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Kathryn E. Watts

Publications and source records attributed to Kathryn E. Watts.

24 records · Page 2Linked to original sources

Probing the volcanic-plutonic connection and the genesis of crystal-rich rhyolite in a deeply dissected supervolcano in the Nevada Great Basin: Source of the late Eocene Caetano Tuff

Late Cenozoic faulting and large-magnitude extension in the Great Basin of the western USA has created locally deep windows into the upper crust, permitting direct study of volcanic and plutonic rocks within individual calderas. The Caetano caldera in north–central Nevada, formed during the mid-Tertiary ignimbrite flare-up, offers one of the best exposed and most complete records of caldera magmatism. Integrating whole-rock geochemistry, mineral chemistry, isotope geochemistry and geochronology with field studies and geologic mapping, we define the petrologic evolution of the magmatic system that sourced the >1100 km 3 Caetano Tuff. The intra-caldera Caetano Tuff is up to ∼5 km thick, composed of crystal-rich (30–45 vol. %), high-silica rhyolite, overlain by a smaller volume of comparably crystal-rich, low-silica rhyolite. It defies classification as either a monotonous intermediate or crystal-poor zoned rhyolite, as commonly ascribed to ignimbrite eruptions. Crystallization modeling based on the observed mineralogy and major and trace element geochemistry demonstrates that the compositional zonation can be explained by liquid–cumulate evolution in the Caetano Tuff magma chamber, with the more evolved lower Caetano Tuff consisting of extracted liquids that continued to crystallize and mix in the upper part of the chamber following segregation from a cumulate-rich, and more heterogeneous, source mush. The latter is represented in the caldera stratigraphy by the less evolved upper Caetano Tuff. Whole-rock major, trace and rare earth element geochemistry, modal mineralogy and mineral chemistry, O, Sr, Nd and Pb isotope geochemistry, sanidine Ar–Ar geochronology, and zircon U–Pb geochronology and trace element geochemistry provide robust evidence that the voluminous caldera intrusions (Carico Lake pluton and Redrock Canyon porphyry) are genetically equivalent to the least evolved Caetano Tuff and formed from magma that remained in the lower chamber after ignimbrite eruption and caldera collapse. Thus, the Caetano Tuff contradicts models for the mutually exclusive origins of voluminous volcanic and plutonic magmas in the upper crust. Crystal-scale O isotope data indicate that the Caetano Tuff is one of the most 18 O-enriched rhyolites in the Great Basin (δ 18 O magma = 10·2 ± 0·2‰), supporting anatexis of local metasedimentary basement crust. Metapelite xenoliths in the Carico Lake pluton and ubiquitous xenocrystic zircons in the Caetano Tuff provide constraints for the anatexis process; these data point to shallow (<15 km) dehydration melting of a protolith similar to the Proterozoic McCoy Creek Group siliciclastic sediments in eastern Nevada, projected beneath Caetano in fault-stacked shelf sediments that were thickened during Mesozoic crustal shortening. Mean zircon U–Pb ages for different stratigraphic levels of the intra-caldera Caetano Tuff are 34·2–34·5 Ma, 0·2–0·5 Myr older than the caldera sanidine 40 Ar/ 39 Ar age of 34·00 ± 0·03 Ma, documenting protracted duration of assembly and homogenization of isotopically diverse upper crustal melts, followed by crystallization and zonation to generate the Caetano Tuff magma chamber. Sanidine rims in the least evolved Caetano Tuff and in the Carico Lake pluton and Redrock Canyon porphyry have sharply zoned Ba domains that point to crystal growth during magmatic recharge events. The recharge magma is inferred to have been compositionally similar to the Caetano Tuff magma, with increased Ba resulting from remelting of Ba-rich sanidine cumulates. Mush reactivation to generate the Caetano Tuff eruption was sufficiently rapid to preserve compositional gradients in the intracaldera ignimbrite, calling into question models that predict homogeneity as a prerequisite for remobilizing crystal-rich ignimbrite magmas.

Journal of Petrology↗

Chemical abrasion-SIMS (CA-SIMS) U-Pb dating of zircon from the late Eocene Caetano caldera, Nevada

