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Michael J. Kleeschulte

Publications and source records attributed to Michael J. Kleeschulte.

10 recordsLinked to original sources

Borehole Geophysical, Water-Level, and Water-Quality Investigation of a Monitoring Well Completed in the St. Francois Aquifer in Oregon County, Missouri, 2005-08

A deep (more than 2,000 feet) monitoring well was installed in an area being explored for lead and zinc deposits within the Mark Twain National Forest in southern Missouri. The area is a mature karst terrain where rocks of the Ozark aquifer, a primary source of water for private and public supplies and major springs in the nearby Eleven Point National Wild and Scenic River and the Ozark National Scenic Riverways, are exposed at the surface. The potential lead deposits lie about 2,000 feet below the surface within a deeper aquifer, called the St. Francois aquifer. The two aquifers are separated by the St. Francois confining unit. The monitoring well was installed as part of a series of investigations to examine potentiometric head relations and water-quality differences between the two aquifers. Results of borehole flowmeter measurements in the open borehole and water-level measurements from the completed monitoring well USGS-D1 indicate that a seasonal upward gradient exists between the St. Francois aquifer and the overlying Ozark aquifer from about September through February. The upward potentiometric heads across the St. Francois confining unit that separates the two aquifers averaged 13.40 feet. Large reversals in this upward gradient occurred during the late winter through summer (about February through August) when water levels in the Ozark aquifer were as much as 138.47 feet higher (average of 53.84 feet) than water levels in the St. Francois aquifer. Most of the fluctuation of potentiometric gradient is caused by precipitation and rapid recharge that cause large and rapid increases in water levels in the Ozark aquifer. Analysis of water-quality samples collected from the St. Francois aquifer interval of the monitoring well indicated a sodium-chloride type water containing dissolved-solids concentrations as large as 1,300 milligrams per liter and large concentrations of sodium, chloride, sulfate, boron, and lithium. In contrast, water in the overlying Ozark aquifer interval of the monitoring well was a calcium-magnesium-bicarbonate type water containing less than 250 milligrams per liter dissolved solids and substantially smaller concentrations of major and trace elements.

Scientific Investigations Report

Hydrologic investigations concerning lead mining issues in southeastern Missouri

Good stewardship of our Nation's natural resources demands that the extraction of exploitable, minable ore deposits be conducted in harmony with the protection of the environment, a dilemma faced by many land and water management agencies in the Nation's mining areas. As ore is mined, milled, and sent to the smelter, it leaves footprints where it has been in the form of residual trace metals. Often these footprints become remnants that can be detrimental to other natural resources. This emphasizes the importance of understanding the earth's complex physical and biological processes and their interactions at increasingly smaller scales because subtle changes in one component can substantially affect others. Understanding these changes and resulting effects requires an integrated, multidisciplinary scientific approach. As ore reserves are depleted in one area, additional exploitable deposits are required to replace them, and at times these new deposits are discovered in previously unmined areas. Informed decisions concerning resource management in these new, proposed mining areas require an understanding of the potential consequences of the planned mining actions. This understanding is usually based on knowledge that has been accumulated from studying previously mined areas with similar geohydrologic and biologic conditions. If the two areas experience similar mining practices, the information should be transferable. Lead and zinc mining along the Viburnum Trend Subdistrict of southeastern Missouri has occurred for more than 40 years. Additional potentially exploitable deposits have been discovered 30 miles to the south, within the Mark Twain National Forest. It is anticipated that the observation of current (2008) geohydrologic conditions in the Viburnum Trend can provide insight to land managers that will help reasonably anticipate the potential mining effects should additional mining occur in the exploration area. The purpose of this report is to present a compilation of previously unpublished information that was collected as part of a larger multidisciplinary study of lead mining issues in southeastern Missouri. The report resulted from the application of a multidisciplinary approach to investigate current hydrologic and biologic conditions in streams of the Viburnum Trend and the exploration area in the Mark Twain National Forest.

