Water-Quality Study of the Cheney Reservoir Watershed, South-Central Kansas
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Geology topics
Publications and source records attributed to Larry M. Pope.
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About 283,000 pounds of atrazine are applied annually in the 1,100-square-mile Delaware River basin. Of this amount, an annual average of 3,500 pounds runs off into Perry Lake, a public-water supply source and main reservoir in the basin. About 90 percent of the atrazine that runs off to streams occurs between May and July. However, annual average concentrations did not exceed the maximum contaminant level in water from any of 10 stream sites or the outflow of Perry Lake for either the 1993 or 1994 crop years.
Since about 1960, atrazine has been used as an effective pre- and postemergent herbicide in the production of corn and grain sorghum. Atrazine is a triazine-class herbicide and was the most frequently detected herbicide in surface water of the lower Kansas River Basin of southeast Nebraska and northeast Kansas (Stamer and Zelt, 1994). Approximately 95 percent of the atrazine applied in the United States is used in corn and grain-sorghum production, predominately in the Mississippi River Basin where about 82 percent of the Nation's corn acreage is planted (CIBA-GEIGY Corp., 1992). Until recent changes in product labeling, atrazine commonly was applied at relatively high rates to control weeds around commercial and industrial areas and along railroad right-of-ways. Crop yields have increased during the last 40 years due in part to the use of herbicides in reducing weed growth and competition for moisture and nutrients. However, concern on the part of water suppliers, health officials, and the public also has increased regarding the safe and responsible use of herbicides. One issue is whether the widespread use of atrazine may pose a potential threat to public-water supplies in areas where the herbicide is used because of its ability to easily dissolve in water and its possible effects on the health of humans and aquatic life.
Inflow and outflow to a dry-pond detention basin in Topeka, Kansas, were monitored for 19 storms during a 14-month period. Samples of runoff were collected automatically at two inflow and one outflow locations. Inflow and outflow constituent loads were computed with subsequent computation of load-detention efficiencies. Three constituents (dissolved solids, ammonia plus organic nitrogen, and total organic carbon) had negative (larger loads out than in) median detention efficiencies (-78.5 percent, -9.0 percent, and -3.0 percent, respectively). Median detention efficiencies for the other constituents were: suspended solids (2.5 percent), chemical oxygen demand (15.5 percent), nitrite plus nitrate nitrogen (20.0 percent), ammonia nitrogen (69.0 percent), total phosphorus (18.5 percent), dissolved phosphorus (0.0 percent), total lead (66.0 percent), and total zinc (65.0 percent).
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Overland runoff from urban areas can cause concentrations of some water-quality constituents in local receiving streams to increase. The U.S. Geological Survey in cooperation with the Kansas Department of Health and Environment investigated the water-quality characteristics of streams draining Topeka, Kansas, and adjacent parts of the Shunganunga Creek basin from October 1979 through November 1981. The purpose of this investigation was to provide the data and interpretation necessary to determine the effects of runoff from urban areas on the water-quality characteristics of receiving streams. Water-quality characteristics for three streamflow conditions were determined: (1) dry-weather streamflow--a combination of base flow and point-source contributions, (2) storm streamflow--mainly provided by overland runoff from storms, and (3) snowmelt streamflow- mainly provided by overland runoff from snowmelt. Median concentrations of trace metals and nutrients were larger in storm streamflow than in dry-weather streamflow. Median concentrations of total lead and zinc were largest in storm streamflow from the more urban basins. Regression equations were developed to estimate median concentrations of total lead and zinc in storm streamflow from the percentage of drainage area in residential plus commercial land-use areas (correlation coefficients were 0.98 for total lead and 0.88 for total zinc); and from street density in lane miles per square mile (correlation coefficients were 0.89 for total lead and 0.84 for total zinc). Median concentrations of dissolved nitrite plus nitrate nitrogen and total phosphorus averaged, respectively, 76-percent and 70-percent larger during storm streamflow than during dry-weather streamflow and were largest in storm streamflow from the more agricultural basins. Median concentrations of dissolved sodium, chloride, and solids in snowmelt streamflow at all study sites averaged 218-percent larger for dissolved sodium, 296-percent larger for dissolved chloride, and 71-percent larger for dissolved solids relative to median concentrations in dry-weather streamflow. Regression equations also were developed to estimate median concentrations of dissolved sodium, chloride, and solids in snowmelt streamflow from the summation of percentages of the drainage area in residential, commercial, and industrial land-use areas (correlation coefficients were 0.97 for each of the three relationships) and from street density in lane miles per square mile (correlation coefficients were 0.93 for dissolved sodium and 0.94 for both dissolved chloride and dissolved solids). Multiple-correlation and regression analysis relating storm-runoff volumes and average constituent concentrations to land-use and storm characteristics produced significant relations (0.05 level of significance) for storm-runoff volume (0.81 coefficient of determination), total lead (0.71 coefficient of determination), total zinc (0.50 coefficient of determination), and suspended sediment (0.58 coefficient of determination).
Quality-of-water data, collected October 21-23, 1980, and a statistical summary are presented for 42 coal-mined strip pits in Crawford and Cherokee Counties, Southeastern Kansas. The statistical summary includes minimum and maximum observed values , mean, and standard deviation. Simple linear regression equations relating specific conductance, dissolved solids, and acidity to concentrations of dissolved solids, sulfate, calcium, and magnesium, potassium, aluminum, and iron are also presented. (USGS)