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Mario A. Guzman

Publications and source records attributed to Mario A. Guzman.

4 recordsLinked to original sources

Microtextural evidence for the recrystallization of opal-A to quartz in epithermal veins: A case study from the McLaughlin deposit, California

High-grade ores in low-sulfidation epithermal deposits commonly consist of banded veins containing quartz as the most abundant gangue mineral. Previous studies suggested that at least some of the quartz has formed as a product of recrystallization from a noncrystalline silica precursor. Detailed petrographic studies confirm that high-grade veins from the <2.2 Ma McLaughlin deposit in California were originally entirely composed of opal-A G . The noncrystalline silica is isotropic in crossed-polarized light and consists of compacted microspheres that are up to several micrometers in size. In many bands of the high-grade veins, the thermodynamically unstable opal-A G has matured to quartz. The recrystallization of the noncrystalline silica resulted in the development of quartz and ore textures that mask the original conditions of vein formation. Incipient recrystallization of the opal-A G caused the formation of lepispheres consisting of opal-CT as well as the development of concentrically banded silica spheres. Continued maturation led to the growth of elongated quartz crystals or complexly shaped quartz aggregates in the cores of the concentrically banded silica spheres. Amalgamation of quartz crystals caused the development of mosaic quartz or flamboyant quartz. Ripening produced large prismatic quartz crystals, which are characterized by zones of feathery appearance. Fluid inclusions within the quartz formed through recrystallization are typically highly irregular in shape and show inconsistent liquid-to-vapor volumetric proportions, but assemblages with consistent ratios are also present. Bands rich in fluid inclusions occurring along former recrystallization fronts in prismatic quartz crystals resemble growth zones in zonal quartz. Recrystallization of the silica matrix resulted in grain coarsening of the ore minerals and encapsulation of ore minerals by quartz. In areas where recrystallization of the noncrystalline silica proceeded to completeness, the quartz textures could be easily misinterpreted to indicate that quartz growth occurred in open space with the ore minerals infilling vug spaces. Correct recognition of recrystallization textures has significant implications for paragenetic investigations on vein material from epithermal deposits as well as the design of fluid inclusion studies.

California

Evidence for a high-level porphyritic intrusion below the Sunnyside epithermal vein deposit, Colorado

High-temperature quartz veins were identified in drill core at ~600 m below the Sunnyside epithermal base and pre-cious metal deposit in southwestern Colorado. The veins consist of early anhedral quartz that shows a bluish ca-thodoluminescence emission and hosts heterogenous silicate melt inclusions. The early quartz is overgrown by a later generation of quartz that exhibits euhedral termina-tions with oscillatory growth zones showing a bright pink to purple cathodoluminescence emission. Both types of quartz are crosscut by ubiquitous planes of vapor-rich inclusions and some hypersaline liquid inclusions. In addi-tion, secondary planes of intermediate-density inclusions occur. The petrographic characteristics of the two quartz types are similar to those in ‘A’ and ‘B’ veins encountered in shallow- and intermediate-depth porphyry deposits. The relationships at Sunnyside imply that these high-temperature veins formed from magmatic-hydrothermal fluids derived from an intrusion located not far below the lowest level of drilling. Sunnyside appears to be a rare example of an epithermal deposit that is directly connected to a high-level porphyritic intrusion.

Colorado, New Mexico

Critical minerals in Climax-type magmatic-hydrothermal systems

Today’s global economy is challenged to meet the growing demand for commodities used in existing and emerging advanced technologies. Critical minerals are commodities found in a wide variety of ore deposits that are vital to the economic or national security of individual nations that are vulnerable to supply disruption. The U.S. Geological Survey is striving to advance understanding of critical mineral resources by employing a Mineral Systems approach. Climax-type systems are one of 17 mineral systems currently under investigation. The aim of this work is to inventory and assess knowledge gaps on the abundance of 50 critical minerals in Climax-type systems. Here we synthesize geochemical data from ore concentrates, ore, waste, and minerals together with information on production from, and resources in, ore deposits. The goal of this work is to estimate the amount of critical minerals present in processed mine waste and unmined resources, discuss those that could potentially be recovered in the future, and identify important future areas of research.

Conference Paper

Characterization of Geologic Structures and Host Rock Properties Relevant to the Hydrogeology of the Standard Mine in Elk Basin, Gunnison County, Colorado

The Standard Mine Superfund Site is a source of mine drainage and associated heavy metal contamination of surface and groundwaters. The site contains Tertiary polymetallic quartz veins and fault zones that host precious and base metal sulfide mineralization common in Colorado. To assist the U.S. Environmental Protection Agency in its effort to remediate mine-related contamination, we characterized geologic structures, host rocks, and their potential hydraulic properties to better understand the sources of contaminants and the local hydrogeology. Real time kinematic and handheld global positioning systems were used to locate and map precisely the geometry of the surface traces of structures and mine-related features, such as portals. New reconnaissance geologic mapping, field and x-ray diffraction mineralogy, rock sample collection, thin-section analysis, and elemental geochemical analysis were completed to characterize hydrothermal alteration, mineralization, and subsequent leaching of metallic phases. Surface and subsurface observations, fault vein and fracture network characterization, borehole geophysical logging, and mercury injection capillary entry pressure data were used to document potential controls on the hydrologic system.

Open-File Report