Geology topics
Publications and source records attributed to Leslie A. DeSimone.
This article highlights major findings from two USGS reports: DeSimone (2009) and DeSimone and others (2009). These reports can be accessed at http://water.usgs.gov/nawqa. This article is followed by a summary of treatment considerations and options for owners of private domestic wells, written by Cliff Treyens of the National Ground Water Association.
The Scituate Reservoir is the primary source of drinking water for more than 60 percent of the population of Rhode Island. Water-quality data and streamflow data collected at 37 surface-water monitoring stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 1995 through September 30, 2002, (water years (WY) 1996-2002) were analyzed to determine water-quality conditions and constituent loads in the drainage area. Trends in water quality, including physical properties and concentrations of constituents, were investigated for the same period and for a longer period from October 1, 1982 through September 30, 2002 (WY 1983-2002). Water samples were collected and analyzed by Providence Water Supply Board, the agency that manages the Scituate Reservoir. Streamflow data were collected by the U.S. Geological Survey. Median values and other summary statistics were calculated for WY 1996-2002 for all 37 monitoring stations for pH, color, turbidity, alkalinity, chloride, nitrite, nitrate, total coliform bacteria, Escherichia coli (E. coli) bacteria, orthophosphate, iron, and manganese. Instantaneous loads and yields (loads per unit area) of total coliform and E. coli bacteria (indicator bacteria), chloride, nitrite, nitrate, orthophosphate, iron, and manganese were calculated for all sampling dates during WY 1996-2002 for the 23 stations with streamflow data. Values of physical properties and concentrations of constituents were compared to State and Federal water-quality standards and guidelines, and were related to streamflow, land-use characteristics, and road density. Tributary stream water in the Scituate Reservoir drainage area for WY 1996-2002 was slightly acidic (median pH of all stations equal to 6.1) and contained low concentrations of chloride (median 13 milligrams per liter (mg/L)), nitrate (median 0.04 mg/L as N), and orthophosphate (median 0.04 mg/L as P). Turbidity and alkalinity values also were low with median values of 0.62 nephelometric turbidity units and 4.8 mg/L as calcium carbonate, respectively. Indicator bacteria were detected in samples from all stations, but median concentrations were low, 23 and 9 colony-forming units per 100 mL for total coliform and E. coli bacteria, respectively. Median values of several physical properties and median concentrations of several constituents that can be related to human activities correlated positively with the percentages of developed land and correlated negatively with the percentages of forest cover in the drainage areas of the monitoring stations. Median concentrations of chloride also correlated positively with the density of roads in the drainage areas of monitoring stations, likely reflecting the effects of road-salt applications. Median values of color correlated positively with the percentages of wetlands in the drainage areas of monitoring stations, reflecting the natural sources of color in tributary stream waters. Negative correlations of turbidity, indicator bacteria, and chloride with streamflow likely reflect seasonal patterns, in which higher values and concentrations of these properties and constituents occur during low-flow conditions at the ends of water years. Similar seasonal patterns were observed for pH, alkalinity, and color. Loads and yields of chloride, nitrate, orthophosphate, and bacteria varied among monitoring stations in the Scituate Reservoir drainage area. Loads generally were higher at stations with larger drainage areas and at stations in the eastern, more developed parts of the Scituate Reservoir drainage area. Yields generally were higher at stations in the eastern parts of the drainage area. Upward trends in pH were identified for nearly half the monitoring stations and may reflect regional reductions in acid precipitation. Upward and downward trends were identified in chloride concentrations at various stations; upward trends may reflect the effects of increasing development, whereas strong downward trends at
