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Larry P. Gough

Publications and source records attributed to Larry P. Gough.

17 recordsLinked to original sources
USGS2019

Soil mineralogy and geochemistry along a north-south transect in Alaska and the relation to source-rock terrane

Soils collected along a predominately north-south transect in Alaska were used to evaluate regional differences in the soil mineralogy and geochemistry in the context of a geotectonic framework for Alaska. The approximately 1,395-kilometer-long transect followed the Dalton, Elliott, and Richardson Highways from near Prudhoe Bay to Valdez. Sites were selected with a site spacing of approximately 10 road-kilometers; soil was sampled by soil horizon at 175 sites. Terrane boundaries were estimated from digitized versions of the lithotectonic terrane map of Alaska (Silberling and others, 1994). Terrane assignments for each site were based on the site’s distance along the transect. We also present data for 15 minerals or mineral groups and 58 elements, as well as total, inorganic, and organic carbon. Quantitative mineralogy of the mineral-soil horizons was characterized by X-ray diffraction. Elemental contents were determined by a combination of inductively coupled plasma-atomic emission spectrometry (ICP-AES) and inductively coupled plasma-mass spectrometry (ICP-MS) analysis following a multi-acid or sodium-sinter decomposition of the samples. Total carbon and carbonate carbon contents were determined using an automated carbon analyzer and coulometric titration, respectively; organic carbon content was obtained by calculating the difference between total and carbonate carbon. Mercury and selenium were analyzed using cold-vapor atomic absorption (CV-AA), and hydride-generation atomic absorption spectrometry (HG-AAS), respectively. The mineralogical and geochemical patterns from these soils are used to assess the relation between soil characteristics and the geology of surrounding terranes.

Alaska↗
USGS2013

Effect of ultramafic intrusions and associated mineralized rocks on the aqueous geochemistry of the Tangle Lakes Area, Alaska

Stream water was collected at 30 sites within the Tangle Lakes area of the Delta mineral belt in Alaska. Sampling focused on streams near the ultramafic rocks of the Fish Lake intrusive complex south of Eureka Creek and the Tangle Complex area east of Fourteen Mile Lake, as well as on those within the deformed metasedimentary, metavolcanic, and intrusive rocks of the Specimen Creek drainage and drainages east of Eureka Glacier. Major, minor, and trace elements were analyzed in aqueous samples for this reconnaissance aqueous geochemistry effort. The lithologic differences within the study area are reflected in the major-ion chemistry of the water. The dominant major cation in streams draining mafic and ultramafic rocks is Mg 2+ ; abundant Mg and low Ca in these streams reflect the abundance of Mg-rich minerals in these intrusions. Nickel and Cu are detected in 84 percent and 87 percent of the filtered samples, respectively. Nickel and Cu concentrations ranged from Ni <0.4 to 10.1 micrograms per liter (mg/L), with a median of 4.2 mg/L, and Cu <0.5 to 27 mg/L, with a median of 1.2 mg/L. Trace-element concentrations in water are generally low relative to U.S. Environmental Protection Agency freshwater aquatic-life criteria; however, Cu concentrations exceed the hardness-based criteria for both chronic and acute exposure at some sites. The entire rare earth element (REE) suite is found in samples from the Specimen Creek sites MH5, MH4, and MH6 and, with the exception of Tb and Tm, at site MH14. These samples were all collected within drainages containing or downstream from Tertiary gabbro, diabase, and metagabbro (Trgb) exposures. Chondrite and source rock fractionation profiles for the aqueous samples were light rare earth element depleted, with negative Ce and Eu anomalies, indicating fractionation of the REE during weathering. Fractionation patterns indicate that the REE are primarily in the dissolved, as opposed to colloidal, phase.

