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Michael J. Kunk

Publications and source records attributed to Michael J. Kunk.

At least 55 records · Page 3Linked to original sources
USGS2002

Fluid-rock reactions in an evaporitic melange, Permian Haselgebirge, Austrian Alps

Tectonically isolated blocks of carbonate rocks present within the anhydritic Haselgebirge melange of the Northern Calcareous Alps record a complex history of deformation and associated deep-burial diagenetic to very low-grade metamorphic reactions. Fluids were hot (up to ~ 250 ??C) and reducing brines charged with carbon dioxide. Individual carbonate outcrops within the melange record different regimes of brine-rock reactions, ranging from pervasive dolomite recrystallization to dedolomitization. Early diagenetic features in these carbonates were almost entirely obliterated. Matrix dolomite alteration was related to thermochemical sulphate reduction (TSR) recognized by the replacement of anhydrite by calcite + pyrite ?? native sulphur. Pyrite associated with TSR is coarsely crystalline and characterized by a small sulphur isotope fractionation relative to the precursor Permian anhydrite. Carbonates associated with TSR show low Fe/Mn ratios reflecting rapid reaction of ferrous iron during sulphide precipitation. As a result, TSR-related dolomite and calcite typically show bright Mn(II)-activated cathodoluminescence in contrast to the dull cathodoluminescence of many (ferroan) carbonate cements in other deep-burial settings. In addition to carbonates and sulphides, silicates formed closely related to TSR, including quartz, K-feldspar, albite and K-mica. 40Ar/39Ar analysis of authigenic K-feldspar yielded mostly disturbed step-heating spectra which suggest variable cooling through the argon retention interval for microcline during the Late Jurassic. This timing coincides with the recently recognized subduction and closure of the Meliata-Hallstatt ocean to the south of the Northern Calcareous Alps and strongly suggests that the observed deep-burial fluid-rock reactions were related to Jurassic deformation and melange formation of these Permian evaporites.

Sedimentology↗
USGS2002

Eagle collapse center: Interpretation of evidence for late Cenozoic evaporite-related deformation in the Eagle River basin, Colorado

Evaporite tectonism resulted in deformation and collapse over an area of ~2500 km2 that is referred to as the Eagle collapse center. The collapse center includes much of the Eagle and Colorado River drainage basins between Vail, Dotsero, and McCoy, Colorado. The volume loss of evaporitic rocks by dissolution in the collapse center is estimated to be nearly 1700 km3 3 . Before ca. 10 Ma, Miocene basaltic flows partly covered an extensive, nearly horizontal, low-relief surface. Parts of this surface collapsed 1.3 km near the present-day Eagle and Colorado Rivers. Remnants of this surface outside the area of collapse, such as highlands of the White River uplift, the flank of the Gore Range, and Basalt Mountain, stand at elevations of 2.9–3.6 km. The high-standing Castle Peak basaltic cap, situated near the center of the Eagle collapse center, may not have collapsed, or collapsed little. The areas of collapse lie within or nearby known and inferred limits of the Pennsylvanian Eagle Valley Evaporite (mostly halite, gypsum, and anhydrite) that was deposited in the Central Colorado trough. Our geologic mapping and research in the Eagle collapse center delineate synclinal sags in the basaltic flows with amplitudes of 0.5–1 km, sinuous and discontinuous high-angle faults that cut basaltic flows, elongate grabens, evaporite-cored anticlines, and an ellipsoidal fault system that drops a 30 km X 10 km mountain block of younger strata into evaporite. Collapse as far as 20 km from the Colorado and Eagle Rivers suggests that the greater load on evaporite beneath surrounding highlands causes lateral flow of evaporite toward anticlinal crests in river valleys. Thus, gravity-driven evaporite flow and removal of evaporite by dissolution in groundwater and by subsequent discharge to surface waters combine to produce large-scale collapse. Although most evaporite tectonism post dates the basaltic flow capped surface, local angular unconformities under this surface record earlier, possibly Laramide evaporite tectonism, and overthickened post-evaporite red beds record some late Paleozoic evaporite deformation

Colorado↗
USGS2002

Correlation of late Cenozoic basaltic lava flows in the Carbondale and Eagle collapse centers in west-central Colorado based on geochemical, isotopic, age, and petrographic data

