Geology topics

M.A. Clynne

Publications and source records attributed to M.A. Clynne.

At least 19 recordsLinked to original sources

USGS2017

Age of the Rockland tephra, western USA

The age of the Rockland tephra , which includes an ash-flow tuff south and west of Lassen Peak in northern California and a widespread ash-fall deposit that produced a distinct stratigraphic marker in western North America , is constrained to 565,000 to 610,000 yr by 40 Ar/ 39 Ar and U–Pb dating. 40 Ar/ 39 Ar ages on plagioclase from pumice in the Rockland have a weighted mean age of 609,000 ± 7000 yr. Isotopic ages of spots on individual zircon crystals , analyzed by the SHRIMP-RG ion microprobe , range from ∼500,000 to ∼800,000 yr; a subpopulation representing crystal rims yielded a weighted-mean age of 573,000 ± 19,000 yr. Overall stratigraphic constraints on the age are provided by two volcanic units, including the underlying tephra of the Lava Creek Tuff erupted within Yellowstone National Park that has an age of 639,000 ± 2000 yr. The basaltic andesite of Hootman Ranch stratigraphically overlies the Rockland in the Lassen Peak area and has 40 Ar/ 39 Ar ages of 565,000 ± 29,000 and 565,000 ± 12,000 yr for plagioclase and groundmass, respectively. Identification of Rockland tephra in ODP core 1018 offshore of central California is an important stratigraphic age that also constrains the eruption age to between 580,000 and 600,000 yr.

Quaternary Research↗

USGS2013

Hydrogen isotope investigation of amphibole and glass in dacite magmas erupted in 1980-1986 and 2005 at Mount St. Helens, Washington

In active, shallow, sub-volcanic magma conduits the extent of the dehydrogenation–oxidation reaction in amphibole phenocrysts is controlled by energetic processes that cause crystal lattice damage or conditions that increase hydrogen diffusivity in magmatic phases. Amphibole phenocrysts separated from dacitic volcanic rocks erupted from 1980 to 1986 and in 2005 at Mount St. Helens (MSH) were analyzed for δD, water content and Fe 3 +/Fe 2 +, and fragments of glassy groundmass were analyzed for δD and water content. Changes in amphibole δD values through time are evaluated within the context of carefully observed volcanic eruption behavior and published petrological and geochemical investigations. Driving forces for amphibole dehydrogenation include increase in magma oxygen fugacity, decrease in amphibole hydrogen fugacity, or both. The phenocryst amphibole (δD value c. –57‰ and 2 wt % H 2 O) in the white fallout pumice of the May 18, 1980 plinian eruptive phase is probably little modified during rapid magma ascent up an ∼7 km conduit. Younger volcanic rocks incorporate some shallowly degassed dacitic magma from earlier pulses, based on amphibole phenocryst populations that exhibit varying degrees of dehydrogenation. Pyroclastic rocks from explosive eruptions in June–October 1980 have elevated abundances of mottled amphibole phenocrysts (peaking in some pyroclastic rocks erupted on July 22, 1980), and extensive amphibole dehydrogenation is linked to crystal damage from vesiculation and pyroclastic fountain collapse that increased effective hydrogen diffusion in amphibole. Multiple amphibole δD populations in many 1980 pyroclastic rocks combined with their groundmass characteristics (e.g. mixed pumice textures) support models of shallow mixing prior to, or during, eruption as new, volatile-rich magma pulses blended with more oxidized, degassed magma. Amphibole dehydrogenation is quenched at the top surface of MSH dacite lava lobes, but the diversity in the δD amph populations in original fresh lava flow surfaces may occur from blending magma domains with different ascent histories in the sub-volcanic environment immediately before eruption. Multi-stage open-system magma degassing operated in each parcel of magma rising toward the surface, whereas the magma below ∼7 km was a relatively closed system, at least to the October 1986 eruption based on the large population of minimally dehydrogenated, rim-free amphibole in the lavas. Magma degassing and possibly H isotope exchange with low-δD fluids around the roof zone may have accompanied the ∼1·5 km upward migration of the 1980 magma body. The low-δDamph (c. –188 to –122‰) oxy-amphibole phenocrysts in lava spines extruded in May 2005 reflect dehydrogenation as ascending viscous magma degassed and crystallized, and fractures that admitted oxygen into the hot solidified lava spine interior facilitated additional iron oxidation.

