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Neil V. Maimer

Publications and source records attributed to Neil V. Maimer.

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Completion summary for boreholes USGS 148, 148A, and 149 at the Materials and Fuels Complex, Idaho National Laboratory, Idaho

In 2019, the U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, drilled and constructed boreholes USGS 148A and USGS 149 for stratigraphic framework analyses and long-term groundwater monitoring of the eastern Snake River Plain aquifer at the Idaho National Laboratory (INL) in southeastern Idaho. Initially, boreholes USGS 148A and USGS 149 were continuously cored to allow the USGS and INL subcontractor to collect select geophysical and seismic data and evaluate properties of recovered core material. The USGS geophysical data and descriptions of core material are described in this report; however, data collected by the INL contractor, including seismic data, are not included as part of the report. The unsaturated zone at both borehole locations is relatively thick, depth to water was measured at approximately 663.6 feet (ft) below land surface (BLS) in USGS 148A, and at approximately 654.1 ft BLS at USGS 149. On completion of coring and data collection, both boreholes (USGS 148A and USGS 149) were repurposed as monitoring wells. Well USGS 148A was constructed to a depth of 759 ft BLS and instrumented with a dedicated submersible pump and measurement line; well USGS 149 was constructed to a depth of 974 ft BLS and instrumented with a multilevel monitoring system (Westbay TM ). Geophysical data, collected by the USGS, were used to characterize the subsurface geology and aquifer conditions. Natural gamma log measurements were used to assess sediment-layer thickness and location. Neutron and gamma-gamma source logs were used to confirm fractured and vesicular basalt identified for aquifer testing and multilevel monitoring well zone testing. Acoustic televiewer logs, collected for well USGS 149, were used to identify fractures and assess groundwater movement when compared with neutron measurements. Furthermore, gyroscopic deviation measurements were used to measure horizontal and vertical displacement for the constructed boreholes USGS 148A and USGS 149. A single-well aquifer test was done in well USGS 148A during November 6–7, 2019, to provide estimates of transmissivity and hydraulic conductivity. Estimates for transmissivity and hydraulic conductivity were 6.34×10 3 feet squared per day and 3.17 feet per day, respectively. The aquifer test was run overnight (21.3 hours) and measured drawdown was relatively small (0.09 ft) at sustained pumping rates ranging from 15.7 to 16.1 gallons per minute. The transmissivity estimates for well USGS 148A were slightly lower than those determined from previous aquifer tests for wells near the Materials and Fuels Complex, but well within range of other aquifer tests done at the INL. Water-quality samples, collected from well USGS 148A and from four zones in well USGS 149, were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for most of the inorganic constituents showed similar chemistry in USGS 148A and all four zones in USGS 149. Water samples for stable isotopes of oxygen and hydrogen indicated some possible influence of irrigation on the water quality. Nitrate plus nitrite concentrations indicated influence from anthropogenic sources. The volatile organic compound and radiochemical data indicated that wastewater disposal practices at the Materials and Fuels Complex or from drilling had no detectable influence on these wells.

Idaho

Optimization of the Idaho National Laboratory water-quality aquifer monitoring network, southeastern Idaho

Long-term monitoring of water-quality data collected from wells at the Idaho National Laboratory (INL) has provided essential information for delineating the movement of radiochemical and chemical wastes in the eastern Snake River Plain aquifer, southeastern Idaho. Since 1949, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, has maintained as many as 200 wells in the INL water-quality monitoring network. A network design tool, distributed as an R package, was developed to evaluate and optimize groundwater monitoring in the existing network based on water-quality data collected at 153 sampling sites since January 1, 1989. The objective of the optimization design tool is to reduce well monitoring redundancy while retaining sufficient data to reliably characterize water-quality conditions in the aquifer. A spatial optimization was used to identify a set of wells whose removal leads to the smallest increase in the deviation between interpolated concentration maps using the existing and reduced monitoring networks while preserving significant long-term trends and seasonal components in the data. Additionally, a temporal optimization was used to identify reductions in sampling frequencies by minimizing the redundancy in sampling events. Spatial optimization uses an islands genetic algorithm to identify near-optimal network designs removing 10, 20, 30, 40, and 50 wells from the existing monitoring network. With this method, choosing a greater number of wells to remove results in greater cost savings and decreased accuracy of the average relative difference between interpolated maps of the reduced-dataset and the full-dataset. The genetic search algorithm identified reduced networks that best capture the spatial patterns of the average concentration plume while preserving long-term temporal trends at individual wells. Concentration data for 10 analyte types are integrated in a single optimization so that all datasets may be evaluated simultaneously. A constituent was selected for inclusion in the spatial optimization problem when the observations were sufficient to (1) establish a two-range variability model, (2) classify at least one concentration time series as a continuous record block, and (3) make a prediction using the quantile-kriging interpolation method. The selected constituents include sodium, chloride, sulfate, nitrate, carbon tetrachloride, 1,1-dichloroethylene, 1,1,1-trichloroethane, trichloroethylene, tritium, strontium-90, and plutonium-238. In temporal optimization, an iterative-thinning method was used to find an optimal sampling frequency for each analyte-well pair. Optimal frequencies indicate that for many of the wells, samples may be collected less frequently and still be able to characterize the concentration over time. The optimization results indicated that the sample-collection interval may be increased by an of average of 273 days owing to temporal redundancy.

