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Norman E. Peters

Publications and source records attributed to Norman E. Peters.

18 recordsLinked to original sources

The evolving perceptual model of streamflow generation at the Panola Mountain Research Watershed

The Panola Mountain Research Watershed (PMRW) is a 41‐hectare forested catchment within the Piedmont Province of the Southeastern United States. Observations, experimentation, and numerical modelling have been conducted at Panola over the past 35 years. But to date, these studies have not been fully incorporated into a more comprehensive synthesis. Here we describe the evolving perceptual understanding of streamflow generation mechanisms at the PMRW. We show how the long‐term study has enabled insights that were initially unforeseen but are also unachievable in short‐term studies. In particular, we discuss how the accumulation of field evidence, detailed site characterization, and modelling enabled a priori hypotheses to be formed, later rejected, and then further refined through repeated field campaigns. The extensive characterization of the soil and bedrock provided robust process insights not otherwise achievable from hydrometric measurements and numerical modelling alone. We focus on two major aspects of streamflow generation: the role of hillslopes (and their connection to the riparian zone) and the role of catchment storage in controlling fluxes and transit times of water in the catchment. Finally, we present location‐independent hypotheses based on our findings at PMRW and suggest ways to assess the representativeness of PMRW in the broader context of headwater watersheds.

Georgia↗

Quantifying climate-related interactions in shallow and deep storage and evapotranspiration in a forested, seasonally water-limited watershed in the Southeastern United States

The Southeastern United States experiences recurring hydrological droughts, which can reduce water availability and can result in water-limiting conditions. Long-term monitoring at Panola Mountain Research Watershed, a small, forested, seasonally water-limited watershed near Atlanta, Georgia, was used to quantify the interactions of climatic variability with shallow and deep storage and evapotranspiration. Watershed storage (WS) and actual evapotranspiration (AET) were estimated monthly from 1985 through 2015 using a water-budget approach combined with a WS-baseflow relationship. Shallow storage (SS) was assessed from a soil moisture profile. Soil moisture transitioned from recharge to surplus as SS increased from its field capacity to a nearly saturated state during the dormant season, and transitioned from utilization to climatic water deficits as SS declined from its field capacity to its wilting point during the growing season. Deeper storage was unavailable to AET during dry conditions. The majority of deeper storage recharge occurred during the dormant season and required SS to be wet. WS was an effective drought indicator. Growing season droughts typically occurred when WS was below normal at the end of the dormant season and growing season precipitation (P) was below or near normal. A hydrologic persistence analysis found that monthly-standardized WS was significantly correlated (p-value <0.05) with past monthly-standardized WS for the previous 19 months and with past monthly P for the previous 11 months, indicating the importance of past hydrologic conditions on WS. Expected climatic changes affected recharge during the dormant season and deficits during the growing season.

Water Resources Research↗

Evaluation of high-frequency mean streamwater transit-time estimates using groundwater age and dissolved silica concentrations in a small forested watershed

Many previous investigations of mean streamwater transit times (MTT) have been limited by an inability to quantify the MTT dynamics. Here, we draw on (1) a linear relation ( r 2 = 0.97) between groundwater 3 H/ 3 He ages and dissolved silica (Si) concentrations, combined with (2) predicted streamwater Si concentrations from a multiple-regression relation ( R 2 = 0.87) to estimate MTT at 5-min intervals for a 23-year time series of streamflow [water year (WY) 1986 through 2008] at the Panola Mountain Research Watershed, Georgia. The time-based average MTT derived from the 5-min data was ~8.4 &plusmn; 2.9 years and the volume-weighted (VW) MTT was ~4.7 years for the study period, reflecting the importance of younger runoff water during high flow. The 5-min MTTs are normally distributed and ranged from 0 to 15 years. Monthly VW MTTs averaged 7.0 &plusmn; 3.3 years and ranged from 4 to 6 years during winter and 8&ndash;10 years during summer. The annual VW MTTs averaged 5.6 &plusmn; 2.0 years and ranged from ~5 years during wet years (2003 and 2005) to >10 years during dry years (2002 and 2008). Stormflows are composed of much younger water than baseflows, and although stormflow only occurs ~17 % of the time, this runoff fraction contributed 39 % of the runoff during the 23-year study period. Combining the 23-year VW MTT (including stormflow) with the annual average baseflow for the period (~212 mm) indicates that active groundwater storage is ~1,000 mm. However, the groundwater storage ranged from 1,040 to 1,950 mm using WY baseflow and WY VW MTT. The approach described herein may be applicable to other watersheds underlain by granitoid bedrock, where weathering is the dominant control on Si concentrations in soils, groundwater, and streamwater.