Washington↗

USGS2012

Late Cenozoic volcanism, subduction, and extension in the Lassen region of California, southern Cascade Range

Some 537 volcanic vents younger than 7 Ma are identified and these are classified into five age intervals and five compositional categories based on SiO2 content. Maps of vents by age and composition illustrate regionally representative volcanic trends. By 2 Ma, the eastern limit of volcanism had contracted westward toward the late Quaternary arc. Late Quaternary volcanism is concentrated around and north of the silicic Lassen volcanic center. The belt of most recent volcanism (25-0 ka) has been active since at least 2 Ma. Most mafic volcanism is calcalkaline basalt and basaltic andesite. Normal faults and linear groups of vents are evidence of widespread crustal extension throughout most of the Lassen region. NNW orientation of maximum horizontal stress is indicated. The Lassen volcanic region is thought to occur above the subducting Gorda North plate but also within a broad zone of distributed extension that occurs in the North American lithosphere east and southeast of the present Cascadia subduction zone. The scarcity of volcanic rocks older than 7 Ma suggests that a more compressive lithospheric stress regime prior to the late Miocene extensional episode may have suppressed volcanism. -from Authors

Journal of Geophysical Research Solid Earth↗

USGS2012

Stratigraphic, lithologic, and major element geochemical constraints on magmatic evolution at Lassen volcanic center, California

The Lassen volcanic center is the most recent of several long-lived volcanic centers in the southernmost Cascade Range. These centers have erupted products ranging from basaltic andesite to rhyolite and are superimposed on a background of regional basaltic to andesitic volcanism. The evolution of the Lassen volcanic center is described in three stages. Stages I and II comprise the Brokeoff volcano, and 80 km 3 andesitic stratocone, active from 600 to 400 ka. Brokeoff volcano is compositionally equivalent to the regional basaltic andesite to andesite volcanism in the Lassen region and is the result of structurally controlled focusing of the diffuse regional mafic magmatism. Stage III comprises a silicic dome field and adjacent area of hybrid andesites and has a total volume of about 100 km 3 . Volcanism during stage III was episodic and is subdivided into four sequences of lithologically and temporally distinct lavas. Stage III began at 400 ka with a rhyolitic, caldera-forming pyroclastic eruption and chemically related lavas. Additional sequences of dacite erupted between 250–200 ka and 100–0 ka. Hybrid andesites erupted adjacent to the silicic dome field between 300 and 0 ka. Porphyritic andesite and dacite with high Al 2 O 3 , low TiO 2 , medium K 2 O and FeO/MgO ratios of 1.5–2.0 are the most abundant rock types in the Lassen volcanic center. However, the single most voluminous unit is sparsely phyric rhyolite pumice. In general, the lavas of Lassen volcanic center form a single coherent trend on major element variation diagrams and in pseudo-quaternary phase space, consistant with an origin either by fractional crystallization or magma mixing. In detail, however, the lack of systematic temporal change in silica and subtly crossing trends indicate a complex origin. A variety of statistically successful fractional crystallization models can be constructed that derive Brokeoff andesites from regional magmas. An important conclusion of the modeling is that if fractional crystallization is the process responsible for generation of Brokeoff andesite, then the parent magma must be low to medium K in geochemical affinity in order to explain the variation in K 2 O. However, although major element variation can be modeled by fractional crystallization, petrographic and stratigraphic evidence indicates that magma mixing is an important but subtle process in Brokeoff lavas and suggests that lavas evolved in small independent batches. Lavas erupted during stage III, while predominantly silicic, range from 53 to 75% SiO 2 . Disequilibrium mineral assemblages in the stage III lavas indicate that they are not directly derived from Brokeoff andesite by fractional crystallization. Mixing of silicic magma with regional mafic magma and disaggregation of andesitic quenched magmatic inclusions play dominant roles in the compositional diversity of stage III lavas.

