Geology topics

Kimberly R. Beisner

Publications and source records attributed to Kimberly R. Beisner.

35 records · Page 2Linked to original sources

USGS2020

Rethinking groundwater flow on the South Rim of the Grand Canyon, USA: Characterizing recharge sources and flow paths with environmental tracers

In the arid landscape south of the Grand Canyon, natural springs and seeps are a critical resource for endemic species and Native American tribes. Groundwater is potentially threatened by expanding populations, visitations, and mineral extraction activities. Environmental tracers including noble gases, stable isotopes of hydrogen and oxygen in water, tritium, and carbon-14 were used to characterize recharge sources and flow paths in South Rim aquifers. Results confirm the regional Redwall-Muav Aquifer as the primary groundwater source to springs. However, a second local recharge source is required to explain the detection of tritium. Two probable sources are identified as: low-elevation infiltration of surface run-off with warm noble gas recharge temperatures, high excess air, and relatively low fractions of winter recharge, and high-elevation plateau recharge with cool recharge temperatures, low excess air, and fraction of winter recharge of ~ 1. Previous investigators have linked spring occurrence with regional faults and fractures. We show such features are also the likely control chemical mixing between the regional and local groundwater sources, the transport of deeply sourced and local recharge fluids, groundwater age, and thus the relative vulnerability of groundwater to depletion and contamination. The new conceptual model of groundwater sources and flow paths suggest many South Rim springs may respond on the order of 10s to 100s of years to groundwater depletion and contamination, even though the majority of groundwater flow is along longer flow paths with longer lag times. The magnitude of response to short term changes in the flow system remains unclear.

Arizona↗

USGS2020

Critical evaluation of stable isotope mixing end-members for estimating groundwater recharge sources: Case study from the South Rim of the Grand Canyon, Arizona, USA

Springs and groundwater seeps along the South Rim of the Grand Canyon serve an important function for the region’s ecosystems, residents (both human and wild animal), and economy. However, these springs and seeps are potentially vulnerable to contamination, increased groundwater extraction, or reduced recharge due to climate change. Protection of South Rim groundwater resources requires improved understanding of the regional groundwater system. In this study, statistical methods are used to investigate δ2H and δ18O in precipitation, surface water, and groundwater. A mixing model for δ18O is developed using statistically distinct seasonal end-members represented by modeled winter (Nov-Apr.) precipitation and summer (May-Oct.) surface water run-off. The calculated fraction of winter recharge (Fwin) indicates that South Rim groundwater is primarily sourced from snow-melt and winter rains with an average Fwin of 0.97 ± 0.09. Groundwater sourced from the highest elevations of the study area are more depleted than the winter end-member suggesting values of Fwin are overestimated or a meaningful portion of recharge occurs at lower elevations. Lower elevation recharge from the Coconino Plateau is supported by consistent spatial trends in δ2H and δ18O with respect to longitude, Fwin values less than 0.9 for 9 of the 50 samples, and age tracer data indicating young groundwater discharging from springs which is distinct from old groundwater observed in the regional flow system. These results suggest a new conceptual model is needed to account for recharge sources from low elevation and summer precipitation. Results imply resource managers need to reconsider current land-use and water management practices on the South Rim to protect future water quantity and quality.

Arizona↗

USGS2020

Geochemical characterization of groundwater evolution south of Grand Canyon, Arizona (USA)

Better characterization of the geochemical evolution of groundwater south of Grand Canyon, Arizona (USA), is needed to understand natural conditions and assess potential effects from breccia-pipe uranium mining in the region. Geochemical signatures of groundwater at 28 sampling locations were evaluated; baseline concentrations for select trace elements (As, B, Ba, Cr, Li, Mo, Rb, Se, Sr, Th, Tl, U, V) were established, and anomalous chemistry characteristics were identified. Concentrations at some groundwater sites exceeded the USEPA drinking water standard for As of 10 μg/L (Red Canyon, Miners, JT, Havasu, and Warm Springs) and U of 30 μg/L (Salt Creek Spring). Four springs from the study area (Blue, Havasu, Fern, and Warm Springs) had unique chemistry, which may indicate a deep flow path or potential contribution of fluids from lower in the crust. Other springs in the study area were distinguished by major anion water type: sulfate, bicarbonate, and a mixture of the two. Water type distinctions were somewhat spatially segregated, with sulfate type present on the western side of the study area, bicarbonate type on the eastern side, and a mixture of the two interspersed between the endmember sites. Sulfate-type water from this study area had low strontium isotopic ratio (87Sr/86Sr) values. The location of spring discharge within single drainages of the Grand Canyon may influence chemistry, as groundwater discharging from bedrock was altered after flowing through alluvial material. Geochemical analysis of groundwater in Grand Canyon indicates the importance of continued monitoring and better understanding of short-term chemical fluctuations.

