Geology Reports⌕ Search

Geology topics

Keith A. Kvenvolden

Publications and source records attributed to Keith A. Kvenvolden.

At least 55 records · Page 3Linked to original sources
USGS1990

Hydrothermally derived petroleum: examples from Guaymas Basin, Gulf of California, and Escanaba Trough, northeast Pacific Ocean

In the Guaymas Basin, a spreading axis in the Gulf of California, petroleum having a wide range of compositions forms by hydrothermal alteration of organic matter in Quaternary sediment composed mainly of marine diatomaceous ooze and muddy turbidites. In Escanaba Trough, at the southern end of the Gorda Ridge spreading axis offshore northern California, petroleum is formed by hydrothermal processes acting on mainly terrigenous organic material in Quaternary turbiditic river-derived sediment. Comparisons of the distributions of hydrocarbons - n-alkanes, isoprenoids, terpanes, steranes, and aromatics - show that chemical differences among four petroleum samples are such that two samples from Guaymas Basin can be distinguished from two samples from Escanaba Trough. Distinguishing characteristics resulting from differences in sources include n-alkane distributions and certain sterane ratios; distinguishing characteristics resulting from differences in thermal histories of the organic matter include hopane and sterane epimer ratios and various distributions of polycyclic aromatic hydrocarbons. These oils differ from conventionally derived petroleum in that they are admixtures of products generated over a wide range of thermal regimes, and their generation, expulsion, and migration occurred simultaneously over an instantaneous geological time period. The potential economic significance of hydrothermal derived petroleum is uncertain, but the fact that petroleum can form at active oceanic spreading axes adds a new facet to understanding the processes of petroleum generation, expulsion, and migration.

Escanaba Trough and Guaymas Basin in the system of↗
USGS1990

Diagenesis and interstitial-water chemistry at the Peruvian continental margin; major constituents and strontium isotopes

Two distinct hydrogeochemical regimes currently dominate the Peruvian continental margin. One, in shallower water (150-450 m) shelf to upper-slope regions, is characterized by interstitial waters with strong positive chloride gradients with depth. The maximum measured value of 1043 mM chloride at Site 680 at ITS corresponds to a degree of seawater evaporation of ~2 times. Major ion chemistry and strontioum isotopic composition of the interstitial waters suggest that a subsurface brine that has a marine origin and is of pre-early Miocene "age," profoundly influences the chemistry and diagenesis of this shelf environment. Site 684 at ~9°S must be closest to the source of this brine, which becomes diluted with seawater and/or interstitial water as it flows southward toward Site 686 at ~13°S (and probably beyond) at a rate of approximately 3 to 4 cm/yr, since early Miocene time. The other regime, in deep water (3000-5000 m) middle to lower-slope regions, is characterized by interstitial waters with steep negative and nonsteady-state chloride gradients with depth. The minimum measured value of 454 mM chloride, at Site 683 at ITS, corresponds to —20% dilution of seawater chloride The most probably sources of these low-chloride fluids are gas hydrate dissociation and mineral (particularly clay) dehydration reactions. Fluid advection is consistent with (1) the extent of dilution shown in the chloride profiles, (2) the striking nonsteady-state depth profiles of chlorides at Sites 683 and 688 and of 87Sr/86Sr ratios at Site 685, and (3) the temperatures resulting from an average geothermal gradient of 50°C/km and required for clay mineral dehydration reactions. Strontium isotope data reveal two separate fluid regimes in this slope region: a more northerly one at Sites 683 and 685 that is influenced by fluids with a radiogenic continental strontium signature, and a southerly one at Sites 682 and 688 that is influenced by fluids with a nonradiogenic oceanic signatures. Stratigraphically controlled fluid migration seems to prevail in this margin. Because of its special tectonic setting, Site 679 at ITS is geochemically distinct. The interstitial waters are characterized by seawater chloride concentrations to —200 mbsf and deeper by a significantly lower chloride concentration of about two-thirds of the value in seawater, suggesting mixing with a meteoric water source. Regardless of the hydrogeochemical regime, the chemistry and isotopic compositions of the interstitial waters at all sites are markedly modified by diagenesis, particularly by calcite and dolomite crystallization.