Idaho

Field methods, quality-assurance, and data management plan for water-quality activities and water-level measurements, Idaho National Laboratory, Idaho

Introduction Water-quality activities and water-level measurements conducted by the U.S. Geological Survey (USGS) Idaho National Laboratory (INL) Project Office coincide with the USGS mission of appraising the quantity and quality of the Nation’s water resources. The activities are conducted in cooperation with the U.S. Department of Energy’s (DOE) Idaho Operations Office. Results of water-quality and hydraulic head investigations are presented in various USGS publications or in refereed scientific journals, and the data are stored in the National Water Information System (NWIS) database. The results of the studies are used by researchers, regulatory and managerial agencies, and civic groups. In its broadest sense, “quality assurance” refers to doing the job right the first time. It includes the functions of planning for products, review and acceptance of the products, and an audit designed to evaluate the system that produces the products. Quality control and quality assurance differ in that quality control ensures that things are done correctly given the “state-of-the-art” technology, and quality assurance ensures that quality control is maintained within specified limits.

Idaho

An update of hydrologic conditions and distribution of selected constituents in water, Eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2016–18

Since 1952, wastewater discharged to infiltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer and perched groundwater wells in the USGS groundwater monitoring networks during 2016–18. From March–May 2015 to March–May 2018, water levels in wells completed in the ESRP aquifer declined in the northern part of the INL and increased in the southwestern part. Water-level decreases ranged from 0.5 to 3.0 feet (ft) in the northern part of the INL and increases ranged from 0.5 to 3.0 ft in the southwestern part. Detectable concentrations of radiochemical constituents in water samples from wells in the ESRP aquifer at the INL generally decreased or remained constant during 2016–18. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2018, concentrations of tritium in water samples collected from 46 of 111 aquifer wells were greater than the reporting level of three times the sample standard deviation and ranged from 260±50 to 5,100±190 picocuries per liter (pCi/L). Tritium concentrations in water from 10 wells completed in deep perched groundwater above the ESRP aquifer near the Advanced Test Reactor (ATR) Complex generally were greater than or equal to the reporting level during at least one sampling event during 2016–18, and concentrations ranged from 150 ±50 to 12,900 ±200 pCi/L. Concentrations of strontium-90 in water from 17 of 60 ESRP aquifer wells sampled during April or October 2018 exceeded the reporting level, ranging from 2.2±0.7 to 363±19 pCi/L. Strontium-90 was not detected in the ESRP aquifer beneath the ATR Complex. During at least one sampling event during 2016–18, concentrations of strontium-90 in water from eight wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex equaled or exceeded the reporting levels, and concentrations ranged from 0.57±0.17 to 34.3±1.2 pCi/L. During 2016–18, concentrations of cesium-137 were less than the reporting level in all but one ESRP aquifer well, and concentrations of plutonium-238, -239, and -240 (undivided), and americium-241 were less than the reporting level in water samples from all ESRP aquifer wells. In April 2009, the dissolved chromium concentration in water from one ESRP aquifer well, USGS 65, south of the ATR Complex equaled the maximum contaminant level (MCL) of 100 micrograms per liter (μg/L). In April 2018, the concentration of chromium in water from that well had decreased to 76.0 μg/L, less than the MCL. Concentrations in water samples from 62 other ESRP aquifer wells sampled ranged from less than 0.6 to 21.6 μg/L. During 2016–18, dissolved chromium was detected in water from all wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex, and concentrations ranged from 4.2 to 98.8 μg/L. In 2018, concentrations of sodium in water from most ESRP aquifer wells in the southern part of the INL were greater than the western tributary background concentration of 8.3 milligrams per liter (mg/L). After the new percolation ponds were put into service in 2002 southwest of the Idaho Nuclear Technology and Engineering Center (INTEC), concentrations of sodium in water samples from the Rifle Range well increased steadily until 2008, when concentrations generally began decreasing. The increases and decreases were attributed to disposal variability in the new percolation ponds. During 2016–18, dissolved sodium concentrations in water from 18 wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex ranged from 6.37 to 143 mg/L. In 2018, concentrations of chloride in most water samples from ESRP aquifer wells south of the INTEC and at the Central Facilities Area exceeded the background concentrations. Chloride concentrations in water from wells south of the INTEC generally have decreased since 2002 when chloride disposal to the old percolation ponds was discontinued. After the new percolation ponds southwest of the INTEC were put into service in 2002, concentrations of chloride in water samples from