Arizona↗

USGS2019

Characterization and load estimation of polychlorinated biphenyls (PCBs) from selected Rio Grande tributary stormwater channels in the Albuquerque urbanized area, New Mexico, 2017–18

In cooperation with the New Mexico County of Bernalillo, the U.S. Geological Survey characterized potential polychlorinated biphenyl (PCB) concentration and estimated loading into the Rio Grande from watersheds that are under the county’s jurisdiction. Water and sediment samples were collected in 2017–18 from six sites within four stormwater drainage basins in the Albuquerque, New Mexico, urbanized area for the analysis of PCB congeners and other water-quality constituents during dry and wet seasons. Also, the rainfall-runoff model Arid Lands Hydrologic Model (AHYMO) was used to estimate stormwater discharge at the two sample collection sites not affected by pump station operation. Along with the PCB analysis, the discharge data were used to estimate total PCB stormflow event loads for eight events in these urban Rio Grande tributaries. PCBs were detected in 34 of 36 water samples at concentrations as high as 65.8 nanograms per liter and in 12 of 13 sediment samples at concentrations as high as 163,000 nanograms per kilogram dry weight. Six of the 36 water samples exceeded the New Mexico surface-water quality standard for protection of wildlife habitat and aquatic life of 14 nanograms per liter for PCBs. None of the water samples exceeded the U.S. Environmental Protection Agency’s National Pollutant Discharge Elimination System permit level limit of 200 nanograms per liter for PCBs in stormwater systems discharging into the Rio Grande. PCB concentrations in water samples in this study were not linearly related to antecedent precipitation or measured water-quality parameters, but PCB concentrations had a statistically significant positive Kendall’s tau correlation with total suspended solids for water samples and with total organic carbon for sediment samples. The PCB congener profiles indicate that sources to stormwater drainage basins in Bernalillo County originate both from legacy sources, such as Aroclors (for example, in landfills and old building materials), and from current-use sources, such as yellow pigments (for example, in printed materials and packaging in urban litter or refuse). Total PCB stormflow event loads were calculated with average potential minimum and maximum event loads of 0.73 and 4.32 milligrams per storm event, respectively, at the Adobe Acres pump station site and 56.78 and 315.13 milligrams per storm event at the Sanchez Farms inflow at Albuquerque, N. Mex., site.

New Mexico↗

USGS2018

Brackish groundwater and its potential as a resource in the southwestern United States

Secure, reliable, and sustainable water resources are fundamental to food production, energy independence, and the health of humans and ecosystems. But the large-scale development of fresh groundwater resources has stressed aquifers in some areas, causing declines in the amount of groundwater in storage and decreases in discharge to surface-water bodies like rivers and springs (Reilly and others, 2008). In some parts of the southwestern United States, the water supply is not adequate to meet demand without substantial effects on groundwater storage or surface discharge, and severe drought intensifies the stresses affecting water resources. In support of the national census of water resources, the U.S. Geological Survey (USGS) completed the national brackish groundwater assessment to provide information about brackish groundwater as a potential resource to augment or replace freshwater supplies (Stanton and others, 2017). The objectives of the brackish groundwater assessment were to consolidate available data into a comprehensive database of brackish groundwater resources in the United States and to produce a summary report about the distribution, physical and chemical characteristics, and use of brackish groundwater. This fact sheet summarizes the occurrence of brackish groundwater and factors affecting its usability in the southwestern United States (specifically the Southwest Basins region) reported for the national study. The map below (fig. 1) summarizes the brackish zones for the five largest principal aquifers within the southwestern United States, along with groundwater resources in the remaining part of the region (Reilly and others, 2008).

