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Neil S. Fishman

Publications and source records attributed to Neil S. Fishman.

At least 19 recordsLinked to original sources
USGS2019

Pyritization history in the middle to upper Cambrian Alum Shale, Scania Sweden: Evidence for ongoing diagenetic processes

Detailed diagenetic studies of the late Cambrian Alum Shale in southern Sweden were undertaken across an interval that includes the peak Steptoean Positive Carbon Isotope Excursion (SPICE) event to evaluate the pyrite mineralization history in the formation. Samples were collected from the Andrarum-3 core (Scania, Sweden); here the Alum was deposited in the distal, siliciclastic mudstone-rich end of a shelf system. Abundant cryptobioturbation is observed in the Alum, which points to oxic–dysoxic conditions prevailing during deposition. Petrographic examination of polished thin sections ( n = 65) reveals the presence of numerous texturally distinct types of pyrite, including matrix framboids, two different types of framboid concretions (those with rims of iron-dolomite and those lacking rims), disseminated euhedral pyrite crystals, concretions of euhedral pyrite crystals, overgrowths of pyrite on these different pyrite generations, anhedral pyrite intergrown with bedding parallel mineralized fractures (i.e., “beef”), and massive vertical/subvertical accumulations of pyrite. Paragenetic relationships outline the relative timing of formation of the texturally distinct pyrite. Framboids and framboid concretions formed prior to precipitation of any euhedral pyrite crystals, and these pyrite generations precipitated prior to the pyrite overgrowths on them. As Alum Shale sediments are all distorted by these texturally different pyrite generations, they are likely to have formed early in the postdepositional history of the formation. In contrast, pyrite associated with “beef” is likely temporally related to the onset of hydrocarbon generation, which in this part of Sweden is thought to have been many tens of millions of years after deposition. Because vertical/subvertical massive pyrite features distort “beef,” they clearly postdate it. Of all these pyrite textures, only framboid concretions appear to be restricted to the SPICE interval. The texturally distinct nature of the pyrite generations, along with evidence of their formation at different times in the postdepositional history of the Alum Shale, is the key outcome of this petrographic study. Because the petrographic data presented herein point to a postdeposition origin for all generations of pyrite, diagenetic processes—not those processes associated with deposition—were responsible for the complex pyritization history observed in the Alum, in the Andrarum-3 core.

Scania↗
USGS2015

Unconventional energy resources: 2015 review. Shale gas and liquids

Introduction As the source rocks from which petroleum is generated, organic-rich shales have always been considered an important component of petroleum systems. Over the last few years, it has been realized that in some mudrocks, sufficient hydrocarbons remain in place to allow for commercial development, although advanced drilling and completion technology is typically required to access hydrocarbons from these reservoirs. Tight oil reservoirs (also referred to as continuous oil accumulations) contain hydrocarbons migrated from source rocks that are geologically/stratigraphically interbedded with or occur immediately overlying/underlying them. Migration is minimal in charging these tight oil accumulations (Gaswirth and Marra 2014 ). Companies around the world are now successfully exploiting organic-rich shales and tight rocks for contained hydrocarbons, and the search for these types of unconventional petroleum reservoirs is growing. Unconventional reservoirs range in geologic age from Ordovician to Tertiary (Silverman et al. 2005 ; EIA 2013a ).

Natural Resources Research↗
USGS2015

Petrology and diagenetic history of the upper shale member of the Late Devonian-Early Mississippian Bakken Formation, Williston Basin, North Dakota

The organic-rich upper shale member of the upper Devonian–lower Mississippian Bakken Formation (Williston Basin, North Dakota, USA) has undergone significant diagenetic alteration, irrespective of catagenesis related to hydrocarbon generation. Alteration includes precipitation of numerous cements, replacement of both detrital and authigenic minerals, multiple episodes of fracturing, and compaction. Quartz authigenesis occurred throughout much of the member, and is represented by multiple generations of microcrystalline quartz. Chalcedonic quartz fills radiolarian microfossils and is present in the matrix. Sulfide minerals include pyrite and sphalerite. Carbonate diagenesis is volumetrically minor and includes thin dolomite overgrowths and calcite cement. At least two generations of fractures are observed. Based on the authigenic minerals and their relative timing of formation, the evolution of pore waters can be postulated. Dolomite and calcite resulted from early postdepositional aerobic oxidation of some of the abundant organic material in the formation. Following aerobic oxidation, conditions became anoxic and sulfide minerals precipitated. Transformation of the originally opaline tests of radiolaria resulted in precipitation of quartz, and quartz authigenesis is most common in more distal parts of the depositional basin where radiolaria were abundant. Because quartz authigenesis is related to the distribution of radiolaria, there is a link between diagenesis and depositional environment. Furthermore, much of the diagenesis in the upper shale member preceded hydrocarbon generation, so early postdepositional processes were responsible for occlusion of significant original porosity in the member. Thus, diagenetic mineral precipitation was at least partly responsible for the limited ability of these mudstones to provide porosity for storage of hydrocarbons.