Continued population growth and land development for commercial, industrial, and residential uses have created concerns regarding the future supply of potable water and the quantity of ground water discharging to streams in the area of Interstate 495 in eastern Massachusetts. Two ground-water models developed in 2002-2004 for the Assabet and Upper Charles River Basins were used to simulate water supply and land-use scenarios relevant for the entire Interstate-495 corridor. Future population growth, water demands, and commercial and residential growth were projected for year 2030 by the Metropolitan Area Planning Council. To assess the effects of future development on subbasin streamflows, seven scenarios were simulated by using existing computer-based ground-water-flow models with the data projected for year 2030. The scenarios incorporate three categories of projected 2030 water- and land-use data: (1) 2030 water use, (2) 2030 land use, and (3) a combination of 2030 water use and 2030 land use. Hydrologic, land-use, and water-use data from 1997 through 2001 for the Assabet River Basin study and 1989 through 1998 for the Upper Charles River Basin study were used to represent current conditions - referred to as 'basecase' conditions - in each basin to which each 2030 scenario was compared. The effects of projected 2030 land- and water-use change on streamflows in the Assabet River Basin depended upon the time of year, the hydrologic position of the subbasin in the larger basin, and the relative areas of new commercial and residential development projected for a subbasin. Effects of water use and land use on streamflow were evaluated by comparing average monthly nonstorm streamflow (base flow) for March and September simulated by using the models. The greatest decreases in streamflow (up to 76 percent in one subbasin), compared to the basecase, occurred in September, when streamflows are naturally at their lowest level. By contrast, simulated March streamflows decreased less than 6.5 percent from basecase streamflows in all subbasins for all scenarios. The simulations showed similar effects in the Upper Charles River Basin, but increased water use contributed to decreased simulated streamflow in most subbasins. Simulated changes in March streamflows for 2030 in the Upper Charles River Basin were within +- 6 percent of the basecase for all scenarios and subbasins. Percentage decreases in simulated September streamflows for 2030 were greater than in March but less than the September decreases that resulted for some subbasins in the Assabet River Basin. Only two subbasins of the Upper Charles River Basin had projected decreases greater than 5 percent. In the Mill River subbasin, the decrease was 11 percent, and in the Mine Brook subbasin, 6.6 percent. Changes in water use and wastewater return flow generally were found to have the greatest effect in the summer months when streamflow and aquifer recharge rates are low and water use is high. September increases in main-stem streamflow of both basins were due mainly to increased discharge of treated effluent from wastewater-treatment facilities on the main-stem rivers. In the Assabet River Basin, wastewater-treatment-facility discharge became a smaller proportion of total streamflow with distance downstream. In contrast, wastewater-treatment facility discharge in the Upper Charles River Basin became a greater proportion of streamflow with distance downstream. The effects of sewer-line extension and low-impact development on streamflows in two different subbasins of the Assabet River Basin also were simulated. The result of extending sewer lines with a corresponding decrease in septic-system return flow caused September streamflows to decrease as much as 15 percent in the Fort Pond Brook subbasin. The effect of low-impact development was simulated in the Hop Brook subbasin in areas projected for commercial development. In this simulation, the greater the area where low-i
An accounting of the inflows, outflows, and uses of water in the rapidly developing Assabet River Basin, along Interstate 495 in eastern Massachusetts, was done to quantify how people's activities alter the hydrologic system. The study identified subbasins and seasons in which outflows resulting from people's activities were relatively large percentages of total flows, and quantified the fraction of streamflow in the Assabet River that is treated wastewater. Computer models of ground-water flow were also used to test how the components of the hydrologic system, particularly streamflow, would change with future development and increased water use. Computer simulations showed that, when water use was increased to currently permitted levels, streamflows in tributaries would decrease, particularly during the low-flow period. In the Assabet River, increased wastewater discharges resulted in a slight increase in total streamflow and an increase in the fraction of streamflow in the river that is wastewater, relative to existing conditions.