Fact Sheet↗

USGS2018

Assessment of geochemical and hydrologic conditions near Old Yuma Mine in Saguaro National Park, Arizona, 2014–17

The Old Yuma Mine is an abandoned copper, lead, zinc, silver, and gold mine located within the boundaries of Saguaro National Park, Tucson Mountain District, Arizona. This study analyzed the geochemistry of sediments associated with the Old Yuma Mine and assessed hydrologic and geochemical conditions of groundwater to evaluate the area surrounding the Old Yuma Mine. The purpose of the study was to establish the geochemical signature of material associated with the Old Yuma Mine and to compare it with background material and groundwater in the area. Few groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) drinking water standards. Concentrations of several elements were elevated in the waste rock and mine tailings compared with concentrations in sediments collected in background areas. A subset of 15 sediment samples was leached to simulate precipitation interacting with the solid material. Analysis of leachate samples compared to groundwater samples suggests that groundwater samples collected in this study are distinct from leachate samples associated with mining related material. Results suggest that at this time groundwater samples collected during this investigation are not influenced by elements leached from Old Yuma Mine materials.

Arizona↗

USGS2018

Geochemical characterization and modeling of regional groundwater contributing to the Verde River, Arizona between Mormon Pocket and the USGS Clarkdale gage

We use synoptic surveys of stream discharge, stable isotopes, and dissolved noble gases to identify the source of groundwater discharge to the Verde River in central Arizona. The Verde River more than doubles in discharge in Mormon Pocket over a 1.4 km distance that includes three discrete locations of visible spring input to the river and other diffuse groundwater inputs. A detailed study of the Verde River between Mormon Pocket and the USGS Clarkdale Gage was conducted to better constrain the location of groundwater inputs, the geochemical signature and constrain the source of groundwater input. Discharge, water quality parameters (temperature, pH, specific conductance, and dissolved oxygen), stable isotopes (δ18O and δ2H), noble gases (He, Ne, Ar, Kr and Xe), and radon (222Rn) from river water were collected. Groundwater samples from springs and wells in the area were collected and analyzed for tracers measured in the stream along with some additional analytes (major ions, strontium isotopes (87Sr/86Sr), carbon-14, δ13C, and tritium). Groundwater isotopic signature is consistent with a regional groundwater source. Groundwater springs discharging to the river have a depleted stable isotopic signature indicating recharge source up to 1000 m higher than the discharge location in the Verde River and are significantly fresher than stream water. Spring water has a radiocarbon age of several thousand years and some areas have tritium less than the laboratory reporting level or low concentrations of tritium (1.5 TU). The strontium isotopes indicate groundwater interaction with tertiary volcanic rock and Paleozoic sedimentary rocks. Along the study reach with distance downstream, Verde stream water chemistry shows increased 222Rn, freshening, increased 4He, and isotopic depletion with distance downstream. We estimated total groundwater discharge by inverting a stream transport model against 222Rn and discharge measured in the stream. The salinity, 4He, and stable isotope composition of discharging groundwater was then estimated by fitting modeled values to observed in-stream values. Estimated groundwater inflow to the stream was well within the ranges observed in springs, indicating that the main source of streamflow is deep, regional groundwater. These results show that synoptic surveys of environmental tracers in streams can be used to estimate the isotopic composition and constrain the source of groundwater discharging to streams. Our data provide direct field evidence that deep, regional groundwater discharge can be a significant source of streamflow generation in arid, topographically complex watersheds.

Arizona↗

USGS2017

Geochemical characterization of groundwater discharging from springs north of the Grand Canyon, Arizona, 2009–2016