Journal of Geophysical Research Solid Earth↗

USGS2012

Trace element and isotopic constraints on magmatic evolution at Lassen volcanic center

Magmatic evolution at the Lassen volcanic center (LVC) is characterized by a transition from predominantly andesitic to predominantly silicic volcanism with time. Magmas of the andesitic, or “Brokeoff phase” of volcanism range in composition from basaltic andesite io dacite, whereas those of silicic, or “Lassen phase” range in composition from basaltic andesite to rhyolite. The compositions of magmas from each phase define well organized but distinct variation trends. Compared with Brokeoff-phase magmas of similar SiO 2 content, most Lassen-phase magmas contain lower concentrations of most incompatible minor and trace elements. Based on the behavior of both incompatible and compatible trace elements, the geochemical trends defined by the Brokeoff-phase magmas cannot be ascribed merely to fractional crystallization from a single or multiple mafic parental magmas, Moreover, the Lassen-phase magmas cannot be derived from the Brokeoff-phase magmas by fractional crystallization. Rather, the geochemical trends that characterize each volcanic phase define arrays that primarily indicate mixing between well-homogenized silicic and heterogeneous mafic magmas. The distinctive mixing-dominated arrays for each volcanic phase manifest the generation and evolution of two physically distinct, but genetically related magma systems. The LVC magmas have Sr, Nd, and Pb isotopic characteristics that approximate two-component mixing arrays. One isotopic component is similar in composition to that of NE Pacific Ocean ridge and seamount basalts (“MORB” component), the other to mafic Mesozoic granitoids sampled from the neighboring KSamath and Sierra Nevada provinces (“KSN” component). The isotopic compositions of the most silicic LVC magmas lie within the ranges defined by the more mafic LVC magmas, which in turn lie within broad ranges defined by primitive mafic lavas sampled from the Lassen region. The lack of a correlation between the major element and isotopic compositions of LVC magmas seriously limits any model for magmatic evolution that relies on assimilation of old middle to upper crust by isotopically homogeneous mafic magmas during their ascent through the crust. Alternatively, the isotopic and geochemical uniformity of the most silicic magmas of the Brokeoff and Lassen phases suggests that they are well-homogenized partial melts. The likely source region for these silicic melts is the lower crust, which we envision to consist primarily of mafic igneous rocks that are similar in geochemical and isotopic diversity to the regional mafic lavas. Magmatic evolution at LVC can be viewed in terms of a series of mantle melting events that subsequently stimulated meiting in a progressively increasing volume of the lower crust. In general, the LVC magmas represent slightly fractionated mixtures of the mantle-derived mafic magmas and silicic partial melts of the lower crust, the latter melts increasing in relative proportion over the history of the volcanic center. The voluminous rhyolitic lavas and pyroclastic materials erupted during the early Lassen phase represent lower crustal melts thai pooled into sufficient volumes to avoid significant blending and dilution with intruding mafic magmas. The geochemical and isotopic heterogeneity of both Brokeoff-phase andésites and mafic magmatic inclusions in the silicic Lassen-phase magmas must in part record the corresponding diversity of the mantle-derived contributions to arc magmagenesis in this region.

Journal of Geophysical Research Solid Earth↗

USGS2012

Hydrogen isotope investigation of amphibole and biotite phenocrysts in silicic magmas erupted at Lassen Volcanic Center, California

