Geology topics

Nathan Stein

Publications and source records attributed to Nathan Stein.

6 recordsLinked to original sources

USGS2024

Manganese-rich sandstones as an indicator of ancient oxic lake water conditions in Gale crater, Mars

Manganese has been observed on Mars by the NASA Curiosity rover in a variety of contexts and is an important indicator of redox processes in hydrologic systems on Earth. Within the Murray formation, an ancient primarily fine-grained lacustrine sedimentary deposit in Gale crater, Mars, have observed up to 45× enrichment in manganese and up to 1.5× enrichment in iron within coarser grained bedrock targets compared to the mean Murray sediment composition. This enrichment in manganese coincides with the transition between two stratigraphic units within the Murray: Sutton Island, interpreted as a lake margin environment, and Blunts Point, interpreted as a lake environment. On Earth, lacustrine environments are common locations of manganese precipitation due to highly oxidizing conditions in the lakes. Here, we explore three mechanisms for ferromanganese oxide precipitation at this location: authigenic precipitation from lake water along a lake shore, authigenic precipitation from reduced groundwater discharging through porous sands along a lake shore, and early diagenetic precipitation from groundwater through porous sands. All three scenarios require highly oxidizing conditions and we discuss oxidants that may be responsible for the oxidation and precipitation of manganese oxides. This work has important implications for the habitability of Mars to microbes that could have used Mn redox reactions, owing to its multiple redox states, as an energy source for metabolism.

JGR Planets↗

USGS2022

Geology and stratigraphic correlation of the Murray and Carolyn Shoemaker formations across the Glen Torridon region, Gale crater, Mars

The Glen Torridon (GT) region within Gale crater, Mars, occurs in contact with the southern side of Vera Rubin ridge (VRR), a well-defined geomorphic feature that is comparatively resistant to erosion. Prior to detailed ground-based investigation of GT, its geologic relationship with VRR was unknown. Distinct lithologic subunits within the Jura member (Murray formation), which forms the upper part of VRR, made it possible to be also identified within GT. This indicates that the strata pass across the geomorphic divide between regions. Furthermore, the cross-bedded lower part of the overlying Knockfarril Hill member (Carolyn Shoemaker formation) also occurs within both VRR and GT. Correlation of both units demonstrates that the strata form a continuous stratigraphic succession regardless of large-scale geomorphic expression. The lithologic change from mudstone (Jura member) to cross-bedded sandstone (Knockfarril Hill member) heralds a significant shift in paleoenvironment from lacustrine to fluvial. The upper part of the Knockfarril Hill member consists of interbedded mudstone and sandstone that transitions to the overlying finely laminated mudstone of the Glasgow member, and a return to lacustrine deposition. In GT, the Stimson formation unconformably overlies the Glasgow member, where it demarks the southern boundary of GT. Contacts for each stratigraphic unit were defined and transferred to a high-resolution image base to make a geologic map and cross sections perpendicular to the NE strike. Stratal dips cannot exceed 2° NW to retain the positions of stratigraphic units in the locations they are exposed throughout GT.

Journal of Geophysical Research: Planets↗

USGS2022

Sedimentological and geochemical perspectives on a marginal lake environment recorded in the Hartmann’s Valley and Karasburg members of the Murray formation, Gale crater, Mars

This study utilizes instruments from the Curiosity rover payload to develop an integrated paleoenvironmental and compositional reconstruction for the 65-m thick interval of stratigraphy comprising the Hartmann's Valley and Karasburg members of the Murray formation, Gale crater, Mars. The stratigraphy consists of cross-stratified sandstone (Facies 1), planar-laminated sandstone (Facies 2), and planar-laminated mudstone (Facies 3). Facies 1 is composed of sandstone showing truncated sets of concave-curvilinear laminae stacked into cosets. Sets are estimated to be meter-to sub-meter-scale, consistent with low-height dunes. Thin stratigraphic intervals of Facies 1 and stacking patterns with Facies 2 and 3 support a wet aeolian dune interpretation. Meter-thick packages of planar-laminated sandstone (Facies 2) are interpreted to represent interfingering dune-interdune strata. Facies 3 consists of meter-thick packages of planar-laminated mudstone interpreted to represent lacustrine deposition with persistent standing water. Integration of geochemistry with each facies reveals some compositional control based on the depositional process. Models for source rock composition from Alpha Particle X-Ray Spectrometer measurements show that facies derived from a basaltic source. Alteration indices and geochemical trends provide evidence that moderate chemical weathering occurred before compositional changes due to diagenesis. Differences in wt% FeO (T) and TiO 2 between facies are minimal, though trends point to sediment sorting in transport. Comparisons to terrestrial basaltic sedimentary systems indicate that the Hartmann's Valley and Karasburg facies reflect deposition in an environment where diverse subaqueous and subaerial facies persisted adjacent to a long-lived body of water.