Major-, minor-, and trace-element abundance data on 220, late Cenozoic, basaltic rocks in and around the Carbondale and Eagle collapse centers in west-central Colorado are combined with isotopic, age, and petrographic data to correlate lava flows and establish the timing and minimum areal extent of collapse events associated with removal of Pennsylvanian evaporite. On the basis of these data, 46 distinct compositional groups of volcanic rocks were identified. The rocks within each group, which are represented by at least two samples, have compositions and ages that are indistinguishable from each other and are either (1) undifferentiated samples from the same eruption and possibly from outcrops of the same flow, (2) differentiated from the same magma batch erupted at different times or (3) related to each other by very small differences in the degree of partial melting. The areal extent of chemically correlated and dated volcanic flows in the region was established and these results were used to recognize and understand many of the collapse events as described in companion papers in this volume. Compositional data are also used to infer the petrogenetic processes that generated the parental magmas. Subtle but significant differences among rocks that are broadly similar in geochemical and isotopic composition and were erupted over a small time interval (<0.5 m.y.) suggests that the mantle source region of these magmas is quite heterogeneous. Over the past 11 m.y., the lavas became less mafic and more enriched in incompatible trace elements. This heterogeneity is attributed to variable contributions of subducted material in the lithosphere during the melting processes. To account for its isotopic features, the source material must be at least mid-Proterozoic in age. A melt contribution from underlying asthenospheric mantle can not be ruled out but none of the volcanic rocks have clear characteristics of oceanic-island basalts or mid-oceanic-ridge basalts. The trace-element compositions of rocks that were sampled from multiple stacked flows are indistinguishable from one another.This suggests that lower and/or upper crustal assimilation had a minor effect on their overall chemistry. However, Pb isotopic data suggest that crustal contamination of at least some samples did occur.

Colorado↗
USGS2002

40Ar/39Ar ages of late Cenozoic volcanic rocks within and around the Carbondale and Eagle collapse centers, Colorado: Constraints on the timing of evaporite-related collapse and incision of the Colorado River

40 Ar/ 39 Ar dating results of 133 samples from 84 late Cenozoic volcanic rocks provide emplacement ages that constrain the timing of evaporite collapse and the incision rates of the Colorado River. Our samples are from areas in west-central Colorado, both within and outside of the Carbondale and Eagle collapse centers. Significant pulses of volcanic activity occurred in the intervals from 24 to 22, 16 to 13, 11 to 9, and 8 to 7 Ma. In addition, small flows, widely spaced in time and space were emplaced during the last 4 m.y. Although individual basaltic flows appear to be chemically and isotopically homogeneous, there are significant geochemical and isotopic differences between flows, even between some flows that apparently have the same age within the limits of analytical precision. A low-relief early to middle Miocene erosional surface has been postulated in west-central Colorado. Our studies are consistent with the existence of a low-relief paleotopographic surface that is now at a minimum elevation range of ~2.9–3.4 km outside areas of collapse. Elevation departures from this range suggest that 1000 m of subsidence due to evaporite removal has locally occurred in the Carbondale and Eagle collapse centers. 40 Ar/ 39 Ar ages from downdropped and disrupted basaltic flows in the Carbondale center constrain initial collapse to >13 Ma, the timing of much of the evaporite-related collapse to the past 10–8 m.y., and an increase in the rate of collapse during the last 3 m.y. Ages and elevations of basaltic rocks above the Colorado River in Glenwood Canyon are used to calculate average apparent incision rates for the Colorado River in Glenwood Canyon of 24 mm/k.y. from 7.8 to 3.0 Ma. The average apparent incision rate increased by an order of magnitude to 242 mm/k.y. during the last 3 m.y

Colorado↗
USGS2002

Tertiary cooling and tectonic history of the White River uplift, Gore Range, and western Front Range, central Colorado: Evidence from fission-track and 39Ar/ 40Ar ages