Peruvian Continental Margin↗
USGS1990

Hydrocarbon gases in Tertiary and Quaternary sediments offshore Peru; results and comparisons

Hydrocarbon gases (methane, ethane, propane, isobutane, «-butane, ethene, and propene) are present in Tertiary and Quaternary shelf, upper-slope, and lower-slope deposits of the Peruvian continental margin. Methane dominates the composition of the hydrocarbon gas at all 10 sites examined during Ocean Drilling Program (ODP) Leg 112. Generation of methane is regulated by the amount of sulfate in pore water. Wherever sulfate concentrations approach or equal zero, methane concentrations increase rapidly, reaching values near 100,000 /tL/L of wet sediment at eight of the 10 sites. Methane at all 10 sites results from methanogenesis, which is inhibited where sulfate is present and microbial reduction of sulfate occurs. Hydrocarbon gases heavier than methane also are present, but at much lower concentrations than methane. These hydrocarbons are thought to result from early thermal and microbial diagenesis, based on relative gas compositions and trends of concentrations with depth. With few exceptions, the results obtained in the shipboard and shore-based laboratories are comparable for methane and ethane in sediments of Leg 112. Reanalyses of canned sediments from ODP Leg 104 and from Deep Sea Drilling Project (DSDP) Legs 76 and 84 show that gas samples can be stored for as long as 8 yr, but the amounts of individual hydrocarbon gases retained vary. Nevertheless, the trends of the data sets with depth are similar for fresh and stored samples.

ODP Leg 112↗
USGS1990

Gas hydrates of the Peruvian outer continental margin

Gas hydrates were recovered during coring by Ocean Drilling Program (ODP) Leg 112 at Sites 685 and 688 on the Peruvian outer continental margin at latitudes of 9° and 11.5°S, where water depths are 5070 and 3820 m, respectively. In addition, nearby Sites 682 and 683 yielded compelling evidence that gas hydrates are present, but gas hydrates were not directly observed there. Anomalous acoustic reflectors, known as bottom-simulating reflectors (BSRs), on marine seismic profiles from the region also provided inferential evidence that gas hydrates are present. Geothermal gradients of about 43 and 49°C/km were calculated on the basis of relations between depths to BSRs, bottom-water temperatures, and the pressure-temperature stability field of gas hydrates. Geochemical studies revealed that methane concentrations increase rapidly with depth after pore-water sulfate concentrations have been depleted. The relationship between methane and sulfate suggests that microbial processes account for the generation of methane, and the relationship between the carbon isotopic composition of methane and dissolved carbon dioxide supports this suggestion. We believe that decreasing chlorinity in pore water from squeezed sediment at the four sites results mainly from the decomposition of gas hydrates and is a dilution artifact observed as a result of the squeezing procedure. Maximum chlorinity values at or near the surface result from excess salt that comes from the formation of gas hydrates composed of freshwater. Record alkalinity attests to the intensity of diagenetic processes and has significant effects on salinity profiles at these sites. Gas hydrates were recovered at 99 and 166 meters below the seafloor (mbsf) at Site 685, and at 141 mbsf at Site 688 in Pleistocene diatomaceous mud. Methane constitutes more than 99% of the hydrocarbon gas mixture in the gas hydrates. The volumetric ratio of methane to water in the sample from Site 685 is 100, indicating that the sampled gas hydrate is either undersaturated with respect to methane or had partially decomposed during core recovery or both. The discovery of gas hydrates in lower slope deposits of the Peruvian outer continental margin extends our knowledge of gas-hydrate formation and occurrence in the Circum-Pacific region.

ODP Leg 112↗
USGS1990

Hydrocarbons in sediment of the Weddell Sea, Antarctica

Heavy hydrocarbons (about C15+) are ubiquitous but minor components in sediment from three sites (692, 693, and 694) drilled during Ocean Drilling Program (ODP) Leg 113. This preliminary report is the first to describe the distribution of some of these hydrocarbons in sediment of the Weddell Sea. Samples from Sites 692 and 693, located on a mid-slope bench along the margin of Queen Maud Land, span a time interval from Early Cretaceous to Pleistocene. In samples from the Tertiary portion of the record, having an average organic-carbon content of about 0.2%, n-alkanes are common and are characterized by populations that indicate both marine and terrigenous sources. In contrast, samples from the Cretaceous portion of the record, having an average organic carbon content of about 4%, contain mixtures of hydrocarbons in which n-alkanes are secondary in abundance to the isoprenoid hydrocarbons, pristane and phytane. Diasterenes, sterenes, and hopenes are present in anomalously high concentrations and indicate immaturity. The Cretaceous hydrocarbons appear to be mainly primary, whereas the Tertiary hydrocarbons contain compounds which indicate that the sediment, along with its organic content, has been recycled. Samples from Site 694, located in the Weddell Sea on the abyssal plain, range in age from late Miocene to early Pliocene.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1989

