Geology Reports⌕ Search

Geology topics

Lauren M. Zinsser

Publications and source records attributed to Lauren M. Zinsser.

12 recordsLinked to original sources

Fate and effects to the benthic community of a copper treatment to eradicate invasive mussels in a large western river, USA

Copper-based chemical treatments are commonly used to eradicate invasive mussels in small ponds and lakes, but their use in large rivers has been limited. In 2023, in response to a detection of invasive quagga mussels, a 10-km reach of the Snake River (Idaho, USA), was treated with an unprecedented 19,300 kg of chelated copper molluscicide to a target concentration of 1,000 µg/L for 10 days. We assessed the transport and fate of the copper and its exposure and effects on the nontarget benthic community downstream. Water samples were collected at seven locations throughout the treatment period, and sediment, periphyton, and benthic macroinvertebrates were collected pre- and posttreatment. Nearly half of the original mass of copper was removed from the water column via sedimentation, sorption to algae, or biological uptake within the 10-km treatment reach and the first 15 km downstream. Even so, dissolved copper concentrations exceeded the acute toxicity threshold at least as far as 28 km downstream for more than 2 weeks. Sediment copper increased by up to 8.3-fold, exceeding the consensus-based sediment quality threshold effect concentration at several sites. Effects on benthic macroinvertebrates varied by taxa. From 0–28 km downstream, invertebrate abundances decreased 52%–94%, with gastropods among the most affected. Of the unique taxa present at these sites pretreatment, 52%–64% were not found posttreatment but were replaced by other taxa, indicating a reorganization of the base of the food web. Additionally, from 0–15 km downstream, the percentage of individuals from tolerant taxa increased two to15-fold. Findings from this study can help watershed managers plan future invasive mussel responses while protecting culturally, economically, and ecologically important nontarget species in large rivers.

Idaho↗

Bioaccumulation and trophic transfer of selenium in a large oligotrophic river

In flowing waters with elevated selenium concentrations, fish are often considered to be at risk from selenium toxicity owing to dietary exposure and accumulation in ovary tissues and subsequent deformities in developing larvae. We studied selenium throughout components of the aquatic food webs at geomorphically distinct locations along the oligotrophic Kootenai River (Montana and Idaho, USA), a river with moderately elevated dissolved selenium concentrations (~ 1 µg/L). Components included water, sediment, freshly accrued biofilms, in-situ periphyton, sestonic detritus, aquatic invertebrates, and fish, with spring and fall sampling. Selenium concentrations were similar among the sediment, biofilm, periphyton, and detritus samples with most concentrations ranging between 0.5 to 2.0 (mg/kg dry weight (dw)). Among the aquatic invertebrates, the highest selenium concentrations were observed in Paraleptophlebia sp. mayflies (>15 mg/kg dw) and oligochaetes (>30 mg/kg dw). Selenium in chironomids was higher in the spring than fall, but otherwise, no consistent concentration patterns with season or feeding traits were observed. Fish tissue selenium concentrations were highly variable among species and tissue type. Selenium in fish tissues tended to be highest in livers of rainbow trout and mountain whitefish relative to egg/ovary, muscle, and carcass tissue. With northern pikeminnow, redside shiner, and slimy sculpin, selenium concentrations tended to be highest in ovary tissues. For example, selenium in rainbow trout livers ranged from an average (range) of 37 (4.5 to 151) compared to 8.7 (2.7 to 12.3) in northern pikeminnow livers. Egg/ovary concentrations ranged from a high of 26 (10.7 to 64) in redside shiner in contrast to 12.2 (6.9 to 17) mg/kg dw in slimy sculpin. A drawback of the fish-tissue approach to monitoring and managing selenium risks in freshwaters is the need to kill multiple fish per site and event. Potential alternative monitoring approaches are illustrated using aquatic invertebrates or using the food web monitoring results to derive monitoring targets for selenium in water or invertebrate tissue that could avoid the need to kill fish to assess whether fish protection guidelines are met.

