 2 -EOR oil potential and 61 percent of the mean assessed CO 2 retention. Other regions with significant resource potential include the Midcontinent region and the Rocky Mountains and Northern Great Plains region.

Continental United States↗

Assessing global geologic carbon dioxide storage resources

The U.S. Geological Survey (USGS), in conjunction with the U.S. Department of Energy (U.S. DOE) Office of Fossil Energy and Carbon Management (FECM), the IEA Greenhouse Gas R&D Programme (IEAGHG), and the Clean Energy Ministerial Carbon Capture, Utilization and Storage Initiative (CEM-CCUS Initiative), plans to work with partner nations to assess geologic carbon dioxide (CO2) storage resources globally. The goal of this work is to help countries, particularly those with emerging economies, understand the mass of CO2 they could potentially store in geologic units within their borders. Knowledge of the CO2 storage resources in their geologic units can provide countries pathways for reducing emissions to meet their future climate mitigation goals.

Conference Paper↗

Assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources of the United States

In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources that could be produced using current carbon dioxide enhanced oil recovery (CO2-EOR) technologies in amenable conventional oil reservoirs underlying onshore and State-owned offshore waters (herein after, onshore and State waters areas) of the conterminous United States. Our assessment also includes estimates of the mass of CO2 that could be stored (retained) in the assessed oil reservoirs following the application of the CO2-EOR process. The USGS assessment team evaluated more than 3,500 oil reservoirs that were amenable to miscible CO2 injection. The assessed reservoirs are located in 185 plays previously defined by a USGS National Oil and Gas Assessment in 33 petroleum provinces of seven national regions. The team estimated that the total technically recoverable oil resulting from the application of the CO2-EOR process ranges from approximately 25,000 million barrels (MMbbl) at the P5 probability percentile to as much as 32,000 MMbbl at the P95 probability percentile, with a mean of 29,000 MMbbl. The associated CO2 retention ranges from approximately 7,400 million metric tons (Mt) at the P5 percentile to as much as 9,500 Mt at the P95 percentile, with a mean of 8,400 Mt.

conterminous United States↗

Methodology for estimating the prospective CO2 storage resource of residual oil zones at the national and regional scale

Residual oil zones (ROZs) are increasingly gaining interest as potential reservoirs for carbon dioxide (CO 2 ) storage. Here, we present a national- and regional-scale methodology for estimating prospective CO 2 storage resources in residual oil zones. This methodology uses a volumetric equation that accounts for CO 2 storage as a free phase in pore space and as a dissolved phase in oil and does not assume any oil production associated with CO 2 storage. Reservoir modeling and the CO 2 -SCREEN tool are used to demonstrate that CO 2 storage in residual oil zones will predominantly take place in the free phase (approximately 92–97%) with some storage as dissolution in oil (approximately 3–8 %). Based on this preliminary demonstration, the CO 2 storage efficiency for ROZs using this national- and regional-scale method ranges from 0.61 to 7.1 %. This range indicates ROZs have a similar efficiency potential for storing CO 2 as deep saline formations (0.51–5.4 %).

International Journal of Greenhouse Gas Control↗

A probabilistic assessment methodology for carbon dioxide enhanced oil recovery and associated carbon dioxide retention

