Geology topics

Mark A. Huebner

Publications and source records attributed to Mark A. Huebner.

4 recordsLinked to original sources

USGS2012

Water chemistry and electrical conductivity database for rivers in Yellowstone National Park, Wyoming

Chloride flux has been used to estimate heat flow in volcanic environments since the method was developed in New Zealand by Ellis and Wilson (1955). The method can be applied effectively at Yellowstone, because nearly all of the water discharged from its thermal features enters one of four major rivers (the Madison, Yellowstone, Snake, and Falls Rivers) that drain the park, and thus integration of chloride fluxes from all these rivers provides a means to monitor the total heat flow from the entire Yellowstone volcanic system (Fournier and others, 1976; Fournier, 1979). Fournier (1989) summarized the results and longterm heat-flow trends from Yellowstone, and later efforts that applied the chloride inventory method to estimate heat flow were described by Ingebritsen and others (2001) and Friedman and Norton (2007). Most recently, the U.S. Geological Survey (USGS), in conjunction with the National Park Service, has provided publicly accessible reports on solute flux, based on periodic sampling at selected locations (Hurwitz and others, 2007a,b). While these studies have provided a wealth of valuable data, winter travel restrictions and the great distances between sites present significant logistical challenges and have limited collection to a maximum of 28 samples per site annually. This study aims to quantify relations between solute concentrations (especially chloride) and electrical conductivity for several rivers in Yellowstone National Park (YNP), by using automated samplers and conductivity meters. Norton and Friedman (1985) found that chloride concentrations and electrical conductivity have a good correlation in the Falls, Snake, Madison, and Yellowstone Rivers. However, their results are based on limited sampling and hydrologic conditions and their relation with other solutes was not determined. Once the correlations are established, conductivity measurements can then be used as a proxy for chloride concentrations, thereby enabling continuous heat-flow estimation on a much finer timescale and at lower cost than is currently possible with direct sampling. This publication serves as a repository for all data collected during the course of the study from May 2010 through July 2011, but it does not include correlations between solutes and conductivity or recommendations for quantification of chloride through continuous electrical conductivity measurements. This will be the object of a future document.

Wyoming↗

USGS2007

River Chemistry and Solute Flux in Yellowstone National Park

Introduction The Yellowstone Volcano Observatory (YVO) was established to 'To strengthen the long-term monitoring of volcanic and earthquake unrest in the Yellowstone National Park region'. Yellowstone National Park is underlain by a voluminous magmatic system overlain by the most active hydrothermal system on Earth. Tracking changes in water and gas chemistry is of great importance because anomalous fluxes might signal one of the earliest warnings of volcanic unrest. Because of the tremendous number, chemical diversity, and large aerial coverage of Yellowstone's thermal features, it remains daunting to monitor individual features that might serve as proxies for anomalous activity in the hydrothermal system. Sampling rivers provides some advantages, because they integrate chemical fluxes over a very large area and therefore, river fluxes may reveal large-scale spatial patterns (Hurwitz et al., 2007). In addition, based on the application of the chloride-enthalpy method (Fournier, 1979), quantifying chloride flux in rivers provides an estimate of the total heat discharge from the Yellowstone volcanic system (Norton and Friedman 1985; Fournier, 1989; Friedman and Norton, in press). Intermittent sampling of the large rivers draining Yellowstone National Park began in the 1960's (Fournier et al., 1976) and continuous sampling has been carried out since water year (1 October - 30 September) 1983 excluding water years 1995 and 1996 (Norton and Friedman, 1985, 1991; Friedman and Norton, 1990, 2000, 2007). Between 1983 and 2001 only Cl concentrations and fluxes were determined. Starting in water year 2002, the concentrations and fluxes of other anions of possible magmatic origin (F-, Br-, HCO3- , and SO42-) were also determined, and several new sampling sites were established (Hurwitz et al., 2007). The ongoing sampling and analysis of river solute flux is a key component in the current monitoring program of YVO, and it is a collaboration between the U.S. Geological Survey and Yellowstone National Park.

Data Series↗

USGS2002

Report of hydrologic investigations in the Three Sisters area of central Oregon, Summer 2001

An ongoing episode of crustal uplift centered in the Separation Creek drainage of the Three Sisters area, central Oregon Cascades, may result from a magmatic intrusion that began in 1998. An investigation of springs in this drainage in summer 2001 revealed slightly elevated water temperatures and chloride (Cl-) concentrations of up to about 5?C and 20 milligrams per liter (mg/L), respectively, above background. The total discharge of anomalous Cl- in Separation Creek was 9.2 grams per second, which in combination with the temperature-Cl- relation in the springs results in a total advective heat discharge of 16 MW (megawatts). Comparison with similar findings obtained a decade earlier suggests that total Cl- and heat discharges in the groundwater drainage are unaffected by the current uplift. However, the isotopic composition of the dissolved inorganic carbon (DIC) in the spring waters (delta carbon-13 (13C) = -9.03 to -11.6?; carbon-14 (14C) <25 pmC) combined with helium-3/helium-4 (3He/4He) ratios near 8 RA and C/3He ratios <1010 in two of the springs are indicative of a magmatic source. The high 3He/4He ratios indicate that the magmatic gas is derived from a relatively recent, if not ongoing, intrusion. The concentration of magmatic carbon is low, a few millimoles per liter (mmol/L) at most, with an average value of 1.53 mmol/L for all the springs sampled in the drainage. Combining this average with the late-summer water flow in Separation Creek suggests a discharge of 21 tonnes/day of magmatic carbon dioxide (CO2). The presence of magmatic carbon in the shallow groundwater system, and the fact that DIC is uncorrelated with Cl-, suggests that some magmatic gas could escape diffusely through the soils.

Water-Resources Investigations Report↗

USGS1979

Sulfate geothermometry of thermal waters in the western United States

Sulfate geothermometry recently gained acceptance as a geothermal exploration tool when it was adopted as one of the geothermometers in the Assessment of Geothermal Resources of the United States-1978 (Muffler 1979). Over 120 samples, 75 of which are from Known Geothermal Resource Areas, were used in the assessment. Data required for calculation of the sulfate geothermometer temperatures, along with Na-K-Ca, quartz, and chalcedony geothermometer temperatures for comparison, are listed in table 1. For greater accuracy data from new or better samples have occasionally supplemented or replaced data used in the 1978 assessment. Samples from Yellowstone National Park has been omitted because they were discussed by McKenzie and Truesdell (1974).

Open-File Report↗