Chemical contaminants to Tampa Bay
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Geology topics
Publications and source records attributed to Mario Fernandez.
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Coastal wetlands in Tampa Bay consist of mangrove forest and tidal salt marsh. Wetlands buffer storm surges, provide fish and wildlife habitat, and enhance water quality through the removal of water-borne nutrients and contaminants. Substantial areas of both mangrove and salt marsh have been lost to agricultural, residential and industrial development in this urban estuary. Wetlands restoration has been initiated in Tampa Bay. Baseline studies on the current condition of wetlands and historical and prehistorical information is needed for successful restoration planning and evaluation. A major objective of this component of the Tampa Bay pilot program was to characterize wetlands in Tampa Bay beginning with areas that differ in their degree of human-induced disturbance ( Fig. 1 ). The Alafia River area is urbanized, industrialized and dredged, whereas the Terra Ceia area has a history of agricultural use with associated soil berms and mosquito ditches, but has not been farmed for at least 20 years ( Fig. 2 ).
This report summarizes a reconnaissance study, conducted July 20-30, 1998, of chemical and physical characteristics of recently deposited bottom sediments in the Caloosahatchee River and Estuary. Recently deposited sediments were identified using an isotopic chronometer, Beryllium-7 (7Be), a short-lived radioisotope. Fifty-nine sites were sampled in an area that encompasses the Caloosahatchee River (River) about three miles upstream from the Franklin Lock (S-79), the entire tidally affected length of the river (estuary), and the contiguous water bodies of Matlacha Pass, San Carlos Bay, Estero Bay, Tarpon Bay, and Pine Island Sound in Lee County, Florida. Bottom sediments were sampled for 7Be at 59 sites. From the results of the 7Be analysis, 30 sites were selected for physical and chemical analysis. Sediments were analyzed for particle size, total organic carbon (TOC), trace elements, and toxic organic compounds, using semiquantitative methods for trace elements and organic compounds. The semiquantitative scans of trace elements indicated that cadmium, copper, lead, and zinc concentrations, when normalized to aluminum, were above the natural background range at 24 of 30 sites. Particle size and TOC were used to characterize sediment deposition patterns and organic content. Pesticides, polychlorinated biphenyls (PCBs), and carcinogenic polycyclic aromatic hydrocarbons (CaPAHs) were determined at 30 sites using immunoassay analysis. The semiquantitative immunoassay analyses of toxic organic compounds indicated that all of the samples contained DDT, cyclodienes as chlordane (pesticides), and CaPAHs. PCBs were not detected. Based on analyses of the 30 sites, sediments at 10 of these sites were analyzed for selected trace elements and toxic organic compounds, including pesticides, PCBs, and PAHs, using quantitative laboratory procedures. No arsenic or cadmium was detected. Zinc was detected at two sites with concentrations greater than the lower limit of the range of sediment contaminant concentrations that are usually or always associated with adverse effects (Florida Department of Environmental Protection's Sediment Quality Assessment Guidelines). Organochlorine pesticides were detected at four sites at concentrations below the reporting limits; there were no organophosphorus pesticides or PCBs detected. PAHs were detected at eight sites; however, only four sites had concentrations above the reporting limit.
An investigation of three detention ponds in Pinellas County, Florida indicated little potential for chemical contamination of surficial-aquifer ground water; however, concentrations of contami- nants in some sediments are sufficient to indicate possible hazardous levels of bioconcentration in benthic organisms. The general direction of ground- water movement at three pond sites indicates that the ponds are ground-water discharge points. Shallow ground water tends to move laterally toward these ponds, which have surface outflow, instead of from the ponds into the aquifer. Surface-water and pond-sediment samples from a 1-year-old pond were collected and analyzed for inorganic constituents and organic compounds. The concentrations were either near or below analytical detection limits. Surface-water and pond-sediment samples from the other two ponds, 20- and 30-years old, respectively, also were analyzed for inorganic constituents and organic compounds. The water quality of these older ponds was not significantly different from that of the 1-year-old pond. However, bottom sediments in the 20- and 30-year-old ponds contained 16 and 23 organic compounds, respectively. None of the organic compounds were in sufficient concentrations to cause concern about their chronic effects on aquatic life. Concentrations of dichlordiphenyl-trichlorethane, dieldrin, and heptachlor were above the hazardous level with respect to bioconcentration in the food chain.
The Little Manatee River, a coastal stream that empties into Tampa Bay, Florida, may be used as a source of freshwater. Reduction of streamflow will result in upstream movement of saltwater in the stream. Data on streamflow, tide stage, and specific conductance describe the salinity distribution of the estuary. Vertical conductivity profiles indicate that the river is vertically homogeneous during low flow. The maximum upstream location of the saltwater-freshwater interface (800 micromhos) in the river was described by multiple regression analysis involving mean daily streamflow and high-high tide. The coefficient of determination is 0.94 with a root mean square error of + or - 0.4 mile. The location on the river where the estuarine system ends and the riverine system begins is at about 9.9 miles above the reference station at Shell Point. Duration analysis of conductivity indicates that the maximum upstream location of the interface exceeded 9.7 miles about 17 percent of the days for the period of study. Reduction by 50 percent of streamflow for the 90day, 2-year and 20-year recurrence-interval low flow would relocate the maximum intrusion of the interface at the 2-year and 20-year flows upstream by 0.7 and 0.2 mile, respectively.
