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P.J. Wallace

Publications and source records attributed to P.J. Wallace.

3 recordsLinked to original sources

Understanding melt evolution and eruption dynamics of the 1666 C.E. eruption of Cinder Cone, Lassen Volcanic National Park, California: Insights from olivine-hosted melt inclusions

Cinder Cone is the youngest scoria cone volcano in the continental United States. Erupted in 1666 C.E. within what is now Lassen Volcanic National Park, Cinder Cone is an un-vegetated scoria cone with well-preserved lava flows and tephra deposits that display complex geochemical variability. In this study, we utilize the volatile (H 2 O, CO 2, Cl), major, and trace element chemistry of olivine-hosted melt inclusions from the tephra deposit of Cinder Cone to better understand the sub-surface evolution of magmas that erupt to produce scoria cones. High-Fo olivine phenocrysts from all erupted units contain melt inclusions that are more primitive in composition than the erupted material. The evolved compositions of the lava and bulk tephra and the abundance of quartz xenocrysts within the deposits suggest the basaltic parental magmas were rapidly contaminated by granitic material in the middle to upper crust, after melt inclusion entrapment. Distinct compositional variability between early and late erupted units suggests two different mantle-derived basaltic magmas were tapped and erupted sequentially as two distinct eruptive phases. The CO 2 concentrations in the melt inclusions, after correction for the presence of vapor bubbles, suggest minimum entrapment depths of ~9.5–20 km and show no resolvable differences between early and late erupted units at the time of olivine crystallization. Diffusion modeling of Ni and Fo gradients in olivine rims indicates that olivine residence times in an evolving magma were on the order of weeks to years, similar to those calculated for longer-lived scoria cone eruptions, such as Jorullo, in Mexico. Additionally, geochemical evidence suggests that the evolution of parental magmas was likely driven by the partial melting, disaggregation, and assimilation of granitic material in the upper crust. Our combined results provide new insight into the complexities of short-lived monogenetic eruptions.

California

Summit CO 2 emission rates by the CO 2 /SO 2 ratio method at Kīlauea Volcano, Hawaiʻi, during a period of sustained inflation

The emission rate of carbon dioxide escaping from the summit of Kīlauea Volcano, Hawaiʻi, proved highly variable, averaging 4900 ± 2000 metric tons per day (t/d) in June–July 2003 during a period of summit inflation. These results were obtained by combining over 90 measurements of COSPEC-derived SO 2 emission rates with synchronous CO 2 /SO 2 ratios of the volcanic gas plume along the summit COSPEC traverse. The results are lower than the CO 2 emission rate of 8500 ± 300 t/d measured by the same method in 1995–1999 during a period of long-term summit deflation [Gerlach, T.M., McGee, K.A., Elias, T., Sutton, A.J. and Doukas, M.P., 2002. Carbon dioxide emission rate of Kīlauea Volcano: Implications for primary magma and the summit reservoir. Journal of Geophysical Research-Solid Earth, 107(B9): art. no.-2189.]. Analysis of the data indicates that the emission rates of the present study likely reflect changes in the magma supply rate and residence time in the summit reservoir. It is also likely that emission rates during the inflation period were heavily influenced by SO 2 pulses emitted adjacent to the COSPEC traverse, which biased CO 2 /SO 2 ratios towards low values that may be unrepresentative of the global summit gas plume. We conclude that the SO 2 pulses are consequences of summit re-inflation under way since 2003 and that CO 2 emission rates remain comparable to, but more variable than, those measured prior to re-inflation.

Hawaii

Magmatic vapor source for sulfur dioxide released during volcanic eruptions: Evidence from Mount Pinatubo

Sulfur dioxide (SO2) released by the explosive eruption of Mount Pinatubo on 15 June 1991 had an impact on climate and stratospheric ozone. The total mass of SO2 released was much greater than the amount dissolved in the magma before the eruption, and thus an additional source for the excess SO2 is required. Infrared spectroscopic analyses of dissolved water and carbon dioxide in glass inclusions from quartz phenocrysts demonstrate that before eruption the magma contained a separate, SO2-bearing vapor phase. Data for gas emissions from other volcanoes in subduction-related arcs suggest that preeruptive magmatic vapor is a major source of the SO2 that is released during many volcanic eruptions.

Science