Water-supply withdrawals and wastewater disposal in the Assabet River Basin in eastern Massachusetts alter the flow and water quality in the basin. Wastewater discharges and stream-flow depletion from ground-water withdrawals adversely affect water quality in the Assabet River, especially during low-flow months (late summer) and in headwater areas. Streamflow depletion also contributes to loss of aquatic habitat in tributaries to the river. In 19972001, water-supply withdrawals averaged 9.9 million gallons per day (Mgal/d). Wastewater discharges to the Assabet River averaged 11 Mgal/d and included about 5.4 Mgal/d that originated from sources outside of the basin. The effects of current (2004) and future withdrawals and discharges on water resources in the basin were investigated in this study. Steady-state and transient ground-water-flow models were developed, by using MODFLOW-2000, to simulate flow in the surficial glacial deposits and underlying crystalline bedrock in the basin. The transient model simulated the average annual cycle at dynamic equilibrium in monthly intervals. The models were calibrated to 19972001 conditions of water withdrawals, wastewater discharges, water levels, and nonstorm streamflow (base flow plus wastewater discharges). Total flow through the simulated hydrologic system averaged 195 Mgal/d annually. Recharge from precipitation and ground-water discharge to streams were the dominant inflow and outflow, respectively. Evapotranspiration of ground water from wetlands and non-wetland areas also were important losses from the hydrologic system. Water-supply withdrawals and infiltration to sewers averaged 5 and 1.3 percent, respectively, of total annual out-flows and were larger components (12 percent in September) of the hydrologic system during low-flow months. Water budgets for individual tributary and main stem subbasins identified areas, such as the Fort Meadow Brook and the Assabet Main Stem Upper subbasins, where flows resulting from anthropo-genic activities were relatively large percentages, compared to other subbasins, (more than 20 percent in September) of total out-flows. Wastewater flows in the Assabet River accounted for 55, 32, and 20 percent of total nonstorm streamflow (base flow plus wastewater discharge) out of the Assabet Main Stem Upper, Middle, and Lower subbasins, respectively, in an average September. The ground-water-flow models were used to evaluate water-management alternatives by simulating hypothetical scenarios of altered withdrawals and discharges. A scenario that included no water management quantified nonstorm stream-flows that would result without withdrawals, discharges, septic-system return flow, or consumptive use. Tributary flows in this scenario increased in most subbasins by 2 to 44 percent relative to 19972001 conditions. The increases resulted mostly from variable combinations of decreased withdrawals and decreased infiltration to sewers. Average annual nonstorm streamflow in the Assabet River decreased slightly in this scenario, by 2 to 3 percent annually, because gains in ground-water discharge were offset by the elimination of wastewater discharges. A second scenario quantified the effects of increasing withdrawals and discharges to currently permitted levels. In this simulation, average annual tributary flows decreased in most subbasins, by less than 1 to 10 percent relative to 19972001 conditions. In the Assabet River, flows increased slightly, 1 to 5 percent annually, and the percentage of wastewater in the river increased to 69, 42, and 27 percent of total nonstorm streamflow out of the Assabet Main Stem Upper, Middle, and Lower subbasins, respectively, in an average September. A third set of scenarios quantified the effects of ground-water discharge of wastewater at four hypothetical sites, while maintaining 19972000 wastewater discharges to the Assabet River. Wastewater, discharged at a constant rate that varied among sites from 0.3 to 1
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This geographic information system (GIS) data layer shows the generalized lithologic and geochemical, termed lithogeochemical, character of near-surface bedrock in the New England Coastal Basin (NECB) study area of the U.S. Geological Survey's National Water Quality Assessment (NAWQA) Program. The area encompasses 23,000 square miles in western and central Maine, eastern Massachusetts, most of Rhode Island, eastern New Hampshire and a small part of eastern Connecticut. The NECB study area includes the Kennebec, Androscoggin, Saco, Merrimack, Charles, and Blackstone River Basins, as well as all of Cape Cod. Bedrock units in the NECB study area are classified into lithogeochemical units based on the relative reactivity of their constituent minerals to dissolution and the presence of carbonate or sulfide minerals. The 38 lithogeochemical units are generalized into 7 major groups: (1) carbonate-bearing metasedimentary rocks; (2) primarily noncalcareous, clastic sedimentary rocks with restricted deposition in discrete fault-bounded sedimentary basins of Mississipian or younger age; (3) primarily noncalcareous, clastic sedimentary rocks at or above biotite-grade of regional metamorphism; (4) mafic igneous rocks and their metamorphic equivalents; (5) ultramafic rocks; (6) felsic igneous rocks and their metamorphic equivalents; and (7) unconsolidated and poorly consolidated sediments.