North Dakota↗
USGS2014

Occurrence of pesticides in groundwater and sediments and mineralogy of sediments and grain coatings underlying the Rutgers Agricultural Research and Extension Center, Upper Deerfield, New Jersey, 2007

Water and sediment samples were collected from June through October 2007 from seven plots at the Rutgers Agricultural Research and Extension Center in Upper Deerfield, New Jersey, and analyzed for a suite of pesticides (including fungicides) and other physical and chemical parameters (including sediment mineralogy) by the U.S. Geological Survey. Plots were selected for inclusion in this study on the basis of the crops grown and the pesticides used. Forty-one pesticides were detected in 14 water samples; these include 5 fungicides, 13 herbicides, 1 insecticide, and 22 pesticide degradates. The following pesticides and pesticide degradates were detected in 50 percent or more of the groundwater samples: 1-amide-4-hydroxy-chorothalonil, alachlor sulfonic acid, metolachlor oxanilic acid, metolachlor sulfonic acid, metalaxyl, and simazine. Dissolved-pesticide concentrations ranged from below their instrumental limit of detection to 36 micrograms per liter (for metolachlor sulfonic acid, a degradate of the herbicide metolachlor). The total number of pesticides found in groundwater samples ranged from 0 to 29. Fourteen pesticides were detected in sediment samples from continuous cores collected within each of the seven sampled plots; these include 4 fungicides, 2 herbicides, and 7 pesticide degradates. Pesticide concentrations in sediment samples ranged from below their instrumental limit of detection to 34.2 nanograms per gram (for azoxystrobin). The total number of pesticides found in sediment samples ranged from 0 to 8. Quantitative whole-rock and grain-coating mineralogy of sediment samples were determined by x-ray diffraction. Whole-rock analysis indicated that sediments were predominantly composed of quartz. The materials coating the quartz grains were removed to allow quantification of the trace mineral phases present.

New Jersey↗
USGS2013

Traces in the dark: sedimentary processes and facies gradients in the upper shale member of the Upper Devonian-Lower Mississippian Bakken Formation, Williston Basin, North Dakota, U.S.A.

Black, organic-rich rocks of the upper shale member of the Upper Devonian–Lower Mississippian Bakken Formation, a world-class petroleum source rock in the Williston Basin of the United States and Canada, contain a diverse suite of mudstone lithofacies that were deposited in distinct facies belts. The succession consists of three discrete facies associations (FAs). These comprise: 1) siliceous mudstones; 2) quartz- and carbonate-bearing, laminated mudstones; and 3) macrofossil-debris-bearing massive mudstones. These FAs were deposited in three facies belts that reflect proximal to distal relationships in this mudstone system. The macrofossil-debris-bearing massive mudstones (FA 3) occur in the proximal facies belt and contain erosion surfaces, some with overlying conodont and phosphate–lithoclast lag deposits, mudstones with abundant millimeter-scale siltstone laminae showing irregular lateral thickness changes, and shell debris. In the medial facies belt, quartz- and carbonate-bearing, laminated mudstones dominate, exhibiting sub-millimeter-thick siltstone layers with variable lateral thicknesses and localized mudstone ripples. In the distal siliceous mudstone facies belt, radiolarites, radiolarian-bearing mudstones, and quartz- and carbonate-bearing, laminated mudstones dominate. Overall, total organic carbon (TOC) contents range between about 3 and 10 wt %, with a general proximal to distal decrease in TOC content. Abundant evidence of bioturbation exists in all FAs, and the lithological and TOC variations are paralleled by changes in burrowing style and trace-fossil abundance. While two horizontal traces and two types of fecal strings are recognized in the proximal facies belt, only a single horizontal trace fossil and one type of fecal string characterize mudstones in the distal facies belt. Radiolarites intercalated into the most distal mudstones are devoid of traces and fecal strings. Bedload transport processes, likely caused by storm-induced turbidity currents, were active across all facies belts. Suspended sediment settling from near the ocean surface, however, most likely played a role in the deposition of some of the mudstones, and was probably responsible for deposition of the radiolarites. The distribution pattern of high-TOC sediments in proximal and lower-TOC deposits in some distal facies is interpreted as a function of higher accumulation rates during radiolarian depositional events leading to a decrease in suspension-derived organic carbon in radiolarite laminae. The presence of burrows in all FAs and nearly all facies in the upper Bakken shale member indicates that dysoxic conditions prevailed during its deposition. This study shows that in intracratonic high-TOC mudstone successions such as the upper Bakken shale member bed-load processes most likely dominated sedimentation, and conditions promoted a thriving infaunal benthic community. As such, deposition of the upper Bakken shale member through dynamic processes in an overall dysoxic environment represents an alternative to conventional anoxic depositional models for world-class source rocks.