Hydrogen isotope ratio, water content and Fe 3 + /Fe 2 + in coexisting amphibole and biotite phenocrysts in volcanic rocks can provide insight into shallow pre- and syn-eruptive magmatic processes such as vesiculation, and lava drainback with mixing into less devolatilized magma that erupts later in a volcanic sequence. We studied four ~ 35 ka and younger eruption sequences (i.e. Kings Creek, Lassen Peak, Chaos Crags, and 1915) at the Lassen Volcanic Center (LVC), California, where intrusion of crystal-rich silicic magma mushes by mafic magmas is inferred from the varying abundances of mafic magmatic inclusions (MMIs) in the silicic volcanic rocks. Types and relative proportions of reacted and unreacted hydrous phenocryst populations are evaluated with accompanying chemical and H isotope changes. Biotite phenocrysts were more susceptible to rehydration in older vesicular glassy volcanic rocks than coexisting amphibole phenocrysts. Biotite and magnesiohornblende phenocrysts toward the core of the Lassen Peak dome are extensively dehydroxylated and reacted from prolonged exposure to high temperature, low pressure, and higher f O2 conditions from post-emplacement cooling. In silicic volcanic rocks not affected by alteration, biotite phenocrysts are often relatively more dehydroxylated than are magnesiohornblende phenocrysts of similar size; this is likely due to the ca 10 times larger overall bulk H diffusion coefficient in biotite. A simplified model of dehydrogenation in hydrous phenocrysts above reaction closure temperature suggests that eruption and quench of magma ascended to the surface in a few hours is too short a time for substantial H loss from amphibole. In contrast, slowly ascended magma can have extremely dehydrogenated and possibly dehydrated biotite, relatively less dehydrogenated magnesiohornblende and reaction rims on both phases. Eruptive products containing the highest proportions of mottled dehydrogenated crystals could indicate that within a few days prior to eruption, degassed vesiculated magma or lava had drained back down the volcanic conduit and mixed with less devolatilized magma. The vesiculated magma contained hydrous phenocrysts with lattice damage, which locally raised the effective H diffusion coefficient by ca 10–100 × and resulted in increased mineral dehydrogenation. Remobilization of dacite magma mush by relatively more reduced mafic magma appears to have generated further f O2 variations in May 1915 as oxidized magma from shallow levels circulated to depths where dehydrogenation of hydrous phenocrysts began. The δD Magmatic H2O expressed in LVC acid hot springs is likely a mixture derived from devolatilized ascending mafic magmas and crystallizing silicic magma mush.

California↗

USGS2011

Diverse, discrete, mantle-derived batches of basalt erupted along a short normal fault zone: The Poison Lake chain, southernmost Cascades

The Poison Lake chain consists of small, monogenetic, calc-alkaline basaltic volcanoes located east of the Cascade arc axis, 30 km ENE of Lassen Peak in northeastern California. This chain consists of 39 distinguishable units in a 14-km-long and 2-kmwide zone trending NNW, parallel to nearby Quaternary normal faults. The 39 units fall into nine coherent groups based on stratigraphy, field characteristics, petrography, and major-element compositions. Petrographic differences among groups are expressed by different amounts and proportions of phenocrysts. MgO-SiO 2, K 2O-SiO 2, and TiO 2-SiO 2 variation diagrams illustrate clear differences in compatible and incompatible elements among the groups. Variation of K 2O/ TiO 2 and K 2O/P 2O 5 with MgO indicates that most of the basalts of the Poison Lake chain cannot be related by crystal fractionation at different pressures and that compositions have not been affected significantly by incorporation of low-degree silicic crustal melt or interaction with sialic crust. Limited traceelement and whole-rock isotopic data also suggest little if any incorporation of uppercrustal material, and that compositional variation among groups primarily reflects source compositional differences. Precise 40Ar/ 39Ar determinations show that the lavas were erupted between 100 and 110 ka. The migration of paleomagnetic remanent directions over 30?? suggests that the entire Poison Lake chain could represent three short-lived episodes of volcanism within a period as brief as 500 yr. The diverse geologic, petrographic, chemical, paleomagnetic, and age data indicate that each of the nine groups represents a small, discrete magma batch generated in the mantle and stored briefly in the lower crust. A NNW normal fault zone provided episodic conduits that allowed rapid ascent of these batches to the surface, where they erupted as distinct volcanic groups, each aligned along a segment of the Poison Lake chain. Compositional diversity of these primitive magmas argues against widespread, long-lived ponding of uniform basalt magma at the base of the crust in this region and against interaction with a zone of melting, assimilation, storage, and homogenization (MASH) in the lower crust. ?? 2011 Geological Society of America.