Organic matter at sites 642, 643, and 644, ODP Leg 104

Sedimentary extractable organic matter was analyzed at three ODP Leg 104 sites in the Norwegian Sea. Organic carbon content ranged from less than 0.1% to a maximum of 1.8%. Extractable organic matter content and unresolved complex mixture concentrations were low and randomly distributed. Low levels of aliphatic (branched and normal) and aromatic hydrocarbons were detected in all of the sediments analyzed. Total aliphatic and aromatic hydrocarbon concentrations ranged from 176 to 3,214 and 6 to 820 ppb, respectively. The concentrations of individual aliphatic (n-C15 to n-C32) and aromatic (two- to five-ring) hydrocarbons were generally less than 50 ppb and less than 10 ppb, respectively. No significant trend with sub-bottom depth was observed in either bulk organic matter or individual hydrocarbon concentrations. The predominant source of Cenozoic sedimentary hydrocarbons is concluded to be ice-rafted debris from the adjacent continent. All sites contain a mixture of recycled, mature petroleum-related and terrestrially derived hydrocarbons.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1989

Hydrocarbon gases in sediment of the Voring Plateau, Norwegian Sea

Geochemical studies at three ODP Leg 104 sites on the Wring Plateau help define the distribution of hydrocarbon gases in sediment of this prominent feature of the Norwegian continental margin. Low levels of hydrocarbon gas were encountered in sediment of the outer part of the plateau, but sediment of the inner part of the plateau is very gassy. The molecular composition of inner plateau gases ( > 99.9% methane) and the carbon isotopic composition of the methane (avg. = - 76%o relative to the PDB standard) clearly show that the gas is biogenic. Heavier hydrocarbon gases accompany this methane, and their presence is probably a result of both chemical and microbial low-temperature diagenesis. Although these heavier hydrocarbons were not detected in sediment of the outer part of the plateau during shipboard analyses, subsequent shore-based analyses showed that these compounds are present at very low concentrations. Methane in the gassy sediment of the inner part of the plateau may be present as gas hydrates, judging from sedimentological and inorganic geochemical considerations, but no discernible gas hydrates were recovered during drilling.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1989

Organic geochemistry on Leg 104

The Leg 104 organic geochemistry program consisted of monitoring (a) hydrocarbon gases, (b) organic and inorganic carbon, and (c) parameters resulting from Rock-Eval pyrolysis at three sites on the Vdring Plateau. The results amplify some of those obtained earlier on Deep Sea Drilling Project (DSDP) Leg 38. In a regional sense there is an inverse correlation between amounts of hydrocarbon gas and organic carbon. For example, significant concentrations of methane are present only at Site 644 in the inner part of the plateau where organic carbon contents are always less than 1%; in contrast, at Site 642 on the outer plateau, methane concentrations are very low (ppm range) whereas amounts of organic carbon approach 2%. Only at Site 644 are the environmental conditions such that methanogenesis is an active diagenetic process. Because of the importance of routine gas analyses to the Ocean Drilling Program (ODP), a procedure was devised to improve the use of Vacutainers for collection of gas samples. Comparison of methods for determining organic carbon showed that at Sites 643 and 644 Rock-Eval TOC could be used as a measure of organic carbon, but not at Site 642. Although no liquid or solid hydrocarbons were encountered at any of the sites, a catalog of potential organic geochemical contaminants was developed in anticipation of such a discovery.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1988

Amino-acid diagenesis and its implication for late Pleistocene lacustrine sediment, Clear Lake, California

The diagenesis of amino acids in sediments from Clear Lake core CL-80-1 is indicated by changes in amino acid concentrations, compositions, and stereochemistry. Concentrations of total amino acids decrease with depth, but the decrease is not systematic, possibly reflecting a nonuniformity in sedimentary and postdepositional processes affecting the amino acids. Ratios of neutral/acidic amino acids may indicate that the pH of interstitial water is slightly alkaline to slightly acidic and that the organic matter is well humified. Ratios of nonprotein/protein amino acids suggest that some changes in amino acids with depth result from microbial degradations. The extent of racemization of alanine increases with depth; the trends of these data may be explained, in part, by rapid sedimentation within the lake. Agreement between extents of alanine racemization for sediments from equivalent depths in two cores from the lake suggests that diagenetic temperatures are uniform within the sediments of the northern basin of Clear Lake.