North Dakota↗
USGS2013

Petrologic and isotopic data from the Cretaceous (Campanian) Blackhawk Formation and Star Point Sandstone (Mesaverde Group), Wasatch Plateau, Utah

The presence of discrete minerals associated with coal—whether (1) detrital or authigenic constituents of the coals or in thin mudstone or siltstone units interbedded with coals, or (2) authigenic phases that formed along cleats—might influence its utilization as an energy resource. The build-up of sintered ash deposits on the surfaces of heat exchangers in coal-fired power plants, due to the alteration of minerals during combustion of the coal, can seriously affect the functioning of the boiler and enhance corrosion of combustion equipment. In particular, the presence of sodium in coals has been considered a key factor in the fouling of boilers; however, other elements (such as calcium or magnesium) and the amount of discrete minerals burned with coal can also play a significant role in the inefficiency of and damage to boilers. Previous studies of the quality of coals in the Cretaceous (Campanian) Blackhawk Formation of the Wasatch Plateau, Utah, revealed that the sodium content of the coals varied across the region. To better understand the origin and distribution of sodium in these coals, petrologic studies were undertaken within a sedimentological framework to evaluate the timing and geochemical constraints on the emplacement of sodium-bearing minerals, particularly analcime, which previously had been identified in coals in the Blackhawk Formation. Further, the study was broadened to include not just coals in the Blackhawk Formation from various localities across the Wasatch Plateau, but also sandstones interbedded with the coals as well as sandstones in the underlying Star Point Sandstone. The alteration history of the sandstones in both formations was considered a key component of this study because it records the nature and timing of fluids passing through them and the associated precipitation of sodium-bearing minerals; thus, the alteration history could place constraints on the distribution and timing of sodium mineralization in the interbedded or overlying Blackhawk coals. Although some preliminary results were previously presented at scientific meetings, the petrologic and geochemical data have not been fully compiled and reported. The purpose of this report is to present the methods of data acquisition and the results of petrologic and isotopic analyses on coal and sandstone samples from the Blackhawk Formation as well as sandstones of the underlying Star Point Sandstone.

Utah↗
USGS2010

Gas storage in the Upper Devonian-Lower Mississippian Woodford Shale, Arbuckle Mountains, Oklahoma: how much of a role do the cherts play?

How gas is stored in shale-gas systems is a critical element in characterizing these potentially prolific, low-porosity/permeability reservoirs. An integrated mineralogic, geochemical, and porosity/permeability study is of the Upper Devonian-Lower Mississippian Woodford Shale, Arbuckle Mountains, southern Oklahoma, at locations previously described through detailed stratigraphic and spectral gamma surveys, was undertaken to provide insights into possible mechanisms by which natural gas might be stored in Woodford reservoirs in the adjacent Anadarko Basin. The outcrops in the Arbuckle Mountains are an ideal location to study the Woodford because here the formation is immature or marginally mature for oil generation (Comer and Hinch, 1987; Lewan, 1987), so deep burial and thermal maturation are much less pronounced than is the case for the Woodford in the basin, and as such the samples we studied are not overprinted by possible alterations resulting from deep burial and heating.