The U.S. Energy Independence and Security Act of 2007 authorized the U.S. Geological Survey (USGS) to conduct a national assessment of the potential volume of hydrocarbons recoverable by injection of carbon dioxide (CO 2 ) into known oil reservoirs with historical production. The implementation of CO 2 enhanced oil recovery (CO 2 -EOR) techniques could increase the U.S. recoverable hydrocarbon resource base. Use of anthropogenic CO 2 in the CO 2 -EOR process could reduce the amount of CO 2 released to the atmosphere by allowing a percentage of the injected CO 2 to remain in reservoir pore space once occupied by produced oil and water or by CO 2 dissolution in oil and water in the reservoir. The USGS has developed a new methodology for the national assessment of technically recoverable oil resources that may be produced by using current CO 2 -EOR technologies. The methodology relies on a proprietary reservoir-level database, the comprehensive resource database (CRD). The CRD incorporates commercially available geologic and engineering data, and USGS-defined play averages or province averages of reservoir data were used to populate incomplete records. Values from the CRD are used to estimate the original oil in place ( OOIP ) for each reservoir. The inputs are reviewed by USGS geologists, particularly when play or province averages have been used. Monte Carlo simulation is used to produce a numerical probability distribution for the OOIP for each reservoir, with the mean defined as the value of the OOIP in the CRD. A reservoir model (CO 2 Prophet, developed for the U.S. Department of Energy by Texaco, Inc.) is used to determine the incremental recovery factors for oil during the CO 2 -EOR process, on an individual reservoir basis. The model is also used to estimate the volume of CO 2 remaining in the reservoir after the CO 2 -EOR process is complete. Empirical decline curve analysis and comparison with data from published papers and reports on CO 2 -EOR projects are utilized to substantiate the simulation results. Numerical distributions of recovery factors are prepared for variations in the reservoir lithology (clastic or carbonate). The distribution of incremental oil is computed by multiplying the appropriate probability distribution of recovery factors by the individual reservoir distribution of the OOIP . A way to estimate the CO 2 remaining in the reservoir after the completion of the CO 2 -EOR process is also included in the methodology. Assessment results will be aggregated to play, petroleum province, regional, and national scales. This assessment methodology has been tested on the Horseshoe Atoll, Upper Pennsylvanian-Wolfcampian play in the Permian Basin Province in Texas; the play consists of 27 reservoirs having at least 2 billion barrels of OOIP that are amenable to the CO 2 -EOR process. The play was selected as a test case because CO 2 -EOR production data and published reports are available for several reservoirs within the play. Preliminary estimates of oil recoverable by implementation of miscible CO 2 -EOR are comparable to those reported in the literature and obtained by reservoir decline curve analysis.

Scientific Investigations Report↗

Preliminary GIS representation of deep coal areas for carbon dioxide storage in the contiguous United States and Alaska

This report and its accompanying geospatial data outline many areas of coal in the United States beneath more than 3,000 ft of overburden. Based on depth, these areas may be targets for injection and storage of supercritical carbon dioxide. Additional areas where coal exists beneath more than 1,000 ft of overburden are also outlined; these may be targets for geologic storage of carbon dioxide in conjunction with enhanced coalbed methane production. These areas of deep coal were compiled as polygons into a shapefile for use in a geographic information system (GIS). The coal-bearing formation names, coal basin or field names, geographic provinces, coal ranks, coal geologic ages, and estimated individual coalbed thicknesses (if known) of the coal-bearing formations were included. An additional point shapefile, coal_co2_projects.shp, contains the locations of pilot projects for carbon dioxide injection into coalbeds. This report is not a comprehensive study of deep coal in the United States. Some areas of deep coal were excluded based on geologic or data-quality criteria, while others may be absent from the literature and still others may have been overlooked by the authors.

Open-File Report↗

Assessment of coal mine methane (CMM) and abandoned mine methane (AMM) resource potential of longwall mine panels: example from Northern Appalachian Basin, USA

"Coal mine methane (CMM) and abandoned mine methane (AMM), are by-products of underground coal mining. The quantity and the emission rate of CMM and AMM may vary depending on the type of mine, gas content of the mined coal seam, and gas sourced from strata and coal beds in overlying and underlying formations affected by mining. Therefore, if a mine has the potential of accumulating gas after being abandoned and sealed properly, methane may be produced and used as an energy source to serve to local communities around the mine. Producing AMM also prevents methane, which is a potent greenhouse gas, from leaking to the atmosphere through seals, shaft plugs or surface cracks. One of the technical barriers in front of investments to economical utilization of CMM and AMM is the difficulty to predict how much methane may be available in the gas emission zone (GEZ) as a resource during mining, and after the panels are sealed and the mine is abandoned. Another difficulty is to estimate how much of the potential methane resource can be produced, and its production feasibility with boreholes, such as gob gas ventholes (GGV) converted to capture AMM. In this study, a comparative assessment is presented to address the issues stated above. The assessment was conducted on two adjacent panels of a longwall mine that operated until 2016 in the Pennsylvania section of the Northern Appalachian Basin. The study is based on two approaches that might be used depending on the availability of data, extensive or minimal. The first approach uses an extensive geological data set, geostatistics, and measured shaft gas emission and GGV production values that were collected while the panel(s) were active to assess the AMM resource. The second approach uses a minimal amount of geologic data and its uncertainty as probabilistic distributions as well as predicted during-mining emissions using a publicly available software. Results showed that both approaches provide relatively comparable estimates of AMM resources and AMM recovery potential using wellbores. The differences in assessed quantities are mostly due to the characteristics of the two methods. In that regard, this paper can be considered as guidance to choose the assessment approach based on data availability. "