Ground water is the primary source of drinking water for towns in the upper Charles River Basin, an area of 105 square miles in eastern Massachusetts that is undergoing rapid growth. The stratified-glacial aquifers in the basin are high yield, but also are thin, discontinuous, and in close hydraulic connection with streams, ponds, and wetlands. Water withdrawals averaged 10.1 million gallons per day in 1989?98 and are likely to increase in response to rapid growth. These withdrawals deplete streamflow and lower pond levels. A study was conducted to develop tools for evaluating water-management alternatives at the regional scale in the basin. Geologic and hydrologic data were compiled and collected to characterize the ground- and surface-water systems. Numerical flow modeling techniques were applied to evaluate the effects of increased withdrawals and altered recharge on ground-water levels, pond levels, and stream base flow. Simulation-optimization methods also were applied to test their efficacy for management of multiple water-supply and water-resource needs. Steady-state and transient ground-water-flow models were developed using the numerical modeling code MODFLOW-2000. The models were calibrated to 1989?98 average annual conditions of water withdrawals, water levels, and stream base flow. Model recharge rates were varied spatially, by land use, surficial geology, and septic-tank return flow. Recharge was changed during model calibration by means of parameter-estimation techniques to better match the estimated average annual base flow; area-weighted rates averaged 22.5 inches per year for the basin. Water withdrawals accounted for about 7 percent of total simulated flows through the stream-aquifer system and were about equal in magnitude to model-calculated rates of ground-water evapotranspiration from wetlands and ponds in aquifer areas. Water withdrawals as percentages of total flow varied spatially and temporally within an average year; maximum values were 12 to 13 percent of total annual flow in some subbasins and of total monthly flow throughout the basin in summer and early fall. Water-management alternatives were evaluated by simulating hypothetical scenarios of increased withdrawals and altered recharge for average 1989?98 conditions with the flow models. Increased withdrawals to maximum State-permitted levels would result in withdrawals of about 15 million gallons per day, or about 50 percent more than current withdrawals. Model-calculated effects of these increased withdrawals included reductions in stream base flow that were greatest (as a percentage of total flow) in late summer and early fall. These reductions ranged from less than 5 percent to more than 60 percent of model-calculated 1989?98 base flow along reaches of the Charles River and major tributaries during low-flow periods. Reductions in base flow generally were comparable to upstream increases in withdrawals, but were slightly less than upstream withdrawals in areas where septic-system return flow was simulated. Increased withdrawals also increased the proportion of wastewater in the Charles River downstream of treatment facilities. The wastewater component increased downstream from a treatment facility in Milford from 80 percent of September base flow under 1989?98 conditions to 90 percent of base flow, and from 18 to 27 percent of September base flow downstream of a treatment facility in Medway. In another set of hypothetical scenarios, additional recharge equal to the transfer of water out of a typical subbasin by sewers was found to increase model-calculated base flows by about 12 percent of model-calculated base flows. Addition of recharge equal to that available from artificial recharge of residential rooftop runoff had smaller effects, augmenting simulated September base flow by about 3 percent. Simulation-optimization methods were applied to an area near Populatic Pond and the confluence of the Mill and Charles Rivers in Franklin,
A water-quality monitoring program is proposed that would provide data to meet multiple information needs of Massachusetts agencies and other users concerned with the condition of the State's water resources. The program was designed by the U.S. Geological Survey and the Massachusetts Department of Environmental Protection, Division of Watershed Management, with input from many organizations involved in water-quality monitoring in the State, and focuses on inland surface waters (streams and lakes). The proposed monitoring program consists of several components, or tiers, which are defined in terms of specific monitoring objectives, and is intended to complement the Massachusetts Watershed Initiative (MWI) basin assessments. Several components were developed using the Neponset River Basin in eastern Massachusetts as a pilot area, or otherwise make use of data from and sampling approaches used in that basin as part of a MWI pilot assessment in 1994. To guide development of the monitoring program, reviews were conducted of general principles of network design, including monitoring objectives and approaches, and of ongoing monitoring activities of Massachusetts State agencies.Network tiers described in this report are primarily (1) a statewide, basin-based assessment of existing surface-water-quality conditions, and (2) a fixed-station network for determining contaminant loads carried by major rivers. Other components, including (3) targeted programs for hot-spot monitoring and other objectives, and (4) compliance monitoring, also are discussed. Monitoring programs for the development of Total Maximum Daily Loads for specific water bodies, which would constitute another tier of the network, are being developed separately and are not described in this report. The basin-based assessment of existing conditions is designed to provide information on the status of surface waters with respect to State water-quality standards and designated uses in accordance with the reporting requirements [Section 305(b)] of the Clean Water Act (CWA). Geographic Information System (GIS)-based procedures were developed to inventory streams and lakes in a basin for these purposes. Several monitoring approaches for this tier and their associated resource requirements were investigated. Analysis of the Neponset Basin for this purpose demonstrated