one well rose steadily until 2008 then began decreasing. During 2016–18, dissolved chloride concentrations in deep perched groundwater above the ESRP aquifer from 18 wells at the ATR Complex ranged from 3.89 to 176 mg/L. In 2018, sulfate concentrations in water samples from ESRP aquifer wells in the south-central part of the INL exceeded the background concentration of sulfate and ranged from 22 to 151 mg/L. The greater-than-background concentrations in water from these wells probably resulted from sulfate disposal at the ATR Complex infiltration ponds or the old INTEC percolation ponds. In 2018, sulfate concentrations in water samples from wells near the Radioactive Waste Management Complex (RWMC) mostly were greater than background concentrations and could have resulted from well construction techniques and (or) waste disposal at the RWMC or the ATR complex. The maximum dissolved sulfate concentration in shallow perched groundwater above the ESRP aquifer near the ATR Complex was 215 mg/L in well CWP 3 in April 2016. During 2018, dissolved sulfate concentrations in water from wells completed in deep perched groundwater above the ESRP aquifer near the cold-waste ponds at the ATR Complex ranged from 65.8 to 171 mg/L. In 2018, concentrations of nitrate in water from most ESRP aquifer wells at and near the INTEC exceeded the western tributary background concentration of 0.655 mg/L. Concentrations of nitrate in wells southwest of the INTEC and farther away from the influence of disposal areas and the Big Lost River show a general decrease in nitrate concentration through time. Two wells south of the INTEC show increasing trends that could be the result of wastewater beneath the INTEC tank farm being mobilized to the aquifer. During 2016–18, water samples from several ESRP aquifer wells were collected and analyzed for volatile organic compounds (VOCs). Sixteen VOCs were detected. At least 1 and as many as 7 VOCs were detected in water samples from 15 wells. The primary VOCs detected include carbon tetrachloride, trichloromethane, tetrachloroethene, 1,1,1-trichloroethane, and trichloroethene. In 2016–18, concentrations for all VOCs were less than their respective MCLs for drinking water, except carbon tetrachloride in water from two wells and trichloroethene in one well. During 2016–18, variability and bias were evaluated from 37 replicate and 15 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were major ions, trace elements, nutrients, and VOCs. All radiochemical constituents had acceptable reproducibility except for gross alpha- and beta-particle radioactivity. The gross alpha- and beta-particle radioactivity samples that did not meet reproducibility criteria had low concentrations. Bias from sample contamination was evaluated from equipment, field, and source-solution blanks. Cadmium had a concentration slightly greater than its reporting level in a source-solution blank, and chloride and ammonia had concentrations that were slightly greater than their respective reporting levels in field and equipment blanks. Subtracting concentrations of chloride and ammonia in field blanks from the concurrently collected equipment blank indicates that adjusted concentrations for chloride and ammonia in the equipment blanks were less than their respective reporting levels. Therefore, no sample bias was observed for any of the sample periods.

Idaho

Iodine-129 in the Eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2017–18

From 1953 to 1988, approximately 0.941 curies of iodine-129 ( 129 I) were contained in wastewater generated at the Idaho National Laboratory, with almost all of it discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC). Until 1984, most of the wastewater was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well; however, some wastewater was also discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. During 2017–18, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected samples for 129 I from 30 wells that monitor the ESRP aquifer to track concentrations and changes of the carcinogenic radionuclide that has a 15.7 million-year half-life. Concentrations of 129 I in the aquifer ranged from 0.000016 ± 0.000001 to 0.88+/- 0.03 picocuries per liter (pCi/L), and concentrations generally decreased in wells near the INTEC as compared with previously collected samples. The average concentration of 15 wells sampled during 5 different sample periods decreased from 1.15 pCi/L in 1990–91 to 0.168 pCi/L in 2017–18, but average concentrations were similar to 2011–12 within analytical uncertainty. All but four wells within a 3-mile radius of the INTEC showed decreases in concentration, and all samples had concentrations less than the U.S. Environmental Protection Agency’s maximum contaminant level of 1 pCi/L. These decreases are attributed to the discontinuation of disposal of 129 I in wastewater and to dilution and dispersion in the aquifer. Some wells southeast of INTEC showed increasing trends; these increases were attributed to variable transmissivity. Although wells near INTEC sampled in 2017–18 showed decreases in concentrations compared with data collected previously, some wells south of the INL boundary showed small increases. These increases are attributed to historical variable discharge rates of wastewater that eventually moved to these well locations as a pulse of water from a particular disposal period.