California↗
USGS1988

Organic geothermometry of petroleum from Escanaba Trough, offshore northern California

We have measured the extent of hopane and sterane isomerization and of monoaromatic-steroid-hydrocarbon aromatization in a sample of hydrothermally derived petroleum from the Escanaba Trough, a sediment-covered, volcanically active ridge axis. The results, along with kinetic parameters, predict the possible time-temperature history of the petrolum-forming process for this sample. The extent of these reactions is consistent with petroleum formation by intense heating (about 300–350°C) if the time period of this heating was as short as about 100 yr. Such a time scale is reasonable for hydrothermal-discharge events associated with ridge-crest volcanism.

California↗
USGS1988

Aliphatic hydrocarbons in sediments from Prydz Bay, Antarctica

High molecular weight aliphatic hydrocarbons were extracted from sediments at two sites (741 and 742) drilled during ODP Leg 119 in Prydz Bay. The distributions of n-alkanes and triterpenoid and steroid hydrocarbons suggest that the n- alkanes and steranes are mainly of terrestrial origin and that the hydrocarbons are immature to slightly mature in the Lower Cretaceous sediments and immature to mature in the Tertiary sediments. At Site 741, the Lower Cretaceous depositional sequence, which is generally characterized by immature hydrocarbons, is interrupted by sediment having more mature components, suggesting a change of source during part of Early Cretaceous time. At Site 742, the mature geochemical parameters of a Pliocene sample correlate with results reported elsewhere for Site 739. In all but one of the other Tertiary samples, the geochemical parameters indicate intermediate maturity. The Lower Cretaceous and Pliocene sediments average about 1.9% organic carbon, a value of interest from the point of view of potential sources of petroleum offshore of Antarctica.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1987

Multiple sources of alkanes in Quaternary oceanic sediment of Antarctica

Normal alkanes ( n -C 13 n -C 36 ), isoprenoid hydrocarbons ( i -C 15 , i -C 16 , i -C 18 , i -C 19 , and i -C 20 ) triterpanes (C 27 C 32 ), and (C 27 C 29 ) are present in low concentrations offshore Antarctica in near-surface, Quaternary sediment of the Wilkes Land continental margin and of the western Ross Sea. The distributions of these hydrocarbons are interpreted relative to possible sources and processes. The hydrocarbons appear to be mixtures of primary and recycled material from marine and terrigenous sources. The n -alkanes are most abundant and are characterized by two distinct populations, one of probable marine origin and the other likely from terrigenous, vascular plant sources. Because the continent of Antarctica today is devoid of higher plants, the plant-derived hydrocarbons in these offshore sediments probably came from wind-blown material and recycled Antarctic sediment that contains land-plant remains from an earlier period of time. Isoprenoid hydrocarbons are partially recycled and mainly of marine origin; the dominance of pristane over phytane suggests oxic paleoenvironmental conditions. Both modern and ancient triterpanes and steranes are present, and the distribution of these indicates a mixture of primary and recycled bacterial, algal, and possible higher-plant materials. Although the sampled sediments were deposited during the Quaternary, they apparently contain a significant component of hydrocarbons of pre-Quaternary age.

Organic Geochemistry↗
USGS1986

Isotopic composition of interstitial fluids in sediment of the Nankai Trough, Deep Sea Drilling Project Leg 87

The isotopic compositions of dissolved CO2 and CH4 in sediments of the Nankai Trough indicate that CH4 is formed during early diagenesis by microbial reduction of CO2 . At the shallowest sampled depths, the CO2 dissolved in the pore water is unusually enriched in 12C (δ13C = - 35.2‰), indicating contribution of CO2 from oxidation of CH4 . The most intense microbiological activity appears to be confined to the uppermost 50 m of sediment, based on relative lack of change in the isotopic compositions below this depth. Gas hydrate probably is not present at these localities (Sites 582, 583) because of CH4 concentrations that are insufficient to saturate the pore water with respect to gas hy drate stability

