M. Fuhrmann | Geology Reports

USGS2022

Basis for technical guidance to evaluate evapotranspiration covers

This report provides technical guidance to evaluate evapotranspiration (ET) cover design criteria with emphasis on applications to long-term disposal sites such as Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA) sites. Water balance covers, also known as ET covers, reduce percolation by storing precipitation then allowing vegetation to cycle it back to the atmosphere. For long-term (over 200 years) waste isolation, ET covers may provide significant benefits over conventional, resistive covers that rely on engineered components, such as compacted clay barriers and geomembranes, to divert precipitation. UMTRCA covers were designed to impede and attenuate radioactive radon-222 gas flux from the underlying tailings, while minimizing percolation of any contaminants to groundwater. Such covers have implicit regulatory compliance post-construction. Alternative cover systems, such as ET covers, must explicitly meet some anticipated performance, and demonstrate beneficial use. While all engineered structures will change over time, an ET cover evolves with nature rather than resisting it, which may perpetuate a more reliable waste isolation system. For example, UMTRCA sites must provide safe and environmentally sound disposal, long-term stabilization, and control of uranium mill tailings and remain effective for up to 1,000 years, to the extent reasonably achievable, and, in any case, for at least 200 years. UMTRCA covers rely on the engineered properties to meet regulatory requirements during and immediately after construction. Subsequent compliance is implicit in the design. The design of an ET cover is far more dependent on mesoscale meteorology, native vegetation, and edaphic soil properties which are site-specific. Therefore, the design and anticipated performance of an ET cover must be demonstrated through a combination of modeling, natural analogues and pilot studies, and then verified with monitoring data. There is no single ET cover design that can likely meet performance standards across different climates, available soils, and vegetation. The technical information presented in this report reviews guidelines and performance criteria commonly used for ET covers at municipal waste facilities and the consideration factors of such covers to meet the regulatory requirements at long-term disposal sites.

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USGS2015

Uranium Sequestration During Biostimulated Reduction and In Response to the Return of Oxic Conditions In Shallow Aquifers

A proposed approach for groundwater remediation of uranium contamination is to generate reducing conditions by stimulating the growth of microbial populations through injection of electron donor compounds into the subsurface. Sufficiently reducing conditions will result in reduction of soluble hexavalent uranium, U(VI), and precipitation of the less soluble +4 oxidation state uranium, U(IV). This process is termed biostimulated reduction. A key issue in the remediation of uranium (U) contamination in aquifers by biostimulated reduction is the long term stability of the sequestered uranium. Three flow-through column experiments using aquifer sediment were used to evaluate the remobilization of bioreduced U sequestered under conditions in which biostimulation extended well into sulfate reduction to enhance precipitation of reduced sulfur phases such as iron sulfides. One column received added ferrous iron, Fe(II), increasing production of iron sulfides, to test their effect on remobilization of the sequestered uranium, either by serving as a redox buffer by competing for dissolved oxygen, or by armoring the reduced uranium. During biostimulation of the ambient microbial population with acetate, dissolved uranium was lowered by a factor of 2.5 or more with continued removal for over 110 days of biostimulation, well after the onset of sulfate reduction at ~30 days. Sequestered uranium was essentially all U(IV) resulting from the formation of nano-particulate uraninite that coated sediment grains to a thickness of a few 10’s of microns, sometimes in association with S and Fe. A multicomponent biogeochemical reactive transport model simulation of column effluents during biostimulation was generally able to describe the acetate oxidation, iron, sulfate, and uranium reduction for all three columns using parameters derived from simulations of field scale biostimulation experiments. Columns were eluted with artificial groundwater at equilibrium with atmospheric oxygen to simulate the upper limit of dissolved oxygen in recharge water. Overall about 9% of total uranium removed from solution during biostimulation was remobilized. Release of U during oxic elution was a continuous process over 140 days with dissolved uranium concentrations about 0.2 and 0.8 aM for columns with and without ferrous iron addition, respectively. Uranium remaining on the sediment was in the reduced form. The prolonged period of biostimulation and concomitant sulfate reduction appears to limit the rate of U(IV) oxidative remobilization in contrast to a large release observed for columns in previous studies that did not undergo sulfate reduction. Although continued sulfate reduction may cause decreased permeability from precipitation of iron sulfide, the greater apparent stability of the sequestered U(IV) provided by the sustained biostimulation should be considered in design of field scale remediation efforts. Remobilization of uranium following biostimulated reduction should be tested further at the field scale.

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