Apatite fission-track (AFT) data from Proterozoic and Paleozoic rocks in the mountains of north central Colorado (White River Uplift, Gore Range, and western Front Range) record significant cooling that began with uplift and erosion related to the Laramide Orogeny and continued through the Tertiary to Pliocene time. The mountains immediately flanking the Blue River half graben (Williams Fork Mountains to the east and the Gore Range to the west) cooled significantly during the Neogene. The AFT ages along the flanks of the Blue River half graben are significantly younger than AFT ages farther to the east in the central and eastern Front Range and to the west in the White River uplift. In both of these areas, the apatite ages suggest Laramide cooling. The Williams Fork Mountains–Gore Range zone of young AFT ages extends southward adjacent to the axis of the Rio Grande rift through southern Colorado and New Mexico. These young ages result from a combination of elevated heat flow, uplift, and erosion along the axis of the Rio Grande rift during Neogene time. Zircons from Proterozoic rocks yield Proterozoic fission-track ages, indicating that this part of the Colorado basement has not been heated to temperatures 200 C since Middle Proterozoic time. A sanidine 40 Ar/ 39 Ar age of 27 Ma from a rhyolite tuff just above a basal boulder conglomerate of the Troublesome Formation in a tilted fault block within the Blue River half graben shows that Tertiary deposition started there in middle Oligocene time. Xenocrystic sanidine from a basalt stratigraphically higher than the rhyolite tuff has an age of 24 Ma. Thus, the basalt is significantly younger than its postulated source, the 32 Ma laccolithic complex at Green Mountain.

Colorado↗
USGS2002

Evaporite tectonism in the lower Roaring Fork River valley, west-central Colorado

Evaporite tectonism in the lower Roaring Fork River valley in west-central Colorado has caused regional subsidence of a differentially downdropped area in the southern part of the Carbondale collapse center during the late Cenozoic. A prominent topographic depression coincides with this collapse area, and drainage patterns within the collapse area contrast sharply with those outside of it. Miocene volcanic rocks are downdropped as much as 1220 m in the collapse area. Much of the structural lowering occurred along the margins of the collapse area. Major Laramide-age structures bound the east and west sides of the collapse area, but movement on these structures during late Cenozoic collapse was in an opposite direction to their Laramide movement. Within the interior part of the collapse area faults and folds have as much as 300 m of structural relief. Large blocks of rock may be rafting into the Roaring Fork River valley as underlying evaporite flows toward the valley. Sinkholes are common in the collapse area, as are closed, or nearly closed, structurally controlled topographic depressions that are formed in both surficial deposits and bedrock. Upper Cenozoic deltaic and lacustrine deposits preserved on ridgelines and mesas document the positions of former structural depressions that were initially filled with sediments and later breached by erosion. At least 450 m of syn-collapse sediments accumulated in a collapse depression on the north side of Mount Sopris. Complexly deformed and brecciated deposits in the interior parts of the collapse center are interpreted as collapse debris. Evaporite flow is an important element in the collapse process, and during early stages of collapse it was perhaps the primary means of deformation. Flow by itself, does not remove evaporite from the collapse area. Dissolution and accompanying transport of dissolved constituents by groundwater and surface water are the ultimate means by which evaporite exits the collapse area. Collapse continues today, as evidenced by historic sinkholes and modern high-salinity loads in rivers and thermal springs. Thick evaporite deposits still underlie much of the collapse area, so collapse will likely continue in the future.

Colorado↗
USGS2002

SHRIMP U-Pb and 40Ar/39Ar age constraints for relating plutonism and mineralization in the Boulder batholith region, Montana

