Geology topics

Kendra J. Lynn

Publications and source records attributed to Kendra J. Lynn.

36 records · Page 2Linked to original sources

USGS2025

The progression of basaltic–rhyolitic melt storage at Yellowstone Caldera

Yellowstone Caldera is one of the largest volcanic systems on Earth, hosting three major caldera-forming eruptions in the past two million years, interspersed with periods of less explosive, smaller-volume eruptions 1 . Caldera-forming eruptions at Yellowstone are sourced by rhyolitic melts stored within the mid- to upper crust. Seismic tomography studies have suggested that a broad region of rhyolitic melt extends beneath Yellowstone Caldera, with an estimated melt volume that is one to four times greater than the eruptive volume of the largest past caldera-forming eruption, and an estimated melt fraction of 6–28 per cent 2 , 3 , 4 , 5 . Seismic velocity is strongly influenced by temperature, pressure and melt; however, magnetotelluric data are primarily sensitive to the presence of melt, making these data ideal for constraining volcanic systems. Here we utilize magnetotelluric data to model the resistivity structure of Yellowstone Caldera’s crustal magma reservoir and constrain the region’s potential for producing major volcanic eruptions. We find that rhyolitic melts are stored in segregated regions beneath the caldera with low melt fractions, indicating that the reservoirs are not eruptible. Typically, these regions have melt volumes equivalent to small-volume post-caldera Yellowstone eruptions. The largest region of rhyolitic melt storage, concentrated beneath northeast Yellowstone Caldera, has a storage volume similar to the eruptive volume of Yellowstone’s smallest caldera-forming eruption. We identify regions of basalt migrating from the lower crust, merging with and supplying heat to the northeast region of rhyolitic melt storage. On the basis of our analysis, we suggest that the locus of future rhyolitic volcanism has shifted to northeast Yellowstone Caldera.

Idaho, Montana, Wyoming↗

USGS2024

Considerations and perspectives on pregnancy and fieldwork

Fieldwork is integral to geoscience but can come with risks that increase for fieldworkers who are pregnant. Consultation with medical staff and completion of risk assessments are essential steps, but pregnant individuals also benefit from supportive colleagues, reasonable accommodations, and the freedom to adapt plans as pregnancy progresses.

Nature Reviews Earth and Environment↗

USGS2024

Real-time lava flow forecasting during the 2022 Mauna Loa eruption response

On November 27, 2022, Mauna Loa (Hawai‘i) erupted for the first time in 38 years, initially producing lava flows that covered the floor of its summit caldera, Moku‘āweoweo. Over the first 12 h following the summit eruption, four main fissures opened on Mauna Loa’s Northeast Rift Zone, with “fissure 3” quickly becoming the dominant source of lava flows. For the next 12 days, fissure 3 produced a 19-km-long lava flow to the north, crossing the Mauna Loa Weather Observatory access road and coming within 2.8 km of inundating the Daniel K. Inouye Highway (Saddle Road). Within 40 min of fissure 3 opening, inundation modeling efforts had begun. For the duration of the eruption, the computational fluid dynamics model Lava2d was run in real time, using flow front locations and other field observations to make sequential forecast improvements, eventually producing a set of models which accurately predicted the routing and arrival times of lava from fissure 3. These models were used to inform timing estimates of possible future inundation of the Saddle Road. As the eruption progressed, almost 4000 Lava2d models were made using high-performance computing resources, providing critical information on uncertainty in multi-week forecasts. To our knowledge, this was the first ever real-time physics-based ensemble lava flow modeling and forecasting effort. Here, we present a chronology of these real-time efforts, focusing on the successes and limitations of this approach.