Geological Society of America Bulletin↗

USGS2010

Zircon reveals protracted magma storage and recycling beneath Mount St. Helens

Current data and models for Mount St. Helens volcano (Washington, United States) suggest relatively rapid transport from magma genesis to eruption, with no evidence for protracted storage or recycling of magmas. However, we show here that complex zircon age populations extending back hundreds of thousands of years from eruption age indicate that magmas regularly stall in the crust, cool and crystallize beneath the volcano, and are then rejuvenated and incorporated by hotter, young magmas on their way to the surface. Estimated dissolution times suggest that entrained zircon generally resided in rejuvenating magmas for no more than about a century. Zircon elemental compositions reflect the increasing influence of mafic input into the system through time, recording growth from hotter, less evolved magmas tens of thousands of years prior to the appearance of mafic magmas at the surface, or changes in whole-rock geochemistry and petrology, and providing a new, time-correlated record of this evolution independent of the eruption history. Zircon data thus reveal the history of the hidden, long-lived intrusive portion of the Mount St. Helens system, where melt and crystals are stored for as long as hundreds of thousands of years and interact with fresh influxes of magmas that traverse the intrusive reservoir before erupting. ?? 2010 Geological Society of America.

Geology↗

USGS2009

Multiple dendrochronological responses to the eruption of Cinder Cone, Lassen Volcanic National Park, California

Two dendrochronological properties – ring width and ring chemistry – were investigated in trees near Cinder Cone in Lassen Volcanic National Park, northeastern California, for the purpose of re-evaluating the date of its eruption. Cinder Cone is thought to have erupted in AD 1666 based on ring-width evidence, but interpreting ring-width changes alone is not straightforward because many forest disturbances can cause changes in ring width. Old Jeffrey pines growing in Cinder Cone tephra and elsewhere for control comparison were sampled. Trees growing in tephra show synchronous ring-width changes at AD 1666, but this ring-width signal could be considered ambiguous for dating the eruption because changes in ring width can be caused by other events. Trees growing in tephra also show changes in ring phosphorus, sulfur, and sodium during the late 1660s, but inter-tree variability in dendrochemical signals makes dating the eruption from ring chemistry alone difficult. The combination of dendrochemistry and ring-width signals improves confidence in dating the eruption of Cinder Cone over the analysis of just one ring-growth property. These results are similar to another case study using dendrochronology of ring width and ring chemistry at Parícutin, Michoacán, Mexico, a cinder cone that erupted beginning in 1943. In both cases, combining analysis with ring width and ring chemistry improved confidence in the dendro-dating of the eruptions.

California↗

USGS2008

Multiple plagioclase crystal populations identified by crystal size distribution and in situ chemical data: Implications for timescales of magma chamber processes associated with the 1915 eruption of Lassen Peak, CA

Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge–magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0·5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0·1 and 0·5 mm) that have core An contents of 66–69, and microlites (long axis < 0·1 mm) with variable An core contents from 64 to 52. Phenocrysts are interpreted to form in an isolated dacitic magma chamber that experienced slow cooling. Based on textural, compositional, and isotopic data for the magma represented by the dacitic component, magma recharge was not an important process until just prior to the 1915 eruption. Average residence times for phenocrysts are in the range of centuries to millennia. Microphenocrysts formed in a hybrid layer that resulted from mixing between end-member reservoir dacite and recharge magma of basaltic andesite composition. High thermal contrast between the two end-member magmas led to relatively high degrees of undercooling, which resulted in faster crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution–precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than the melt of the other three compositions. We suggest that mixing of an intruding basaltic andesite and reservoir dacite before magma began ascending in the conduit allowed formation of a compositionally distinct microlite population. Melt in the other three products was more evolved because it had undergone differentiation during the months following initial mixing; as a consequence, melt and microlites among these three products have similar compositions. The results of this study highlight the integrated use of crystal size distribution, textural, and in situ chemical data in identifying distinct crystal populations and linking these populations to the thermal and chemical characteristics of complex magma bodies.