A geochemical study was conducted on 37 springs discharging from the Toroweap Formation, Coconino Sandstone, Hermit Formation, Supai Group, and Redwall Limestone north of the Grand Canyon near areas of breccia-pipe uranium mining. Baseline concentrations were established for the elements As, B, Li, Se, SiO 2 , Sr, Tl, U, and V. Three springs exceeded U.S. Environmental Protection Agency drinking water standards: Fence Spring for arsenic, Pigeon Spring for selenium and uranium, and Willow (Hack) Spring for selenium. The majority of the spring sites had uranium values of less than 10 micrograms per liter (μg/L), but six springs discharging from all of the geologic units studied that are located stratigraphically above the Redwall Limestone had uranium values greater than 10 μg/L (Cottonwood [Tuckup], Grama, Pigeon, Rock, and Willow [Hack and Snake Gulch] Springs). The geochemical characteristics of these six springs with elevated uranium include Ca-Mg-SO 4 water type, circumneutral pH, high specific conductance, correlation and multivariate associations between U, Mo, Sr, Se, Li, and Zn, low 87 Sr/ 86 Sr, low 234 U/ 238 U activity ratios (1.34–2.31), detectable tritium, and carbon isotopic interpretation indicating they may be a mixture of modern and pre-modern waters. Similar geochemical compositions of spring waters having elevated uranium concentrations are observed at sites located both near and away from sites of uranium-mining activities in the present study. Therefore, mining does not appear to explain the presence of elevated uranium concentrations in groundwater at the six springs noted above. The elevated uranium at the six previously mentioned springs may be influenced by iron mineralization associated with mineralized breccia pipe deposits. Six springs discharging from the Coconino Sandstone (Upper Jumpup, Little, Horse, and Slide Springs) and Redwall Limestone (Kanab and Side Canyon Springs) contained water with corrected radiocarbon ages as much as 9,300 years old. Of the springs discharging water with radiocarbon age, Kanab and Side Canyon Springs contain tritium of more than 1.3 picocuries per liter (pCi/L), indicating they may contain a component of modern water recharged after 1952. Springs containing high values of tritium (greater than 5.1 pCi/L), which may suggest a significant component of modern water, include Willow (Hack), Saddle Horse, Cottonwood (Tuckup), Hotel, Bitter, Unknown, Hole in the Wall, and Hanging Springs. Fence and Rider Springs, located on the eastern end of the study area near the Colorado River, have distinctly different geochemical compositions compared to the other springs of the study. Additionally, water from Fence Spring has the highest 87 Sr/ 86 Sr for samples analyzed from this study with a value greater than those known in sedimentary rocks from the region. Strontium isotope data likely indicate that water discharging at Fence Spring has interacted with Precambrian basement rocks. Rider Spring had the most depleted values of stable O and H isotopes indicating that recharge, if recent, occurred at higher elevations or was recharged during earlier, cooler-climate conditions.

Arizona↗

USGS2016

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234 U/ 238 U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.

Arizona↗

USGS2016

Analysis of stable isotope ratios (δ 18 O and δ 2 H) in precipitation of the Verde River watershed, Arizona 2003 through 2014

Stable isotope delta values (δ 18 O and δ 2 H) of precipitation can vary with elevation, and quantification of the precipitation elevation gradient can be used to predict recharge elevation within a watershed. Precipitation samples were analyzed for stable isotope delta values between 2003 and 2014 from the Verde River watershed of north-central Arizona. Results indicate a significant decrease in summer isotopic values overtime at 3,100-, 4,100-, 6,100-, 7,100-, and 8,100-feet elevation. The updated local meteoric water line for the area is δ 2 H = 7.11 δ 18 O + 3.40. Equations to predict stable isotopic values based on elevation were updated from previous publications in Blasch and others (2006), Blasch and Bryson (2007), and Bryson and others (2007). New equations were separated for samples from the Camp Verde to Flagstaff transect and the Prescott to Chino Valley transect. For the Camp Verde to Flagstaff transect, the new equations for winter precipitation are δ 18 O = -0.0004z − 8.87 and δ 2 H = -0.0029z − 59.8 (where z represents elevation in feet) and the summer precipitation equations were not statistically significant. For the Prescott to Chino Valley transect, the new equations for summer precipitation are δ 18 O = -0.0005z − 3.22 and δ 2 H = -0.0022z − 27.9; the winter precipitation equations were not statistically significant and, notably, stable isotope values were similar across all elevations. Interpretation of elevation of recharge contributing to surface and groundwaters in the Verde River watershed using the updated equations for the Camp Verde to Flagstaff transect will give lower elevation values compared with interpretations presented in the previous studies. For waters in the Prescott and Chino Valley area, more information is needed to understand local controls on stable isotope values related to elevation.