Missouri

Recharge area, base-flow and quick-flow discharge rates and ages, and general water quality of Big Spring in Carter County, Missouri, 2000-04

Exploration for lead deposits has occurred in a mature karst area of southeast Missouri that is highly valued for its scenic beauty and recreational opportunities. The area contains the two largest springs in Missouri (Big Spring and Greer Spring), both of which flow into federally designated scenic rivers. Concerns about potential mining effects on the area ground water and aquatic biota prompted an investigation of Big Spring. Water-level measurements made during 2000 helped define the recharge area of Big Spring, Greer Spring, Mammoth Spring, and Boze Mill Spring. The data infer two distinct potentiometric surfaces. The shallow potentiometric surface, where the depth-to-water is less than about 250 feet, tends to mimic topographic features and is strongly controlled by streams. The deep potentiometric surface, where the depth-to-water is greater than about 250 feet represents ground-water hydraulic heads within the more mature karst areas. A highly permeable zone extends about 20 mile west of Big Spring toward the upper Hurricane Creek Basin. Deeper flowing water in the Big Spring recharge area is directed toward this permeable zone. The estimated sizes of the spring recharge areas are 426 square miles for Big Spring, 352 square miles for Greer Spring, 290 square miles for Mammoth Spring, and 54 square miles for Boze Mill Spring. A discharge accumulation curve using Big Spring daily mean discharge data shows no substantial change in the discharge pattern of Big Spring during the period of record (water years 1922 through 2004). The extended periods when the spring flow deviated from the trend line can be attributed to prolonged departures from normal precipitation. The maximum possible instantaneous flow from Big Spring has not been adequately defined because of backwater effects from the Current River during high-flow conditions. Physical constraints within the spring conduit system may restrict its maximum flow. The largest discharge measured at Big Spring during the period of record (water years 1922 through 2004) was 1,170 cubic feet per second on December 7, 1982. The daily mean water temperature of Big Spring was monitored during water years 2001 through 2004 and showed little variability, ranging from 13 to 15° C (degree Celsius). Water temperatures generally vary less than 1° C throughout the year. The warmest temperatures occur during October and November and decrease until April, indicating Big Spring water temperature does show a slight seasonal variation. The use of the traditional hydrograph separation program HYSEP to determine the base flow and quick flow or runoff components at Big Spring failed to yield base-flow and quick-flow discharge curves that matched observations of spring characteristics. Big Spring discharge data were used in combination with specific conductance data to develop an improved hydrograph separation method for the spring. The estimated annual mean quick flow ranged from 15 to 48 cubic feet per second for the HYSEP analysis and ranged from 26 to 154 cubic feet per second for the discharge and specific conductance method for water years 2001 to 2004. Using the discharge and specific conductance method, the estimated base-flow component rises abruptly as the spring hydrograph rises, attains a peak value on the same day as the discharge peak, and then declines abruptly from its peak value. Several days later, base flow begins to increase again at an approximately linear trend, coinciding with the time at which the percentage of quick flow has reached a maximum after each recharge-induced discharge peak. The interval between the discharge peak and the peak in percentage quick flow ranges from 8 to 11 days for seven hydrograph peaks, consistent with quick-flow traveltime estimates by dye-trace tests from the mature karst Hurricane Creek Basin in the central part of the recharge area. Concentrations of environmental tracers chlorofluorocarbons (CFCs: CFC-11, CFC-12, CFC-113), and sulfur hexafluoride in discharge from Big Spring vary approximately linearly with percent quick flow from about 5 to 45 percent of discharge. Linear extrapolation to 100 percent quick flow implies CFC and SF 6 concentrations nearly identical to those in the 2002 atmosphere and indicates a modern age for the quick-flow component. Tracer concentrations for less than about 5 percent quick flow are increasingly lower than those expected from linear extrapolation to zero percent quick flow, indicating that the reservoir of older water in the Big Spring watershed may be a series of water mixtures with piston-flow ages greater than those obtained by extrapolation to zero percent quick flow. Each sample point with a low percentage of quick flow (less than 5 percent) may be a unique mixture. Environmental tracer data from Big Spring plot intermediate to the simple binary mixing of modern and old, pre-tracer water and results from the exponential mixture model. The mean ages of waters in the base-flow component approximately range from 30 to 200 years. The mean age of the base-flow component is youngest (30 to 40 years) in samples containing the highest quick-flow component (45 percent quick flow) and increases to 200 years or more as the fraction of quick flow decreases to less than 5 percent. Tritium data are consistent with a model of dilution of a modern component with an old, pre-tracer component and indicates that the old fraction is mostly pre-1960s in age with mean residence time of more than several hundred years. All of the samples from Big Spring and Greer Spring have water temperatures warmer than their nitrogen-argon recharge temperature, which range from approximately 10.5 to 14° C, suggesting recharge to the Big Spring watershed occurs primarily in late winter to early spring. The water temperatures at Big Spring are consistent with relatively shallow circulation (less than about 600 feet), and the water does not appear to be warmed by deep circulation along a geothermal gradient. Specific conductance values and concentrations of most inorganic constituents in water samples from Big Spring generally decrease with increasing discharge because of dilution with quick-flow water of lower ionic strength. Concentrations of some constituents such as chloride and nitrite plus nitrate, and fecal coliform densities, however, did not decrease with increasing discharge, indicating that quick flow probably is a more important source of these constituents compared to base flow. Water samples from Big Spring plot along the line of dolomite dissolution by carbonic acid, are at equilibrium with dolomite and calcite, and have a molar ratio of Ca:Mg of near 1, indicating dissolution of the mineral dolomite as the primary control on concentrations of calcium, magnesium, and bicarbonate. The flux of calcium and magnesium from Big Spring represents the dissolution of about 1,950 cubic feet of dolomite per day. The suspended sediment load of Big Spring was estimated to range from about 1 to about 70 tons per day, and the sediment load during base-flow periods ranged from about 1 to about 7 tons per day.

