Paul Edwards | Geology Reports

USGS2021

Numerical modelling of mine pollution to inform remediation decision-making in watersheds

Prioritisation of mine pollution sources for remediation is a key challenge facing environmental managers. This paper presents a numerical modelling methodology to evaluate potential improvements in stream water quality from remediation of important mine pollution sources. High spatial resolution synoptic sampling data from a Welsh watershed were used to calibrate the OTIS solute transport model. Simulation of mine pollution remediation scenarios using OTIS revealed decreases in stream Zn concentrations between 9% and 62% under mean streamflow conditions. Remediation scenarios under low streamflow conditions were less effective (<1% to 17% decrease in Zn concentrations), due to diffuse and metal-rich groundwater inflows.

Nant Cwmnewyddion watershed↗

USGS2020

Critical shifts in trace metal transport and remediation performance under future low river flows

Exceptionally low river flows are predicted to become more frequent and more severe across many global regions as a consequence of climate change. Investigations of trace metal transport dynamics across streamflows reveal stark changes in water chemistry, metal transformation processes, and remediation effectiveness under exceptionally low-flow conditions. High spatial resolution hydrological and water quality datasets indicate that metal-rich groundwater will exert a greater control on stream water chemistry and metal concentrations because of climate change. This is because the proportion of stream water sourced from mined areas and mineralized strata will increase under predicted future low-flow scenarios (from 25% under Q45 flow to 66% under Q99 flow in this study). However, mineral speciation modelling indicates that changes in stream pH and hydraulic conditions at low flow will decrease aqueous metal transport and increase sediment metal concentrations by enhancing metal sorption directly to streambed sediments. Solute transport modelling further demonstrates how increases in the importance of metal-rich diffuse groundwater sources at low flow could minimize the benefits of point source metal contamination treatment. Understanding metal transport dynamics under exceptionally low flows, as well as under high flows, is crucial to evaluate ecosystem service provision and remediation effectiveness in watersheds under future climate change scenarios.

Environmental Science & Technology↗