Georgia↗

Hydrology and biogeochemistry linkages

This chapter provides an overview of the linkages between hydrology and biogeochemistry in terrestrial and aquatic systems. Selected topics include hydrological pathways on drainage basin slopes, mountain environments, within-river (or in-stream) processes, wetlands, groundwater (and groundwater–surface water interactions), and lakes. Beginning from catchment headwaters, This chapter introduces mechanisms delivering water from hillslopes to stream channels, highlighting the relative importance of biogeochemical processes along hydrological pathways. It considers processes affecting components of the water budget, including snow formation and ablation processes, and interactions with the soil below snow cover and during snowmelt. It presents the concept of nutrient spiraling and the importance of temperature and stream flow variability on biogeochemistry, as well as groundwater–surface water interactions through hyporheic and riparian zones. This chapter contrasts important processes in hydrologically isolated wetlands with those temporally connected to streams and rivers. It addresses stream and groundwater inputs, stratification, and within-lake processes, interactions with sediments, and a discussion about limiting nutrients. This chapter presents information about typical reactions controlled by hydrological pathways, lithology (mineralogy) and biota, the importance of residence time in biogeochemical evolution, and linkages between groundwater Acidic atmospheric deposition

Book chapter↗

Selected achievements, science directions, and new opportunities for the WEBB small watershed research program

Over nearly two decades, the Water, Energy, and Biogeochemical Budgets (WEBB) small watershed research program of the U.S. Geological Survey (USGS) has documented how water and solute fluxes, nutrient, carbon, and mercury dynamics, and weathering and sediment transport respond to natural and humancaused drivers, including climate, climate change, and atmospheric deposition. Together with a continued and increasing focus on the effects of climate change, more investigations are needed that examine ecological effects (e.g., evapotranspiration, nutrient uptake) and responses (e.g., species abundances, biodiversity) that are coupled with the physical and chemical processes historically observed in the WEBB program. Greater use of remote sensing, geographic modeling, and habitat/watershed modeling tools is needed, as is closer integration with the USGS-led National Phenology Network. Better understanding of process and system response times is needed. The analysis and observation of land-use and climate change effects over time should be improved by pooling data obtained by the WEBB program during the last two decades with data obtained earlier and (or) concurrently from other research and monitoring studies conducted at or near the five WEBB watershed sites. These data can be supplemented with historical and paleo-environmental information, such as could be obtained from tree rings and lake cores. Because of the relatively pristine nature and small size of its watersheds, the WEBB program could provide process understanding and basic data to better characterize and quantify ecosystem services and to develop and apply indicators of ecosystem health. In collaboration with other Federal and State watershed research programs, the WEBB program has an opportunity to contribute to tracking the short-term dynamics and long-term evolution of ecosystem services and health indicators at a multiplicity of scales across the landscape.