Journal of Geophysical Research Planets↗

USGS2021

Diagenesis revealed by fine-scale features at Vera Rubin ridge, Gale crater, Mars

Fine-scale (submillimeter to centimeter) depositional and diagenetic features encountered during the Curiosity rover's traverse in Gale crater provide a means to understand the geologic history of Vera Rubin ridge (VRR). VRR is a topographically high feature on the lower north slope of Aeolis Mons, a 5-km high stratified mound within Gale crater. We use high-spatial resolution images from the Mars Hand Lens Imager (MAHLI) as well as grain sizes estimated with the Gini index mean score technique that uses ChemCam Laser-Induced Breakdown Spectroscopy (LIBS) chemical data to constrain the postdepositional history of the strata exposed on this ridge. MAHLI images were used to examine the color, grain size, and style of lamination of the host rocks, as well as to explore the occurrence of nodules, diagenetic crystals, pits, and a variety of dark-gray iron-rich features. This survey revealed abundant and widespread diagenetic features within the rocks exposed on VRR and demonstrated that rock targets estimated to be coarser generally contain more diagenetic features than those estimated to have finer grains, which indicate that grain size may have influenced the degree and type of diagenesis. A subset of rocks within VRR are gray in color and exhibit the highest proportion of diagenetic features. We suggest that these targets experienced a different diagenetic history than the other rocks on VRR and hypothesize that redistribution and recrystallization of iron within specific intervals may have resulted in both the gray color and the abundance of dark-gray iron-rich diagenetic features.

JGR Planets↗

USGS2017

Diagenetic silica enrichment and late-stage groundwater activity in Gale crater, Mars

Diagenetic silica enrichment in fracture-associated halos that crosscut lacustrine and unconformably overlying aeolian sedimentary bedrock is observed on the lower north slope of Aeolis Mons in Gale crater, Mars. The diagenetic silica enrichment is colocated with detrital silica enrichment observed in the lacustrine bedrock yet extends into a considerably younger, unconformably draping aeolian sandstone, implying that diagenetic silica enrichment postdates the detrital silica enrichment. A causal connection between the detrital and diagenetic silica enrichment implies that water was present in the subsurface of Gale crater long after deposition of the lacustrine sediments and that it mobilized detrital amorphous silica and precipitated it along fractures in the overlying bedrock. Although absolute timing is uncertain, the observed diagenesis likely represents some of the most recent groundwater activity in Gale crater and suggests that the timescale of potential habitability extended considerably beyond the time that the lacustrine sediments of Aeolis Mons were deposited.

Geophysical Research Letters↗

USGS2016

High concentrations of manganese and sulfur in deposits on Murray Ridge, Endeavour Crater, Mars

Mars Reconnaissance Orbiter HiRISE images and Opportunity rover observations of the ~22 km wide Noachian age Endeavour Crater on Mars show that the rim and surrounding terrains were densely fractured during the impact crater-forming event. Fractures have also propagated upward into the overlying Burns formation sandstones. Opportunity’s observations show that the western crater rim segment, called Murray Ridge, is composed of impact breccias with basaltic compositions, as well as occasional fracture-filling calcium sulfate veins. Cook Haven, a gentle depression on Murray Ridge, and the site where Opportunity spent its sixth winter, exposes highly fractured, recessive outcrops that have relatively high concentrations of S and Cl, consistent with modest aqueous alteration. Opportunity’s rover wheels serendipitously excavated and overturned several small rocks from a Cook Haven fracture zone. Extensive measurement campaigns were conducted on two of them: Pinnacle Island and Stuart Island. These rocks have the highest concentrations of Mn and S measured to date by Opportunity and occur as a relatively bright sulfate-rich coating on basaltic rock, capped by a thin deposit of one or more dark Mn oxide phases intermixed with sulfate minerals. We infer from these unique Pinnacle Island and Stuart Island rock measurements that subsurface precipitation of sulfate-dominated coatings was followed by an interval of partial dissolution and reaction with one or more strong oxidants (e.g., O 2 ) to produce the Mn oxide mineral(s) intermixed with sulfate-rich salt coatings. In contrast to arid regions on Earth, where Mn oxides are widely incorporated into coatings on surface rocks, our results demonstrate that on Mars the most likely place to deposit and preserve Mn oxides was in fracture zones where migrating fluids intersected surface oxidants, forming precipitates shielded from subsequent physical erosion.

American Mineralogist↗