Alaska↗
USGS2010

Recent U.S. Geological Survey Studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada-Results of a 5-Year Project

This report presents summary papers of work conducted between 2002 and 2007 under a 5-year project effort funded by the U.S. Geological Survey Mineral Resources Program, formerly entitled 'Tintina Metallogenic Province: Integrated Studies on Geologic Framework, Mineral Resources, and Environmental Signatures.' As the project progressed, the informal title changed from 'Tintina Metallogenic Province' project to 'Tintina Gold Province' project, the latter being more closely aligned with the terminology used by the mineral industry. As Goldfarb and others explain in the first chapter of this report, the Tintina Gold Province is a convenient term used by the mineral exploration community for a 'region of very varied geology, gold deposit types, and resource potential'. The Tintina Gold Province encompasses roughly 150,000 square kilometers, bounded by the Kaltag-Tintina fault system on the north and the Farewell-Denali fault system on the south. It extends westward in a broad arc, some 200 km wide, from northernmost British Columbia, through the Yukon, through southeastern and central Alaska, to southwestern Alaska. The climate is subarctic and, in Alaska, includes major physiographic delineations and ecoregions such as the Yukon-Tanana Upland, Tanana-Kuskokwim Lowlands, Yukon River Lowlands, and the Kuskokwim Mountains. Although the Tintina Gold Province is historically important for some of the very first placer and lode gold discoveries in northern North America, it has recently seen resurgence in mineral exploration, development, and mining activity. This resurgence is due to both new discoveries (for example, Pogo and Donlin Creek) and to the application of modern extraction methods to previously known, but economically restrictive, low-grade, bulk-tonnage gold resources (for example, Fort Knox, Clear Creek, and Scheelite Dome). In addition, the Tintina Gold Province hosts numerous other mineral deposit types, possessing both high and low sulfide content, which are not currently in development.

Scientific Investigations Report↗
USGS2007

Understanding Metal Pathways in Mineralized Ecosystems

Successful management of ecosystems containing historical mine wastes requires understanding of processes that are responsible for the distribution, concentration, and bioavailability of potentially toxic elements. U.S. Geological Survey (USGS) scientists recently completed several investigations at historical mine sites in the western United States. These investigations have improved our understanding of how metals are mobilized from mineralized sources, are transported through the environment, and become available to humans and other biota. The new information is being used by Federal, State, and local agencies that manage and remediate abandoned mine lands.

Circular↗
USGS2007

Geochemical data for stream-sediment, surface-water, rock, and vegetation samples from Red Mountain (Dry Creek), an unmined volcanogenic massive sulfide deposit in the Bonnifield District, Alaska Range, east-central Alaska

North-central and northeast Nevada contains numerous large plutons and smaller stocks but also contains many small, shallowly emplaced intrusive bodies, including dikes, sills, and intrusive lava dome complexes. Decades of geologic investigations in the study area demonstrate that many ore deposits, representing diverse ore deposit types, are spatially, and probably temporally and genetically, associated with these igneous intrusions. However, despite the number and importance of igneous instrusions in the study area, no synthesis of geochemical data available for these rocks has been completed. This report presents a synthesis of composition and age data for these rocks. The product represents the first phases of an effort to evaluate the time-space-compositional evolution of Mesozoic and Cenozoic magmatism in the study area and identify genetic associations between magmatism and mineralizing processes in this region.

Alaska↗
USGS2007

Tintina Gold Province Study, Alaska and Yukon Territory, 2002-2007

The Tintina gold province is an arc-shaped 2,000-kilometer-long metallogenic province that extends from northern British Columbia, through the Yukon Territory, and across and into southwestern Alaska. In the United States, the province remains a prime area for gold exploration and includes such large gold deposits as Pogo, Fort Knox-True North, and Donlin Creek. In recent years, gold exploration and development and mining activity have accelerated in the area. Plans have been discussed for public and private projects and infrastructures associated with development. A U.S. Geological Survey study undertaken from 2002 to 2007 provides a context for understanding why and how the mineral resources of the area were formed, why this area is so abundantly endowed, and how the environmental signatures that are characteristic of the area are related to the development of mineral resources. Characterization of natural baseline metal concentrations in the area's watersheds is necessary to address future land-use issues related to mining and/or infrastructure activities. A thorough understanding of water-rock and element-bioavailability processes will help predict the possible environmental impact of development. The five tasks of this study add to the science of defining and understanding an 'intrusion-related gold system.'