Missouri

Stratigraphy and vertical hydraulic conductivity of the St. Francois Confining Unit in the Viburnum Trend and evaluation of the Unit in the Viburnum Trend and exploration areas, southeastern Missouri

The confining ability of the St. Francois confining unit (Derby-Doerun Dolomite and Davis Formation) was evaluated in ten townships (T. 31?35 N. and R. 01?02 W.) along the Viburnum Trend of southeastern Missouri. Vertical hydraulic conductivity data were compared to similar data collected during two previous studies 20 miles south of the Viburnum Trend, in two lead-zinc exploration areas that may be a southern extension of the Viburnum Trend. The surficial Ozark aquifer is the primary source of water for domestic and public-water supplies and major springs in southern Missouri. The St. Francois confining unit lies beneath the Ozark aquifer and impedes the movement of water between the Ozark aquifer and the underlying St. Francois aquifer (composed of the Bonneterre Formation and Lamotte Sandstone). The Bonneterre Formation is the primary host formation for lead-zinc ore deposits of the Viburnum Trend and potential host formation in the exploration areas. For most of the more than 40 years the mines have been in operation along the Viburnum Trend, about 27 million gallons per day were being pumped from the St. Francois aquifer for mine dewatering. Previous studies conducted along the Viburnum Trend have concluded that no large cones of depression have developed in the potentiometric surface of the Ozark aquifer as a result of mining activity. Because of similar geology, stratigraphy, and depositional environment between the Viburnum Trend and the exploration areas, the Viburnum Trend may be used as a pertinent, full-scale model to study and assess how mining may affect the exploration areas. Along the Viburnum Trend, the St. Francois confining unit is a complex series of dolostones, limestones, and shales that generally is 230 to 280 feet thick with a net shale thickness ranging from less than 25 to greater than 100 feet with the thickness increasing toward the west. Vertical hydraulic conductivity values determined from laboratory permeability tests were used to represent the St. Francois confining unit along the Viburnum Trend. The Derby-Doerun Dolomite and Davis Formation are statistically similar, but the Davis Formation would be the more hydraulically restrictive medium. The shale and carbonate values were statistically different. The median vertical hydraulic conductivity value for the shale samples was 62 times less than the carbonate samples. Consequently, the net shale thickness of the confining unit along the Viburnum Trend significantly affects the effective vertical hydraulic conductivity. As the percent of shale increases in a given horizon, the vertical hydraulic conductivity decreases. The range of effective vertical hydraulic conductivity for the confining unit in the Viburnum Trend was estimated to be a minimum of 2 x 10-13 ft/s (foot per second) and a maximum of 3 x 10-12 ft/s. These vertical hydraulic conductivity values are considered small and verify conclusions of previous studies that the confining unit effectively impedes the flow of ground water between the Ozark aquifer and the St. Francois aquifer along the Viburnum Trend. Previously-collected vertical hydraulic conductivity data for the two exploration areas from two earlier studies were combined with the data collected along the Viburnum Trend. The nonparametric Kruskal-Wallis statistical test shows the vertical hydraulic conductivity of the St. Francois confining unit along the Viburnum Trend, and west and east exploration areas are statistically different. The vertical hydraulic conductivity values generally are the largest in the Viburnum Trend and are smallest in the west exploration area. The statistical differences in these values do not appear to be attributed strictly to either the Derby-Doerun Dolomite or Davis Formation, but instead they are caused by the differences in the carbonate vertical hydraulic conductivity values at the three locations. The calculated effective vertical hydraulic conductivity range for the St. Franc