Northern Appalachian Basin↗

Improving pressure-limited CO2 storage capacity in saline formations by means of brine extraction

The carbon dioxide (CO 2 ) storage capacity of saline formations may be constrained by reservoir pressure limitations. Brine extraction could be necessary to increase the CO 2 storage capacity of a given formation, manage the extent of the underground CO 2 plume and induced pressure front, and control the migration direction. To estimate the additional CO 2 storage capacity of a saline formation that can be made accessible by extraction of in-situ brines, a three-dimensional (3D) generic cubic cell containing one CO 2 injector in the middle surrounded by four brine extractors at each corner of the cell was assumed. A series of Tough2-ECO2N reservoir simulations were constructed with varying reservoir properties and run. Based on a series of scenarios, a mechanism was developed and demonstrated that resulted in derivation of a function to provide estimates of the ratio of total CO 2 injection over the brine extraction rate for a given scenario. We selected multiple saline formations in U.S. basins and evaluated the potential to increase the combined dynamic CO 2 storage capacity of the selected saline formations to over 1000 million metric tonnes per year (Mt/yr) of CO 2 for 100 years by means of brine extraction. Such storage capacities may be adequate to accommodate the CO 2 injection rates suggested for the United States under a “beyond two-degree Celsius scenario” (B2DS) that has been proposed to maintain global temperature rise to less than 2°C above pre-industrial reported levels. The results suggest that B2DS goals could be achieved with a volume ratio of brine extraction to CO 2 injection as low as 1:4, which is far lower than the ratios that have been commonly assumed in the literature.

International Journal of Greenhouse Gas Control↗

Carbon dioxide enhanced oil recovery and residual oil zone studies at the U.S. Geological Survey

The U.S. Geological Survey (USGS) is preparing a national resource assessment of the potential hydrocarbons recoverable after injection of carbon dioxide (CO2) into conventional oil reservoirs in the United States. The implementation of CO2-enhanced oil recovery (CO2-EOR) techniques can increase hydrocarbon production, and lead to incidental retention of CO2 in reservoir pore space allowing long-term storage of anthropogenic CO2. A Comprehensive Resource Database (CRD) containing proprietary data on location, geologic, petrophysical, and reservoir parameters, plus production and well counts for major oil and gas reservoirs in onshore areas and State waters of the conterminous United States and Alaska, was developed to support the USGS assessment. Residual oil zones (ROZs) also can provide potential pore space for long-term storage of anthropogenic CO2. However, ROZs are not included in the upcoming USGS national CO2-EOR assessment because assessment methods for ROZs still are being developed. Additional ROZ CO2-EOR and CO2 retention data and reservoir simulations are needed to calibrate national ROZ assessment estimates.

Conference Paper↗

Federal lands greenhouse emissions and sequestration in the United States—Estimates for 2005–14