Hawaii↗

USGS2024

Awakening of Maunaloa linked to melt shared from Kilauea’s mantle source

Maunaloa—the largest active volcano on Earth—erupted in 2022 after its longest known repose period (~38 years) and two decades of volcanic unrest. This eruptive hiatus at Maunaloa encompasses most of the ~35-year-long Puʻuʻōʻō eruption of neighboring Kīlauea, which ended in 2018 with a collapse of the summit caldera and an unusually voluminous (~1 km 3 ) rift eruption. A long-term pattern of such anticorrelated eruptive behavior suggests that a magmatic connection exists between these volcanoes within the asthenospheric mantle source and melting region, the lithospheric mantle, and/or the volcanic edifice. The exact nature of this connection is enigmatic. In the past, the distinct compositions of lavas from Kīlauea and Maunaloa were thought to require completely separate magma pathways from the mantle source of each volcano to the surface. Here, we use a nearly 200-yr record of lava chemistry from both volcanoes to demonstrate that melt from a shared mantle source within the Hawaiian plume may be transported alternately to Kīlauea or Maunaloa on a timescale of decades. This process led to a correlated temporal variation in 206 Pb/ 204 Pb and 87 Sr/ 86 Sr at these volcanoes since the early 19th century with each becoming more active when it received melt from the shared source. Ratios of highly over moderately incompatible trace elements (e.g., Nb/Y) at Kīlauea reached a minimum from ~2000 to 2010, which coincides with an increase in seismicity and inflation at the summit of Maunaloa. Thereafter, a reversal in Nb/Y at Kīlauea signals a decline in the degree of mantle partial melting at this volcano and suggests that melt from the shared source is now being diverted from Kīlauea to Maunaloa for the first time since the early to mid-20th century. These observations link a mantle-related shift in melt generation and transport at Kīlauea to the awakening of Maunaloa in 2002 and its eruption in 2022. Monitoring of lava chemistry is a potential tool that may be used to forecast the behavior (e.g., eruption rate and frequency) of these adjacent volcanoes on a timescale of decades. A future increase in eruptive activity at Maunaloa is likely if the temporal increase in Nb/Y continues at Kīlauea.

Hawaii↗

USGS2024

Triggering the 2022 eruption of Mauna Loa

Distinguishing periods of intermittent unrest from the run-up to eruption is a major challenge at volcanoes around the globe. Comparing multidisciplinary monitoring data with mineral chemistry that records the physical and spatio-temporal evolution of magmas fundamentally advances our ability to forecast eruptions. The recent eruption of Mauna Loa, Earth’s largest active volcano, provides a unique opportunity to differentiate unrest from run-up and improve forecasting of future eruptions. After decades of intermittent seismic and geodetic activity over 38 years of repose, Mauna Loa began erupting on 27 November 2022. Here we present a multidisciplinary synthesis that tracks the spatio-temporal evolution of precursory activity by integrating mineral and melt chemistry, fluid inclusion barometry, numerical modeling of mineral zoning, syn-eruptive gas plume measurements, the distribution and frequency of earthquake hypocenters, seismic velocity changes, and ground deformation. These diverse data indicate that the eruption occurred following a 2-month period of sustained magma intrusion from depths of 3–5 km up to 1–2 km beneath the summit caldera, providing a new model of the plumbing system at this very high threat volcano. Careful correlation of both the geochemistry and instrumental monitoring data improves our ability to distinguish unrest from the run-up to eruption by providing deeper understanding of the both the monitoring data and the magmatic system—an approach that could be applied at other volcanic systems worldwide.

Hawaii↗

USGS2024

Depths in a day - A new era of rapid-response Raman-based barometry using fluid inclusions

