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Margaret Golan-Bac

Publications and source records attributed to Margaret Golan-Bac.

3 recordsLinked to original sources

Hydrocarbon gases in sediment of the Voring Plateau, Norwegian Sea

Geochemical studies at three ODP Leg 104 sites on the Wring Plateau help define the distribution of hydrocarbon gases in sediment of this prominent feature of the Norwegian continental margin. Low levels of hydrocarbon gas were encountered in sediment of the outer part of the plateau, but sediment of the inner part of the plateau is very gassy. The molecular composition of inner plateau gases ( > 99.9% methane) and the carbon isotopic composition of the methane (avg. = - 76%o relative to the PDB standard) clearly show that the gas is biogenic. Heavier hydrocarbon gases accompany this methane, and their presence is probably a result of both chemical and microbial low-temperature diagenesis. Although these heavier hydrocarbons were not detected in sediment of the outer part of the plateau during shipboard analyses, subsequent shore-based analyses showed that these compounds are present at very low concentrations. Methane in the gassy sediment of the inner part of the plateau may be present as gas hydrates, judging from sedimentological and inorganic geochemical considerations, but no discernible gas hydrates were recovered during drilling.

Proceedings of the Ocean Drilling Program: Scienti

Multiple sources of alkanes in Quaternary oceanic sediment of Antarctica

Normal alkanes ( n -C 13 n -C 36 ), isoprenoid hydrocarbons ( i -C 15 , i -C 16 , i -C 18 , i -C 19 , and i -C 20 ) triterpanes (C 27 C 32 ), and (C 27 C 29 ) are present in low concentrations offshore Antarctica in near-surface, Quaternary sediment of the Wilkes Land continental margin and of the western Ross Sea. The distributions of these hydrocarbons are interpreted relative to possible sources and processes. The hydrocarbons appear to be mixtures of primary and recycled material from marine and terrigenous sources. The n -alkanes are most abundant and are characterized by two distinct populations, one of probable marine origin and the other likely from terrigenous, vascular plant sources. Because the continent of Antarctica today is devoid of higher plants, the plant-derived hydrocarbons in these offshore sediments probably came from wind-blown material and recycled Antarctic sediment that contains land-plant remains from an earlier period of time. Isoprenoid hydrocarbons are partially recycled and mainly of marine origin; the dominance of pristane over phytane suggests oxic paleoenvironmental conditions. Both modern and ancient triterpanes and steranes are present, and the distribution of these indicates a mixture of primary and recycled bacterial, algal, and possible higher-plant materials. Although the sampled sediments were deposited during the Quaternary, they apparently contain a significant component of hydrocarbons of pre-Quaternary age.

Organic Geochemistry

Seismic and geochemical evidence for shallow gas in sediment on Navarin continental margin, Bering Sea

Marine seismic studies coupled with geochemical investigations demonstrate that hydrocarbon gases are ubiquitous in the near-surface (<= 250 m or 820 ft depth) sediment of the Navarin continental margin in the northern Bering Sea. Three types of acoustic anomalies appear to be related to the presence of gas in the sediment. These anomalies are most prevalent in the northern half of the Navarin basin. Acoustic anomalies attributed to gas hydrates and to diagenetic boundaries are present on seismic records of the lower slope between Navarinsky and Zhemchug Canyons. Hydrocarbon gases, methane through butanes, are common in the surface (<= 5 m or 17 ft depth) sediment of the Navarin continental margin. Methane, the most abundant hydrocarbon gas, is present in amounts ranging from 84,000 to 1 µL/L of wet sediment. These concentrations are two to three orders of magnitude greater than the other hydrocarbon gases. The highest concentrations of methane (greater than 1,000 µL/L) were measured in sediment of Navarinsky Canyon and over the central part of the Navarin basin. The source of methane is mainly biogenic, but the hydrocarbon gas compositions in 17 of 141 cores suggest the presence of thermogenic gas. Most of these 17 cores are from the continental slope at water depths greater than 150 m (490 ft). No direct correlation could be found between acoustic anomalies and gas concentrations in the sediment. This lack of correlation is probably due to the limited penetration of the gravity corer and the spotty distribution of hydrocarbon concentrations.

Alaska