In January 2016, the Secretary of the U.S. Department of the Interior tasked the U.S. Geological Survey (USGS) with producing a publicly available and annually updated database of estimated greenhouse gas emissions associated with the extraction and use (predominantly some form of combustion) of fossil fuels from Federal lands. In response, the USGS has produced estimates of the greenhouse gas emissions resulting from the extraction and end-use combustion of fossil fuels produced on Federal lands in the United States, as well as estimates of ecosystem carbon emissions and sequestration on those lands. American Indian and Tribal lands were not included in this analysis. The emissions estimates span a 10-year period (2005–14) and are reported for 28 States and two offshore areas. Nationwide emissions from fossil fuels produced on Federal lands in 2014 were 1,279.0 million metric tons of carbon dioxide equivalent (MMT CO 2 Eq.) for carbon dioxide (CO 2 ), 47.6 MMT CO 2 Eq. for methane (CH 4 ), and 5.5 MMT CO 2 Eq. for nitrous oxide (N 2 O). Compared to 2005, the 2014 totals represent decreases in emissions for all three greenhouse gases (decreases of 6.1 percent for CO 2 , 10.5 percent for CH 4 , and 20.3 percent for N 2 O). Emissions from fossil fuels produced on Federal lands represent, on average, 23.7 percent of national emissions for CO 2 , 7.3 percent for CH 4 , and 1.5 percent for N 2 O over the 10 years included in this estimate. In 2005, Federal lands of the conterminous United States stored 82,289 MMT CO 2 Eq. in terrestrial ecosystems. By 2014, carbon storage, or sequestration, was estimated at 83,600 MMT CO 2 Eq., representing an increase of 1.6 percent, or 1,311 MMT CO 2 Eq. Soils stored most of the ecosystem carbon (63 percent), followed by live vegetation (26 percent) and dead organic matter (11 percent). The rate of net carbon uptake in ecosystems ranged from a sink (sequestration) of 475 million metric tons of carbon dioxide per year (MMT CO 2 Eq./yr) to a source (emission) of 51 MMT CO 2 Eq./yr because of annual variability in climate and weather, rates of land-use and land-cover change, and wildfire frequency, among other factors. At the national level, the USGS estimates that terrestrial ecosystems (forests, grasslands, and shrublands) on Federal lands sequestered an average of 195 MMT CO 2 Eq./yr between 2005 and 2014, offsetting approximately 15 percent of the CO 2 emissions resulting from the extraction of fossil fuels on Federal lands and their end-use combustion. The USGS estimates presented in this report represent a first-of-its-kind accounting for the emissions resulting from fossil fuel extraction on Federal lands and the end-use combustion of those fuels, as well as for the sequestration of carbon in terrestrial ecosystems on Federal lands. The net CO 2 emissions estimate, which is the difference between the emitted and sequestered CO 2 , provides an informative combined result describing the emissions (fossil fuel extraction and end-use combustion) associated with a State’s Federal lands and sequestration on those same lands. The estimates included in this report can provide context for future energy decisions, as well as a basis to track change in the future.

Scientific Investigations Report↗

Geologic framework for the national assessment of carbon dioxide storage resources—Atlantic Coastal Plain and Eastern Mesozoic Rift Basins

This chapter presents information pertinent to the geologic carbon dioxide (CO 2 ) sequestration potential within saline aquifers located in the Atlantic Coastal Plain and Eastern Mesozoic Rift Basins of the Eastern United States. The Atlantic Coastal Plain is underlain by a Jurassic to Quaternary succession of sedimentary strata that onlap westward onto strata of the Appalachian Piedmont physiographic province and generally thicken eastward toward the present-day Atlantic coastline and onto the present-day continental shelf. Although no significant petroleum discoveries have been made on the coastal plain, the deep saline aquifers of the region appear to contain porous strata (potential reservoirs, or “storage formations”) that are overlain by fine-grained, laterally continuous strata (potential seals), which are prospective CO 2 sequestration targets. For the Atlantic Coastal Plain, we identify two storage assessment units (SAUs), both of which consist of Cretaceous strata. The two SAUs are the Lower Cretaceous Composite SAU C50700101 and the Upper Cretaceous Composite SAU C50700102. The Eastern Mesozoic Rift Basins are a chain of generally southwest- to northeast-trending, elongate sedimentary basins that either underlie the Atlantic Coastal Plain or crop out within adjacent geologic provinces to the west. Similar to the Atlantic Coastal Plain, there has been no significant oil and gas production from any of the basins, although there is a proven petroleum system in several of them. At least three of these basins appear to contain potential storage formations overlain by potential seal units. Most of the other basins were not assessed because a storage and (or) seal formation could not be established in the timeframe of the assessment, often because of the paucity of subsurface data for these basins in comparison to other petroliferous basins of the United States. Thus, we present information supporting one quantitative assessment in the Newark basin, as well as information supporting two nonquantitative assessments, one for strata in the Gettysburg basin and the other for strata in the Culpeper basin. We briefly discuss six other basins within the Eastern Mesozoic Rift Basins that were not assessed. For all SAUs, we discuss the areal distribution of suitable CO 2 reservoir rock. We also describe the overlying sealing unit and the geologic characteristics that influence the potential CO 2 storage volume and reservoir characteristics. These characteristics include storage formation depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this chapter, the geologic information included herein was used to calculate the potential storage space in the SAUs.