Idaho, Montana↗

Hydrogeologic framework of the Mountain Home area, southern Idaho

In the arid western Snake River Plain around the City of Mountain Home, Idaho, declining groundwater levels concern agricultural, municipal, and other water users who rely on groundwater for sustenance because surface-water resources are limited. The U.S. Geological Survey developed this hydrogeologic framework to provide an updated characterization of groundwater resources in the western Snake River Plain around the City of Mountain Home. The hydrogeologic framework comprises: (1) a conceptual description of hydrogeologic units, (2) a three-dimensional hydrogeologic model and borehole database, (3) a map of groundwater levels and change, and (4) a discussion of groundwater occurrence and movement within the study area. Hydrogeologic units were defined based on existing literature and the borehole database compiled for this study; the five hydrogeologic units are granite, rhyolite, basalt, fine-grained sediments, and coarse-grained sediments. Each unit can bear water, but the main regional aquifer in the study area occurs in the basalt and fine-grained sediment units with depth to water ranging from 150 to 765 feet. A perched groundwater zone near the City of Mountain Home is primarily hosted in basalt and used domestically with most depths to water ranging from 30 to 100 feet. Interflow zones, scoria, and vertical fractures create heterogeneity within the basalt hydrogeologic unit that exerts strong control on groundwater movement, creating horizontal perching conditions and zones of enhanced vertical conductivity that facilitate downward groundwater percolation. In the fine- and coarse-grained sediments and rhyolite units, inferred faults both impede and enhance groundwater movement. The borehole database was constructed by digitizing 540 well-driller reports and was used to build a three-dimensional hydrogeologic framework model which reasonably represents the spatial distribution of hydrogeologic units in the study area. Generally, fine-grained sediments underlie much of the study area, with basalt concentrated in the central and western study area and rhyolite and granite in the uplands to the north. Groundwater levels were measured in 180 wells in March and November 2023; these data were used to develop water-table contour maps and describe groundwater-level change over an irrigation season. Groundwater generally flows south-southwest to the Snake River and groundwater levels declined across most of the study area (from 0.03 to 22.01 feet) between spring and autumn 2023, which is consistent with long-term declines in the Cinder Cone Butte Critical Groundwater Area and Mountain Home Groundwater Management Area. Groundwater levels rose (0.6 to 15.44 feet) over the irrigation season in most wells in the perched groundwater zone near the City of Mountain Home and near the Snake River, indicating the importance of surface-water recharge to groundwater in areas where surface water irrigation occurs. In aggregate, this hydrogeologic framework provides an updated characterization of and new insights into groundwater resources in the study area to help inform water resources management.

Idaho↗

Trace metal and phosphorus loading from groundwater seepage into South Fork Coeur d’Alene River after remediation at the Bunker Hill Superfund Site, northern Idaho, 2022