Fact Sheet↗
USGS2007

Geologic Map of the Big Delta B-1 Quadrangle, East-Central Alaska

Geologic mapping and U-Pb age dating of rocks from the Big Delta B-1 quadrangle, east-central Alaska, have yielded new insights into the geology and gold mineral resource for the headwater region of the Goodpaster River, northeast of Delta, Alaska. The area lies within the Yukon-Tanana Upland and is underlain by Paleozoic and Cretaceous crystalline bedrock and contains several gold mines and prospects. The Paleozoic units include biotite gneiss, quartzite interlayered with metapelite, and amphibolite gneiss. The Paleozoic units were intruded during the Devonian by tonalitic to granitic plutons, which, as a result of regional Mesozoic metamorphism and tectonism, are now augen gneiss and biotite orthogneiss. The Mesozoic regional metamorphism and ductile deformation of the entire Yukon-Tanana Upland culminated by the Late Cretaceous (about 116 Ma) as a result of northwest-directed regional transpression along the southern margin of the North American craton. This dynamothermal episode was followed by invasion of syn- to post-tectonic granodioritic to granitic batholiths during the Late Cretaceous (about 113-107 Ma), followed by a pulse of 100-95 Ma quartz feldspar porphyry intrusions. Gold mineralization is spatially associated with various post-tectonic Late Cretaceous granitic dikes and batholiths throughout the quadrangle. A northeast-trending structural corridor, described herein as the Black Mountain tectonic zone, both controlled the emplacement of some of the Cretaceous intrusive rocks, gold deposits, and prospects, as well as formed a deep-seated crustal conduit along which a subsequent rhyolite flow-dome complex erupted during the Paleocene. Tertiary uplift and erosion resulted in the development of extensive erosional pediments. Quaternary alpine glaciation carved beautiful, broad valleys in the eastern part of the quadrangle, leaving behind terminal moraines in the headwater region of the Goodpaster river drainage. Continued Holocene to Recent deformation along the Black Mountain tectonic zone has offset Tertiary terraces, as well as Quaternary fluvial and alluvial deposits, indicating that the area has a long, complex, and ongoing tectonic history.

Scientific Investigations Map↗
USGS2007

Aufeis accumulations in stream bottoms in arctic and subarctic environments as a possible indicator of geologic structure: Chapter F in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

Thick accumulations of ice, called “aufeis,” form during winter along stream and river valleys in arctic and subarctic regions. In high-gradient alpine streams, aufeis forms mostly as a result of ground-water discharge into the stream channel. The ice occludes this discharge, perturbing the steady-state condition, and causing an incremental rise in the local water table until discharge occurs higher on the stream bank above the previously formed ice. Successive freezing of onlapping ice layers can lead to aufeis accumulations several meters thick. The location and extent of aufeis in high-gradient streams may be useful to relate local hydrology to geologic structure. In the Goodpaster River basin study area, mineral deposits are known to occur, the location of which may be structurally controlled. Therefore, a more thorough understanding of regional geologic structures may facilitate a more detailed understanding of the genesis of the mineral deposits. Extensive aufeis was observed during visits to the Goodpaster River basin in east-central Alaska during 1999, 2001, and 2002. Seeps from the sides of the valleys caused ice to build up, giving the ice surface a concave-upward shape perpendicular to the stream direction. This concavity is evidence for ground-water discharge along the length of the aufeis, as opposed to discharge from a single upstream point. During thaw, streamflow is commonly observed out of the normal channel, evidence that occlusion of the channel (and shallow sediments) by ice is a viable mechanism for causing the water table to rise. The thickest (>3 meters) and most extensive aufeis (100’s of meters to kilometers along valleys) coincided with locations of laterally extensive (>5 kilometers) mapped high-angle brittle fault zones, suggesting that the fault zones are hydraulically conductive. Additional evidence of water flow is provided by observed changes in stream-water chemistry in reaches in which aufeis forms, despite a lack of surface tributaries. Minor or no aufeis was observed in many other drainage valleys where no laterally extensive structures have been mapped, implying that aufeis formation results from more than a topographic effect or discharge from bank storage. Thus, the presence of thick, laterally extensive aufeis in highgradient streams may be a useful aid to geologic structural mapping in arctic and subarctic climates.