Initial Reports of the D.S.D.P.↗
USGS1985

Gas hydrates on the northern California continental margin

The inner continental margin of northern California is underlain by a well-defined and extensive acoustic reflector that crosses other reflectors and mimics the surface of the sea floor. This bottom-simulating reflector (BSR) lies at a typical subsurface depth of about 250 m and has been mapped continuously beneath the Klamath Plateau and upper slope (water depths of 800 to 1200 m) for a distance of more than 130 km; it covers an area of at least 3000 km 2 . Limited data show that the BSR extends northward into Oregon and seaward at least to the base of the slope (3000 m). The water depths, subsurface depths, and pervasive nature of the BSR all suggest that it represents the base of a natural-gas hydrate. Using standard phase boundary diagrams for hydrate stability, we estimate the local geothermal gradient within the gas hydrate to be about 55 °C/km. This value is higher than that of most subduction margins and may be a result of the youthfulness of the subducting oceanic crust. This acoustically inferred gas hydrate is the first to be mapped on the western conterminous United States continental margin.

California↗
USGS1985

Seismic and geochemical evidence for shallow gas in sediment on Navarin continental margin, Bering Sea

Marine seismic studies coupled with geochemical investigations demonstrate that hydrocarbon gases are ubiquitous in the near-surface (<= 250 m or 820 ft depth) sediment of the Navarin continental margin in the northern Bering Sea. Three types of acoustic anomalies appear to be related to the presence of gas in the sediment. These anomalies are most prevalent in the northern half of the Navarin basin. Acoustic anomalies attributed to gas hydrates and to diagenetic boundaries are present on seismic records of the lower slope between Navarinsky and Zhemchug Canyons. Hydrocarbon gases, methane through butanes, are common in the surface (<= 5 m or 17 ft depth) sediment of the Navarin continental margin. Methane, the most abundant hydrocarbon gas, is present in amounts ranging from 84,000 to 1 µL/L of wet sediment. These concentrations are two to three orders of magnitude greater than the other hydrocarbon gases. The highest concentrations of methane (greater than 1,000 µL/L) were measured in sediment of Navarinsky Canyon and over the central part of the Navarin basin. The source of methane is mainly biogenic, but the hydrocarbon gas compositions in 17 of 141 cores suggest the presence of thermogenic gas. Most of these 17 cores are from the continental slope at water depths greater than 150 m (490 ft). No direct correlation could be found between acoustic anomalies and gas concentrations in the sediment. This lack of correlation is probably due to the limited penetration of the gravity corer and the spotty distribution of hydrocarbon concentrations.

Alaska↗
USGS1984

Geochemistry of a naturally occurring massive marine gas hydrate

During Deep Sea Drilling Project (DSDP) Leg 84 a core 1 m long and 6 cm in diameter of massive gas hydrate was unexpectedly recovered at Site 570 in upper slope sediment of the Middle America Trench offshore of Guatemala. This core contained only 5–7% sediment, the remainder being the solid hydrate composed of gas and water. Samples of the gas hydrate were decomposed under controlled conditions in a closed container maintained at 4°C. Gas pressure increased and asymptotically approached the equilibrium decomposition pressure for an ideal methane hydrate, CH 4 .5-3/4H 2 O, of 3930 kPa and approached to this pressure after each time gas was released, until the gas hydrate was completely decomposed. The gas evolved during hydrate decomposition was 99.4% methane, ∼0.2% ethane, and ∼0.4% CO 2 . Hydrocarbons from propane to heptane were also present, but in concentrations of less than 100 p.p.m. The carbon-isotopic composition of methane was −41 to −44 permil(( 0 00 "> 000 ), relative to PDB standard. The observed volumetric methane/water ratio was 64 or 67, which indicates that before it was stored and analyzed, the gas hydrate probably had lost methane. The sample material used in the experiments was likely a mixture of methane hydrate and water ice. Formation of this massive gas hydrate probably involved the following processes: (i) upward migration of gas and its accumulation in a zone where conditions favored the growth of gas hydrates, (ii) continued, unusually rapid biological generation of methane, and (iii) release of gas from water solution as pressure decreased due to sea level lowering and tectonic uplift.

Middle America Trench↗