Widely dispersed waste products from historical mining in northern Idaho’s Coeur d’Alene mining district have long been a concern in the Coeur d’Alene River Basin in northern Idaho. The Central Impoundment Area (CIA), an unlined mining waste repository that is part of the Bunker Hill Superfund Site designated in 1983, is adjacent to the South Fork Coeur d’Alene River between Kellogg and Smelterville, Idaho. Previous studies, including a pre-remediation seepage study completed by the U.S. Geological Survey (USGS) in 2017, have identified groundwater seepage from beneath the CIA as a major contributor to trace-metal and nutrient loads (including zinc, cadmium, and phosphorus) in the South Fork Coeur d’Alene River. A major remediation project, led by the U.S. Environmental Protection Agency from late 2017 to 2021, specifically aimed to reduce groundwater loading to the river via a groundwater collection system (GWCS) at the CIA. In 2022, the USGS completed a post-remediation seepage study to quantify zinc, cadmium, and phosphorus loading from groundwater to the South Fork Coeur d’Alene River in the same reach as the 2017 pre-remediation study. Like in the previous USGS study, discharge measurements and water-quality samples were collected during base-flow conditions in the South Fork Coeur d’Alene River between Kellogg and Smelterville as well as in surface-water inputs to the reach. Results of this study show a reduction in groundwater loads of dissolved zinc, dissolved cadmium, and total phosphorus entering the South Fork Coeur d’Alene River compared to 2017. The largest reductions in groundwater loading to the South Fork Coeur d’Alene River occurred in a discrete section (the middle section) of the reach adjacent to the CIA where the GWCS was expected to have the biggest impact. In the South Fork Coeur d’Alene River middle section, loads from groundwater (presented as a mean plus or minus [±] standard deviation) of dissolved zinc decreased from 85 ± 9.3 kilograms per day (kg/d) in 2017 to 11.6 ± 19.2 kg/d in 2022 (86-percent reduction), dissolved cadmium decreased from 0.59 ± 0.10 kg/d in 2017 to 0.11 ± 0.06 kg/d in 2022 (81-percent reduction), and total phosphorus decreased from 6.5 ± 0.45 kg/d in 2017 to 0.79 ± 0.97 kg/d in 2022 (88-percent reduction). In addition to reduced groundwater loading, lower concentrations of dissolved zinc, dissolved cadmium, and total phosphorus were observed at the site farthest downstream from the GWCS. Furthermore, the ambient water-quality-criteria ratios decreased at all river monitoring sites in 2022, although zinc and cadmium concentrations still exceeded the site-specific criteria designated to protect aquatic life. This post-remediation study indicates that the GWCS at the CIA has reduced groundwater loading of trace metals and phosphorus to the South Fork Coeur d’Alene River. This reduction in trace metals and phosphorus in South Fork Coeur d’Alene River also has implications for water quality downstream in the main-stem Coeur d’Alene River and in Coeur d’Alene Lake.

Idaho↗

Groundwater potentiometric-surface altitude in 2022 and groundwater-level changes between 1968, 1991, and 2022, in the alluvial aquifer in the Big Lost River Valley, south-central Idaho

The U.S. Geological Survey and the Idaho Department of Water Resources measured groundwater levels during spring 2022 and autumn 2022 to create detailed potentiometric-surface maps for the alluvial aquifer in the Big Lost River Valley in south-central Idaho. Wells were assigned to shallow, intermediate, and deep water-bearing units based on well depth, groundwater potentiometric-surface altitude, and hydrogeologic unit. Potentiometric-surface contours were created for each of the three water-bearing units for spring 2022 and autumn 2022. Groundwater flow generally follows topography down valley to the south. The groundwater-level data also were used to calculate changes in groundwater levels from spring to autumn 2022 and from historical measurement events in 1968 and 1991 to 2022. Groundwater levels declined at most wells from spring 1968 to spring 2022 and from spring 1991 to spring 2022. Although groundwater-level changes are sensitive to interannual wet and dry periods, long-term groundwater-level declines suggest that recharge and down-valley groundwater flows are insufficient to fully recover groundwater-level declines from pumping in some parts of the alluvial aquifer in the Big Lost River Valley.

Idaho↗

Surface-water and groundwater interactions in the Big Lost River, south-central Idaho

The Big Lost River of south-central Idaho interacts with the underlying aquifer by gaining and losing streamflow throughout various areas in the Big Lost River Valley. Surface-water and groundwater resources are used throughout the valley to sustain domestic, agricultural, and livestock needs. The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, evaluated streamflow gains and losses by differential streamgaging in the lower Big Lost River, Idaho, during four measurement events: March 27–28, 2019; October 16–17, 2019; October 6–7, 2020; and March 30, 2021. This report presents and analyzes streamflow measurement and uncertainty data from each measurement event to describe surface-water/groundwater interactions. This report is the second chapter of a multi-chapter volume that characterizes water resources in the Big Lost River Basin. During the four measurement events, 100 streamflow measurements were made at 46 unique sites on the Big Lost River, James Creek, and diversions or tributaries between Mackay Reservoir near Mackay and Arco, Idaho. Aquifer lithology and dimensions affected spatial patterns of streamflow gains and losses between the upper, middle, and lower reaches; changes in water supply, groundwater levels, and surface-water management affected seasonal differences within reaches. In the upper reach of the Big Lost River, streamflow losses and gains were greater during the wetter 2019 events and lesser during the drier 2020 and 2021 events. The middle reach includes the largest losses from the Big Lost River to groundwater; these losses occurred in the Darlington Sinks where 42 percent or more of streamflow was lost as the aquifer widens and groundwater deepens. These results suggest that changing surface-water supply, irrigation use, and recharge affect interannual groundwater levels and, in turn, affect patterns of streamflow gains and losses in the middle reach. Finally, surface-water management is the primary control on surface-water/groundwater interactions in the lower reach. Overall patterns of streamflow gains and losses in this study generally were consistent with previous reports. However, paired with the related hydrogeologic framework and water budget, this investigation provides new insights into how hydrogeologic conditions and interannual variability in water supply, groundwater levels, and surface-water management affect surface-water/groundwater interactions in the Big Lost River Valley.