Arizona↗

USGS2015

Hydrology of the middle San Pedro area, southeastern Arizona

In the middle San Pedro Watershed in southeastern Arizona, groundwater is the primary source of water supply for municipal, domestic, industrial, and agricultural use. The watershed comprises two smaller subareas, the Benson subarea and the Narrows-Redington subarea. Early 21st century projections for heavy population growth in the watershed have not yet become a reality, but increased groundwater withdrawals could have undesired consequences - such as decreased base flow to the San Pedro River, and groundwater-level declines - that would lead to the need to deepen existing wells. This report describes the hydrology, hydrochemistry, water quality, and development of a groundwater budget for the middle San Pedro Watershed, focusing primarily on the elements of groundwater movement that could be most useful for the development of a groundwater model Precipitation data from Tombstone, Arizona, and base flow at the stream-gaging station on the San Pedro River at Charleston both show relatively dry periods during the 1960s through the mid-1980s and in the mid-1990s to 2009, and wetter periods from the mid-1980s through the mid-1990s. Water levels in four out of five wells near the mountain fronts show cyclical patterns of recharge, with rates of recharge greatest in the early 1980s through the mid-1990s. Three wells near the San Pedro River recorded their lowest levels during the 1950s to the mid-1960s. The water-level record from one well, completed in the confined part of the coarse-grained lower basin fill, showed a decline of approximately 21 meters. Annual flow of the San Pedro River, measured at the Charleston and Redington gages, has decreased since the 1940s. The median annual streamflow and base flow at the gaging station on the river near Tombstone has decreased by 50 percent between the periods 1968–1986 and 1997–2009. Estimates of streamflow infiltration along the San Pedro River during 1914–2009 have decreased 44 percent, with the largest decreases in the months June–October in the Benson subarea. In the Narrows-Redington subarea, streamflow infiltration has decreased about 65 percent during 1914–2009. The average annual outflow (27.6 hm 3 /year [cubic hectometers per year]) from the Benson subarea aquifer for water years 2001 through 2009 exceeded the inflows (20.0 hm 3 / yr) by 7.60 hm 3 /yr. In the Narrows-Redington subarea for the same period, the average annual outflow (15.7 hm 3 /yr) from the aquifer system exceeded the inflows (13.8 hm 3 /yr) by nearly 2 hm 3 /yr. The largest withdrawals of groundwater in both subareas are for irrigation; these withdrawals peaked in 1973 and have been steadily decreasing since then. Recharge from streamflow infiltration exceeded recharge from the mountain-front and from ephemeral channels in the Benson subarea. In the Narrows-Redington subarea, however, recharge from mountain-front and ephemeral channel recharge exceeded recharge from streamflow infiltration. Evapotranspiration by phreatophytes accounts for the largest outflow of groundwater for both subareas—78 percent of the outflow in the Narrows-Redington subarea and 62 percent of the outflow in the Benson subarea. Precipitation, surface-water, and groundwater chemistry and isotope data indicated the relative age and residence time of groundwater, the amount of interaction between geologic sources and groundwater, and how recharge elevation and season were related to the presence of modern water. The bedrock aquifer receives modern recharge (

Arizona↗

USGS2015

Initial characterization of the groundwater system near the Lower Colorado Water Supply Project, Imperial Valley, California

