Geology topics

L.J. Puckett

Publications and source records attributed to L.J. Puckett.

7 recordsLinked to original sources

USGS2008

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality↗

USGS2005

Transport and fate of nitrate and pesticides: Hydrogeology and riparian zone processes

There is continuing concern over potential impacts of widespread application of nutrients and pesticides on ground- and surface-water quality. Transport and fate of nitrate and pesticides were investigated in a shallow aquifer and adjacent stream, Cow Castle Creek, in Orangeburg County, South Carolina. Pesticide and pesticide degradate concentrations were detected in ground water with greatest frequency and largest concentrations directly beneath and downgradient from the corn (Zea mays L.) field where they were applied. In almost all samples in which they were detected, concentrations of pesticide degradates greatly exceeded those of parent compounds, and were still present in ground waters that were recharged during the previous 18 yr. The absence of both parent and degradate compounds in samples collected from deeper in the aquifer suggests that this persistence is limited or that the ground water had recharged before use of the pesticide. Concentrations of NO3- in ground water decreased with increasing depth and age, but denitrification was not a dominant controlling factor. Hydrologic and chemical data indicated that ground water discharges to the creek and chemical exchange takes place within the upper 0.7 m of the streambed. Ground water had its greatest influence on surface-water chemistry during low-flow periods, causing a decrease in concentrations of Cl-, NO3-, pesticides, and pesticide degradates. Conversely, shallow subsurface drainage dominates stream chemistry during high-flow periods, increasing stream concentrations of Cl-, NO3-, pesticides, and pesticide degradates. These results point out the importance of understanding the hydrogeologic setting when investigating transport and fate of contaminants in ground water and surface water. ?? ASA, CSSA, SSSA.

Journal of Environmental Quality↗

USGS2004

Hydrogeologic controls on the transport and fate of nitrate in ground water beneath riparian buffer zones: Results from thirteen studies across the United States

During the last two decades there has been growing interest in the capacity of riparian buffer zones to remove nitrate from ground waters moving through them. Riparian zone sediments often contain organic carbon, which favors formation of reducing conditions that can lead to removal of nitrate through denitrification. Over the past decade the National Water Quality Assessment (NAWQA) Program has investigated the transport and fate of nitrate in ground and surface waters in study areas across the United States. In these studies riparian zone efficiency in removing nitrate varied widely as a result of variations in hydrogeologic factors. These factors include (1) denitrification in the up-gradient aquifer due to the presence of organic carbon or other electron donors, (2) long residence times (>50 years) along ground-water flow paths allowing even slow reactions to completely remove nitrate, (3) dilution of nitrate enriched waters with older water having little nitrate, (4) bypassing of riparian zones due to extensive use of drains and ditches, and (5) movement of ground water along deep flow paths below reducing zones. By developing a better understanding of the hydrogeologic settings in which riparian buffer zones are likely to be inefficient we can develop improved nutrient management plans.

Water Science and Technology↗

USGS1997

Ground-water age dating and other tools used to assess land-use effects on water quality

A relatively new method for age dating recent ground water along with other investigative tools improve our understanding of land-use effects on the water quality in a surficial aquifer and adjacent streams in the Red River of the North Basin: Ground water commonly takes more than 20 years to reach depths in the surficial aquifer where it is withdrawn for use. Water withdrawn from most drinking-water wells was recharged through land areas greater than 1 mile upgradient. Because of these long travel times and distances, land-management practices on the land and aquifer-protection strategies may take as much as 50 years to produce measurable improvement in water quality. The amount of fertilizer and some herbicides used to enhance crop growth in this study area can be related to the distribution and trends of nitrate and herbicides found in the surficial aquifer.

Red River of the North Basin↗

USGS1991

Spatial variability and collector requirements for sampling throughfall volume and chemistry under a mixed-hardwood canopy

Ion concentrations were generally less variable within storms compared with net ion input data. Concentrations and net inputs of some ions were consistently less variable than others; for example, Ca2+, NO3-, and SO42- were less variable than NH4 + and K+. These patterns of variability were consistent in comparisons both within and among storms. The relatively low variability of NO3- and SO42- is probably due to dry deposition of these ions as anthropogenic pollutants, while the low variability of Ca2+ is the result of deposition in windblown soil particles. The high variability of NH4+ and K+ is probably the result of biological processes. Ammonium is strongly retained by the canopy, and K+ is readily leached from it. Retention by, and leaching from, the canopy can induce spatial variability as a result of spatial heterogeneity in the biota. Throughfall volume also displayed low variability within and among events, requiring an average of 11 collectors to estimate the mean within 10% at the 95% confidence level. -from Author

Canadian Journal of Forest Research↗

USGS1990

Estimates of ion sources in deciduous and coniferous throughfall

Estimates of external and internal sources of ions in net througfall deposition were derived for a deciduous and coniferous canopy by use of multiple regression. The external source component appears to be dominated by dry deposition of Ca 2+ , SO 2 and NO 3 − during dormant and growing seasons for the two canopy types. Increases in the leaching rates of K + and Mg 2+ during the growing season reflect the presence of leaves in the deciduous canopy and increased physiological activity in both canopies. Internal leaching rates for SO 4 2− doubled during the growing season presumably caused by increased physiological activity and uptake of SO 2 through stomates. Net deposition of SO 4 2− in throughfall during the growing season appears highly dependent on stomatal uptake of SO 2 . Estimates of SO 2 deposition velocities were 0.06 cm s −1 and 0.13 cm s −1 for the deciduous and coniferous canopies, respectively, during the dormant seasons, and 0.30 cm s −1 and 0.43 cm s −1 for the deciduous and coniferous canopies, respectively, during the growing season. For the ions of major interest with respect to ecosystem effects, namely H + , NO 3 − and SO 4 2− , precipitation inputs generally outweighed estimates of dry deposition input. However, net throughfall deposition of NO 3 − and SO 4 2− accounted for 20–47 and 34–50 per cent, respectively, of total deposition of those ions. Error estimates of ion sources were at least 50–100 per cent and the method is subject to several assumptions and limitations.

Virginia↗

USGS1982

Acid rain, air pollution, and tree growth in southeastern New York

Whether dendroecological analyses could be used to detect changes in the relationship of tree growth to climate that might have resulted from chronic exposure to components of the acid rain-air pollution complex was determined. Tree-ring indices of white pine ( Pinus strobus L.), eastern hemlock ( Tsuga canadensis (L.) Cart.), pitch pine ( Pinus rigida Mill.), and chestnut oak ( Quercus prinus L.) were regressed against orthogonally transformed values of temperature and precipitation in order to derive a response-function relationship. Results of the regression analyses for three time periods, 1901–1920, 1926–1945, and 1954–1973 suggest that the relationship of tree growth to climate has been altered. Statistical tests of the temperature and precipitation data suggest that this change was nonclimatic. Temporally, the shift in growth response appears to correspond with the suspected increase in acid rain and air pollution in the Shawangunk Mountain area of southeastern New York in the early 1950's. This change could be the result of physiological stress induced by components of the acid rain-air pollution complex, causing climatic conditions to be more limiting to tree growth.

New York↗