The composite Boulder batholith, Montana, hosts a variety of mineral deposit types, including important silver-rich polymetallic quartz vein districts in the northern part of the batholith and the giant Butte porphyry copper-molybdenum pre-Main Stage system and crosscutting copper-rich Main Stage vein system in the southern part of the batholith. Previous dating studies have identified ambiguous relationships among igneous and mineralizing events. Mineralizing hydrothermal fluids for these types of deposits and magma for quartz porphyry dikes at Butte have all been considered to be late-stage differentiates of the Boulder batholith. However, previous dating studies indicated that the Boulder batholith plutons cooled from about 78 to 72 Ma, whereas copper-rich Main Stage veins at Butte were dated at about 61 Ma. Recent efforts to date the porphyry copper-molybdenum pre-Main Stage deposits at Butte resulted in conflicting estimates of both 64 and 76 Ma for the mineralizing events. Silver-rich polymetallic quartz vein deposits elsewhere in the batholith have not been dated previously. To resolve this controversy, we used the U.S. Geological Survey, Stanford, SHRIMP RG ion microprobe to date single-age domains within zircons from plutonic rock samples and 40 Ar/ 39 Ar geochronology to date white mica, biotite, and K-feldspar from mineral deposits. U-Pb zircon ages are Rader Creek Granodiorite, 80.4 ± 1.2 Ma; Unionville Granodiorite, 78.2 ± 0.8 Ma; Pulpit Rock granite, 76.5 ± 0.8 Ma; Butte Granite, 74.5 ± 0.9 Ma; altered Steward-type quartz porphyry dike (I-15 roadcut), 66.5 ± 1.0 Ma; altered Steward-type quartz porphyry dike (Continental pit), 65.7 ± 0.9 Ma; and quartz monzodiorite of Boulder Baldy (Big Belt Mountains), 66.2 ± 0.9 Ma. Zircons from Rader Creek Granodiorite and quartz porphyry dike samples contain Archean inheritance. The 40 Ar/ 39 Ar ages are muscovite, silver-rich polymetallic quartz vein (Basin district), 74.4 ± 0.3 Ma; muscovite, silver-rich polymetallic quartz vein (Boulder district), 74.4 ± 1.2 Ma; muscovite, early dark micaceous vein (Continental pit), 63.6 ± 0.2 Ma; biotite, early dark micaceous vein (Continental pit), 63.6 ± 0.2 Ma; potassium feldspar, early dark micaceous vein (Continental pit), 63 to 59 Ma; and biotite, biotite breccia dike (Continental pit), 63.6 ± 0.2 Ma. Outlying silver-rich polymetallic quartz veins of the Basin and Boulder mining districts probably are directly related to the 74.5 Ma Butte Granite, whereas Steward-type east-west quartz porphyry dikes and Butte pre-Main Stage deposits are parts of a 66 to 64 Ma magmatic-mineralization system unrelated to emplacement of the Boulder batholith. The age of the crosscutting Main Stage veins may be about 61 Ma as originally reported but can only be bracketed as younger than the 64 Ma pre-Main Stage mineralization and older than the about 50 Ma Eocene Lowland Creek intrusions. The 66 Ma age for the quartz monzodiorite of Boulder Baldy and consideration of previous dating studies in the region indicate that small ca. 66 Ma plutonic systems may be common in the Boulder batholith region and especially to the east. The approximately 64 Ma porphyry copper systems at Butte and gold mineralization at Miller Mountain are indicative of regionally important mineralizing systems of this age in the Boulder batholith region. Resolution of the age and probable magmatic source of the Butte pre-Main Stage porphyry copper-molybdenum system and of the silver-rich polymetallic quartz vein systems in the northern part of the Boulder batholith documents that these deposits formed from two discrete periods of hydrothermal mineralization related to two discrete magmatic events.

Montana↗
USGS2001

Late Cenozoic regional collapse due to evaporite flow and Dissolution in the Carbondale Collapse Center, West-Central Colorado

Dissolution and flow of Pennsylvanian evaporitic rocks in west-central Colorado created the Carbondale Collapse Center, a 450 mi2 structural depression with about 4,000 ft of vertical collapse during the late Cenozoic. This paper describes evidence of collapse in the lower Roaring Fork River valley. Both the lateral extent and amount of vertical collapse is constrained by deformed upper Cenozoic volcanic rocks that have been correlated using field mapping, 40Ar/39Ar geochronology, geochemistry, and paleomagnetism. The Carbondale Collapse Center is one of at least two contiguous areas that have experienced major evaporite tectonism during the late Cenozoic. Historic sinkholes, deformed Holocene deposits, and modern high-salinity loads in the rivers and thermal springs indicate the collapse process continues today. Flow of evaporitic rocks is an important element in the collapse process, and during initial stages of collapse it was probably the primary causative mechanism. Dissolution, however, is the ultimate means by which evaporite is removed from the collapse area. As the Roaring Fork River began to rapidly down-cut through a broad volcanic plateau during the late Miocene, the underlying evaporite beds were subjected to differential overburden pressures. The evaporitic rocks flowed from beneath the upland areas where overburden pressures remained high, toward the Roaring Fork River Valley where the pressures were much lower. Along the valley the evaporitic rocks rose upward, sometimes as diapirs, forming or enhancing a valley anticline in bedrock and locally upwarping Pleistocene terraces. Wherever the evaporites encountered relatively fresh ground water, they were dissolved, forming underground voids into which overlying bedrock and surficial deposits subsided. The saline ground water eventually discharged to streams and rivers through thermal springs and by seepage into alluvial aquifers.