that the large number of sites needed in order for all the small streams in a basin to be sampled (about half of stream miles in the basin were headwater or first-order streams) pose substantial resource-based problems for a comprehensive assessment of existing conditions. The many lakes pose similar problems. Thus, a design is presented in which probabilistic monitoring of small streams is combined with deterministic or targeted monitoring of large streams and lakes to meet CWA requirements and to provide data for other information needs of Massachusetts regulatory agencies and MWI teams.The fixed-station network is designed to permit the determination of contaminant loads carried by the State's major rivers to sensitive inland and coastal receiving waters and across State boundaries. Sampling at 19 proposed sites in 17 of the 27 major basins in Massachusetts would provide information on contaminant loads from 67 percent of the total land area of the State; unsampled areas are primarily coastal areas drained by many small streams that would be impossible to sample within realistic resource limitations. Strategies for hot-spot monitoring, a targeted monitoring program focused on identifying contaminant sources, are described with reference to an analysis of the bacteria sampling program of the 1994 Neponset Basin assessment. Finally, major discharge sites permitted under the National Pollutant Discharge Elimination System (NPDES) were evaluated as a basis for ambient water-quality monitoring. The discharge sites are well distributed geographically among basins, but are primarily on large rivers (two-thirds or more
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Quantifying the hydraulic interaction of aquifers and streams is important in the analysis of stream base fow, flood-wave effects, and contaminant transport between surface- and ground-water systems. This report describes the use of two computer programs, STLK1 and STWT1, to analyze the hydraulic interaction of streams with confined, leaky, and water-table aquifers during periods of stream-stage fuctuations and uniform, areal recharge. The computer programs are based on analytical solutions to the ground-water-flow equation in stream-aquifer settings and calculate ground-water levels, seepage rates across the stream-aquifer boundary, and bank storage that result from arbitrarily varying stream stage or recharge. Analysis of idealized, hypothetical stream-aquifer systems is used to show how aquifer type, aquifer boundaries, and aquifer and streambank hydraulic properties affect aquifer response to stresses. Published data from alluvial and stratifed-drift aquifers in Kentucky, Massachusetts, and Iowa are used to demonstrate application of the programs to field settings. Analytical models of these three stream-aquifer systems are developed on the basis of available hydrogeologic information. Stream-stage fluctuations and recharge are applied to the systems as hydraulic stresses. The models are calibrated by matching ground-water levels calculated with computer program STLK1 or STWT1 to measured ground-water levels. The analytical models are used to estimate hydraulic properties of the aquifer, aquitard, and streambank; to evaluate hydrologic conditions in the aquifer; and to estimate seepage rates and bank-storage volumes resulting from flood waves and recharge. Analysis of field examples demonstrates the accuracy and limitations of the analytical solutions and programs when applied to actual ground-water systems and the potential uses of the analytical methods as alternatives to numerical modeling for quantifying stream-aquifer interactions.
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Physical, chemical, and microbial processes controlled transport of a nitrogen-rich ground-water plume through a glacial aquifer. Lithologic heterogeneity and vertical head gradients influenced plume movement and geometry. Nitrate was the predominant nitrogen form and oxygen was depleted in the ground-water plume. However, denitrification transformed only 2 percent of plume nitrogen because of limited organic-carbon availability. Aerobic respiration, nitrification and cation exchange (unsaturated zone) and ammonium sorption (saturated zone) had larger effects.
No abstract available.
Hydrogeologic, water-quality, and biogeochemical data were collected at the site of a septage- treatment facility in Orleans, Massachusetts, from October 1988 through December 1992, where a nitrogen-rich effluent is discharged to the underlying glacial aquifer. The data were collected as part of a study done by the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, Office of Watershed Management, to investigate the effect of effluent discharge on ground-water quality and the transport of effluent nitrogen through the aquifer. Hydrogeologic data include lithologic logs and ground-water levels. Water-quality data include chemical analyses of the treated septage effluent, of ground water at the water table beneath the infiltration beds, and of ground water throughout the aquifer. Dissolved concentrations of dinitrogen gas, nitrous oxide, and dissolved inorganic carbon also were measured. Biogeochemical data include concentrations of total ammonium and solid-phase carbon and nitrogen in aquifer sediments and sediments from the effluent-infiltration beds.
Multiple-regression techniques were used to derive the reaeration coefficients estimating equation for low sloped streams: K2 = 3.83 MBAS-0.41 SL0.20 H-0.76, where K2 is the reaeration coefficient in base e units per day; MBAS is the methylene blue active substances concentration in milligrams per liter; SL is the water-surface slope in foot per foot; and H is the mean-flow depth in feet. Fourteen hydraulic, physical, and water-quality characteristics were regressed against 29 measured-reaeration coefficients for low-sloped (water surface slopes less than 0.002 foot per foot) streams in Massachusetts and New York. Reaeration coefficients measured from May 1985 to October 1988 ranged from 0.2 to 11.0 base e units per day for 29 low-sloped tracer studies. Concentration of methylene blue active substances is significant because it is thought to be an indicator of concentration of surfactants which could change the surface tension at the air-water interface.