Alaska;Yukon↗
USGS2007

Landscape geochemistry near mineralized areas of eastern Alaska: Chapter H in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

The Pogo lode gold deposit was discovered in eastern Alaska in the early 1990s and provided the opportunity to study elemental distribution and mobility in the natural environment prior to mine development. Studying mineralized systems prior to mining allows us to compare the natural biogeochemical signature in mineralized versus nonmineralized areas. The resultant data and interpretation also provide a baseline for evaluating what, if any, changes in elemental distribution result from development. This report investigates the chemistry of stream water, streambed sediment, and soil in the context of regional bedrock geology. The major-ion chemistry of the waters reflects a rock-dominated aqueous system, and the waters are classified as Ca 2+ and Mg 2+ - HCO 3 - to Ca 2+ and Mg 2+ - SO 4 -2 waters. Creeks draining the gneissic lithologies tend to be more sulfate dominated than those draining the intrusive units. Sulfate also dominated creeks draining mineralized areas; however, the underlying paragneiss unit could be contributing substantially to the sulfate concentration, and the sulfate concentration in these creeks may reflect a complex baltholith-paragneiss boundary rather than mineralization. Arsenic concentrations in bed sediments were elevated in mineralized areas relative to nonmineralized areas. Elevated concentrations of nickel, chromium, iron, manganese, and cobalt appear to reflect the presence of ultramafic rocks in the drainage. In general, aqueous metal concentrations were below the State of Alaska’s Aquatic Life Criteria and Drinking Water Standards, with the exception of arsenic in stream water, which ranged in concentration from less than 1 to 14 micrograms per liter (&mu;g/L) and exceeded the drinking water standard at one site. The arsenic and antimony concentration in the A, B, and C soil horizons ranged from 3 to 410 milligrams per kilogram (mg/kg), 6.1 to 440 mg/kg, and 2 to 300 mg/kg, respectively, for arsenic and 0.4 to 24 mg/kg, 0.6 to 25 mg/kg, and 0.2 to 16 mg/kg, respectively, for antimony. The arsenic and antimony concentrations in stream waters correlate well with the concentrations in soils. However, significantly less arsenic and antimony was extracted from C horizon soils in water leaching experiments, indicating that the arsenic and antimony in the C horizon is present in a less available form than in the A or B horizons. Arsenic and antimony uptake by grayleaf willow (Salix glauca L.) appears minimal, with arsenic concentrations ranging from less than 0.01 to 0.14 mg/kg and antimony concentrations ranging from less than 0.003 to 0.23 mg/kg in willow leaves. In general, the highest concentrations of both arsenic and antimony in water and soils were found near mineralized areas. Elevated arsenic concentrations were also found in bed sediments from mineralized areas. In these sample matrices, the presence of arsenic and (or) antimony was a good indicator of contact with mineralized rock units.