Mountain Geologist↗
USGS1999

Active evaporite tectonics and collapse in the Eagle River valley and the southwestern flank of the White River uplift, Colorado

This field trip presents field evidence for Neogene evaporite tectonism, dissolution of evaporates, and related collapse in Eagle River valley and along the southwestern flank of the White River uplift. In the Eagle collapse center, Pennsylvanian evaporite flowed to form anticlinal diapirs, dissolved, and disrupted a lower Miocene basaltic plateau originally at elevations as high as 3.35 km by tilting, faulting, and sagging to elevations as low as about 2.1 km. Also in the Eagle collapse center, the 30 x 10-km, homoclinal Hardscrabble Mountain sank into evaporite during Triassic and Permian collapse followed by Neogene(?) tilting and collapse, based on seismic reflection data. Along the southwestern flank of the White River uplift in the northwestern part of the Carbondale collapse center, parts of the Grand Hogback monocline have collapsed northeastward toward a series of strike-elongate extrusive diapirs. The volume of evaporite removed from the Eagle and Carbondale collapse centers during the Neogene (about 2,250 km 3 from an area of roughly 4,500 km 2 ) was calculated by measuring the departure of collapsed basalts from an assumed original basalt plateau. Regional Neogene uplift and incision of the Rocky Mountains, which locally began about 8-10 Ma, probably triggered dissolution and collapse. Presently the Colorado River removes a dissolved-solids load of about 1.4 x 10 9 kg per year from the two collapse centers.

Colorado↗
USGS1998

Authigenic potassium feldspar: A tracer for the timing of palaeofluid flow in carbonate rocks, Northern Calcareous Alps, Austria

Feldspar is a common authigenic constituent in Permian carbonate rocks which occur as tectonically isolated blocks within the evaporitic Haselgebirge mélange in the Northern Calcareous Alps (NCA). Coexisting with pyrite, anhydrite, (saddle) dolomite, magnesite, fluorite and calcite, K-feldspar and minor albite record an event of regionally extensive interaction of hot brines with carbonate rocks. Detailed petrographic, crystallographic and geochemical studies reveal a variability in crystal size and shape, Al-Si ordering, elemental and stable isotopic compositions of the K-feldspar, which is only partially consistent with the traditional view of authigenic feldspar as a well-ordered, compositionally pure mineral. 40 Ar- 39 Ar step-heating measurements of authigenic potassium feldspar from several localities yield two age populations, an older one of 145–154 Ma, and a younger one of c. 90–97 Ma. Most age spectra reflect cooling through the argon retention temperature interval, which was rapid in some localities (as indicated by plateau ages) and slower in others. Rb-Sr isotope data are more difficult to interpret, because in many K-feldspar samples they are controlled largely by Sr-bearing inclusions. The Jurassic 40 Ar- 39 Ar dates are interpreted as minimum ages of feldspar growth and hence imply that fluid-rock interaction is likely to be simultaneous with or to slightly predate mélange formation. Deformation associated with the closure and subduction of the Meliata-Hallstatt ocean south of the NCA during the Upper Jurassic is regarded as the principal geodynamic driving force for both enhanced fluid circulation and mélange formation. Some localities were reheated beyond the argon retention temperature for microcline during mid-Cretaceous nappe stacking of the NCA, thus obliterating the older signal.

Geological Society Special Publication↗
USGS1997

The inverse problem of argon diffusion from minerals: Determination of kinetic parameters from stepwise-heating experiments

Results of two routine 40 Ar/ 39 Ar stepwise heating experiments on a biotite and a basanite are interpreted in terms of Fick's and Arrhenius' laws. Both patterns represent a saddle-shaped 39 Ar release. Argon isotope spectra are suggested to be controlled by the activation energy of diffusion E and the frequency factor D o . The activation energy of 39 Ar is lower than the one of 40 Ar. This results in a preferable release of 40 Ar relatively to 39 Ar at high-temperature steps and an increasing high-temperature wing in the saddle-shaped age spectrum. At low temperatures, considerable losses and irregularities in release of mainly 39 Ar are observed, which cause the decreasing low-temperature wing in the “saddle”. The suggestion of argon losses (mainly of 39 Ar) from a loose, “unstable” zone of the mineral structures becomes justified. The n -irradiation of the samples and the shift of E of 39 Ar towards lower values seems to explain the saddle-shaped age-spectra often encountered in 40 Ar/ 39 Ar-geochronometry.

