The occurrence of minor elements in ash of low-rank coal from Texas, Colorado, North Dakota, and South Dakota
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Geology topics
Publications and source records attributed to Maurice Deul.
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Detailed studies have been carried out on a uraniferous lignite from the Mendenhall strip mine, Harding County, S. Dak. By means of heavy-liquid separations, a mineral-free concentrate of the lignite was obtained that contained 13.8 percent ash and 0.31 percent uranium in the ash. The minerals (gypsum 69 percent, jarosite 10 percent, quartz 2 percent, kaolinite and clay minerals 19 percent, and calcite trace) contain only 7 percent of the uranium in the original coal, indicating an association of the uranium with the organic components of the lignite.Batch extractions show that 88.5 percent of the uranium can be extracted from the lignite by two consecutive treatments with boiling 1 N hydrochloric acid. Continuous extraction with hot 6 N hydrochloric acid removes 98.6 percent of the uranium.Columns of coal were treated with water, 1 N hydrochloric acid, 6 N hydrochloric acid, and a solution of lanthanum nitrate. The experiment with lanthanum nitrate indicated that only 1.2 percent of the uranium in the coal is held by ion exchange. The elutriation experiments showed that the uranium is held in the coal as an organo-uranium compound or complex that is soluble at a pH of less than 2.18.A geochemical mechanism by which the uranium may have been introduced into and retained by the lignite is discussed.
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A sample of subbituminous uraniferous coal from the Red Desert, Sweetwater County, Wyo., was studied mineralogically. The coal contains gypsum (6 percent), kaolinite (1 percent), quartz (0.3 percent), calcite (trace), and limonite (trace). This suite of minerals and the absence of pyrite show that the coal has been subjected to weathering and oxidation. No uranium minerals have been found; mechanical fractionation has indicated that the uranium is associated with the organic constituents of the coal. The minerals that have been isolated contain 0.0006 percent uranium, a content which is to be expected for nonuraniferous sedimentary rocks. The organic components of the coal contain approximately 0.002 percent uranium. On the basis of material balance calculations, the organic components carry 98 percent of the uranium in the coal. Fischer assays of this weathered coal from the Red Desert indicate a yield of 16.7 gallons of tar per ton on low-temperature retorting. In view of the large reserve of subbituminous coal in the Red Desert, its probable ease of mining, and its tar yield, it may be desirable to carry out further evaluation of the coal as a fuel or raw material for the manufacture of tar or chemicals. If economic factors permit utilization of the coal, the uranium, although present in small percentages, could be recovered as a byproduct.
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