Rapid-response petrological monitoring is a major advance for volcano observatories, allowing them to build and validate models of plumbing systems that supply eruptions in near-real-time. The depth of magma storage has recently been identified as high-priority information for volcanic observatories, yet this information is not currently obtainable via petrological monitoring methods on timescales relevant to eruption response. Fluid inclusion barometry (using micro-thermometry or Raman spectroscopy) is a well-established petrological method to estimate magma storage depths and has been proposed to have potential as a rapid-response monitoring tool, although this has not been formally demonstrated. To address this deficiency, we performed a near-real-time rapid-response simulation for the September 2023 eruption of Kīlauea, Hawaiʻi. We show that Raman-based fluid inclusion barometry can robustly determine reservoir depths within a day of receiving samples — a transformative timescale that has not previously been achieved by petrological methods. Fluid inclusion barometry using micro-thermometric techniques has typically been limited to systems with relatively deep magma storage (>0.4 g/cm 3 or >7 km) where measurements of CO 2 density are easy and accurate because the CO 2 fluid homogenizes into the liquid phase. Improvements of the accuracy of Raman spectroscopy measurements of fluids with low CO 2 density over the past couple of decades has enabled measurements of fluid inclusions from shallower magmatic systems. However, one caveat of examining shallower systems is that the fraction of H 2 O in the fluid may be too high to reliably convert CO 2 density to pressure. To test the global applicability of rapid response fluid inclusion barometry, we compiled a global melt inclusion dataset (>4000 samples) and calculate the fluid composition at the point of vapor saturation (⁠X H 2 O⁠ ). We show that fluid inclusions in crystal-hosts from mafic compositions (<57 wt. % SiO 2 ) — likely representative of magmas recharging many volcanic systems worldwide — trap fluids with X H 2 O low enough to make fluid inclusion barometry useful at many of the world’s most active and hazardous mafic volcanic systems (e.g., Iceland, Hawaiʻi, Galápagos Islands, East African Rift, Réunion, Canary Islands, Azores, Cabo Verde).

Hawaii↗

USGS2024

Reexamining the Honolulu Volcanics: Hawai‘i's classic case of rejuvenation volcanism

Rejuvenated volcanism is a worldwide phenomenon occurring on many oceanic islands in all of the major ocean basins. This plume-related volcanism follows the main edifice-building stage after a hiatus of variable duration (e.g. 0.6–2 Myrs in Hawai'i). The Honolulu Volcanics (HV), the classic case of rejuvenated volcanism, involved monogenetic eruptions from at least 48 vent areas. Previous studies inferred these vents were aligned along 3 to 11 rifts oriented orthogonal to the propagation direction of the Hawaiian plume. HV basalts are known for having high MgO contents (greater than 10 wt %) and upper mantle xenoliths. Thus, HV magmas are assumed to be relatively primitive and to have ascended rapidly (less than 1 day) through the crust. However, new analyses of olivine cores in basalts from 24 HV vents are mostly too low in forsterite content (74–86 mol %) to be in equilibrium with mantle melts. Olivine and clinopyroxene in HV basalts commonly show reverse zoning indicating magma mixing prior to eruption. These results are inconsistent with the rapid ascent of HV magmas directly from their mantle source. Many of the HV magmas underwent storage (probably in the lower crust or uppermost mantle), crystal fractionation and magma mixing prior to eruption. New 40 Ar/ 39 Ar dates were determined for 11 HV lavas to evaluate their eruptive history. These ages, 80 to 685 ka, combined with our previous and other 40 Ar/ 39 Ar ages for HV lavas reveal long gaps (greater than 50 kyr) between some eruptions. Our comprehensive, whole-rock major and trace element database (63 XRF analyses, 57 ICPMS analyses) of basalts from 37 vents show remarkable compositional diversity with no obvious spatial pattern or temporal trends. The two most recent eruptive sequences have the greatest diversity (basanite and melilitite compositions). HV basanites show systematic trace element trends that may reflect mixing of multiple source components. The nephelinites and melilitites require a complex source history that may have involved residual accessory minerals during mantle melting and a metasomatic component that was not carbonatitic. The new ages and geochemical data show eruptions along most of the previously proposed rift systems were unrelated (except for the Koko Rift). Therefore, geodynamic models that relate HV volcanism to these rift systems are invalid. Lava volumes for two HV eruptions were estimated at 0.11 and 0.23 km 3 using surface mapping and water well data. Similar size, recent monogenetic eruptions in Auckland, New Zealand, were inferred to have lasted several months. Thus, if another HV eruption were to occur, which is possible given the long hiatus between eruptions, it would be extremely disruptive for the nearly 1 million residents of Honolulu. None of the existing geodynamic models fully explain the age duration, volumes and the locations of Hawai'i's rejuvenated volcanism. Thus, the cause of this secondary volcanism remains enigmatic.