Idaho↗

Hydrogeologic framework of the Big Lost River Basin, south-central Idaho, chap. A of Zinsser, L.M., ed., Characterization of water resources in the Big Lost River Basin, south-central Idaho

Surface-water and groundwater resources in the Big Lost River Basin of south-central Idaho are extensively interconnected; this interchange affects and is affected by water-resource management for irrigated agriculture and other uses in the basin. Concerns from water users regarding declining groundwater levels, declining streamflows, and drought helped motivate an updated evaluation of water resources in the Big Lost River Basin. The hydrogeologic framework presented in this report provides a conceptual basis for understanding groundwater resources in the Big Lost River Basin and comprises three major parts: (1) conceptual description of four hydrogeologic units, (2) development of a three-dimensional hydrogeologic framework model representing the spatial distribution of the hydrogeologic units, and (3) a description of groundwater occurrence and movement. This hydrogeologic framework represents the first of three planned reports describing water resources in the Big Lost River Basin; subsequent reports are intended to present a groundwater budget for the basin and to describe the results of a series of events measuring gains to and losses from streamflow in the Big Lost River. This report was prepared by the U.S. Geological Survey in cooperation with the Idaho Department of Water Resources. The Big Lost River Basin has four hydrogeologic units. First, the Quaternary unconsolidated sediments unit comprises the basin-fill alluvial aquifer and generally is used within 250 feet of the land surface. The Quaternary unconsolidated sediments unit is spatially heterogeneous, with locally confining conditions in some areas, and is the most heavily used hydrogeologic unit in the basin. Second, the Paleozoic sedimentary rocks unit, composed primarily of carbonates with some siliciclastic rocks, represents the major bedrock aquifer and contributes subsurface recharge at the margins of the alluvial aquifer. Third, the Tertiary volcanic rocks unit, composed primarily of andesite and dacite with lesser tuff, is locally important to water production, particularly in faulted and fractured zones. The Paleozoic sedimentary rocks hydrogeologic unit occurs at the valley margins and underlies tributaries throughout the basin, whereas the Tertiary volcanic rocks hydrogeologic unit primarily occurs in uplands in the western one-half of the basin. Fourth, the Quaternary basalt rocks unit consists of multiple basalt flows that are interbedded with the Quaternary unconsolidated sediments unit in the southern end of the Big Lost River Basin and contains at least three water-bearing zones. Insights gained from this updated hydrogeologic framework will help inform current water-resource management in the Big Lost River Basin.

Idaho↗

Trends in concentration, loads, and sources of trace metals and nutrients in the Spokane River Watershed, northern Idaho, water years 1990–2018

