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Katharine W. Huntington

Publications and source records attributed to Katharine W. Huntington.

3 recordsLinked to original sources

An early Holocene wet period in the southwestern United States

Multiple generations of spring-fed streams traversed ∼800 km 2 of the Las Vegas Valley in southern Nevada between ca. 10.9 ka and 8.5 ka, depositing an extensive tufa network. The scale of this network and diversity of tufa morphologies is novel in North America and offers an opportunity to obtain quantitative paleoclimate data for the region during the early Holocene. We determined isotopic compositions and estimated past temperatures using clumped isotope data from early Holocene tufa on the valley floor (698 m) as well as tufa forming today at higher elevation in the nearby Spring Mountains at Cold Creek Spring (1856 m). Modern and fossil tufa yielded comparably low δ 18 O values, implying that source waters for both were derived from high-elevation winter precipitation. Clumped isotope temperatures of modern tufa average 15.8 ± 2.5 °C, aligning with mean summer temperatures of the emergent spring water, and indicate equilibrium conditions of tufa formation. The early Holocene tufa yielded similar clumped isotope temperatures, averaging 15.2 ± 3.9 °C, meaning it precipitated at temperatures that occur at much higher elevations today. The Las Vegas tufa record, combined with nearby and temporally correlative paleospring and lacustrine records, suggest that cool/wet conditions prevailed throughout the Mojave Desert during the early Holocene. These records also demonstrate that spring ecosystems responded to millennial-scale hydroclimate variations that supersede climate change driven solely by insolation. The previously unrecognized pattern of ecosystem response to hydroclimate documented here may assist in understanding climate drivers for the early Holocene and provide critical information for the fate of groundwater-dependent ecosystems in the southwestern United States.

Nevada↗

Clumped isotopes record a glacial-interglacial shift in seasonality of soil carbonate accumulation in the San Luis Valley, southern Rocky Mountains, USA

Clumped isotope paleothermometry using pedogenic carbonates is a powerful tool for investigating past climate changes. However, location-specific seasonal patterns of precipitation and soil moisture cause systematic biases in the temperatures they record, hampering comparison of data across large areas or differing climate states. To account for biases, more systematic studies of carbonate forming processes are needed. We measured modern soil temperatures within the San Luis Valley of the Rocky Mountains and compared them to paleotemperatures determined using clumped isotopes. For Holocene-age samples, clumped isotope results indicate carbonate accumulated at a range of temperatures with site averages similar to the annual mean. Paleotemperatures for late Pleistocene-age samples (ranging 19–72 ka in age) yielded site averages only 2°C lower, despite evidence that annual temperatures during glacial periods were 5–9°C colder than modern. We use a 1D numerical model of soil physics to support the idea that differences in hydrologic conditions in interglacial versus glacial periods promote differences in the seasonal distribution of soil carbonate accumulation. Model simulations of modern (Holocene) conditions suggest that soil drying under low soil p CO 2 favors year-round carbonate accumulation in this region but peaking during post-monsoon soil drying. During a “glacial” simulation with lowered temperatures and added snowpack, more carbonate accumulation shifted to the summer season. These experiments show that changing hydrologic regimes could change the seasonality of carbonate accumulation, which in this study blunts the use of clumped isotopes to quantify glacial-interglacial temperature changes. This highlights the importance of understanding seasonal biases of climate proxies for accurate paleoenvironmental reconstruction.

Colorado, new Mexico↗

Stable C, O and clumped isotope systematics and 14C geochronology of carbonates from the Quaternary Chewaucan closed-basin lake system, Great Basin, USA: Implications for paleoenvironmental reconstructions using carbonates

Isotopic compositions of lacustrine carbonates are commonly used for dating and paleoenvironmental reconstructions. Here we use carbonate δ13C and δ18O, clumped (Δ47), and 14C compositions to better understand the carbonate isotope system in closed-basin lakes and trace the paleohydrologic and temperature evolution in the Chewaucan closed-basin lake system, northern Great Basin, USA, over the Last Glacial/Holocene transition. We focus on shorezone tufas to establish that they form in isotopic equilibrium with lake water and DIC, they can be dated reliably using 14C, and their clumped isotope composition can be used to reconstruct past lake temperature. Calculations of the DIC budget and reservoir age for the lake indicate residence time is short, and dominated by exchange with atmospheric CO2 at all past lake levels. Modern lake DIC and shorezone tufas yield δ13C and 14C values consistent with isotopic equilibrium with recent fossil fuel and bomb-influenced atmospheric CO2, supporting these calculations. δ13C values of fossil tufas are also consistent with isotopic equilibrium with pre-industrial atmospheric CO2 at all shoreline elevations. This indicates that the 14C reservoir effect for this material is negligible. Clumped isotope (Δ47) results indicate shorezone tufas record mean annual lake temperature. Modern (average 13 ± 2 °C) and 18 ka BP-age tufas (average 6 ± 2 °C) have significantly different temperatures consistent with mean annual temperature lowering of 7 ± 3 °C (1 SE) under full glacial conditions. For shorezone tufas and other lake carbonates, including spring mounds, mollusk shells, and ostracod tests, overall δ13C and δ18O values co-vary according to the relative contribution of spring and lacustrine end member DIC and water compositions in the drainage system, but specific isotope values depend strongly upon sample context and are not well correlated with past lake depth. This contrasts with the interpretation that carbonate isotopes in closed-basin lake systems reflect changes in DIC and water budgets connected to higher or lower lake volumes. Instead, a small overlapping range of isotope compositions characterize multiple lake levels, so that none can be identified uniquely by isotope composition alone. Relative to other lake carbonates, δ13C and δ18O values for ostracods in Ana River Canyon deposits are very strongly influenced by Ana River water, suggesting low lake level and volume characterized Summer Lake for most of the past 100,000 years. Coupled with sedimentologic observations, the Ana River deposits thus suggest dry conditions like today are close to the mean climate state in the northern Great Basin. By contrast, basin-integrating highstands such as that dating to ∼14 ka BP, during the last glacial termination, are hydrologically unique and short-lived. Overall, our results indicate carbonate isotope records must account for the specific geochemical and hydrologic characteristics of lake system in order to provide robust paleoenvironmental reconstructions.

Great Basin↗