Hawaii↗

USGS2024

Olivine diffusion constrains months-scale magma transport within Kīlauea volcano’s summit reservoir system prior to the 2020 eruption

The unprecedented 2018 summit collapse at Kīlauea and subsequent 2020–2021 eruption within the newly deepened Halema‘uma‘u Crater provide an unparalleled opportunity to understand how collapse events impact a volcano’s shallow reservoir system and magmatic processes. Glass and olivine from tephra ejected by lava fountains and several explosions on 20–21 December, within a few hours of the 2020 eruption onset, yield information about pre-eruptive magma storage and transport. The olivine population is bimodal with zoned and non-zoned phenocrysts. Normally zoned olivine crystals with core compositions around Fo 88 have 30–50 μm wide Fo 82 overgrowth rims that have skeletal textures. Two skeletal xenocrysts (cores Fo 74 and Fo 81 ) are also reversely zoned up to Fo 82 rims. The crystal cores have trace element records of at least two cycles of growth and dissolution prior to the formation of the overgrowth rims. These rims and a separate population of non-zoned Fo 82 crystals are in Fe–Mg equilibrium with their host glass (average MgO of 6.9 ± 0.4 wt% (1σ), Mg# [Mg / (Mg + Fe 2+ )] of 0.57), which suggests undercooling after intrusion of magma to shallow levels in the plumbing system. In the years prior to the 2018 collapse, non-zoned Fo 81 olivine and slightly lower MgO glasses (6.8 wt%) reflected continuous mixing and compositional buffering of magma recharge into several km 3 of stored magma in the Halema‘uma‘u reservoir (1–2 km depth). The 2020 olivine crystals lack evidence of an intrusion mixing with resident shallow magma, indicating that magma transport occurred in a disrupted system, and/or it may not have significantly mixed with stored magma remaining in the Halema‘uma‘u reservoir after the events of 2018. Diffusion modeling of Fe–Mg exchange in the zoned 2020 olivine crystals yield timescales that are mostly 60 days prior to the eruption or less, which aligns well with 22–24 October 2020 and subsequent seismic swarms at Nāmakani Paio ~ 5 km west of Kīlauea’s summit caldera. This correlation indicates that magma intruding beneath the summit (volume accommodation, recorded by the olivine crystals) was expressed by tectonic earthquakes along the Ka‘ōiki fault zone (stress accommodation). The absence of precursory SO 2 within minutes prior to eruption also indicates that the 2020 December magma may have risen from 1 to 2 km depth to the surface in as little as 10 min.

Hawaii↗

USGS2024

Island of Hawaiʻi eruptions 2018–present: Profound landscape and human impacts

This three-day field trip examines deposits and landscape evolution associated with recent eruptions of Kīlauea and Mauna Loa, Hawai‘i, USA, beginning with the lower East Rift Zone eruption and associated partial caldera collapse during the summer of 2018. As of this writing, there have been five eruptions within Kīlauea’s summit caldera, one eruption in the Southwest Rift Zone of Kīlauea, and several intrusions into the south caldera and Southwest Rift Zone since 2018. For the first time since 1984, Mauna Loa erupted in 2022, with lava flows in the caldera and along the Northeast Rift Zone. Recent eruptions contrast significantly with the preceding period, characterized by Kīlauea’s long-lived East Rift Zone eruption at Pu‘u‘ō‘ō from 1983 to 2018 and sustained lava lake activity at the summit from 2008 to 2018.

Hawaii↗

USGS2023

Dynamics of magma mixing and magma mobilization beneath Mauna Loa – Insights from the 1950 AD Southwest Rift Zone eruption.