In 2009, the U.S. Geological Survey, in cooperation with the city of Needles, began a study of the hydrogeology along the All-American Canal, which conveys water from the Colorado River to the Imperial Valley. The focus of this study was to gain a better understanding of the effect of lining the All-American Canal, and other management actions, on future total dissolved solids concentrations in groundwater pumped by Lower Colorado Water Supply Project wells that is delivered to the All-American Canal. The study included the compilation and evaluation of previously published hydrogeologic and geochemical information, establishment of a groundwater-elevation and groundwater-quality monitoring network, results of monitoring groundwater elevations and groundwater quality from 2009 to 2011, site-specific hydrologic investigations of the Lower Colorado Water Supply Project area, examination of groundwater salinity by depth by using time-domain electromagnetic surveys, and monitoring of groundwater-storage change by using microgravity methods. Prior to the completion of the All-American Canal in 1940, groundwater in the study area flowed from east to west, and groundwater was recharged primarily by underflow from the Colorado River Valley. After construction of the All-American Canal, groundwater elevations were altered in the study area as seepage of Colorado River water from the All-American Canal and other canals became the dominant recharge source. By 2005, groundwater elevations had increased by as much as 50–70 feet along the All-American Canal. Superimposed on the east-to-west groundwater gradient was groundwater movement away from the All-American Canal to the north and, most likely, to the south into Mexico. After lining the All-American Canal, from 2007 to 2010, groundwater elevations declined as seepage from the All-American Canal decreased. Between 2005 (the last complete groundwater-elevation survey prior to lining the All-American Canal) and 2011, groundwater elevations declined 20–40 feet along the All-American Canal and as much as 40–45 feet in the vicinity of Lower Colorado Water Supply Project pumping wells. Water-quality and isotope data were used to differentiate historically recharged groundwater from groundwater more recently recharged by seepage of Colorado River surface water from the All-American Canal. Prior to the completion of the All-American Canal in 1940, groundwater in the southern part of the study area was primarily sodium-chloride/sulfate type water that had relatively low total dissolved solids concentrations (500–820 milligrams per liter). During 2007–11, groundwater in the southern part of the study area, near the All-American Canal, ranged from sodium-chloride type water to mixed-cation-sulfate type water that had total dissolved solids concentrations generally less than 879 milligrams per liter. The stable-isotopic signature of groundwater near the All-American Canal sampled in 2009–11 indicated inputs of Colorado River water that had been affected by evaporation, and radioactive isotopes indicated that a substantial fraction of water had been recharged recently, within the past 60 years. This contrasted with historically recharged groundwater near the All-American Canal, which had higher sodium and chloride concentrations, and lower calcium and sulfate concentrations, than recent recharge from the All-American Canal. Groundwater at a distance from the All-American Canal, in the East Mesa, Algodones Dunes, Pilot Knob Mesa, and Cargo Muchacho Mountains piedmont, was found to have higher total dissolved solids concentrations (generally greater than 1,000 milligrams per liter) than recently recharged groundwater near the All-American Canal. Time-domain electromagnetic data indicated that low-salinity groundwater was present down to about 377 feet below land surface near the All-American Canal; groundwater salinity at depth increased with distance north from the All-American Canal. Groundwater several miles or more from the canal also did not contain tritium and had a residence time on the order of thousands to tens of thousands of years. The groundwater in the piedmont of the Cargo Muchacho Mountains had a distinctly light stable-isotopic signature indicative of recharge by runoff from local precipitation, whereas the stable isotopic signature of groundwater in the East Mesa and the Algodones Dunes indicated a mixture of local precipitation and historic Colorado River recharge sources. During and after lining the All-American Canal (2007–11), groundwater elevations in the Lower Colorado Water Supply Project area declined, while total dissolved solids concentrations remained relatively constant. The total dissolved solids concentrations in well LCWSP-2 ranged from 650 to 800 milligrams per liter during this study. Depth-specific water-quality and isotope sampling at well LCWSP-2 indicated the groundwater pumped from the deeper part of the screened interval (240–280 feet below land surface) contained a greater proportion of historical groundwater than the groundwater pumped from the shallower part of the screened interval (350–385 feet below land surface). Age-tracer data at well LCWSP-2 indicated that all depths of the screened interval had received recent recharge from seepage of Colorado River water from the All-American Canal.

California↗

USGS2014

Investigation of geochemical indicators to evaluate the connection between inland and coastal groundwater systems near Kaloko-Honokōhau National Historical Park, Hawai‘i

Kaloko-Honokōhau National Historical Park (KAHO) is a coastal sanctuary on the western side of the Island of Hawai‘i that was established in 1978 to preserve, interpret, and perpetuate traditional Native Hawaiian culture and activities. KAHO contains a variety of culturally and ecologically significant water resources and water-related habitat for species that have been declared as threatened or endangered by the U.S. Fish and Wildlife Service, or are candidate threatened or endangered species. These habitats are dependent on coastal unconfined groundwater in a freshwater-lens system. The coastal unconfined-groundwater system is recharged by local infiltration of rainfall but also may receive recharge from an inland groundwater system containing groundwater impounded to high altitudes. The area inland of and near KAHO is being rapidly urbanized and increased groundwater withdrawals from the inland impounded-groundwater system may affect habitat and water quality in KAHO, depending on the extent of connection between the coastal unconfined groundwater and inland impounded-groundwater. An investigation of the geochemistry of surface-water and groundwater samples in and near KAHO was performed to evaluate the presence or absence of a connection between the inland impounded- and coastal unconfined-groundwater systems in the area. Analyses of major ions, selected trace elements, rare-earth elements, and strontium-isotope ratio results from ocean, fishpond, anchialine pool, and groundwater samples were consistent with a linear mixing process between the inland impounded and coastal unconfined-groundwater systems. Stable isotopes of water in many samples from the coastal unconfined-groundwater system require an aggregate recharge altitude that is substantially higher than the boundary between the coastal unconfined and inland impounded systems, a further indication of a hydrologic connection between the two systems. The stable isotope composition of the freshwater component of water samples from KAHO indicates that about 25–70% of the freshwater is derived from the inland impounded system.