Atlantic Coastal Plain and Eastern Mesozoic Rift B↗

Estimating the pressure-limited CO2 injection and storage capacity of the United States saline formations: Effect of the presence of hydrocarbon reservoirs

The U.S. Geological Survey (USGS) national assessment of carbon dioxide (CO 2 ) storage capacity evaluated 192 saline Storage Assessment Units (SAUs) in 33 U.S. onshore sedimentary basins that may be utilized for CO 2 storage (see USGS Circular 1386). Similar to many other available models, volumetric analysis was utilized to estimate the initial CO 2 injection and storage capacity of these SAUs based on aquifer characteristics and buoyant and residual trapping. The factor being almost always overlooked in most CO 2 storage capacity models is that many of the evaluated SAUs contain large numbers of both conventional and unconventional discovered and undiscovered oil and gas reservoirs. The hydrocarbon production and pressure distribution of the resident oil and gas reservoirs may be negatively influenced by the propagated CO 2 plume and pressure front resulting from a CO 2 injection and storage operation in the surrounding SAU. To have a more realistic and accurate estimation of CO 2 injection and storage capacity in saline formations, a model was previously developed that considers the CO 2 injectivity of a given formation, underground pressure build-up limitations imposed by the rock fracturing pressure and the presence of hydrocarbon reservoirs within these aquifers. The developed method estimates the pre–brine extraction, pressure-limited CO 2 injection and storage capacity of a saline formation by applying 3D numerical simulation only on the effective injection area (A eff ) surrounding each CO 2 injection well utilizing TOUGH2-ECO2N simulation software.

Sligo and Hosston Formations↗

Overview of a compre­hensive resource database for the assessment of recoverable hydrocarbons produced by carbon dioxide enhanced oil recovery

A database called the “Comprehensive Resource Database” (CRD) was prepared to support U.S. Geological Survey (USGS) assessments of technically recoverable hydrocarbons that might result from the injection of miscible or immiscible carbon dioxide (CO 2 ) for enhanced oil recovery (EOR). The CRD was designed by INTEK Inc., a consulting company under contract to the USGS. The CRD contains data on the location, key petrophysical properties, production, and well counts (number of wells) for the major oil and gas reservoirs in onshore areas and State waters of the conterminous United States and Alaska. The CRD includes proprietary data on petrophysical properties of fields and reservoirs from the “Significant Oil and Gas Fields of the United States Database,” prepared by Nehring Associates in 2012, and proprietary production and drilling data from the “Petroleum Information Data Model Relational U.S. Well Data,” prepared by IHS Inc. in 2012. This report describes the CRD and the computer algorithms used to (1) estimate missing reservoir property values in the Nehring Associates (2012) database, and to (2) generate values of additional properties used to characterize reservoirs suitable for miscible or immiscible CO 2 flooding for EOR. Because of the proprietary nature of the data and contractual obligations, the CRD and actual data from Nehring Associates (2012) and IHS Inc. (2012) cannot be presented in this report.

Techniques and Methods↗

Geologic assessment of undiscovered conventional oil and gas resources in the Lower Paleogene Midway and Wilcox Groups, and the Carrizo Sand of the Claiborne Group, of the Northern Gulf coast region

The U.S. Geological Survey (USGS) recently conducted an assessment of the undiscovered, technically recoverable oil and gas potential of Tertiary strata underlying the onshore areas and State waters of the northern Gulf of Mexico coastal region. The assessment was based on a number of geologic elements including an evaluation of hydrocarbon source rocks, suitable reservoir rocks, and hydrocarbon traps in an Upper Jurassic-Cretaceous-Tertiary Composite Total Petroleum System defined for the region by the USGS. Five conventional assessment units (AUs) were defined for the Midway (Paleocene) and Wilcox (Paleocene-Eocene) Groups, and the Carrizo Sand of the Claiborne Group (Eocene) interval including: (1) the Wilcox Stable Shelf Oil and Gas AU; (2) the Wilcox Expanded Fault Zone Gas and Oil AU; (3) the Wilcox-Lobo Slide Block Gas AU; (4) the Wilcox Slope and Basin Floor Gas AU; and (5) the Wilcox Mississippi Embayment AU (not quantitatively assessed). The USGS assessment of undiscovered oil and gas resources for the Midway-Wilcox-Carrizo interval resulted in estimated mean values of 110 million barrels of oil (MMBO), 36.9 trillion cubic feet of gas (TCFG), and 639 million barrels of natural gas liquids (MMBNGL) in the four assessed units. The undiscovered oil resources are almost evenly divided between fluvial-deltaic sandstone reservoirs within the Wilcox Stable Shelf (54 MMBO) AU and deltaic sandstone reservoirs of the Wilcox Expanded Fault Zone (52 MMBO) AU. Greater than 70 percent of the undiscovered gas and 66 percent of the natural gas liquids (NGL) are estimated to be in deep (13,000 to 30,000 feet), untested distal deltaic and slope sandstone reservoirs within the Wilcox Slope and Basin Floor Gas AU.