Idaho

Transmissivity and geophysical data for selected wells at and near the Idaho National Laboratory, Idaho, 2017–18

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, conducted aquifer tests during 2017–18 on 101 wells at and near the Idaho National Laboratory, Idaho, to define the hydraulic characteristics for individual wells. These were short-duration aquifer tests, conducted with a limited number of observations during routine sampling. Pumped intervals (water columns) for individual wells ranged from 12 to 790 feet (ft). Semi-constant discharge rates during aquifer testing ranged from 1 to 45 gallons per minute, water-level response to pumping ranged from no observed drawdown to 52.4 ft, and length of aquifer tests for individual wells ranged from 10 to 160 minutes. Individual well data were analyzed to estimate the capacity of the well to produce water (specific capacity) and to estimate values for transmissivity. Estimates of specific capacity for individual wells ranged from less than 1.0 to greater than (>) 3.0 × 10 3 gallons per minute per foot; estimates of transmissivity for individual wells ranged from 2.0 to >5.4 x 10 5 feet squared per day. Geophysical log data, well construction information, and general geology for individual wells were presented and included in this report. Basic hydrogeologic features for individual wells were described, along with a composite of natural gamma, neutron, gamma-gamma dual density, and acoustic televiewer data (when available). The geophysical and geologic data were used to suggest the location and thickness of sediment layers along with fractured and dense basalt areas for individual wells. Geophysical data were used to describe the general geology where geologic descriptions and (or) driller notes were not available.

Idaho

An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2012-15

Since 1952, wastewater discharged to in ltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer, multilevel monitoring system (MLMS) wells in the ESRP aquifer, and perched groundwater wells in the USGS groundwater monitoring networks during 2012-15.

Idaho

Purgeable organic compounds at or near the Idaho Nuclear Technology and Engineering Center, Idaho National Laboratory, Idaho, 2015

During 2015, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected groundwater samples from 31 wells at or near the Idaho Nuclear Technology and Engineering Center (INTEC) at the Idaho National Laboratory for purgeable organic compounds (POCs). The samples were collected and analyzed for the purpose of evaluating whether purge water from wells located inside an areal polygon established downgradient of the INTEC must be treated as a Resource Conservation and Recovery Act listed waste. POC concentrations in water samples from 29 of 31 wells completed in the eastern Snake River Plain aquifer were greater than their detection limit, determined from detection and quantitation calculation software, for at least one to four POCs. Of the 29 wells with concentrations greater than their detection limits, only 20 had concentrations greater than the laboratory reporting limit as calculated with detection and quantitation calculation software. None of the concentrations exceeded any maximum contaminant levels established for public drinking water supplies. Most commonly detected compounds were 1,1,1-trichoroethane, 1,1-dichloroethene, and trichloroethene.

Idaho

Chemical constituents in groundwater from multiple zones in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009-13

From 2009 to 2013, the U.S. Geological Survey’s (USGS) Idaho National Laboratory (INL) Project office, in cooperation with the U.S. Department of Energy, collected water-quality samples from multiple water-bearing zones in the eastern Snake River Plain aquifer. Water samples were collected from 11 monitoring wells completed in about 250–750 feet of the upper part of the aquifer, and samples were analyzed for selected major ions, trace elements, nutrients, radiochemical constituents, and stable isotopes. Each well was equipped with a multilevel monitoring system containing four to seven sampling ports that were each isolated by permanent packer systems. The sampling ports were installed in aquifer zones that were highly transmissive and that represented the water chemistry of the top three to five model layers of a steady-state and transient groundwater‑flow model. The groundwater-flow model and water chemistry are being used to better define movement of wastewater constituents in the aquifer. The water-chemistry composition of all sampled zones for the five new multilevel wells is calcium plus magnesium bicarbonate. One of the zones in well USGS 131A has a slightly different chemistry from the rest of the zones and wells and the difference is attributed to more wastewater influence from the Idaho Nuclear Technology and Engineering Center. One well, USGS 135, was not influenced by wastewater disposal and consisted of mostly older water in all of its zones. Tritium concentrations in relation to basaltic flow units indicate the presence of wastewater influence in multiple basalt flow groups; however, tritium is most abundant in the South Late Matuyama flow group in the southern boundary wells. The concentrations of wastewater constituents in deep zones in wells Middle 2051, USGS 132, USGS 105, and USGS 103 support the concept of groundwater flow deepening in the southwestern corner of the INL, as indicated by the INL groundwater-flow model.