Conference Paper↗

Flowpath contributions of weathering products to stream fluxes at the Panola Mountain Research Watershed, Georgia

Short-term weathering rates (chemical denudation) of primary weathering products were derived from an analysis of fluxes in precipitation and streamwater. Rainfall, streamflow (runoff), and related water quality have been monitored at the Panola Mountain Research Watershed (PMRW) since 1985. Regression relations of stream solute concentration of major ions including weathering products [sodium (Na), magnesium (Mg), calcium (Ca) and silica (H4SiO4)] were derived from weekly and storm-based sampling from October 1986 through September 1998; runoff, seasonality, and hydrologic state were the primary independent variables. The regression relations explained from 74 to 90 percent of the variations in solute concentration. Chloride (Cl) fluxes for the study period were used to estimate dry atmospheric deposition (DAD) by subtracting the precipitation flux from the stream flux; net Cl flux varied from years of net retention during dry years to >3 times more exported during wet years. On average, DAD was 56 percent of the total atmospheric deposition (also assumed for the other solutes); average annual net cation and H4SiO4 fluxes were 50.6 and 85.9 mmol m-2, respectively. The annual cumulative density functions of solute flux as a function of runoff were evaluated and compared among solutes to evaluate relative changes in solute sources during stormflows. Stream flux of weathering solutes is primarily associated with groundwater discharge. During stormflow, Ca and Mg contributions increase relative to Na and H4SiO4, particularly during wet years when the contribution is 10 percent of the annual flux. The higher Ca and Mg contributions to the stream during stormflow are consistent with increased contribution from shallow soil horizons where these solutes dominate.

Conference Paper↗

The geochemical evolution of riparian ground water in a forested piedmont catchment

The principal weathering reactions and their rates in riparian ground water were determined at the Panola Mountain Research Watershed (PMRW) near Atlanta, Georgia. Concentrations of major solutes were measured in ground water samples from 19 shallow wells completed in the riparian (saprolite) aquifer and in one borehole completed in granite, and the apparent age of each sample was calculated from chloroflourocarbons and tritium/helium-3 data. Concentrations of SiO 2 , Na + , and Ca 2+ generally increased downvalley and were highest in the borehole near the watershed outlet. Strong positive correlations were found between the concentrations of these solutes and the apparent age of ground water that was modern (zero to one year) in the headwaters, six to seven years midway down the valley, and 26 to 27 years in the borehole, located ∼500 m downstream from the headwaters. Mass-balance modeling of chemical evolution showed that the downstream changes in ground water chemistry could be largely explained by weathering of plagioclase to kaolinite, with possible contributions from weathering of K-feldspar, biotite, hornblende, and calcite. The in situ rates of weathering reactions were estimated by combining the ground water age dates with geochemical mass-balance modeling results. The weathering rate was highest for plagioclase (∼6.4 μmol/L/year), but could not be easily compared with most other published results for feldspar weathering at PMRW and elsewhere because the mineral-surface area to which ground water was exposed during geochemical evolution could not be estimated. However, a preliminary estimate of the mineral-surface area that would have contacted the ground water to provide the observed solute concentrations suggests that the plagioclase weathering rate calculated in this study is similar to the rate calculated in a previous study at PMRW, and three to four orders of magnitude slower than those published in previous laboratory studies of feldspar weathering. An accurate model of the geochemical evolution of riparian ground water is necessary to accurately model the geochemical evolution of stream water at PMRW.

Groundwater↗

Chemical weathering of the Panola Granite: Solute and regolith elemental fluxes and the weathering rate of biotite

