Geology topics
M. Tuttle
Publications and source records attributed to M. Tuttle.
Denitrification in the recharge area and discharge area of a transient agricultural nitrate plume in a glacial outwash sand aquifer, Minnesota
Recharge rates of nitrate (NO 3 − ) to groundwater beneath agricultural land commonly are greater than discharge rates of NO 3 − in nearby streams, but local controls of NO 3 − distribution in the subsurface generally are poorly known. Groundwater dating (CFC, 3 H) was combined with chemical (ions and gases) and stable isotope (N, S, and C) analyses to resolve the effects of land use changes, flow patterns, and water‐aquifer reactions on the distributions of O 2 , NO 3 − , SO 4 = , and other constituents in a two‐dimensional vertical section leading from upland cultivated fields to a riparian wetland and stream in a glacial outwash sand aquifer near Princeton, Minnesota. Within this section a “plume” of oxic NO 3 − ‐rich groundwater was present at shallow depths beneath the fields and part of the wetland but terminated before reaching the stream or the wetland surface. Groundwater dating and hydraulic measurements indicate travel times in the local flow system of 0 to >40 years, with stratified recharge beneath the fields, downward diversion of the shallow NO 3 − ‐bearing plume by semiconfining organic‐rich valley‐filling sediments under the wetland and upward discharge across the valley and stream bottom. The concentrations and δ 15 N values of NO 3 − and N 2 indicate that the NO 3 − plume section was bounded in three directions by a curvilinear zone of active denitrification that limited its progress; however, when recalculated to remove the effects of denitrification, the data also indicate changes in both the concentrations and δ 15 N values of NO 3 − that was recharged in the past. Isotope data and mass balance calculations indicate that FeS 2 and other ferrous Fe phases were the major electron donors for denitrification in at least two settings: (1) within the glacial‐fluvial aquifer sediments beneath the recharge and discharge areas and (2) along the bottom of the valley‐filling sediments in the discharge area. Combined results indicate that the shape and progress of the oxic NO 3 − plume termination were controlled by a combination of (1) historical and spatial variations in land use practices, (2) contrast in groundwater flow patterns between the agricultural recharge area and riparian wetland discharge area, and (3) distribution and abundance of electron donors in both the sand aquifer and valley‐filling sediments. The data are consistent with slow migration of redox zones through the aquifer in response to recharging oxic groundwater during Holocene time, then an order‐of‐magnitude increase in the flux of electron acceptors as a result of agricultural NO 3 − contamination in the late twentieth century, to which the redox zone configuration still may be adjusting. The importance of denitrification for NO 3 − movement through formerly glaciated terrains should depend on the source areas and depositional environments of the glacial sediments, as well as geomorphology and recent stream‐valley sediment history.
Techniques for visualizing urban growth using a temporal GIS database
No abstract available.
Magnetic forward models of Cement oil field, Oklahoma, based on rock magnetic, geochemical, and petrologic constraints
Magnetic forward models of the Cement oil field, Oklahoma, were generated to assess the possibility that ferrimagnetic pyrrhotite related to hydrocarbon seepage in the upper 1 km of Permian strata contributes to aeromagnetic anomalies at Cement. Six bodies having different magnetizations were constructed for the magnetic models, based on geology and on petrologic and geochemical results, supplemented by rock magnetic measurements of shallow-core and outcrop samples. The column of rock through which hydrocarbons have passed is divided into three sulfide zones on the basis of pyrrhotite content, and the column is capped by a 30 m thick zone that contains ferric oxide minerals formed mainly from oxidized pyrite. Red beds unaffected by sulfidization, as well as a zone of rock depleted in hematite but lacking sulfide, surround sulfidic zones.The synthetic magnetic profiles are controlled mainly by pyrrhotite-bearing strata at depths of 200-500 m. The magnetizations of these bodies are calculated from: (1) petrographic estimates of pyrrhotite content relative to pyrite; (2) content of sulfide sulfur determined from chemical analysis; and (3) values for the magnetic susceptibility of monoclinic pyrrhotite. Total magnetizations of the bodies of highest pyrrhotite content range from about 3 X 10 (super -3) to 56 X 10 (super -3) A/m in the present field direction and yield magnetic anomalies (at 120 m altitude) having amplitudes of less than 1 nT to approximately 6 to 7 nT, respectively. Such amplitudes are much lower than those (as high as 60 nT) reported from the original total-field survey over the Cement field.Numerous assumptions were made in the generation of the models, and thus the results neither prove nor disprove the existence of aeromagnetic anomalies related to hydrocarbon seepage at Cement. Nevertheless, the results suggest that pyrrhotite, formed via hydrocarbon reactions and within a range of concentrations estimated at Cement, is capable of causing magnetic anomalies.