Eruptions from Mauna Loa’s Southwest Rift Zone (SWRZ) pose a significant threat to nearby communities due to high eruption rates and steep slopes resulting in little time for evacuation. Despite the large body of research done on Mauna Loa, knowledge of the timing and duration of magma residence and transfer through its internal plumbing system is still poorly constrained. This study presents a first quantitative look at thermochemical conditions and timescales of potentially deep storage and disaggregation of magmatic mush during the run-up to the voluminous 1950 AD SWRZ eruption. Details of heterogeneous compositions and textures of the macrocryst and glomerocryst cargo in 1950 AD lavas suggest magma mixing and crystal recycling along the entire plumbing system. Furthermore, the crystal cargo contains evidence for the direct interaction between primitive, deeply stored magma and pockets of more evolved magma stored at shallow to intermediate depths. An enigmatic attribute of 1950 near-vent lava is the near-ubiquitous presence of subhedral, unreacted Mg-rich orthopyroxene phenocrysts (Mg#>80). Phase relations of Mauna Loa olivine-tholeiite indicate that orthopyroxene joins olivine as a primary phase at pressures higher than 0.6 GPa. Coexisting Mg-rich olivine and orthopyroxene and the occurrence of harzburgitic (olivine-orthopyroxene) glomerocrysts provide evidence for cognate crystallisation at near-Moho (~ 18 km) depths (Thornber and Trusdell 2008 ). Petrogenetically diverse populations of glomerocrysts and macrocrysts alongside evidence of multilevel magma storage indicate a network of ephemeral and possibly interconnected magma pockets from near-Moho depths to the upper/mid-crust. Fe-Mg diffusion chronometry applied to 1950 AD olivine populations implies rapid mobilisation and transport of large volumes of magma (376×10 6 m 3 ) from near-Moho storage to the surface within less than 8 months, with little residence time (~ 2 weeks) in the shallow (3–5 km) plumbing system.

Hawaii↗

USGS2023

Creating oriented and precisely sectioned mineral mounts for in situ chemical analyses—An example using olivine for diffusion chronometry studies

Diffusion chronometry is now a widely applied methodology for determining the rates and timescales of geologic processes from the chemical zoning observed in minerals. Despite the popularity of the method, several challenges still remain during its application, including: (1) the random sectioning of minerals either in thin sections or grain mounts in which both off-center and oblique sections contribute substantial uncertainty to modeled timescales and (2) diffusion anisotropy needs to be accounted for in models, which generally requires determining the principal crystallographic axes of the mineral using electron backscatter diffraction, a technique that is both challenging and limiting because few scanning electron microscopes have an electron backscatter detector. This guide developed by the U.S. Geological Survey focuses on a step-by-step methodology for mounting individually oriented minerals that are sectioned through their cores prior to polishing for analytical work. Using this technique, one can significantly reduce the uncertainties associated with off-center sections and minimize or completely remove the need for determining crystallographic orientation via electron backscatter diffraction analyses. This report is presented as a guide for using the technique on olivine crystals but can be applied to any minerals that can be extracted for analysis. Two variations of the methodology are included here: (1) The individual crystal method that entails mounting individually sectioned single crystals and crystal groups and (2) the whole mount method in which multiple single crystals or crystal clusters are mounted and sectioned at the same time.

Techniques and Methods↗

USGS2023

Coordinating science during an eruption: Lessons from the 2020–2021 Kīlauea volcanic eruption

Data collected during well-observed eruptions can lead to dramatic increases in our understanding of volcanic processes. However, the necessary prioritization of public safety and hazard mitigation during a crisis means that scientific opportunities may be sacrificed. Thus, maximizing the scientific gains from eruptions requires improved planning and coordinating science activities among governmental organizations and academia before and during volcanic eruptions. One tool to facilitate this coordination is a Scientific Advisory Committee (SAC). In the USA, the Community Network for Volcanic Eruption Response (CONVERSE) has been developing and testing this concept during workshops and scenario-based activities. The December 2020 eruption of Kīlauea volcano, Hawaii, provided an opportunity to test and refine this model in real-time and in a real-world setting. We present here the working model of a SAC developed during this eruption. Successes of the Kīlauea SAC (K-SAC) included broadening the pool of scientists involved in eruption response and developing and codifying procedures that may form the basis of operation for future SACs. Challenges encountered by the K-SAC included a process of review and facilitation of research proposals that was too slow to include outside participation in the early parts of the eruption and a decision process that fell on a small number of individuals at the responding volcano observatory. Possible ways to address these challenges include (1) supporting community-building activities between eruptions that make connections among scientists within and outside formal observatories, (2) identifying key science questions and pre-planning science activities, which would facilitate more rapid implementation across a broader scientific group, and (3) continued dialog among observatory scientists, emergency responders, and non-observatory scientists about the role of SACs. The SAC model holds promise to become an integral part of future efforts, leading in the short and longer term to more effective hazard response and greater scientific discovery and understanding.