Isotopes in Environmental and Health Studies↗
USGS1997

Igneous evolution of a complex laccolith-caldera, the Solitario, Trans-Pecos Texas: Implications for calderas and subjacent plutons

The Solitario is a large, combination laccolith and caldera (herein termed “laccocaldera”), with a 16-km-diameter dome over which developed a 6×2 km caldera. This laccocaldera underwent a complex sequence of predoming sill, laccolith, and dike intrusion and concurrent volcanism; doming with emplacement of a main laccolith; ash-flow eruption and caldera collapse; intracaldera sedimentation and volcanism; and late intrusion. Detailed geologic mapping and 40 Ar/ 39 Ar dating reveal that the Solitario evolved over an interval of approximately 1 m.y. in three distinct pulses at 36.0, 35.4, and 35.0 Ma. The size, duration, and episodicity of Solitario magmatism are more typical of large ash-flow calderas than of most previously described laccoliths.

Texas↗
USGS1996

Authigenic feldspar as an indicator of paleo-rock/water interactions in Permian carbonates of the Northern Calcareous Alps, Austria

Dolostones interbedded with Upper Permian evaporites at the base of the Northern Calcareous Alps contain abundant authigenic K-feldspar. Two petrographically, structurally, and isotopically distinct generations of K-feldspar can be distinguished: crystals composed of an inclusion. rich core and a clear rim, and optically unzoned, transparent crystals. Both feldspar types have essentially identical K-feldspar end-member compositions with >= 99.5 mole % Or component. Low oxygen isotope ratios (+16.1 per thousand to +18.1 per thousand SMOW) suggest precipitation from 18 O-enriched, saline fluids at temperatures in excess of nearly equal 140 degrees C. 40 Ar/ 39 Ar plateau-age spectra of five samples range from 145 + or - 1 to 144 + or -1 Ma (Early Berriasian) and suggest that both types of feldspar were formed within an interval that did not exceed nearly equal 2 m.y. Rb/Sr model ages range from 152 to 140 Ma, assuming that the burial diagenetic regime was buffered with respect to strontium by the associated marine Permian evaporites. Authigenic K-feldspar records two distinct events of hot brine flow, most likely triggered by tectonic movements (detachment) and by an increase in the subsurface temperature in response to thrust loading.

Journal of Sedimentary Research↗
USGS1996

40Ar/39Ar whole-rock data constraints on Acadian diagenesis and Alleghanian cleavage in the Martinsburg formation, eastern Pennsylvania

A comparison of 40 Ar/ 39 Ar age spectra of whole-rock mudstone and slate samples from the Ordovician Martinsburg Formation at Lehigh Gap, Pennsylvania and stratigraphic and thermal constraints support Alleghanian age for regional slaty cleavage and a late Acadian age for diagenesis in these rocks. Age spectra from mud-stones have a sigmodal shape, with slopes that climb steeply from apparent Mesozoic ages to intermediate saddle regions with Devonian apparent ages, and then climb steeply again to Late Proterozoic apparent ages. The steps with these oldest apparent ages are interpreted to be dominated by late Proterzoic detrial muscovite. The saddle region of the mudstone samples gives very Late Silurian to earliest Devonian ages, which are maximum ages of diagenetic micas and which eliminate a Taconic age for the cleavage. The ages of saddle regions of the slate samples constraining cleavage-forming muscovite is <~375. This is the maximum age of this mica and requires an Alleghanian age for the cleavage. These age constraints are supported by ages of individual mica components calculated with knowledge of the total gas ages and mass fractions of the micas and by predictions from thermal modeling. We conclude that the Taconic orogeny in the Martinsburg Formation in eastern Pennsylvania was a very mild event. Not only is the cleavage in these rocks not Taconic in age, but even the mild (~100C) diagenetic growth of illite was Silurian of younger. Thus the Taconic event in these rocks in limited to loading of lass than about 3 km.

Connecticut, Delaware, Maryland, Pennsylvania, New↗