Zircon geochronology is a critical tool for establishing geologic ages and time scales of processes in the Earth's crust. However, for zircons compromised by open system behavior, achieving robust dates can be difficult. Chemical abrasion (CA) is a routine step prior to thermal ionization mass spectrometry (TIMS) dating of zircon to remove radiation-damaged parts of grains that may have experienced open system behavior and loss of radiogenic Pb. While this technique has been shown to improve the accuracy and precision of TIMS dating, its application to high-spatial resolution dating methods, such as secondary ion mass spectrometry (SIMS), is relatively uncommon. In our efforts to U-Pb date zircons from the late Eocene Caetano caldera by SIMS (SHRIMP-RG: sensitive high resolution ion microprobe, reverse geometry), some grains yielded anomalously young U-Pb ages that implicated Pb-loss and motivated us to investigate with a comparative CA and non-CA dating study. We present CA and non-CA 206 Pb/ 238 U ages and trace elements determined by SHRIMP-RG for zircons from three Caetano samples (Caetano Tuff, Redrock Canyon porphyry, and a silicic ring-fracture intrusion) and for R33 and TEMORA-2 reference zircons. We find that non-CA Caetano zircons have weighted mean or bimodal U-Pb ages that are 2&ndash;4% younger than CA zircons for the same samples. CA Caetano zircons have mean U-Pb ages that are 0.4&ndash;0.6 Myr older than the 40 Ar/ 39 Ar sanidine eruption age (34.00 &plusmn; 0.03 Ma; error-weighted mean, 2&sigma;), whereas non-CA zircons have ages that are 0.7&ndash;1.3 Myr younger. U-Pb ages do not correlate with U (~ 100&ndash;800 ppm), Th (~ 50&ndash;300 ppm) or any other measured zircon trace elements (Y, Hf, REE), and CA and non-CA Caetano zircons define identical trace element ranges. No statistically significant difference in U-Pb age is observed for CA versus non-CA R33 or TEMORA-2 zircons. Optical profiler measurements of ion microprobe pits demonstrate consistent depths of ~ 1.6 &mu;m for CA and non-CA Caetano, R33 and TEMORA-2 zircons, and do not indicate variations in secondary ion sputtering rates due to chemical or structural changes from the CA treatment. Our new data underscore the potential for cryptic Pb-loss to go unrecognized in other geologically young magmatic centers that do not have zircons with high U, statistically discordant isotope ratios, high common Pb, or metamict textures.

Nevada↗

Revised Wonoka isotopic anomaly in South Australia and Late Ediacaran mass extinction

The global Late Ediacaran Shuram–Wonoka carbon isotope anomaly has been regarded as the largest and longest known isotopic anomaly in the ocean, assuming that all Ediacaran carbonate is marine. Disregarding carbonate in South Australia shown here to be palaeosol or palaeokarst, the synchronous marine organic–carbonate excursion is only −8‰ for δ 13 C organic and −6‰ for δ 13 C carbonate, and lasted less than a million years. This revised magnitude and duration is comparable with perturbations across the Permian–Triassic boundary, and correlative with a global Late Ediacaran acritarch mass extinction. Like Permian–Triassic isotopic excursions, the revised organic–carbonate Wonoka excursion may also have been a greenhouse palaeoclimatic warm spike, which terminated valley incision and glacioeustatic drawdown during the mid-Ediacaran Fauquier Glaciation, and preceded chill of the Late Ediacaran Billy Springs Glaciation.

Flinders Ranges↗

Linking rapid magma reservoir assembly and eruption trigger mechanisms at evolved Yellowstone-type supervolcanoes

The geological record contains evidence of volcanic eruptions that were as much as two orders of magnitude larger than the most voluminous eruption experienced by modern civilizations, the A.D. 1815 Tambora (Indonesia) eruption. Perhaps nowhere on Earth are deposits of such supereruptions more prominent than in the Snake River Plain&ndash;Yellowstone Plateau (SRP-YP) volcanic province (northwest United States). While magmatic activity at Yellowstone is still ongoing, the Heise volcanic field in eastern Idaho represents the youngest complete caldera cycle in the SRP-YP, and thus is particularly instructive for current and future volcanic activity at Yellowstone. The Heise caldera cycle culminated 4.5 Ma ago in the eruption of the &sim;1800 km 3 Kilgore Tuff. Accessory zircons in the Kilgore Tuff display significant intercrystalline and intracrystalline oxygen isotopic heterogeneity, and the vast majority are 18 O depleted. This suggests that zircons crystallized from isotopically distinct magma batches that were generated by remelting of subcaldera silicic rocks previously altered by low-&delta; 18 O meteoric-hydrothermal fluids. Prior to eruption these magma batches were assembled and homogenized into a single voluminous reservoir. U-Pb geochronology of isotopically diverse zircons using chemical abrasion&ndash;isotope dilution&ndash;thermal ionization mass spectrometry yielded indistinguishable crystallization ages with a weighted mean 206 Pb/ 238 U date of 4.4876 &plusmn; 0.0023 Ma (MSWD = 1.5; n = 24). These zircon crystallization ages are also indistinguishable from the sanidine 40 Ar/ 39 Ar dates, and thus zircons crystallized close to eruption. This requires that shallow crustal melting, assembly of isolated batches into a supervolcanic magma reservoir, homogenization, and eruption occurred extremely rapidly, within the resolution of our geochronology (10 3 &ndash;10 4 yr). The crystal-scale image of the reservoir configuration, with several isolated magma batches, is very similar to the reservoir configurations inferred from seismic data at active supervolcanoes. The connection of magma batches vertically distributed over several kilometers in the upper crust would cause a substantial increase of buoyancy overpressure, providing an eruption trigger mechanism that is the direct consequence of the reservoir assembly process.

