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P.W. Swarzenski

Publications and source records attributed to P.W. Swarzenski.

25 records · Page 2Linked to original sources
USGS2003

The behavior of U- and Th-series nuclides in groundwater

Groundwater has long been an active area of research driven by its importance both as a societal resource and as a component in the global hydrological cycle. Key issues in groundwater research include inferring rates of transport of chemical constituents, determining the ages of groundwater, and tracing water masses using chemical fingerprints. While information on the trace elements pertinent to these topics can be obtained from aquifer tests using experimentally introduced tracers, and from laboratory experiments on aquifer materials, these studies are necessarily limited in time and space. Regional studies of aquifers can focus on greater scales and time periods, but must contend with greater complexities and variations. In this regard, the isotopic systematics of the naturally occurring radionuclides in the U- and Th- decay series have been invaluable in investigating aquifer behavior of U, Th, and Ra. These nuclides are present in all groundwaters and are each represented by several isotopes with very different half-lives, so that processes occurring over a range of time-scales can be studied (Table 1 ⇓ ). Within the host aquifer minerals, the radionuclides in each decay series are generally expected to be in secular equilibrium and so have equal activities (see Bourdon et al. 2003 ). In contrast, these nuclides exhibit strong relative fractionations within the surrounding groundwaters that reflect contrasting behavior during release into the water and during interaction with the surrounding host aquifer rocks. Radionuclide data can be used, within the framework of models of the processes involved, to obtain quantitative assessments of radionuclide release from aquifer rocks and groundwater migration rates. The isotopic variations that are generated also have the potential for providing fingerprints for groundwaters from specific aquifer environments, and have even been explored as a means for calculating groundwater ages.

Reviews in Mineralogy and Geochemistry↗
USGS2001

Using multiple geochemical tracers to characterize the hydrogeology of the submarine spring off Crescent Beach, Florida

A spectacular submarine spring is located about 4 km east of Crescent Beach, FL, in the Atlantic Ocean. The single vent feature of Crescent Beach Spring provides a unique opportunity to examine onshore–offshore hydrogeologic processes, as well as point source submarine ground water discharge. The Floridan aquifer system in northeastern Florida consists of Tertiary interspersed limestone and dolomite strata. Impermeable beds confine the water-bearing zones under artesian pressure. Miocene and younger confining strata have been eroded away at the vent feature, enabling direct hydrologic communication of Eocene ground water with coastal bottom waters. The spring water had a salinity of 6.02, which was immediately diluted by ambient seawater during advection/mixing. The concentration of major solutes in spring water and onshore well waters confirm a generalized easterly flow direction of artesian ground water. Nutrient concentrations were generally low in the reducing vent samples, and the majority of the total nitrogen species existed as NH 3 . The submarine ground water tracers, Rn-222 (1174 dpm l −1 , dpm), methane (232 nM) and barium (294.5 nM) were all highly enriched in the spring water relative to ambient seawater. The concentrations of the reverse redox elements U, V and Mo were expectedly low in the submarine waters. The strontium isotope ratio of the vent water ( 87 Sr/ 86 Sr=0.70798) suggests that the spring water contain an integrated signature indicative of Floridan aquifer system ground water. Additional Sr isotopic ratios from a series of surficial and Lower Floridan well samples suggest dynamic ground water mixing, and do not provide clear evidence for a single hydrogeologic water source at the spring vent. In this karst-dominated aquifer, such energetic mixing at the vent feature is expected, and would be facilitated by conduit and fractured flow. Radium isotope activities were utilized to estimate flow-path trajectories and to provide information on potential travel times between an onshore well and the spring. Using either 223 Ra and 224 Ra or 228 Ra, and qualifying this approach with several key assumptions, estimates of water mass travel times from an upper Floridan well in Crescent Beach to the submarine vent feature (distance=4050 m) are in the order of ∼0.01–0.1 m min −1 .

Florida↗
USGS2000

Beryllium-7 as a tracer of short-term sediment deposition and resuspension in the Fox River Wisconsin