Gulf of Mexico↗

3D Pressure‐limited approach to model and estimate CO2 injection and storage capacity: saline Mount Simon Formation

To estimate the carbon dioxide (CO 2 ) injection and storage capacity of saline formations, we used Tough2‐ECO2N simulation software to develop a pressure‐limited (dynamic) simulation approach based on applying three‐dimensional (3D) numerical simulation only on the effective injection area (A eff ) surrounding each injection well. A statistical analysis was performed to account for existing reservoir heterogeneity and property variations. The accuracy of the model simulation results (such as CO 2 plume extension and induced injection well bottomhole pressure values) were tested and verified against the data obtained from the Decatur CO 2 injection study of the Mount Simon Formation. Next, we designed a full‐field CO 2 injection pattern by populating the core sections of this formation with a series of the simulated effective injection areas such that each simulated A eff acts as a closed domain. The results of this analysis were used to estimate the optimum number and location of the required CO 2 injection wells, along with the dynamic annual CO 2 injection rate and overall pressure‐limited storage capacity of this formation. This approach enabled us to model separate CO 2 injection activities independently at different sections of the same saline formation and to model and simulate faults and natural barriers by considering them as boundary conditions for each simulated A eff without constructing full‐field models. Using this approach, a series of modeled A eff with relevant properties may be redesigned to model any other saline formation with a similar structure.

Mount Simon Formation↗

A database and probabilistic assessment methodology for carbon dioxide enhanced oil recovery and associated carbon dioxide retention in the United States

The U.S. Geological Survey (USGS) has developed an assessment methodology for estimating the potential incremental technically recoverable oil resources resulting from carbon dioxide-enhanced oil recovery (CO 2 -EOR) in reservoirs with appropriate depth, pressure, and oil composition. The methodology also includes a procedure for estimating the CO 2 that remains in the reservoir after the CO 2 -EOR process is complete. The methodology relies on a reservoir-level database that incorporates commercially available geologic and engineering data. The mathematical calculations of this assessment methodology were tested and produced realistic results for the Permian Basin Horseshoe Atoll, Upper Pennsylvanian-Wolfcampian Play (Texas, USA). The USGS plans to use the new methodology to conduct an assessment of technically recoverable hydrocarbons and associated CO 2 sequestration resulting from CO 2 -EOR in the United States.

Energy Procedia↗

Environmental drivers of differences in microbial community structure in crude oil reservoirs across a methanogenic gradient

Stimulating in situ microbial communities in oil reservoirs to produce natural gas is a potentially viable strategy for recovering additional fossil fuel resources following traditional recovery operations. Little is known about what geochemical parameters drive microbial population dynamics in biodegraded, methanogenic oil reservoirs. We investigated if microbial community structure was significantly impacted by the extent of crude oil biodegradation, extent of biogenic methane production, and formation water chemistry. Twenty-two oil production wells from north central Louisiana, USA, were sampled for analysis of microbial community structure and fluid geochemistry. Archaea were the dominant microbial community in the majority of the wells sampled. Methanogens, including hydrogenotrophic and methylotrophic organisms, were numerically dominant in every well, accounting for, on average, over 98% of the total Archaea present. The dominant Bacteria groups were Pseudomonas, Acinetobacter , Enterobacteriaceae, and Clostridiales, which have also been identified in other microbially-altered oil reservoirs. Comparing microbial community structure to fluid (gas, water, and oil) geochemistry revealed that the relative extent of biodegradation, salinity, and spatial location were the major drivers of microbial diversity. Archaeal relative abundance was independent of the extent of methanogenesis, but closely correlated to the extent of crude oil biodegradation; therefore, microbial community structure is likely not a good sole predictor of methanogenic activity, but may predict the extent of crude oil biodegradation. However, when the shallow, highly biodegraded, low salinity wells were excluded from the statistical analysis, no environmental parameters could explain the differences in microbial community structure. This suggests that the microbial community structure of the 5 shallow, up-dip wells was different than the 17 deeper, down-dip wells. Also, the 17 down-dip wells had statistically similar microbial communities despite significant changes in environmental parameters between oil fields. Together, this implies that no single microbial population is a reliable indicator of a reservoir's ability to degrade crude oil to methane, and that geochemistry may be a more important indicator for selecting a reservoir suitable for microbial enhancement of natural gas generation.

Louisiana↗