Conference Paper↗
USGS2008

Geologic controls on the growth of petroleum reserves

The geologic characteristics of selected siliciclastic (largely sandstone) and carbonate (limestone and dolomite) reservoirs in North America (largely the continental United States) were investigated to improve our understanding of the role of geology in the growth of petroleum reserves. Reservoirs studied were deposited in (1) eolian environments (Jurassic Norphlet Formation of the Gulf Coast and Pennsylvanian-Permian Minnelusa Formation of the Powder River Basin), (2) interconnected fluvial, deltaic, and shallow marine environments (Oligocene Frio Formation of the Gulf Coast and the Pennsylvanian Morrow Formation of the Anadarko and Denver Basins), (3) deeper marine environments (Mississippian Barnett Shale of the Fort Worth Basin and Devonian-Mississippian Bakken Formation of the Williston Basin), (4) marine carbonate environments (Ordovician Ellenburger Group of the Permian Basin and Jurassic Smackover Formation of the Gulf of Mexico Basin), (5) a submarine fan environment (Permian Spraberry Formation of the Midland Basin), and (6) a fluvial environment (Paleocene-Eocene Wasatch Formation of the Uinta-Piceance Basin). The connection between an oil reservoir's production history and geology was also evaluated by studying production histories of wells in disparate reservoir categories and wells in a single formation containing two reservoir categories. This effort was undertaken to determine, in general, if different reservoir production heterogeneities could be quantified on the basis of gross geologic differences. It appears that reserve growth in existing fields is most predictable for those in which reservoir heterogeneity is low and thus production differs little between wells, probably owing to relatively homogeneous fluid flow. In fields in which reservoirs are highly heterogeneous, prediction of future growth from infill drilling is notably more difficult. In any case, success at linking heterogeneity to reserve growth depends on factors in addition to geology, such as engineering and technological advances and political or cultural or economic influences.

Bulletin↗
USGS2001

Regional fluid migration in the Illinois basin: Evidence from in situ oxygen isotope analysis of authigenic K-feldspar and quartz from the Mount Simon Sandstone

Oxygen isotope compositions of widespread, authigenic K-feldspar and quartz overgrowths and cements in the Upper Cambrian Mount Simon Sandstone were measured by ion microprobe in 11 samples distributed across the Illinois basin and its periphery. Average K-feldspar δ 18 O values increase systematically from +14‰ ± 1‰ in the southernmost and deepest samples in Illinois to +24‰ ± 2‰ in the northernmost outcrop sample in Wisconsin. A similar trend was observed for quartz overgrowths (22‰ ± 2‰ to 28‰ ± 2‰). Constant homogenization temperatures (100–130 °C) of fluid inclusions associated with quartz overgrowths throughout the basin suggest that the geographic trend in oxygen isotope compositions is a result of diagenetic modification of a south to north migrating basinal fluid.

Illinois, Indiana, Kentucky↗
USGS2001

Energy resources and changing land use, Front Range of Colorado: AAPG-EMD field trip guide, in association with the 2001 AAPG-EMD annual meeting

Over the past 30 years, communities in the Northern Front Range of Colorado have experienced tremendous urban and commercial growth rivaling or surpassing that in most other parts of the United States. Much of this growth coincides with areas underlain by critically needed natural resources (such as oil, natural gas, construction aggregate (stone, sand, and gravel), and water), thus presenting serious challenges for city, county, and state planners as well as producers of these natural resources. With projections for as much as a 51 percent increase in population in Colorado over the next 25 years (Colorado Department of Local Affairs, 2001), it is likely that these challenges will increase. This field trip will blend petroleum and coal geology with discussions of urban development to highlight the interplay between growth in the Front Range and energy resource production. On the trip we will also explore the effects of past production on land use. A total of 6 stops will be made in various locations around the Front Range area.