Geology↗

Crustal-scale recycling in caldera complexes and rift zones along the Yellowstone hotspot track: O and Hf isotopic evidence in diverse zircons from voluminous rhyolites of the Picabo volcanic field, Idaho

Rhyolites of the Picabo volcanic field (10.4–6.6 Ma) in eastern Idaho are preserved as thick ignimbrites and lavas along the margins of the Snake River Plain (SRP), and within a deep (>3 km) borehole near the central axis of the Yellowstone hotspot track. In this study we present new O and Hf isotope data and U–Pb geochronology for individual zircons, O isotope data for major phenocrysts (quartz, plagioclase, and pyroxene), whole rock Sr and Nd isotope ratios, and whole rock geochemistry for a suite of Picabo rhyolites. We synthesize our new datasets with published Ar–Ar geochronology to establish the eruptive framework of the Picabo volcanic field, and interpret its petrogenetic history in the context of other well-studied caldera complexes in the SRP. Caldera complex evolution at Picabo began with eruption of the 10.44±0.27 Ma (U–Pb) Tuff of Arbon Valley (TAV), a chemically zoned and normal-δ 18 O (δ 18 O magma=7.9‰) unit with high, zoned 87 Sr/ 86 Sr i (0.71488–0.72520), and low-ε Nd (0) (−18) and ε Hf (0) (−28). The TAV and an associated post caldera lava flow possess the lowest ε Nd (0) (−23), indicating ∼40–60% derivation from the Archean upper crust. Normal-δ 18 O rhyolites were followed by a series of lower-δ 18 O eruptions with more typical (lower crustal) Sr–Nd–Hf isotope ratios and whole rock chemistry. The voluminous 8.25±0.26 Ma West Pocatello rhyolite has the lowest δ 18 O value (δ 18 O melt =3.3‰), and we correlate it to a 1,000 m thick intracaldera tuff present in the INEL-1 borehole (with published zircon ages 8.04–8.35 Ma, and similarly low-δ 18 O zircon values). The significant (4–5‰) decrease in magmatic-δ 18 O values in Picabo rhyolites is accompanied by an increase in zircon δ 18 O heterogeneity from ∼1‰ variation in the TAV to >5‰ variation in the late-stage low-δ 18 O rhyolites, a trend similar to what is characteristic of Heise and Yellowstone, and which indicates remelting of variably hydrothermally altered tuffs followed by rapid batch assembly prior to eruption. However, due to the greater abundance of low-δ 18 O rhyolites at Picabo, the eruptive framework may reflect an intertwined history of caldera collapse and coeval Basin and Range rifting and hydrothermal alteration. We speculate that the source rocks with pre-existing low-δ 18 O alteration may be related to: (1) deeply buried and unexposed older deposits of Picabo-age or Twin Falls-age low-δ 18 O volcanics; and/or (2) regionally-abundant late Eocene Challis volcanics, which were hydrothermally altered near the surface prior to or during peak Picabo magmatism. Basin and Range extension, specifically the formation of metamorphic core complexes exposed in the region, could have facilitated the generation of low-δ 18 O magmas by exhuming heated rocks and creating the large water-rock ratios necessary for shallow hydrothermal alteration of tectonically (rift zones) and volcanically (calderas) buried volcanic rocks. These interpretations highlight the major processes by which supereruptive volumes of magma are generated in the SRP, mechanisms applicable to producing rhyolites worldwide that are facilitated by plume driven volcanism and extensional tectonics.

Idaho↗

Voluminous low δ18O magmas in the late Miocene Heise volcanic field, Idaho: Implications for the fate of Yellowstone hotspot calderas

We report oxygen isotope compositions of phenocrysts and U-Pb ages of zircons in four large caldera-forming ignimbrites and post-caldera lavas of the Heise volcanic field, a nested caldera complex in the Snake River Plain, that preceded volcanism in Yellowstone. Early eruption of three normal δ18O voluminous ignimbrites with δ18Oquartz = 6.4‰ and δ18Ozircon = 4.8‰ started at Heise at 6.6 Ma, and was followed by a 2‰–3‰ δ18O depletion in the subsequent 4.45 Ma Kilgore caldera cycle that includes the 1800 km3 Kilgore ignimbrite, and post-Kilgore intracaldera lavas with δ18Oquartz = 4.3‰ and δ18Ozircon = 1.5‰. The Kilgore ignimbrite represents the largest known low-δ18O magma in the Snake River Plain and worldwide. The post-Kilgore low δ18O volcanism likely represents the waning stages of silicic magmatism at Heise, prior to the reinitiation of normal δ18O silicic volcanism 100 km to the northeast at Yellowstone. The occurrence of low δ18O magmas at Heise and Yellowstone hallmarks a mature stage of individual volcanic cycles in each caldera complex. Sudden shifts in δ18O of silicic magmas erupted from the same nested caldera complexes argue against any inheritance of the low δ18O signature from mantle or crustal sources. Instead, δ18O age trends indicate progressive remelting of low δ18O hydrothermally altered intracaldera rocks of previous eruptions. This trend may be generally applicable to older caldera complexes in the Snake River Plain that are poorly exposed.

Geology↗