Short-term (∼monthly) sediment deposition and resuspension rates of surficial bed sediments in two PCB-laden impoundments on the Fox River, WI, were determined in the summer and fall of 1998 using 7 Be, a naturally occurring radioisotope produced in the atmosphere. Decay-corrected activities and inventories of 7 Be were measured in bed sediment and in suspended particles. Beryllium-7 activities generally decreased with depth in the top 5−10 cm of sediments and ranged from undetectable to ∼0.9 pCi cm - 3 . Inventories of 7 Be, calculated from the sum of activities from all depths, ranged from 0.87 to 3.74 pCi cm - 2 , and the values covaried between sites likely reflecting a common atmospheric input signal. Activities of 7 Be did not correlate directly with rainfall. Partitioning the 7 Be flux into “new” and “residual” components indicated that net deposition was occurring most of the time during the summer. Net erosion, however, was observed at the upstream site from the final collection in the fall. This erosion event was estimated to have removed 0.10 g (cm of sediment) - 2 , corresponding to ∼0.5 cm of sediment depth, and ∼6−10 kg of polychlorinated biphenyls (PCBs) over the whole deposit. Short-term accumulation rates were up to ∼130 times higher than the long-term rates calculated from 137 Cs profiles, suggesting an extremely dynamic sediment transport environment, even within an impounded river system.

Environmental Science & Technology↗
USGS1999

Uranium biogeochemistry across the redox transition zone of a permanently stratified fjord: Framvaren, Norway

During August 1995, the vertical concentration profile of dissolved and particulate uranium exhibited strong non-conservative characteristics in the upper 30 m of Framvaren Fjord. There was a pronounced peak in both particulate (> 0.2 ??m; 1.09 nM) and dissolved (< 0.2 ??m; 17.06 nM) uranium in the finely stratified waters at the O2/H2S interface which is positioned well within the euphotic zone at about 20-21 m. Such concentration maxima at the redox boundary are also observed for dissolved organic carbon (DEC), Sr and Ba. Dissolved U levels seen in the water column from 18 m down to 30 m exceeded the high salinity (salinity = 35) U concentrations (13.63 ?? 0.84 nM; Chen, J.H., Edwards, R.L., Wasserburg, G.L., 1986. 238U, 234U and 232Th in seawater. Earth Planet Sci. Lett. 80, 241-251.) observed uniformly in the open ocean. A prolific population of S microbes (e.g., Chromatium, Chlorobium sp.) flourishes at the O2/H2S interface. The source of elevated U at the redox boundary must be due to microbial uptake and subsequent release processes rather than dilution from oceanic uranium. Uranium oxidation state determinations in waters from 1, 22 and 30 m depth reveal that reduced U(IV) is not present in significant abundance, and that the chemical and/or biological reduction of hexavalent uranium is largely inhibited. Our results suggest that U and other trace constituents such as DOC, Sr, Ba, Fe(II), Mn(II) are greatly modified by direct and indirect microbial transformation reactions which are most concentrated across the redox transition zone in Framvaren Fjord.

Marine Chemistry↗
USGS1998

Seasonal uranium distributions in the coastal waters off the Amazon and Mississippi Rivers

The chemical reactivity of uranium was investigated across estuarine gradients from two of the world’s largest river systems: the Amazon and Mississippi. Concentrations of dissolved (<0.45 μm) uranium (U) were measured in surface waters of the Amazon shelf during rising (March 1990), flood (June 1990) and low (November 1991) discharge regimes. The dissolved U content was also examined in surface waters collected across estuarine gradients of the Mississippi outflow region during April 1992, August 1993, and November (1993). All water samples were analyzed for U by isotope dilution inductively coupled plasma mass spectrometry (ICP-MS). In Amazon shelf surface waters uranium increased nonconservatively from about 0.01 μg I −1 at the river’s mouth to over 3 μg I −1 at the distal site, irrespective of river discharge stage. Observed large-scale U removal at salinities generally less than 15 implies a) that riverine dissolved U was extensively adsorbed by freshly-precipitated hydrous metal oxides (e.g., FeOOH, MnO 2 ) as a result of flocculation and aggregation, and b) that energetic resuspension and reworking of shelf sediments and fluid muds on the Amazon shelf released a chemically reactive particle/colloid to the water column which can further scavenge dissolved U across much of the estuarine gradient. In contrast, the estuarine chemistry of U is inconclusive within surface waters of the Mississippi shelf-break region. U behavior is most likely controlled less by traditional sorption and/or desorption reactions involving metal oxides or colloids than by the river’s variable discharge regime (e.g., water parcel residence time during estuarine mixing, nature of particulates, sediment storage and resuspension in, the confined lower river), and plume dispersal. Mixing of the thin freshwater lens into ambient seawater is largely defined by wind-driven rather than physical processes. As a consequence, in the Mississippi outflow region uranium predominantly displays conservative behavior; removal is evident only during anomalous river discharge regimes. ‘Products-approach’ mixing experiments conducted during the Flood of 1993 suggest the importance of small particles and/or colloids in defining a depleted U versus salinity distribution.

Louisiana↗