Colorado↗
USGS1990

Iron sulfide minerals at Cement oil field, Oklahoma: Implications for magnetic detection of oil fields

Aeromagnetic anomalies at Cement oil field (Anadarko basin, Oklahoma) have been attributed to authigenic magnetite. The following characteristics of the magnetite, however, indicate that it is contamination introduced by drilling: (1) occurrence as sharp angular blades and as spheres, commonly with metallographic textures typical of industrial alloys and with associated steel and wustite (FeO); (2) presence only in well cuttings and absence from core and quarry samples; and (3) lack of association with detrital framework grains or with authigenic carbonate and sulfide minerals. Ferrimagnetic pyrrhotite occurs in well cuttings, cores, and quarry samples at Cement and is a possible natural source of the magnetic anomalies. Pyrrhotite, which is intergrown with more abundant FeS 2 minerals, formed as a result of hydrocarbon seepage. Pyrrhotite is confined to beds above oil and gas reservoirs. These beds, which lack detrital organic matter, contain higher mineral sulfide and lower mineral sulfate sulfur (1.7 and 0.1 wt %, respectively) than do correlative beds off the field (0.2 and 1.1 wt %, respectively). In the field, isotopic values of sulfide S show a systematic decrease upward through the Permian section from positive values (maximum, +12 per mil at ∼610-760 m depth) to negative values (-1 to -11 per mil between 32 and 230 m; -26 to -30 per mil at the surface). Geochemical results, together with time-temperature data derived from burial curves, limit the major sources of the sulfide in the Fe-S minerals to two possibilities. Isotopically heavy sulfide was generated either inorganically at temperatures >∼90 °C in beds beneath Permian beds, or by bacterial sulfate reduction at temperatures <∼60 °C in Permian strata. If the latter, microbial sulfate reduction occurred under sulfate-limited conditions. The isotopically light sulfide occurring in minerals near the present surface is attributed to bacterial reduction of sulfate. Sulfate-reducing bacteria derived metabolic energy from leaking hydrocarbons and associated organic compounds.

Oklahoma↗
USGS1989

Source of anomalous magnetization in an area of hydrocarbon potential: Petrologic evidence from the Jurassic Preuss Sandstone, Wyoming-Idaho thrust belt

The Jurassic Preuss Sandstone, which crops out in the central part of the Wyoming-Idaho thrust belt on trend with a hydrocarbon-producing region to the south, has been previously identified as the source of anomalous magnetization in the area. Elsewhere, anomalous magnetization in sedimentary rocks near hydrocarbon accumulations has been attributed to hydrocarbon-engendered magnetic minerals, but magnetization of the Preuss is controlled by detrital magnetite. Evidence of a detrital origin for magnetite includes (1) concentration of magnetite grains along laminations containing other heavy minerals, (2) the presence of exsolved ilmenite, hematite, and spinel in the magnetite grains, and (3) titanium contents typical of igneous-derived magnetite. That detrital magnetite is responsible for the anomalous magnetization in the Preuss is further indicated by the systematic eastward decrease in magnetite abundance corresponding to a similar eastward decrease in magnetic susceptibility and remanent magnetization of the unit. Petrologic and vitrinite reflectance studies indicate a complex low-temperature (<150°C or 302°F) diagenetic history for the Preuss. Nevertheless, preservation of detrital magnetite, the presence of diagenetically early ferric oxide minerals, and the absence of sulfide minerals all indicate that the Preuss has not experienced sulfidic-reducing conditions common in areas of hydrocarbon seepage. The marine carbon isotopic composition of calcite that cements most Preuss sandstones (^dgr13C values ranging from -2.47 to 1.48^pmil is evidence that carbonate diagenesis also was not influenced by hydrocarbons. The results of this multidisciplinary study of the Preuss underscore the importance of similar studies when evaluating the sources of aeromagnetic anomalies in areas of hydrocarbon potential.

Idaho, Utah, Wyoming↗
USGS1989

Sulfide mineralization and magnetization, Cement oil field, Oklahoma

Geochemical, petrographic, and rock-magnetic studies were undertaken to investigate possible sources for reported positive aeromagnetic anomalies over the Cement oil field, Oklahoma. Ferrimagnetic pyrrhotite (monoclinic, Fe 7 S 8 ), intergrown with more-abundant, nonmagnetic pyrite (FeS 2 ), is present in well-cutting, core, and quarry samples at Cement, and it is the only identified source of possible enhanced magnetization in rocks over the field. Magnetite, found only in well cuttings from Cement, is contamination from drilling. Magnetite was considered previously by others to be the source of magnetic anomalies at Cement.

Oklahoma↗