Hawaii↗

USGS2023

The 2018 eruption of Kīlauea: Insights, puzzles, and opportunities for volcano science

The science of volcanology advances disproportionately during exceptionally large or well-observed eruptions. The 2018 eruption of Kīlauea Volcano (Hawai‘i) was its most impactful in centuries, involving an outpouring of more than one cubic kilometer of basalt, a magnitude 7 flank earthquake, and the volcano’s largest summit collapse since at least the nineteenth century. Eruptive activity was documented in detail, yielding new insights into large caldera-rift eruptions; the geometry of a shallow magma storage-transport system and its interaction with rift zone tectonics; mechanisms of basaltic tephra-producing explosions; caldera collapse mechanics; and the dynamics of fissure eruptions and high-volume lava flows. Insights are broadly applicable to a range of volcanic systems and should reduce risk from future eruptions. Multidisciplinary collaboration will be required to fully leverage the diversity of monitoring data to address many of the most important outstanding questions.

Hawai‘i↗

USGS2022

Magma storage and transport timescales for the 1959 Kīlauea Iki eruption and implications for diffusion chronometry studies using time-series samples versus tephra deposits

Complex crystal cargo in basaltic eruptions has the potential to yield diverse insights on pre- and syn-eruptive timescales of magma storage and transport. Research on eruption products from the 1959 eruption from Kīlauea Iki Crater at Kīlauea volcano (Hawai‘i) demonstrates that time-series samples collected during an eruption can yield a wealth of information not accessible by studying the fall deposit alone. Major element zoning in olivine crystals illustrates four environments of magma storage that were variably mixed and progressively involved in the eruption. Diffusion timescales retrieved from crystals < 1 mm in size are typically much shorter than those from crystals > 1 mm, illustrating the additional complexity of information recorded by different grain sizes and olivine populations. The timescales can be divided into two groups: (1) t > 100 days reflect longer-term magma recharge into Kīlauea’s deep (8–10 km) reservoir system and (2) t < 100 days broadly correspond to a period of unrest and inflation beginning ~ 3 months prior to eruption. Some timescales reflect syn-eruptive processes, where diffusion began after the eruption onset. Progressive changes in zoning populations in the time-series scoriae samples illustrate how quickly diffusive re-equilibration can erase older magmatic histories and information and underscores that studies on fall deposits can lead to an incomplete record of magmatic processes. Thus, diffusion timescales from fall deposits alone should be cautiously interpreted with the caveat that they may be missing a substantial part of the total eruptive event and, therefore, the record of magmatic histories inferred from crystal cargo.

Hawaii↗

USGS2022

Trace elements in olivine fingerprint the source of 2018 magmas and shed light on explosive-effusive eruption cycles at Kīlauea Volcano

Understanding magma genesis and the evolution of intensive parameters (temperature, pressure, composition, degree of melting) in the mantle source of highly active volcanic systems is crucial for interpreting magma supply changes over time and recognizing cyclic behavior to anticipate future volcanic behavior. Major and trace elements in olivine are commonly used to study variations in mantle lithologies and melting conditions (e.g., temperature, pressure, oxygen fugacity) affecting the mantle over time. Here, we track the temporal evolution of primary melts through the most recent cycle of explosive and effusive eruptions at Kīlauea (Hawai‘i), which spans the last ∼500 years. We report major and trace elements in olivine from the last explosive period (∼1500 – early 1820’s Keanakāko‘i Tephra) and the most recent decade of the current effusive period (2018 LERZ, 2015–2018 Pu‘u‘ō‘ō, 2008–2018 lava lake and 2020 eruption in Halema‘uma‘u). Scandium concentrations in olivine allow characterizing changes in mantle source between 1500 and 2018, and suggest that the recent (2015–2018) magma feeding the Pu‘u‘ō‘ō cone did not significantly interact with the magma that erupted in the LERZ in 2018. The evolution of olivine and melt compositions over the past 500 years is not easily reconcilable with variations in mantle potential temperature, pressure of mantle melt pooling and storage, or oxygen fugacity. Instead, Sc, Mn, and Co concentrations and Ni/Mg ratio in high forsterite (Fo >87) olivine advocate for an increase in the proportion of clinopyroxene in the mantle source associated with a slightly higher degree of partial melting from 1500 to 2018. Changes in primitive melt compositions and degrees of mantle melting may well modulate magma supply to the crust and formation-replenishment of steady or ephemeral summit reservoirs, and thereby control transitions between explosive and effusive periods at Kīlauea. Analyzing trace elements in olivine at Kīlauea and elsewhere could therefore provide important clues on subtle changes occurring at the mantle level that might herald changes in volcanic behavior.