Journal of Petrology↗

USGS2008

Oxygen isotope geochemistry of the lassen volcanic center, California: Resolving crustal and mantle contributions to continental Arc magmatism

This study reports oxygen isotope ratios determined by laser fluorination of mineral separates (mainly plagioclase) from basaltic andesitic to rhyolitic composition volcanic rocks erupted from the Lassen Volcanic Center (LVC), northern California. Plagioclase separates from nearly all rocks have δ 18 O values (6·1–8·4‰) higher than expected for production of the magmas by partial melting of little evolved basaltic lavas erupted in the arc front and back-arc regions of the southernmost Cascades during the late Cenozoic. Most LVC magmas must therefore contain high 18 O crustal material. In this regard, the δ 18 O values of the volcanic rocks show strong spatial patterns, particularly for young rhyodacitic rocks that best represent unmodified partial melts of the continental crust. Rhyodacitic magmas erupted from vents located within 3·5 km of the inferred center of the LVC have consistently lower δ 18 O values (average 6·3‰ ± 0·1‰) at given SiO 2 contents relative to rocks erupted from distal vents (>7·0 km; average 7·1‰ ± 0.1‰). Further, magmas erupted from vents situated at transitional distances have intermediate values and span a larger range (average 6·8‰ ± 0·2‰). Basaltic andesitic to andesitic composition rocks show similar spatial variations, although as a group the δ 18 O values of these rocks are more variable and extend to higher values than the rhyodacitic rocks. These features are interpreted to reflect assimilation of heterogeneous lower continental crust by mafic magmas, followed by mixing or mingling with silicic magmas formed by partial melting of initially high 18 O continental crust (∼9·0‰) increasingly hybridized by lower δ 18 O (∼6·0‰) mantle-derived basaltic magmas toward the center of the system. Mixing calculations using estimated endmember source δ 18 O values imply that LVC magmas contain on a molar oxygen basis approximately 42 to 4% isotopically heavy continental crust, with proportions declining in a broadly regular fashion toward the center of the LVC. Conversely, the δ 18 O values of the rhyodacitic rocks suggest that the continental crust in the melt generation zones beneath the LVC has been substantially modified by intrusion of mantle-derived basaltic magmas, with the degree of hybridization ranging on a molar oxygen basis from approximately 60% at distances up to 12 km from the center of the system to 97% directly beneath the focus region. These results demonstrate on a relatively small scale the strong influence that intrusion of mantle-derived mafic magmas can have on modifying the composition of pre-existing continental crust in regions of melt production. Given this result, similar, but larger-scale, regional trends in magma compositions may reflect an analogous but more extensive process wherein the continental crust becomes progressively hybridized beneath frontal arc localities as a result of protracted intrusion of subduction-related basaltic magmas.

Journal of Petrology↗

USGS2006

Extreme U-Th disequilibrium in rift-related basalts, rhyolites and granophyric granite and the timescale of rhyolite generation, intrusion and crystallization at Alid volcanic center, Eritrea

Rhyolite pumices and co-erupted granophyric (granite) xenoliths yield evidence for rapid magma generation and crystallization prior to their eruption at 15·2 ± 2·9 ka at the Alid volcanic center in the Danikil Depression, Eritrea. Whole-rock U and Th isotopic analyses show 230 Th excesses up to 50% in basalts <10 000 years old from the surrounding Oss lava fields. The 15 ka rhyolites also have 30–40% 230 Th excesses. Similarity in U–Th disequilibrium, and in Sr, Nd, and Pb isotopic values, implies that the rhyolites are mostly differentiated from the local basaltic magma. Given the ( 230 Th/ 232 Th) ratio of the young basalts, and presumably the underlying mantle, the ( 230 Th/ 232 Th) ratio of the rhyolites upon eruption could be generated by in situ decay in about 50 000 years. Limited (∼5%) assimilation of old crust would hasten the lowering of ( 230 Th/ 232 Th) and allow the process to take place in as little as 30 000 years. Final crystallization of the Alid granophyre occurred rapidly and at shallow depths at ∼20–25 ka, as confirmed by analyses of mineral separates and ion microprobe data on individual zircons. Evidently, 30 000–50 000 years were required for extraction of basalt from its mantle source region, subsequent crystallization and melt extraction to form silicic magmas, and final crystallization of the shallow intrusion. The granophyre was then ejected during eruption of the comagmatic rhyolites.