A long history of mining and widespread metals contamination in the Coeur d’Alene River watershed and downstream into the Spokane River has led to the area’s designation as a Superfund site and to extensive, ongoing (as of 2020) remedial actions. Long-term water-quality and streamflow data, collected by the U.S. Geological Survey for up to 29 years at 20 sampling sites in the Coeur d’Alene, Spokane and St. Joe River watersheds, were analyzed to evaluate the impact of remedial actions on metals in surface water. Analyses focused on total and dissolved cadmium, zinc and lead. Trends in total phosphorus, total nitrogen and dissolved orthophosphate were also evaluated; although these nutrients are not constituents of concern for the Superfund site, they are important to the health of Coeur d’Alene Lake. Dissolved cadmium, zinc and lead concentrations were compared to ambient water-quality criteria at 20 sample sites. For the 12 sites with the most extensive data records, Weighted Regressions on Time, Discharge and Season (WRTDS) models were developed to estimate flow-normalized annual mean concentrations and flow-normalized annual total loads; these results were used to evaluate trends because flow-normalization dampens the impact of interannual streamflow variability on concentrations and loads. WRTDS models with Kalman filtering (WRTDS_K) were developed to estimate annual mean concentrations and annual total loads; these results were used to evaluate spatial patterns in constituent sources. Models were developed for total and dissolved cadmium, lead, and zinc; total phosphorus and nitrogen; and dissolved orthophosphate, although not all constituents were modeled for all sites due to limited sample sizes. Bootstrapped confidence intervals were constructed to determine the statistical likelihood of trends and the slope of trends in flow-normalized concentrations and loads during the period of record (13–29 years, depending on the site), water years 1999–2009, and water years 2009–18.

Idaho↗

Trace metal and nutrient loads from groundwater seepage into the South Fork Coeur d’Alene River near Smelterville, northern Idaho, 2017

The Coeur d’Alene mining district in northern Idaho historically was a globally important source of lead, zinc, and silver, but over 100 years of mining has left a legacy of metals contamination in the Coeur d’Alene River valley. Previous studies by the U.S. Geological Survey (USGS) and others have indicated that groundwater discharging into the South Fork Coeur d’Alene River between Kellogg and Smelterville, Idaho, is a substantial source of dissolved zinc, dissolved cadmium, and total phosphorus. As part of its ongoing cleanup efforts, the U.S. Environmental Protection Agency is constructing a groundwater collection and treatment system to intercept and treat this contaminated water before it reaches the river. To establish conditions prior to construction, the USGS conducted a seepage study in September 2017 to quantify the rate and quality of groundwater discharging into the South Fork Coeur d’Alene River between Kellogg and Smelterville. Repeated measurements of streamflow were taken at multiple locations in the river and tributaries, and water-quality samples were collected and analyzed for trace metals and nutrients. Results showed consistent increases in streamflow (5.8 ± 1.3 cubic feet per second); and in dissolved zinc (85 ± 9.3 kilograms per day [kg/d]), dissolved cadmium (0.58 ± 0.10 kg/d) and total phosphorus (6.3 ± 0.45 kg/d) loads in a discrete segment of the reach. These gains exceeded tributary inputs, thereby implicating groundwater discharge as the main source of loading. Zinc and cadmium loads from groundwater in 2017 were less than those measured in 1999 but comparable to those measured from 2003 to 2008. This suggests that remedial actions in the late 1990s and early 2000s decreased trace-metal loading from 1999 to 2003, but that conditions remained similar from 2003 to 2017. A second seepage study will be conducted after construction and treatment plant system optimization are complete; this second study will evaluate changes in groundwater discharge to and water quality in the South Fork Coeur d’Alene River compared to the pre-construction conditions.

Idaho↗

Spatial and temporal trends in selenium in the upper Blackfoot River watershed, southeastern Idaho, 2001–16