Hawaii↗

USGS2022

Olivine and glass chemistry record cycles of plumbing system recovery after summit collapse events at Kīlauea Volcano, Hawai‘i

The eruptive activity of Kīlauea Volcano (Hawai‘i) in the past 2500 years has alternated between centuries-long periods dominated either by explosive or effusive eruptions. The onset of explosive periods appears to be marked by caldera collapse events at the volcano's summit accompanied by draining of Kīlauea's magmatic plumbing system. Here we leverage >1800 olivine forsterite (Fo) contents, >900 glass MgO contents, and estimated magma supply rates from the past six centuries to describe the relationships between summit collapse and the composition of erupted material. On a first order basis, the major element chemistry of the centuries-long eruptive periods largely originates from fundamental differences between fractional crystallization of shallowly stored magmas during high-supply effusive-dominated periods versus little evolution of mafic recharge magmas during low-supply explosive-dominated periods. The modern effusive period (1820s-present) is dominated by relatively evolved olivine forsterite contents (Fo81–82) for Kīlauea, which is interpreted to reflect a buffered crustal reservoir system in which shallow storage and fractional crystallization control the composition of magmas. In contrast, olivine crystals from the explosive Keanakāko‘i Tephra (1500 - early 1800s C.E.) are dominated by higher olivine forsterite contents (Fo89) which are interpreted to reflect more primitive compositions, are correlated with glass MgO compositions extending to high values (e.g.,11.0 wt%), and show signs of magma mixing (zoned olivine, bimodal Fo populations). These signatures reflect a disrupted reservoir system in which high-MgO recharge melts mix with melts left over from draining of the shallow (<5 km) magma plumbing. Superimposed on these explosive-effusive periods are three decades- to centuries long periods of progressively evolving olivine and glass compositions. Eruptions that occur after caldera collapse in ~1500C.E. and smaller scale crater collapse events in 1790 (inferred) and 1924 have heterogeneous olivine populations dominated by ≥Fo88 and typically high MgO glasses. These compositions reflect inefficient mixing of stored and primitive recharge magmas after the disruption of the shallow plumbing system. After these collapses, olivine Fo and glass MgO subsequently evolve to <Fo82 and <7.0 wt% compositions, reflecting the recovery of the crustal plumbing system to an end-member system state characterized by efficient mixing of recharge and stored magmas that serve to buffer the shallow magma reservoirs. These evolved signatures suggest that a mature and buffered reservoir system may be a key condition for significant disruptions of volcanic plumbing systems. Plumbing system recovery is slower following large-scale caldera collapse (hundreds of years) compared to recovery following smaller crater collapse (tens of years), which may be modulated by differences in magma supply rates. Following the 2018 crater collapse olivine populations have high-Fo but glasses are low MgO, suggesting that this collapse might have disrupted shallow magma pathways but not strongly impacted the reservoir(s). Ultimately, olivine and glass major element chemistry record the impacts of caldera and smaller but significant summit crater collapse events at Kīlauea and could be used to provide a framework for better characterizing long-term volcano evolution in Hawai‘i and shield volcanoes elsewhere.