Journal of Petrology↗

USGS2004

Erosion by flowing lava: Geochemical evidence in the Cave Basalt, Mount St. Helens, Washington

We sampled basaltic lava flows and underlying dacitic tuff deposits in or near lava tubes of the Cave Basalt, Mount St. Helens, Washington to determine whether the Cave Basalt lavas contain geochemical evidence of substrate contamination by lava erosion. The samples were analyzed using a combination of wavelength-dispersive X-ray fluorescence spectrometry and inductively-coupled plasma mass spectrometry. The results indicate that the oldest, outer lava tube linings in direct contact with the dacitic substrate are contaminated, whereas the younger, inner lava tube linings are uncontaminated and apparently either more evolved or enriched in residual liquid. The most heavily contaminated lavas occur closer to the vent and in steeper parts of the tube system, and the amount of contamination decreases with increasing distance downstream. These results suggest that erosion by lava and contamination were limited to only the initially emplaced flows and that erosion was localized and enhanced by vigorous laminar flow over steeper slopes. After cooling, the initial Cave Basalt lava flows formed an insulating lining within the tubes that prevented further erosion by later flows. This interpretation is consistent with models of lava erosion that predict higher erosion rates closer to sources and over steeper slopes. A greater abundance of xenoliths and xenocrysts relative to xenomelts in hand samples indicates that mechanical erosion rather than thermal erosion was the dominant erosional process in the Cave Basalt, but further sampling and petrographic analyses must be performed to verify this hypothesis. ?? Springer-Verlag 2003.

Bulletin of Volcanology↗

USGS2002

Solubility of NaCl in aqueous electrolyte solutions from 10 to 100°C

The solubilities of NaCl in aqueous KCl, MgCl2, CaCl2, and mixed CaCl2-KCl solutions have been determined from 10 to 100??C. The data were fit to an equation, and the equation was used to calculate values of the change in solubility of NaCl, ???[NaCl]/???T. These values are required for calculations of the rate of migration of fluids in a thermal gradient in rock salt. The data obtained here indicate that the values of ???[NaCl]/???T are 36-73% greater for solutions containing divalent ions than for the NaCl-H2O system.

Journal of Chemical and Engineering Data↗

USGS2002

Solubility of some alkali and alkaline earth chlorides in water at moderate temperatures

Solubilities for the binary systems, salt-H2O, of the chlorides of lithium, rubidium, cesium, magnesium, calcium, strontium, and barium from near 0??C to the saturated boiling point are reported. The experimental data and coefficients of an equation for a smoothed curve describing each system are listed in the tables. The data are improvements on those previously reported in the literature, having a precision on the average of ??0.09%.

Journal of Chemical and Engineering Data↗

USGS2000

Re-Os isotopic systematics of primitive lavas from the Lassen region of the Cascade arc, California

Rhenium-osmium isotopic systematics of primitive calc-alkaline lavas from the Lassen region appear to be controlled by mantle wedge processes. Lavas with a large proportion of slab component have relatively low Re and Os abundances, and have radiogenic Os and mid ocean ridge basalt-like Sr and Pb isotopic compositions. Lavas with a small proportion of slab component have higher Re and Os elemental abundances and display mantle-like Os, Sr, Nd, and Pb isotopic compositions. Assimilation with fractional crystallization can only generate the Re-Os systematics of the Lassen lavas from a common parent if the distribution coefficient for Re in sulfide is ~40-1100 times higher than most published estimates and if most incompatible element abundances decrease during differentiation. High Re/Os ratios in mid ocean ridge basalts makes subducted oceanic crust a potential source of radiogenic Os in volcanic arcs. The slab beneath the southernmost Cascades is estimated to have 187Os/188Os ratios as high as 1.4. Mixing between a slab component and mantle wedge peridotite can generate the Os isotopic systematics of the Lassen lavas provided the slab component has a Sr/Os ratio of ~7.5X105 and Os abundances that are 100-600 times higher than mid ocean ridge basalts. For this model to be correct, Os must be readily mobilized and concentrated in the slab component, perhaps as a result of high water and HCl fugacities in this subduction environment. Another possible mechanism to account for the correlation between the magnitude of the subduction geochemical signature and Os isotopic composition involves increasing the stability of an Os-bearing phase in mantle wedge peridotites as a result of fluxing with the slab component. Melting of such a source could yield low Os magmas that are more susceptible to crustal contamination, and hence have more radiogenic Os isotopic compositions, than magmas derived from sources with a smaller contribution from the slab. Thus, the addition of the slab component to the mantle wedge appears to result in either the direct or indirect addition of radiogenic Os to arc magmas. (C) 2000 Elsevier Science B.V. All rights reserved.