Alaska;Yukon↗
USGS2007

Environmental geochemical study of Red Mountain--an undisturbed volcanogenic massive sulfide deposit in the Bonnifield District, Alaska range, east-central Alaska: Chapter I in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

The Red Mountain volcanogenic massive sulfide (VMS) deposit exhibits well-constrained examples of acid-generating, metal-leaching, metal-precipitation, and self-mitigation (via co-precipitation, dilution, and neutralization) processes that occur in an undisturbed natural setting, a rare occurrence in North America. The unmined pyrite-rich deposit displays a remarkable environmental footprint of natural acid generation, high metal concentrations, and exceedingly high rare-earth-element (REE) concentrations in surface waters. Dissolution of pyrite and associated secondary reactions under near-surface, oxidizing conditions are the primary causes for the acid generation and metal leaching. The deposit is hosted in Devonian to Mississippian felsic metavolcanic rocks of the Mystic Creek Member of the Totatlanika Schist. Water samples with the lowest pH values, highest specific conductances, and highest major- and trace-element concentrations are from springs and streams within the quartz-sericite-pyrite alteration zone. Aluminum, As, Cd, Co, Cu, Fe, Mn, Ni, Pb, Y, and particularly Zn and the REEs are all found in high concentrations, ranging across four orders of magnitude. Waters collected upstream from the alteration zone have near-neutral pH values, lower specific conductances, lower metal concentrations, and measurable alkalinities. Water samples collected downstream of the alteration zone have pH values and metal concentrations intermediate between these two extremes. Stream sediments are anomalous in Zn, Pb, S, Fe, Cu, As, Co, Sb, and Cd relative to local and regional background abundances. Red Mountain Creek and its tributaries do not support, and probably never have supported, significant megascopic faunal aquatic life.

Alaska;Yukon↗
USGS2007

The biogeochemistry and occurrence of unusual plant species inhabiting acidic, metal-rich water, Red Mountain, Bonnifield district, Alaska Range: Chapter J in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

This report presents results on the occurrence and biogeochemistry of unusual plant species, and of their supporting sediment, in an undisturbed volcanogenic massive sulfide deposit in the Tintina Gold Province (see fig. 1 of Editors’ Preface and Overview). The extraordinary plant assemblage found growing in the acidic metal-rich waters that drain the area is composed predominantly of bryophytes (liverworts and mosses). Ferricrete-cemented silty alluvial sediments within seeps and streams are covered with the liverwort Gymnocolea inflata, whereas the mosses Polytrichum commune and P. juniperinum inhabit the area adjacent to the water and within the splash zone. Both the liverwort-encrusted sediment and Polytrichum thalli have high concentrations of major- and trace-metal cations (for example, Al, As, Cu, Fe, Hg, La, Mn, Pb, and Zn). Soils in the area do not reflect the geochemical signature of the mineral deposit, and we suspect that they are most influenced by the chemistry of airborne dust (aeolian material) derived from outside the area.