Present-day elemental and mineral weathering rates based on solute fluxes are compared quantitatively to past long-term rates determined from solid-state elemental fractionation in a saprolitic granite regolith at Panola, Georgia, USA. Saturated fluid flow across a low-permeability kaolin duripan controls the rate of steady-state unsaturated flow in the underlying saprolite. Water and Cl mass balances and experimental conductivities produce a minimum fluid flux density of 8x10 -2 m yr -1 and a fluid residence time of 12 years. Solute Si flux, based on pore water concentrations and infiltration rates, is 27 mmoles yr -1 , compared to a long-term flux rate of 17 mmoles yr -1 , based on regolith Si loss and reported 36 Cl dating of the regolith surface. Similarities in short- and long-term fluxes imply that parameters influencing silicate weathering, including precipitation, temperature, and vegetative cover, while not necessarily constant, have not significantly impacted Si leaching rates during the last several hundred thousand years. Linear decreases in solid-state Mg with decreasing regolith depth permit the calculation of the long-term biotite weathering rate under isovolumetric steady-state weathering conditions. A rate constant of 3x10 -17 moles m -2 s -1 is up to 5 orders of magnitude slower than that reported for experimental dissolution of biotite, implying very different reaction kinetics during natural weathering. Short-term biotite weathering fails to produce expected increases in solute Mg and K concentrations with increasing depth and fluid residence times in the regolith. This discrepancy indicates that ion exchange disequilibrium and open-system biologic uptake in an aggrading forest ecosystem are of sufficient magnitudes to overwhelm solute fluxes resulting from biotite weathering.

Georgia↗

Water quality degradation effects on freshwater availability: Impacts of human activities

The quality of freshwater at any point on the landscape reflects the combined effects of many processes along water pathways. Human activities on all spatial scales affect both water quality and quantity. Alteration of the landscape and associated vegetation has not only changed the water balance, but typically has altered processes that control water quality. Effects of human activities on a small scale are relevant to an entire drainage basin. Furthermore, local, regional, and global differences in climate and water flow are considerable, causing varying effects of human activities on land and water quality and quantity, depending on location within a watershed, geology, biology, physiographic characteristics, and climate. These natural characteristics also greatly control human activities, which will, in turn, modify (or affect) the natural composition of water. One of the most important issues for effective resource management is recognition of cyclical and cascading effects of human activities on the water quality and quantity along hydrologic pathways. The degradation of water quality in one part of a watershed can have negative effects on users downstream. Everyone lives downstream of the effects of some human activity. An extremely important factor is that substances added to the atmosphere, land, and water generally have relatively long time scales for removal or clean up. The nature of the substance, including its affinity for adhering to soil and its ability to be transformed, affects the mobility and the time scale for removal of the substance. Policy alone will not solve many of the degradation issues, but a combination of policy, education, scientific knowledge, planning, and enforcement of applicable laws can provide mechanisms for slowing the rate of degradation and provide human and environmental protection. Such an integrated approach is needed to effectively manage land and water resources.

Water International↗

Panola Mountain, Georgia: A Water, Energy, and Biogeochemical Budgets Program Site

The Panola Mountain Research Watershed (PMRW) is a 41-hectare forested watershed in the southern Piedmont physiographic province near Atlanta, Georgia. The watershed contains a naturally regenerated second-growth forest on abandoned agricultural land, typical of the Piedmont. Research at PMRW has focused on how streamflow is generated, and in particular, on how water and solutes move from hillslopes to the stream. The research shows that streamflow and solute concentrations of precipitation, throughfall, soil water and streamwater change rapidly during rainstorms. Furthermore, these variations are strongly associated with the soil-moisture conditions, the soil type and thickness, and the rainfall intensity, all of which effect the chemical interactions and mixing of water traveling along hydrological pathways over and through the bedrock and soils.

Georgia↗

Tracer and hydrometric study of preferential flow in large undisturbed soil cores from the Georgia Piedmont, USA

We studied the temporal patterns of tracer throughput in the outflow of large (30 cm diameter by 38 cm long) undisturbed cores from the Panola Mountain Research Watershed, Georgia. Tracer breakthrough was affected by soil structure and rainfall intensity. Two rainfall intensities (20 and 40 mm hr -1 ) for separate Cl - and Br - amended solutions were applied to two cores (one extracted from a hillslope soil and one extracted from a residual clay soil on the ridge). For both low and high rainfall intensity experiments, preferential flow occurred in the clay core, but not in the hillslope core. The preferential flow is attributed to well-developed interpedal macrochannels that are commonly found in structured clay soils, characteristic of the ridge site. However, each rainfall intensity exceeded the matrix infiltration capacity at the top of the hillslope core, but did not exceed the matrix infiltration capacity at the middle and bottom of the hillslope core and at all levels in the clay core. Localized zones of saturation created when rainfall intensity exceeds the matrix infiltration capacity may cause water and tracer to overflow from the matrix into macrochannels, where preferential flow occurs to depth in otherwise unsaturated soil. Copyright © 1999 John Wiley & Sons, Ltd.