Hawaii↗

USGS2019

Geochemical evolution of Keanakāko‘i Tephra, Kīlauea Volcano, Hawai‘i

The Keanakāko‘i Tephra was deposited from 1500 to ca. 1820 CE, when Kīlauea’s magmatic output was ~2% of the average output during historical times (post–1823 CE). The tephra consists of deposits from numerous phreatomagmatic and phreatic eruptions, three episodes of high lava fountains, and one lava. Fresh glass is available from most tephra units. Major elements and trace elements were determined for glass from 49 tephra units and three pretephra lavas. Olivine crystals from 11 high-MgO tephra glasses were also analyzed. These results were compared to compositions from Kīlauea’s historical period to evaluate ~500 yr of Kīlauea geochemical evolution. Keanakāko‘i Tephra glass composition ranged widely (e.g., 3.4–11.2 wt% MgO). The observed large variations in FeO, CaO, TiO 2 , and K 2 O at a given MgO indicate numerous compositionally distinct parental magmas, with the two early nineteenth-century pumice eruptions showing the most diverse compositions. These two magmas were erupted on opposite sides of the caldera and probably tapped different magma bodies. The common occurrence of high-MgO olivine compositions (forsterite [Fo] 88%–89%) in MgO-rich tephra glasses indicates that primitive magma (Mg# 73–74) was routinely supplied to Kīlauea’s summit. Wide ranges and reverse zoning in olivine core compositions from some units show that magma mixing occurred before some eruptions. Modeling of compositional variations within Keanakāko‘i Tephra units using alphaMELTS showed that the most consistent trends for crystal fractionation involved shallow magma (1–2 km), with low water content (0.2 wt% in parental magma) and oxygen fugacity just below the quartz-fayalite-magnetite (QFM) buffer (–0.5 log units). Keanakāko‘i Tephra glasses have lower La/Yb and Nb/Y ratios than historical Kīlauea lavas. Low ratios have been observed during periods of high magma output for historical lava, which is inconsistent with the low magma output at Kīlauea’s summit during 1500–1820 CE. The most likely explanation for this inconsistency is endogenous growth within Kīlauea during this period, following formation of the modern summit caldera. No correlation was found between glass chemistry and eruption style for Keanakāko‘i Tephra deposits. Glass samples from many explosive units have lower Nb/Y and La/Yb ratios compared to glass from high lava-fountain units and historical effusive eruptions. The explosive character of Keanakāko‘i Tephra eruptions was probably caused by interaction of magma with shallow or surface water.

Hawaii↗

USGS2017

Timescales of mixing and storage for Keanakāko‘i Tephra magmas (1500-1823 C.E.), Kīlauea Volcano, Hawai‘i

The last 2500 years of activity at Kīlauea Volcano (Hawai‘i) have been characterized by centuries-long periods dominated by either effusive or explosive eruptions. The most recent period of explosive activity produced the Keanakāko‘i Tephra (KT; ca. 1500–1820 C.E.) and occurred after the collapse of the summit caldera (1470–1510 C.E.). Previous studies suggest that KT magmas may have ascended rapidly to the surface, bypassing storage in crustal reservoirs. The storage conditions and rapid ascent hypothesis are tested here using chemical zoning in olivine crystals and thermodynamic modeling. Forsterite contents (Fo; [Mg/(Mg + Fe) × 100]) of olivine core and rim populations are used to identify melt components in Kīlauea’s prehistoric (i.e., pre-1823) plumbing system. Primitive (≥Fo 88 ) cores occur throughout the 300+ years of the KT period; they originated from mantle-derived magmas that were first mixed and stored in a deep crustal reservoir. Bimodal olivine populations (≥Fo 88 and Fo 83–84 ) record repeated mixing of primitive magmas and more differentiated reservoir components shallower in the system, producing a hybrid composition (Fo 85–87 ). Phase equilibria modeling using MELTS shows that liquidus olivine is not stable at depths >17 km. Thus, calculated timescales likely record mixing and storage within the crust. Modeling of Fe–Mg and Ni zoning patterns (normal, reverse, complex) reveal that KT magmas were mixed and stored for a few weeks to several years before eruption, illustrating a more complex storage history than direct and rapid ascent from the mantle as previously inferred for KT magmas. Complexly zoned crystals also have smoothed compositional reversals in the outer 5–20 µm rims that are out of Fe–Mg equilibrium with surrounding glasses. Diffusion models suggest that these rims formed within a few hours to a few days, indicating that at least one additional, late-stage mixing event may have occurred shortly prior to eruption. Our study illustrates that the lifetimes of KT magmas are more complex than previously proposed, and that most KT magmas did not rise rapidly from the mantle without modification during shallow crustal storage.

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