Geology topics

L. Shang

Publications and source records attributed to L. Shang.

2 recordsLinked to original sources

USGS2009

Determination of diffusion coefficients of hydrogen in fused silica between 296 and 523 K by Raman spectroscopy and application of fused silica capillaries in studying redox reactions

Diffusion coefficients ( D ) of hydrogen in fused silica capillaries (FSC) were determined between 296 and 523 K by Raman spectroscopy using CO 2 as an internal standard. FSC capsules (3.25 × 10 −4 m OD, 9.9 × 10 −5 m ID, and ∼0.01 m long) containing CO 2 and H 2 were prepared and the initial relative concentrations of hydrogen in these capsules were derived from the Raman peak-height ratios between H 2 (near 587 cm −1 ) and CO 2 (near 1387 cm −1 ). The sample capsules were then heated at a fixed temperature ( T ) at one atmosphere to let H 2 diffuse out of the capsule, and the changes of hydrogen concentration were monitored by Raman spectroscopy after quench. This process was repeated using different heating durations at 296 (room T ), 323, 375, 430, 473, and 523 K; the same sample capsule was used repeatedly at each temperature. The values of D (in m 2 s −1 ) in FSC were obtained by fitting the observed changes of hydrogen concentration in the FSC capsule to an equation based on Fick’s law. Our D values are in good agreement with the more recent of the two previously reported experimental data sets, and both can be represented by: ln D = - ( 16.471 ± 0.035 ) - 44589 ± 139 RT ( R 2 = 0.99991 ) "> lnD=-(16.471±0.035)-44589±139RT(R2=0.99991) where R is the gas constant (8.3145 J/mol K), T in Kelvin, and errors at 1 σ level. The slope corresponds to an activation energy of 44.59 ± 0.14 kJ/mol. The D in FSC determined at 296 K is about an order of magnitude higher than that in platinum at 723 K, indicating that FSC is a suitable membrane for hydrogen at temperature between 673 K and room temperature, and has a great potential for studying redox reactions at these temperatures, especially for systems containing organic material and/or sulphur.

Geochimica et Cosmochimica Acta↗

USGS2008

Containment of fluid samples in the hydrothermal diamond-anvil cell without the use of metal gaskets: Performance and advantages for in situ analysis

Metal gaskets (Re, Ir, Inconel, or stainless steel) normally used to contain fluid samples in the hydrothermal diamond-anvil cell (HDAC) are sometimes undesirable due to possible contamination and to gasket deformation at high pressures and temperatures resulting in nonisochoric behavior. Furthermore, in x-ray spectroscopic experiments, metal gaskets may attenuate the incident x-ray beam and emitted fluorescence x-rays, and the interaction of scattered radiation with the gasket may produce fluorescence that interferes with the x-ray spectrum of the sample. New arrangements and procedures were tested for the operation of the HDAC without using the metal gaskets. Distilled, de-ionized water was loaded into the sample chamber, a laser-milled recess 300 ??m in diameter and ???50 ??m deep centered in the 1.0 mm face of the lower diamond anvil, and sealed by pressing the top diamond anvil face directly against the lower one without a metal gasket in between. A maximum sample pressure of 202 MPa at 617 ??C was maintained for a duration of 10 min without evidence of leakage. A small change in fluid density was observed in one experiment where the sample was held at 266 MPa at 708 ??C for 10 min. The gasketless HDAC was also employed in x-ray absorption spectroscopy experiments, where, in addition to the sample chamber in the lower diamond, two grooves were milled at a 90?? angle to each other around the sample chamber to minimize the attenuation of incident and fluorescent x rays. With a minimum distance between the sample chamber and the grooves of 80 ??m, a pressure of 76 MPa at 500 ??C was maintained for 2 h with no change in the original fluid density. ?? 2008 American Institute of Physics.

Review of Scientific Instruments↗