Hydrological Processes↗

Evaluation of streamwater quality in the Atlanta region

A water-quality index (WQI) was developed from historical data for streams in the Atlanta region. The WQI was derived from percentile ranks of individual water-quality parameter values at each stream by normalizing the constituent ranks for values from all sites in the area for the period from 1990 to 1995. WQIs were developed primarily for nutrients and nutrient-related parameters, because data for metals, organics (pesticides and herbicides), biological conditions, and suspended sediment generally were unavailable. Average WQI of the individual parameter WQIs for sites in the region ranged from 0.26 (good quality) to 0.86 (poor quality), and increased downstream of known nutrient sources. Annual average site WQI decreased at most long-term monitoring sites from 1986 to 1995. Temporal trends, in part, reflect effects of a drought in the late 1980's and normal to higher-than-normal rainfall and runoff in the 1990's. For several sites, particularly in the northern part of the region where major development is ongoing, WQI increased dramatically from 1994 to 1995. Interannual WQI variability typically was less than spatial variability. Average annual site WQI for individual parameters correlated with annual hydrologic characteristics, particularly precipitation amount and water yield, reflecting the effect of dilution on individual water-quality parameter values.

Georgia↗

Specific conductance; theoretical considerations and application to analytical quality control

This report considers several theoretical aspects and practical applications of specific conductance to the study of natural waters. A review of accepted measurements of conductivity of secondary standard 0.01 N KCl solution suggests that a widely used algorithm for predicting the temperature variation in conductivity is in error. A new algorithm is derived and compared with accepted measurements. Instrumental temperature compensation circuits based on 0.01 N KCl or NaCl are likely to give erroneous results in unusual or special waters, such as seawater, acid mine waters, and acid rain. An approach for predicting the specific conductance of a water sample from the analytically determined major ion composition is described and critically evaluated. The model predicts the specific conductance to within ?8 percent (one standard deviation) in waters with specific conductances of 0 to 600 microS/cm. Application of this approach to analytical quality control is discussed.

Water Supply Paper↗

Evaluation of environmental factors affecting yields of major dissolved ions of streams in the United States

The seven major dissolved ions in streams-sodium, potassium, magnesium, calcium, chloride, sulfate, and bicarbonate and their sum dissolved solids from 56 basins in the conterminous United States and Hawaii were correlated with bedrock type, annual precipitation, population density, and average stream temperature of their respective basins through multiple linear-regression equations to predict annual yields. The study was restricted to basins underlain by limestone, sandstone, or crystalline rock. Depending on the constituent, yields ranged from about 10 to 100,000 kilograms per square kilometer. Predicted yields were within 1 order of magnitude of measured yields. The most important factor in yield prediction was annual precipitation, which accounted for 58 to 71 percent of all yields. Rock type was second in importance. Yields of magnesium, calcium, bicarbonate, and dissolved solids from limestone basins were 4 to 10 times larger than those from sandstone or crystalline basins as a result of carbonate weathering. Population density was an ineffective indicator of all constituents except sodium and chloride; it accounted for 13 percent of the annual sodium yield and 20 percent of the annual chloride yield. Average stream temperature was significant only for calcium and bicarbonate in limestone basins. Its relationship with yields was consistently negative. Either carbonate dissolution increases at low temperatures, or weathering in northern basins, which contain glacial deposits and have the lowest stream temperatures, is greater than in southern basins. Average ion contributions from atmospheric deposition accounted for 30 percent of the sodium and chloride and 60 percent of the sulfate in annual yields. The amount of sulfate derived from atmospheric contributions was higher in sandstone and crystalline basins (65 and 80 percent, respectively) than limestone basins (38 percent). This disparity is attributed to the lack of available sulfate in crystalline rock and the chemical precipitation of sulfate in the sandstone basins, most of which are in semi-arid or arid areas.