Hawaii↗

USGS2014

Assessment of metal and trace element contamination in water, sediment, plants, macroinvertebrates, and fish in Tavasci Marsh, Tuzigoot National Monument, Arizona

Tavasci Marsh is a large freshwater marsh within the Tuzigoot National Monument in central Arizona. It is the largest freshwater marsh in Arizona that is unconnected to the Colorado River and is designated as an Important Bird Area by the Audubon Society. The marsh has been altered significantly by previous land use and the monument’s managers are evaluating the restoration of the marsh. In light of historical mining activities located near the marsh from the first half of the 20th century, evaluations of water, sediment, plant, and aquatic biota in the marsh were conducted. The evaluations were focused on nine metals and trace elements commonly associated with mining and other anthropogenic activities (As, Cd, Cr, Cu, Hg, Ni, Pb, Se, and Zn) together with isotopic analyses to understand the presence, sources and timing of water and sediment contaminants to the marsh and the occurrence in aquatic plants, dragonfly larvae, and fish. Results of water analyses indicate that there were two distinct sources of water contributing to the marsh during the study: one from older high elevation recharge entering the marsh at Shea Spring (as well as a number of unnamed seeps and springs on the northeastern edge of the marsh) and the other from younger low elevation recharge or from Pecks Lake. Water concentrations for arsenic exceeded the U.S. Environmental Protection Agency primary drinking water standard of 10 μg/L at all sampling sites. Surface waters at Tavasci Marsh may contain conditions favorable for methylmercury production. All surficial and core sediment samples exceeded or were within sample concentration variability of at least one threshold sediment quality guideline for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn. Several sediment sites were also above or were within sample concentration variability of severe or probable effect sediment quality guidelines for As, Cd, and Cu. Three sediment cores collected in the marsh have greater metal and trace element concentrations at depth for Bi, Cd, Cu, Hg, In, Pb, Sb, Sn, Te, and Zn. Radioisotope dating indicates that the elevated metal and trace element concentrations are associated with sediments deposited before 1963. Arsenic concentration was greater in cattail roots compared with surrounding sediment at Tavasci Marsh. Concentrations of As, Ni, and Se from yellow bullhead catfish (Ameiurus natalis) in Tavasci Marsh exceeded the 75th percentile of several other regional studies. Mercury concentration in dragonfly larvae and fish from Tavasci Marsh were similar to or greater than in Tavasci Marsh sediment. Future work includes a biologic risk assessment utilizing the data collected in this study to provide the monument management with additional information for their restoration plan.

Arizona↗

USGS2012

Maps of estimated nitrate and arsenic concentrations in basin-fill aquifers of the southwestern United States

Human-health concerns and economic considerations associated with meeting drinking-water standards motivated a study of the vulnerability of basin-fill aquifers to nitrate contamination and arsenic enrichment in the southwestern United States. Statistical models were developed by using the random forest classifier algorithm to predict concentrations of nitrate and arsenic across a model grid representing about 190,600 square miles of basin-fill aquifers in parts of Arizona, California, Colorado, Nevada, New Mexico, and Utah. The statistical models, referred to as classifiers, reflect natural and human-related factors that affect aquifer vulnerability to contamination and relate nitrate and arsenic concentrations to explanatory variables representing local- and basin-scale measures of source and aquifer susceptibility conditions. Geochemical variables were not used in concentration predictions because they were not available for the entire study area. The models were calibrated to assess model accuracy on the basis of measured values. Only 2 percent of the area underlain by basin-fill aquifers in the study area was predicted to equal or exceed the U.S. Environmental Protection Agency drinking-water standard for nitrate as N (10 milligrams per liter), whereas 43 percent of the area was predicted to equal or exceed the standard for arsenic (10 micrograms per liter). Areas predicted to equal or exceed the drinking-water standard for nitrate include basins in central Arizona near Phoenix; the San Joaquin Valley, the Santa Ana Inland, and San Jacinto Basins of California; and the San Luis Valley of Colorado. Much of the area predicted to equal or exceed the drinking-water standard for arsenic is within a belt of basins along the western portion of the Basin and Range Physiographic Province that includes almost all of Nevada and parts of California and Arizona. Predicted nitrate and arsenic concentrations are substantially lower than the drinking-water standards in much of the study area-about 93 percent of the area underlain by basin-fill aquifers was less than one-half the standard for nitrate as N (5.0 milligrams per liter), and 50 percent was less than one-half the standard for arsenic (5.0 micrograms per liter). The predicted concentrations and the improved understanding of the susceptibility and vulnerability of southwestern basin-fill aquifers to nitrate contamination and arsenic enrichment can be used by water managers as a qualitative tool to assess and protect the quality of groundwater resources in the Southwest.