Water-Resources Investigations Report

Regional ground-water flow directions and spring recharge areas in and near the Fort Leonard Wood Military Reservation, Missouri

Regional ground-water flow at the Fort Leonard Wood Military Reservation (FLWMR) generally is east and west away from a regional ground-water divide towards the Big Piney River and Roubidoux Creek. Ground-water flow in the northern FLWMR is strongly affected by solution-enlarged fractures and bedding planes in the Roubidoux Formation and Gasconade Dolomite. Several large springs located on the FLWMR (Sandstone Spring) and off the FLWMR (Shanghai Spring, Roubidoux Spring, and Miller Spring) receive water from precipitation recharge and stream flow loss on the FLWMR.

Fact Sheet

Hydrologic data for the Fristoe Unit of the Mark Twain National Forest, southern Missouri, 1988-93

Background hydrologic data were collected from 1988 to 1993 in the Fristoe Unit of the Mark Twain National Forest. Water-quality data collected from area streams, springs, and wells were analyzed using trilinear diagrams, stiff diagrams, boxplots, and summary statistics. The water is a calcium- magnesium-bicarbonate type. Streams generally have slightly larger potassium, barium, and total organic carbon concentrations than spring or well water. Well water has larger bicarbonate and zinc concen- trations and larger variability in sodium, chloride, and nitrate concentrations than stream and spring water samples. The bulk mineralogy for streambed material is primarily coarse grain quartz. Quantitative elemental (chemistry) analysis on the less than 63 micrometer fraction of bulk material was performed. The heavy mineral concentrate in the streambed material was analyzed using semi- quantitative optical mineralogy and 37-element semi- quantitative emission spectrography. Water levels were measured in 57 area wells in the spring and fall from 1990 to 1993 to determine ground-water level fluctuations. Ground-water fluctuations ranged from less than 1.0 to 205.1 feet in these wells. Continuous water-level recorders were installed on three area wells. Depth to water ranged from 289.68 to 333.39 feet in the lower Eleven Point well, which is completed in the Ozark aquifer. Depth to water ranged from 78.73 to 90.20 feet in Ozark Lead Well 1 which is completed in the Ozark aquifer and St. Francois confining unit. Depth to water ranged from 127.53 to 135.67 feet in Ozark Lead Well 2, which is completed in the St. Francois confining unit and the St. Francois aquifer.

Open-File Report