Water Supply Paper↗

Chemical composition of bulk precipitation in the North-Central and Northeastern United States, December 1980 through February 1981

Samples of bulk precipitation were collected at 179 sites in the North-Central and Northeastern United States for 3 months during winter 1980-81 to provide data on the distribution of chemical constituents. Concentrations and average daily loads of 29 dissolved constituents were determined. Sodium and chloride deposition was relatively high in coastal areas and adjacent to some urban centers. Regional patterns of to daily loads of hydrogen ion, nitrate, lead, and iron correlate well with one another and form a concentric pattern around the center of high deposition in eastern Ohio and western Pennsylvania, suggesting an urban-industrial source. Samples from this area had low pH (<4.2), whereas samples from southern Minnesota and Illinois had a more neutral pH (>5.7). The latter samples had high concentrations of calcium and total inorganic carbon, suggesting pH control by soil-derived carbonate minerals. Deposition patterns of ammonium, nitrate, and sulfate display regional highs in Illinois, Indiana, and southwestern Michigan, suggesting agricultural sources such as fertilizer. Median loads of zinc, iron, and lead were lower than reported in previous studies for North America. The apparent decrease in lead since 1950 throughout the area is attributed to reduced consumption of leaded fuels and lower deposition in winter.

Circular↗

Temporal trends in the acidity of precipitation and surface waters of New York

Statistical analyses of precipitation data from a nine-station monitoring network indicate little change in pH from 1965-78 within New York State as a whole but suggest that pH of bulk precipitation has decreased in the western part of the State by approximately 0.2 pH units since 1965 and increased in the eastern part by a similar amount. This trend is equivalent to an annual change in hydrogen-ion concentration of 0.2 microequivalents per liter. An average annual increase in precipitation quantity of 2 to 3 percent since 1965 has resulted in an increased acid load in the western and central parts of the State. During 1965-78, sulfate concentration in precipitation decreased an average of 1-4 percent annually. In general, no trend in nitrate was detected. Calculated trends in hydrogen-ion concentration do not correlate with measured trends of sulfate and nitrate, which suggests variable neutralization of hydrogen ion, possibly by particles from dry deposition. Neutralization has produced an increase of about 0.3 pH units in nonurban areas and 0.7 pH units in urban areas. Statistical analyses of chemical data from several streams throughout New York suggest that sulfate concentrations decreased an average of 1 to 4 percent per year. This decrease is comparable to the sulfate decrease in precipitation during the same period. In most areas of the State, chemical contributions from urbanization and farming, as well as the neutralizing effect of carbonate soils, conceal whatever effects acid precipitation may have on pH of streams.

Water Supply Paper↗

Acid-rain weathering of a metasedimentary rock basin, Herkimer County, New York

A geochemical balance of major chemical constituents of precipitation inflow with those of surface-water outflow was used to evaluate the effect of acid rainfall (average pH = 4.3) on weathering rates of metasedimentary rocks underlying a surface-water basin in New York State. Precipitation samples and surface-water samples show that approximately 45 percent of the net cation outflow is due to weathering by precipitation acidity. The remaining 55 percent of the cation load in the outflow is attributed to interactions between atmosphere, rock, and soil water in the unsaturated zone. Comparison of the acidity of acid precipitation and air-equilibrated distilled water suggests that since preindustrial time, precipitation acidity has probably increased weathering rates for this basin approximately 75 percent. The increased acidity of the precipitation may also increase the rate of dissolution of heavy metals from water-piping systems.

New York↗