Alaska;Yukon↗
USGS2003

Geologic map of the Big Delta B-2 quadrangle, east-central Alaska

New 1:63,360-scale geologic mapping of the Big Delta B-2 quadrangle provides important data on the structural setting and age of geologic units, as well as on the timing of gold mineralization plutonism within the Yukon-Tanana Upland of east-central Alaska. Gold exploration has remained active throughout the region in response to the discovery of the Pogo gold deposit, which lies within the northwestern part of the quadrangle near the south bank of the Goodpaster River. Geologic mapping and associated geochronological and geochemical studies by the U.S. Geological Survey (USGS) and the Alaska Department of Natural Resources, Division of Mining and Water Management, provide baseline data to help understand the regional geologic framework. Teck Cominco Limited geologists have provided the geologic mapping for the area that overlies the Pogo gold deposit as well as logistical support, which has lead to a much improved and informative product. The Yukon-Tanana Upland lies within the Tintina province in Alaska and consists of Paleozoic and possibly older(?) supracrustal rocks intruded by Paleozoic (Devonian to Mississippian) and Cretaceous plutons. The oldest rocks in the Big Delta B-2 quadrangle are Paleozoic gneisses of both plutonic and sedimentary origin. Paleozoic deformation, potentially associated with plutonism, was obscured by intense Mesozoic deformation and metamorphism. At least some of the rocks in the quadrangle underwent tectonism during the Middle Jurassic (about 188 Ma), and were subsequently deformed in an Early Cretaceous contractional event between about 130 and 116 Ma. New U-Pb SHRIMP data presented here on zircons from the Paleozoic biotite gneisses record inherited cores that range from 363 Ma to about 2,130 Ma and have rims of euhedral Early Cretaceous metamorphic overgrowths (116 +/- 4 Ma), interpreted to record recrystallization during Cretaceous west-northwest-directed thrusting and folding. U-Pb SHRIMP dating of monazite from a Paleozoic gneiss sample yields an age of 112 +/- 2 Ma; the monazite presumably grew during the waning stages of the intense regional Cretaceous ductile deformation. The Cretaceous ductile deformation was followed closely by granite plutonism and gold mineralization. The main pulse of gold mineralization is temporally and spatially associated with the Cretaceous granitic dikes and plutons and occurred during regional uplift and extension.

IMAP↗
USGS1995

The biogeochemistry of wetlands in the San Luis Valley, Colorado: The effects of acid drainage from natural and mine sources

The Summitville Mine, located near the old mining town of Summitville in Rio Grande County, Colorado, operated between July 1986 and December 1992 as a large-tonnage open-pit heap-leach gold mine. During its 6 years of existence the trace metal levels in drainage water from the mine site were elevated over historical (pre-1986) levels (Moran and Wentz, 1974) due to input from three sources—heap leach water, seeps that occur throughout the mine workings, and an increase in the metal load of water coming from the old Reynolds Adit. Mine-drainage waters flow into Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the San Luis Valley. The increase in the trace metal burden of the Alamosa River watershed is of concern to farmers, land owners, and Federal and State wildlife agencies. The information presented here is largely abstracted from reports previously published (Balistrieri and others, 1995; Gough and others, 1995).

Colorado↗
USGS1985

The occurrence of extractable elements in soils from the northern Great Plains

The modes of occurrence of extractable elements from 21 A and C horizon samples of uncultivated soils were examined using R-mode factor analysis. The extractants (DTPA, EDTA, HCl, hydroquinone, magnesium nitrate, and ammonium oxalate) cover a wide range of chemical attack. Four major elements (Ca, K, Mg, and Na) and eight trace elements (Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn) were determined in each extractant solution. A variety of chemical, mineralogical, and physical variables were also determined on each sample. Four varimax factors (clay, organic, Fe and Mn oxides, and soluble-Na) accounted for 74.2% of the total variance of the 90 variables for the A horizon. Seven varimax factors (Fe and Mn oxides, clay, CEC, soluble-Na, organic, Fe and Mn, and plagioclase) accounted for 77.2% of the total variance of the 79 variables for the C horizon. A and C horizon extractable trace elements are most generally related to Fe and Mn oxides, as indicated by loadings on the Fe and Mn oxide factor for both the A and C horizons. Each extractant generally operates on different modes of occurrence of an element in soil. For example, substantial differences occur between the HCl-, oxalate-, and hydroquinone-extractable trace elements. However, the modes of occurrence for trace elements removed by DTPA and EDTA were very similar, suggesting strong relationships between elements dissolved by these two extractants. The modes of occurrence for each individual major element are similar with each of the six extractants. A horizon Ca and Mg, and C horizon K and Mg are strongly related to a clay factor. C horizon Ca and A horizon K are strongly related to the CEC and organic factors, respectively. Both A and C horizon extractable Na are very strongly related to the soluble-Na factor. These results suggest that extractable major elements are water-soluble and are associated with the constituents that are responsible for that factor. Consequently, strong relationships should occur for any individual major element dissolved by any pair of extractants.

northern Great Plains↗