Idaho

Water-quality characteristics and trends for selected wells possibly influenced by wastewater disposal at the Idaho National Laboratory, Idaho, 1981-2012

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, analyzed water-quality data collected from 64 aquifer wells and 35 perched groundwater wells at the Idaho National Laboratory (INL) from 1981 through 2012. The wells selected for the study were wells that possibly were affected by wastewater disposal at the INL. The data analyzed included tritium, strontium-90, major cations, anions, nutrients, trace elements, total organic carbon, and volatile organic compounds. The analyses were performed to examine water-quality trends that might influence future management decisions about the number of wells to sample at the INL and the type of constituents to monitor. The data were processed using custom computer scripts developed in the R programming language. Summary statistics were calculated for the datasets. Water-quality trends were determined using a parametric survival regression model to fit the observed data, including left-censored, interval-censored, and uncensored data. The null hypothesis of the trend test was that no relation existed between time and concentration; the alternate hypothesis was that time and concentration were related through the regression equation. A significance level of 0.05 was selected to determine if the trend was statistically significant. Trend test results for tritium and strontium-90 concentrations in aquifer wells indicated that nearly all wells had decreasing or no trends. Similarly, trends in perched groundwater wells were mostly decreasing or no trends; trends were increasing in two perched groundwater wells near the Advanced Test Reactor Complex. Decreasing trends generally are attributed to lack of recent wastewater disposal and radioactive decay. Trend test results for chloride, sodium, sulfate, nitrite plus nitrate (as nitrogen), chromium, trace elements, and total organic carbon concentrations in aquifer wells indicated that most wells had either decreasing or no trends. The decreasing trends in these constituents are attributed to decrease in disposal of these constituents, as well as discontinued use of the old percolation ponds south of the Idaho Nuclear Technology and Engineering Center (INTEC) and redirection of wastewater to the new percolation ponds 2 miles southwest of the INTEC in 2002. Chloride (along with sodium, sulfate, and some nitrate) concentrations in wells south of the INTEC may be influenced by episodic recharge from the Big Lost River. These constituent concentrations decrease during wetter periods when there is probably more recharge from the Big Lost River and increase during dry periods, when there is less recharge. Some wells downgradient of the Central Facilities Area and near the southern boundary of the INL showed increasing trends in sodium concentration, whereas there was no trend in chloride. The increasing trend for sodium could be due to the long term influence of wastewater disposal from upgradient facilities and the lack of trend for chloride could be because chloride is more mobile than sodium and more dispersed in the aquifer system. Volatile organic compound concentration trends were analyzed for nine aquifer wells. Trend test results indicated an increasing trend for carbon tetrachloride for the Radioactive Waste Management Complex Production Well for the period 1987–2012; however, trend analyses of data collected since 2005 show no statistically significant trend indicating that engineering practices designed to reduce movement of volatile organic compounds to the aquifer may be having a positive effect on the aquifer.

Idaho

Field methods and quality-assurance plan for water-quality activities and water-level measurements, U.S. Geological Survey, Idaho National Laboratory, Idaho

Water-quality activities and water-level measurements by the personnel of the U.S. Geological Survey (USGS) Idaho National Laboratory (INL) Project Office coincide with the USGS mission of appraising the quantity and quality of the Nation’s water resources. The activities are carried out in cooperation with the U.S. Department of Energy (DOE) Idaho Operations Office. Results of the water-quality and hydraulic head investigations are presented in various USGS publications or in refereed scientific journals and the data are stored in the National Water Information System (NWIS) database. The results of the studies are used by researchers, regulatory and managerial agencies, and interested civic groups. In the broadest sense, quality assurance refers to doing the job right the first time. It includes the functions of planning for products, review and acceptance of the products, and an audit designed to evaluate the system that produces the products. Quality control and quality assurance differ in that quality control ensures that things are done correctly given the “state-of-the-art” technology, and quality assurance ensures that quality control is maintained within specified limits.

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