Sanitary and industrial wastes at the Pinellas Plant of the U.S. Department of Energy, prior to December 1982, were combined, treated, and disposed of by ponding and spray irrigation on a 10-acre tract within the plant site. Prior to 1972, the treated wastes were released to surface drainage features. An electromagnetic survey for ground conductivity was made to identify changes in the ground conductivity that may be due to the spray irrigation disposal operations. Water samples from four test wells drilled into the surficial aquifer and the two disposal ponds and bottom material from the ponds were analyzed for priority and nonpriority pollutants, total organic carbon, volatile organic carbon, herbicides, insecticides, trace metals, nutrients, and major constituents. Overall, concentrations of constituents in the water samples were (1) less than the detection limits, (2) within U.S. Environmental Protection Agency quality criteria for water, or (3) within the range of results for a designated background water-quality site. Concentrations of 12 priority pollutants were found to be considerably above detection limits. Concentrations of these compounds, mostly coal-tar derivatives, ranged from 220 to 5,500 micrograms per kilogram; the detection limit for these compounds is 10 micrograms per kilogram. Included in these compounds were anthracene, pyrenes, and chrysene.
The Pinellas County landfill site is on a flat, coastal area characterized by a high water table is subject to tidal flooding. Altitudes within the study area range from 8 to 12 feet above sea level. Three geohydrologic units underlie the landfill site: a surficial aquifer about 19 feet thick composed of sand and shells; a confining bed about 35 feet thick composed of marl and clay; and the Floridan aquifer composed of limestone. The rate of lateral movement of ground water away from the site is about 1.2 feet per year; however, the rate of movement along the boundary of the landfill cells is about 20 feet per year. Vertical movement through the confining layer is about 0.005 foot per year. Landfill operations have not altered surface-water quality. Leachate migration downward into the Floridan aquifer is not indicated, but data do indicate leachate is migrating from the oldest section of the landfill site through the surficial aquifer. Peaks in concentration of selected chemical parameters and flow-rate analysis of water from trenches indicate the possibility of slug-flow leachate. (USGS)
Solid waste is defined along with various methods of disposal and the hydrogeologic factors to be considered when locating land-fills is presented. Types of solid waste, composition, and sources are identified. Generation of municipal solid waste in Florida has been estimated at 4.5 pounds per day per person or about 7.8 million tons per year. Leachate is generated when precipitation and ground water percolate through the waste. Gases, mainly carbon dioxide and methane, are also produced. Leachate generally contains high concentrations of dissolved organic and inorganic matter. The two typical hydrogeologic conditions in west-central Florida are (1) permeable sand overlying clay and limestone and (2) permeable sand overlying limestone. These conditions are discussed in relation to leachate migration. Factors in landfill site selection are presented and discussed, followed by a discussion on monitoring landfills. Monitoring of landfills includes the drilling of test holes, measuring physical properties of the corings, installation of monitoring wells, and water-quality monitoring. (USGS)
No abstract available.
Water-quality data collected between January 1979 and August 1980 at the landfill leachate treatment site in Pinellas County, Fla., are presented. Data include field and laboratory measurements of physical properties, major chemical constituents , nitrogen and phosphorus species, chemical oxygen demand, trace metals, coliform bacteria, taxonomy of macroinvertebrates and phytoplankton, and chlorophyll analyses. Data were collected as part of a study to determine water-quality changes resulting from aeration and ponding of leachate pumped from landfill burial trenches and for use in determining the rate of movement and quality changes as the leachate migrates through the surficial aquifer. Samples were collected from 81 surficial-aquifer water-quality monitoring wells constructed in January 1975, February 1979, and March 1979, and 8 surface-water quality monitoring sites established in January 1975, February 1978, and November 1978.
Ground water in and near a proposed landfill site can become contaminated by leachates from the fill material. Realizing that potential, Pinellas County entered into a cooperative investigation with the U.S. Geological Survey to determine background water-quality conditions, and to evaluate the potential effects of landfill leachate on the quality of ground water at a landfill site in Pinellas County (fig. 1). The investigation started in May 1975 and landfill operation began in November 1975. The purpose of this report is to make available well records, logs of wells, and surface- and ground-water quality data for planning purposes, and to provide basic data for a subsequent interpretive report. From May 1975 to October 1977, surface- and ground-water samples were collected periodically to obtain information on certain background water-quality conditions at the landfill site. Specific conductance and pH were determined in the field. Sodium, potassium, calcium, magnesium, chloride, trace metals, chemical and biochemical oxygen demands, coliform, select herbicides and pesticides, and nitrogen and phosphorus species were determined in the laboratory.
Periodic water-quality data were collected at four landfills in Hillsborough County from January 1974 through October 1977. Water samples were analyzed for nitrogen and phosphorous species, cations, trace metals, chloride, specific conductance, chemical oxygen demand, biological oxygen demand, and coliforms. Select ground-water samples were analyzed for herbicide and pesticide. Results of chemical and bacteriological analysis form four landfills are presented as basic data. Geologic logs and well descriptions are presented for wells drilled at the landfills after January 1974.
From November 1973 to July 1977, water samples were collected from wells to identify background water-quality conditions and to determine the effects on ground-water quality by St. Petersburg 's sludge-disposal operation (sod farm). Specific conductance and pH were determined in the field. Samples were collected for laboratory determination of selected nitrogen and phosphorus species, sodium, potassium, calcium, magnesium, chloride, trace metals, chemical and biochemical oxygen demand, and coliforms. (Woodard-USGS)