Phosphate mining in southeastern Idaho has been an important economic driver for the region and State for over 100 years, but weathering of mining waste rock has also released selenium into the Blackfoot River. This report analyzes and presents data from three separate but complementary studies monitoring selenium in streams in the region. The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management, has been collecting streamflow and water-quality samples year-round on the Blackfoot River above reservoir near Henry, Idaho, (USGS streamgage 13063000) since 2001. Over the same period, the Idaho Department of Environmental Quality (IDEQ) has collected streamflow and water-quality samples from the Blackfoot River and tributaries during spring runoff. Data collected from 2001 to 2012 during these two studies were analyzed previously. This report extends the analysis using new data collected through 2016. This report also presents the results of a joint USGS and IDEQ seepage study conducted in June 2016 in the Blackfoot River near Dry Valley. Although limited in scope, this study explored the hypothesis that unaccounted selenium loading (loading in excess of tributary inputs) in this reach could be caused by groundwater inflow. USGS dissolved selenium concentration data from streamgage 13063000 on the Blackfoot River and IDEQ data from the mainstem and mining-affected tributaries are highest shortly after peak runoff and correlate with streamflow magnitude. Although earlier analyses indicated increasing selenium concentrations from 2001 to 2012, this study shows that runoff and baseflow dissolved selenium concentrations increased and then decreased during 2001–16. High median runoff concentrations from 2005 through 2011 are associated with high snowpack and streamflow. This result suggests that more snowmelt moving through selenium-bearing waste rock leads to increased instream concentrations. The time lag between peak runoff and then peak selenium concentrations suggests that selenium mobilization may occur as snowmelt percolates through waste rock rather than by faster surface runoff. However, variability in local snow accumulation and snowmelt conditions likely affects interannual variability in selenium concentrations in the mainstem Blackfoot River and tributaries. In contrast to runoff selenium concentrations, median baseflow (August to October) dissolved selenium concentrations were highest from 2009 to 2013. Aquatic plant senescence and release of selenium is an unlikely explanation for this trend because plants are still growing during this time of year. In addition, this trend is observed during and shortly after the observed period of high snowpack. Thus, increased baseflow selenium concentrations suggest that increased selenium loading to alluvial groundwater may occur during periods of high snowmelt and manifest in later years as higher instream concentrations during baseflows when the majority of streamflow is attributable to groundwater gains. Runoff-period streamflow and selenium loads were calculated for the tributaries and mainstem Blackfoot River. Selenium loads vary from year to year with mainstem loads greater than the total tributary contributions in some years and less than tributary contributions in other years. In general, East Mill Creek usually accounted for the largest proportion of the total Blackfoot River load, and unaccounted loads (loads in excess of tributary inputs) often occurred in the vicinity of Spring Creek and Dry Valley. The latter observation led the USGS and IDEQ to conduct a seepage study to further investigate groundwater and selenium loading to the Blackfoot River near Dry Valley. The seepage study results show consistent albeit small unaccounted increases in streamflow and dissolved selenium load in the Blackfoot River near Dry Valley. Field observation of a spring to the north of the river and independent groundwater monitoring data from Dry Valley to the south of the river suggest that alluvial groundwater may discharge to the river from both sides. However, the small unaccounted selenium load measured in the June 2016 study relative to loads measured during runoff suggest that groundwater loading in this reach may occur primarily during runoff. An improved understanding of alluvial groundwater extent, gradient, hydraulic conductivity, and quality would aid in interpreting unaccounted gains and losses in selenium loads in the Blackfoot River. Finally, State of Idaho selenium water-quality criteria have recently shifted to a hierarchical fish tissue and water concentration scheme. This report summarizes existing fish tissue and water-quality data in the mainstem and offers considerations for future selenium monitoring in the Blackfoot River.

Idaho↗

Coeur d’Alene Basin Environmental Monitoring Program, surface water, northern Idaho—Annual data summary, water year 2017

Streams within the Coeur d’Alene River drainage basin in northern Idaho have been extensively affected by historical mining activities and are subject to ongoing remedial actions as part of the Bunker Hill Mining & Metallurgical Complex Superfund Site. The U.S. Geological Survey (USGS) operates 12 real-time streamgages and collects surface-water-quality samples two to four times annually at 20 sites in the Spokane River and Coeur d’Alene River drainage basins. These data are used by the U.S. Environmental Protection Agency (USEPA) to monitor cleanup progress and to support decisions related to implementing remedial actions throughout the basin. USGS data collection highlights from water year 2017 include: • A rain-on-snow event in March 2017 produced high streamflows and flooding in the basin. • The March event mobilized high concentrations of total metals (cadmium, lead, zinc, and others) in the Coeur d’Alene River near Cataldo, at Rose Lake, and near Harrison; these concentrations were among the highest that have been measured at these sites during flood events sampled by the USGS. • Total lead and dissolved zinc and cadmium concentrations decreased in Canyon Creek in 2017 when compared with water years 2007–16; in contrast, concentrations of dissolved zi

Idaho↗