Earth and Planetary Science Letters↗

USGS1999

A geochemical reconnaissance of the Alid volcanic center and geothermal system, Danakil depression, Eritrea

Geological and geochemical studies indicate that a high-temperature geothermal system underlies the Alid volcanic center in the northern Danakil depression of Eritrea. Alid is a very late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma, some of which vented as lavas and pyroclastic flows. Fumaroles and boiling pools distributed widely over an area of ~10 km2 on the northern half of Alid suggest that an active hydrothermal system underlies much of that part of the mountain. Geothermometers indicate that the fumarolic gases are derived from a geothermal system with temperatures >225??C. The isotopic composition of condensed fumarolic steam is consistent with these temperatures and implies that the source water is derived primarily from either lowland meteoric waters or fossil Red Sea water, or both. Some gases vented from the system (CO2, H2S and He) are largely magmatic in origin. Permeability beneath the volcanic center may be high, given the amount of intrusion-related deformation and the active normal faulting within the Danakil depression.Geological and geochemical studies indicate that a high-temperature geothermal system underlies the Alid volcanic center in the northern Danakil depression of Eritrea. Alid is a very late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma, some of which vented as lavas and pyroclastic flows. Fumaroles and boiling pools distributed widely over an area of approx. 10 km2 on the northern half of Alid suggest that an active hydrothermal system underlies much of that part of the mountain. Geothermometers indicate that the fumarolic gases are derived from a geothermal system with temperatures >225??C. The isotopic composition of condensed fumarolic steam is consistent with these temperatures and implies that the source water is derived primarily from either lowland meteoric waters or fossil Red Sea water, or both. Some gases vented from the system (CO2, H2S and He) are largely magmatic in origin. Permeability beneath the volcanic center may be high, given the amount of intrusion-related deformation and the active normal faulting within the Danakil depression.

Geothermics↗

USGS1999

A complex magma mixing origin for rocks erupted in 1915, Lassen Peak, California

The eruption of Lassen Peak in May 1915 produced four volcanic rock types within 3 days, and in the following order: (1) hybrid black dacite lava containing (2) undercooled andesitic inclusions, (3) compositionally banded pumice with dark andesite and light dacite bands, and (4) unbanded light dacite. All types represent stages of a complex mixing process between basaltic andesite and dacite that was interrupted by the eruption. They contain disequilibrium phenocryst assemblages characterized by the coexistence of magnesian olivine and quartz and by reacted and unreacted phenocrysts derived from the dacite. The petrography and crystal chemistry of the phenocrysts and the variation in rock compositions indicate that basaltic andesite intruded dacite magma and partially hybridized with it. Phenocrysts from the dacite magma were reacted. Cooling, crystallization, and vesiculation of the hybrid andesite magma converted it to a layer of mafic foam. The decreased density of the andesite magma destabilized and disrupted the foam. Blobs of foam rose into and were further cooled by the overlying dacite magma, forming the andesitic inclusions. Disaggregation of andesitic inclusions in the host dacite produced the black dacite and light dacite magmas. Formation of foam was a dynamic process. Removal of foam propagated the foam layer downward into the hybrid andesite magma. Eventually the thermal and compositional contrasts between the hybrid andesite and black dacite magmas were reduced. Then, they mixed directly, forming the dark andesite magma. About 40–50% andesitic inclusions were disaggregated into the host dacite to produce the hybrid black dacite. Thus, disaggregation of inclusions into small fragments and individual crystals can be an efficient magma-mixing process. Disaggregation of undercooled inclusions carrying reacted host-magma phenocrysts produces coexisting reacted and unreacted phenocryst populations.

Journal of Petrology↗