Arizona, California, Colorado, Idaho, Nevada, New ↗

USGS2012

Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps associated with uranium exploration and mining, Browns Hole, Utah

During August of 2008, 35 solid-phase samples were collected from abandoned uranium waste dumps, undisturbed geologic background sites, and adjacent streambeds in Browns Hole in southeastern Utah. The objectives of this sampling program were (1) to assess impacts on human health due to exposure to radium, uranium, and thorium during recreational activities on and around uranium waste dumps on Bureau of Land Management lands; (2) to compare concentrations of trace elements associated with mine waste dumps to natural background concentrations; (3) to assess the nonpoint source chemical loading potential to ephemeral and perennial watersheds from uranium waste dumps; and (4) to assess contamination from waste dumps to the local perennial stream water in Muleshoe Creek. Uranium waste dump samples were collected using solid-phase sampling protocols. Solid samples were digested and analyzed for major and trace elements. Analytical values for radium and uranium in digested samples were compared to multiple soil screening levels developed from annual dosage calculations in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act's minimum cleanup guidelines for uranium waste sites. Three occupancy durations for sites were considered: 4.6 days per year, 7.0 days per year, and 14.0 days per year. None of the sites exceeded the radium soil screening level of 96 picocuries per gram, corresponding to a 4.6 days per year exposure. Two sites exceeded the radium soil screening level of 66 picocuries per gram, corresponding to a 7.0 days per year exposure. Seven sites exceeded the radium soil screening level of 33 picocuries per gram, corresponding to a 14.0 days per year exposure. A perennial stream that flows next to the toe of a uranium waste dump was sampled, analyzed for major and trace elements, and compared with existing aquatic-life and drinking-water-quality standards. None of the water-quality standards were exceeded in the stream samples.

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USGS2010

Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps and human health hazards associated with uranium exploration and mining, Red, White, and Fry Canyons, southeastern Utah, 2007

During May, June, and July 2007, 58 solid-phase samples were collected from abandoned uranium mine waste dumps, background sites, and adjacent streambeds in Red, White, and Fry Canyons in southeastern Utah. The objectives of this sampling program were to (1) assess the nonpoint-source chemical loading potential to ephemeral and perennial drainage basins from uranium waste dumps and (2) assess potential effects on human health due to recreational activities on and around uranium waste dumps on Bureau of Land Management property. Uranium waste-dump samples were collected using solid-phase sampling protocols. After collection, solid-phase samples were homogenized and extracted in the laboratory using a leaching procedure. Filtered (0.45 micron) water samples were obtained from the field leaching procedure and were analyzed for major and trace elements at the Inductively Coupled Plasma-Mass Spectrometry Metals Analysis Laboratory at the University of Utah. A subset of the solid-phase samples also were digested with strong acids and analyzed for major ions and trace elements at the U.S. Geological Survey Geologic Division Laboratory in Denver, Colorado. For the initial ranking of chemical loading potential for uranium waste dumps, results of leachate analyses were compared with existing aquatic-life and drinking-water-quality standards. To assess potential effects on human health, solid-phase digestion values for uranium were compared to soil screening levels (SSL) computed using the computer model RESRAD 6.5 for a probable concentration of radium. One or more chemical constituents exceeded aquatic life and drinking-water-quality standards in approximately 64 percent (29/45) of the leachate samples extracted from uranium waste dumps. Most of the uranium waste dump sites with elevated trace-element concentrations in leachates were located in Red Canyon. Approximately 69 percent (31/45) of the strong acid digestible soil concentration values were greater than a calculated SSL. Uranium waste dump sites with elevated leachate and total digestible concentrations may need to be further investigated to determine the most appropriate remediation method.

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